Materials Science and Engineering Commons^™

Nano-Engineering Of Composite Material Via Reactive Mechanical Alloying/Milling (Rma/M), Edward Andrew Laitila

Dissertations, Master's Theses and Master's Reports - Open

Attempts to strengthen a chromium-modified titanium trialuminide by a combination of grain size refinement and dispersoid strengthening led to a new means to synthesize such materials. This Reactive Mechanical Alloying/Milling process uses in situ reactions between the metallic powders and elements from a process control agent and/or a gaseous environment to assemble a dispersed small hard particle phase within the matrix by a bottom-up approach. In the current research milled powders of the trialuminide alloy along with titanium carbide were produced. The amount of the carbide can be varied widely with simple processing changes and in this case the milling …

Development Of Practical Applications For Reprap Style 3-D Printers In Engineering, Benjamin T. Wittbrodt

Dissertations, Master's Theses and Master's Reports - Open

The current rise in popularity of consumer level 3-D printers introduces a need to understand the application and material property capabilities of the technology. Presented here is data demonstrating the ability for the average U.S. consumer to recuperate the cost of a 3-D printer within one year of ownership. Additionally, using a consumer level 3-D printer, multiple photovoltaic (PV) racking systems were printed and produced with much lower cost compared to commercially available aluminum racking. Additionally, mechanical testing on 3-D printed components showed a temperature dependence on both percent crystallinity and ultimate tensile strength. Conclusions are drawn using the information …

Nanometric Structure-Property Relationship In Hafnium Oxide Thin Films Made By Sputter-Deposition, Mirella Vargas

Open Access Theses & Dissertations

Hafnium oxide (HfO2) is technologically an important material, which exhibits a unique set of properties such as a high dielectric constant (k~25) and wide band gap (~5.7 eV) which make this material attractive in the fields of microelectronics and optoelectronics. HfO2 has become the leading candidate to replace SiO2 dielectrics in gate oxides due to a higher permittivity and reportedly lower electron tunneling effects. HfO2 exhibits various polymorphs; the thermodynamic stability and phase existence depends on the temperature and pressure conditions. In addition, the controlled growth and manipulation of specific HfO2 crystal structures at the nanoscale dimensions is the driving …

Effects Of Sodium Hydroxide Pretreatment On Structural Components Of Biomass, Alicia A. Modenbach, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

Pretreatment is a unit operation in the conversion of biomass to valuable products that utilizes various combinations of conditions, including chemicals, heat, pressure, and time, to reduce the recalcitrance of lignocellulose. Many such pretreatments have been developed over the years, as the operating conditions can be adapted so that lignocellulose is modified in ways unique to each pretreatment. By tailoring pretreatment conditions to achieve these modifications, the types of final products produced can be controlled. The purpose of this review is to provide a consolidated source of information for sodium hydroxide effects on lignocellulose. The structural characteristics of lignocellulose and …

Repeated Load Relaxation Testing Of Pure Polycrystalline Nickel At Room Temperature Using Nanoindentation, D. E. Stegall, M. A. Mamun, B. Crawford, A, A. Elmustafa

Mechanical & Aerospace Engineering Faculty Publications

We present the results of repeated relaxation tests using nanoindentation to derive the activation volume of the dislocation velocity and the ratios of the dislocation density and dislocation velocity. An experimental technique, based on classical uniaxial relaxation experiments, was developed to establish a constant strain during repeated load relaxation transients and then to calculate the stiffness of unloading, and therefore the hardness, across the transients with acceptable results. We found that the activation volume of the dislocation velocity from our nanoindentation methodology was in good agreement when compared to the same reported for uniaxial experiments. © 2014 AIP Publishing LLC.

Growth, Characterisation, And Properties Of Bi1.8lu1.2fe3.6al1.4o12 Garnet Films Prepared Using Two Different Substrate Temperatures, Mohammad Alam, Mikhail Vasiliev, Kamal Alameh

Research outputs 2014 to 2021

We prepare highly Bismuth substituted iron garnet of composition type Bi_1.8Lu_1.2Fe_3.6Al_1.4O₁₂ by using low and high substrate temperatures (250°C and 680°C) during the deposition process inside the vacuum chamber of RF magnetron sputtering system. The crystallisation process of this garnet type thin film materials are performed by means of optimised high temperature oven annealing process and conduct several characterisation techniques to obtain and evaluate their properties. All the optimally annealed samples possess very promising and attractive properties. Comparatively low coercive force (below 15 Oe) is achieved in garnet films prepared at …

The Effects Of Layer Thickness On Dry-Sliding Wear Of Binder Jet Additively Manufactured Stainless Steel And Bronze Composite, Cody Ingenthron

All Graduate Theses, Dissertations, and Other Capstone Projects

Pin on disk wear testing was used to compare additively manufactured binder jet metal matrix composites. The process parameters were changed. The layer thickness and applied forces were varied for the experimental study. Three different layer thicknesses used were, 50μm, 100μm, and 200μm. The pin used was a 420 stainless pin. The wear characteristics of the disk were examined using pin-on-disc method. The material tested was a composite of 420 stainless steel, and 90-10 bronze. Samples were weighed before, during, and after the test to determine differences in mass. Wear tracks were examined using a Scanning Electron Microscope. The results …

Alkali Promoted Molybdenum (Iv) Sulfide Based Catalysts, Development And Characterization For Alcohol Synthesis From Carbon Monoxide And Hydrogen, Belinda Delilah Molina

Open Access Theses & Dissertations

For more than a century transition metal sulfides (TMS) have been the anchor of hydro-processing fuels and upgrading bitumen and coal in refineries worldwide. As oil supplies dwindle and environmental laws become more stringent, there is a greater need for cleaner alternative fuels and/or synthetic fuels. The depletion of oil reserves and a rapidly increasing energy demand worldwide, together with the interest to reduce dependence on foreign oil makes alcohol production for fuels and chemicals via the Fischer Tropsch synthesis (FTS) very attractive. The original Fischer-Tropsch (FT) reaction is the heart of all gas-to-liquid technologies; it creates higher alcohols and …

Growth And Analysis Of Micro And Nano Cdte Arrays For Solar Cell Applications, Brandon Adrian Aguirre

Open Access Theses & Dissertations

CdTe is an excellent material for infrared detectors and photovoltaic applications. The efficiency of CdTe/CdS solar cells has increased very rapidly in the last 3 years to ~20% but is still below the maximum theoretical value of 30%. Although the short-circuit current density is close to its maximum of 30 mA/cm2, the open circuit voltage has potential to be increased further to over 1 Volt. The main limitation that prevents further increase in the open-circuit voltage and therefore efficiency is the high defect density in the CdTe absorber layer. Reducing the defect density will increase the open-circuit voltage above 1 …

Combustion Synthesis Of Molybdenum Silicides And Borosilicides For Ultrahigh-Temperature Structural Applications, Mohammad Shafiul Alam

Open Access Theses & Dissertations

Molybdenum silicides and borosilicides are promising structural materials for gas-turbine power plants. A major challenge, however, is to simultaneously achieve high oxidation resistance and acceptable mechanical properties at high temperatures. For example, molybdenum disilicide (MoSi₂) has excellent oxidation resistance and poor mechanical properties, while Mo-rich silicides such as Mo₅Si₃ (called T₁) have much better mechanical properties but poor oxidation resistance. One approach is based on the fabrication of MoSi₂−T₁ composites that combine high oxidation resistance of MoSi₂ and good mechanical properties of T₁. Another approach involves the …

Gadolinia Doped Hafnia (Gd2o3- Hfo2) Thermal Barrier Coatings For Gas Turbine Applications, Satya Kiran Gullapalli

Open Access Theses & Dissertations

Thermal efficiency of the gas turbines is influenced by the operating temperature of the hot gas path components. The material used for the hot gas path components can only withstand temperature up to a certain limit. Thermal barrier coatings (TBC) provide the additional thermal protection for these components and help the gas turbine achieve higher firing temperatures. Traditionally available yttria stabilized zirconia (YSZ) TBCs have a limitation up to 1200 C due to their phase transformation. The present work focuses on gadolinia based hafnia (GSH) TBCs to study their potential to replace the YSZ coatings. Different compositions of gadolinia doped …

Design Of Three Different Particle Size Distributions In Silver Paste Through Computer Simulation For Higher Electrical Conductivity, Kyungdeok Jang

Open Access Theses & Dissertations

In the field of printed electronics technology, researchers have tried to print highly conductive electrodes with fine width and height in order to manufacture high performance devices.

The purpose of this research is to print particle monolayer silver patterns which have better electrical conductivity than existing ones. The key idea of this experiment is to analyze silver inks with different sized particles. Let us consider a particle monolayer pattern printed with silver ink consisting of mono-sized particles. Inside of the pattern, there are some vacant spaces between the particles, which can lead to low electrical conductivity and discontinuity of the …

Fabrication Of A Nickel-Based Superalloy In Electron Beam Melting And Process Improvements Using Thermal Feedback From A Multi-Wavelength Pyrometer, Jonathan Minjares

Open Access Theses & Dissertations

The focus of this research was to fabricate parts composed of a nickel-based superalloy containing high levels of aluminum and titanium (NSAT) by using electron beam melting (EBM) additive manufacturing (AM) technology and utilizing thermal feedback from a multi-wavelength pyrometer to perform process improvements leading to near defect-free parts. EBM is an AM technology that utilizes metal powder to fabricate parts in layer-by-layer manner. A multi-wavelength pyrometer was implemented in an Arcam S12 (Arcam AB, Sweden) EBM system to observe and record surface temperatures throughout fabrication. Temperature data from the EBM system and the multi-wavelength pyrometer were graphed using MATLAB …

A Study Of Ti-Doped Wo3 Thin Films Using Comparative Theoretical And Experimental Approach, Aurelio Paez

Open Access Theses & Dissertations

Metal oxides like Tungsten Oxide (WO3) are well documented and characterized in the literature, with uses in darkening windows and mirrors, flat computer displays, solar panel cooling, and sensors (of interest in this study). Ti doping of WO3 is less documented and the focus of this study. Sample thin films of pure WO3 and varyingly Ti doped WO3 were prepared using Radio Frequency magnetron sputtering (RF) (13.56 MHz) to grow thin films on a silicon substrate. This study aims to compare multiple Ti doping percentages in WO3 theoretically and then compare with experimental data taken from thin films of various …

Analysis Of The Influence Of Organic Corrosion Inhibitors On Corrosion Of Reinforcement In Concrete Bridge Structure Under Simulated Field Service Environment, Liang Shi, J. Ye, C. C. Chen, Y. Wu, J. Z. Liu

International Conference on Durability of Concrete Structures

For concrete bridge projects in marine environments, attention must be paid to the reinforcement corrosion problems caused by chloride intrusion. As kinds of functional admixtures, which can reduce the reinforcement corrosion rate, corrosion inhibitors are becoming very popular in China in new bridge projects. Corrosion inhibitors cover both inorganic and organic inhibitors. Nitrite is representative of inorganic corrosion inhibitors, but its carcinogenicity has hindered its further development. Organic corrosion inhibitors such as small-molecule-based alcohol amine series are becoming the focus of attention. To guide the scientific applications of organic corrosion inhibitors, China is carrying out broad applications technology research. But …

Processing And Characterization Of Continuous Basalt Fiber Reinforced Ceramic Matrix Composites Using Polymer Derived Ceramics, Sarah Cox

Electronic Theses and Dissertations

The need for high performance vehicles in the aerospace industry requires materials which can withstand high loads and high temperatures. New developments in launch pads and infrastructure must also be made to handle this intense environment with lightweight, reusable, structural materials. By using more functional materials, better performance can be seen in the launch environment, and launch vehicle designs which have not been previously used can be considered. The development of high temperature structural composite materials has been very limited due to the high cost of the materials and the processing needed. Polymer matrix composites can be used for temperatures …

Non-Oxide Porous Ceramics From Polymer Precursor, Xueping Yang

Electronic Theses and Dissertations

Non-oxide porous ceramics exhibit many unique and superior properties, such as better high-temperature stability, improved chemical inertness/corrosive resistance, as well as wide band-gap semiconducting behavior, which lead to numerous potential applications in catalysis, high temperature electronic and photonic devices, and micro-electromechanical systems. Currently, most mesoporous non-oxide ceramics (e.g. SiC) are formed by two-step templating methods, which are hard to adjust the pore sizes, and require a harmful etching step or a high temperature treatment to remove the templates. In this dissertation, we report a novel technique for synthesizing hierarchically mesoporous non-oxide SiC ceramic from a block copolymer precursor. The copolymer …

Freeze Thaw Durability Of Internally Cured Concrete Made Using Superabsorbent Polymers, Wesley A. Jones, W. Jason Weiss

International Conference on Durability of Concrete Structures

The use of superabsorbent polymers (SAPs) to produce internally cured concrete has been shown to be effective in reducing the potential for restrained shrinkage cracking of high performance concrete mixtures. However, not much is known regarding the freeze–thaw durability of concrete mixtures that incorporate SAPs for internal curing (IC). When SAP particles desorb (or partially desorb) the “water” (pore fluid) they contain for the purposes of IC, some believe that the void space created by these particles can provide enough empty voids to accommodate the additional volume caused by water expansion upon freezing. This paper investigates the freeze–thaw durability of …

Influence Of Organic Inhibitor On Corrosion Resistance Of Steel In Simulated Concrete Pore Solution, Jingshun S. Cai, C. C. Chen, J. Z. Liu, J. P. Liu

International Conference on Durability of Concrete Structures

Organic corrosion inhibitor is one of lower cost technologies that limit the deterioration of concrete structures. The influence of a newly prepared organic corrosion inhibitor on the corrosion behavior of carbon steel in simulated concrete pore solution was investigated by polarization curves, electrochemical impedance spectroscopy, and so on. The effect of organic corrosion inhibitors on concrete working performance was also studied. The results show that the corrosion rate decreases with the concentration of inhibitor increase; when the content of inhibitor up to 1.5% versus water, the oxide film was completely passive. Organic corrosion inhibitor had no effect on work performance.

Co2 Sequestration In Cement-Based Materials During Mixing Process Using Carbonated Water And Gaseous Co2, Jacek Kwasny, P. A. Muhammed Basheer, Mark I. Russell, William Doherty, Kieran Owens, Neil Ward

International Conference on Durability of Concrete Structures

This paper presents selected findings from a recently completed research project, aimed at the investigation of CO₂ sequestration in cement-based materials during the early stages of hydration when the cement paste is being mixed. Portland cement pastes were carbonated during the mixing process, using both carbonated water and gaseous CO₂, and their properties were compared to the control non-carbonated mix. All mixes were prepared in a purpose-designed chamber that permitted carbonated water and gaseous CO₂ to be mixed with the cementbased materials during the mixing process, without losses of CO₂ to the external environment. Temperature …

Atomic Layer Deposition, Paul Kubicza

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Correlation Between The Microstructure And Mechanical Properties Of Irradiated Fe-9cr Ods, M. Swenson, C. Dolph, J. Wharry

Materials Science and Engineering Faculty Publications and Presentations

The growing global demand for energy will increasingly call upon fusion reactors and Generation IV nuclear fission reactors to supply safe and reliable energy worldwide. Ferritic/martensitic (F/M) alloys are leading candidates for structural components in these reactors because of their high strength, dimensional stability, and low activation. In novel reactor concepts, these materials will be subject to extreme operating conditions, accumulating doses of irradiation up to a few hundred displacements per atom (dpa) at temperatures as high as 600°C. Oxide dispersion strengthened (ODS) F/M alloys containing a dispersion of Y-Ti-0 nanoclusters have been developed to operate at even higher temperatures.

Electrospinning Applications Air Filtration And Superhydrophobic Materials, Negar Ghochaghi, Adetoun Taiwo

Graduate Research Posters

Electrospinning is a widely applicable technique that generates non-woven fibers in the micro and nano range. In this project two of its applications are highlighted namely filtration media and enhancement of wettability. The first project demonstrates that electrospinning can be used to produce new fiber filtration media with controlled microstructure. The bimodal and unimodal orthogonal and random filters were made and characterized against their filtration efficiency and pressure drop. Figure of Merit (FOM) was also calculated and discussed. It is shown that the FOM increases when the electrospun fibers are arranged into alternating layers of aligned course and fine fibers. …

Mechanical And Transport Properties Of Alkali-Activated Natural Pozzolans As Sustainable Binders, Brittany Radke

Calvert Undergraduate Research Awards

OPC production accounts for 5 to 7% of the global carbon dioxide (CO₂) emissions, contributing to global warming. The desire to reduce CO₂ emissions and produce more durable concrete has given impetus to search for new binders. It is suggested that alkali-activated natural pozzolans have the potential for use as a sustainable replacement for OPC in concrete.

The current study presented herein evaluated fresh, mechanical, and transport properties of alkali-activated natural pozzolan mortars containing various concentrations of sodium hydroxide solutions as an alkaline activator. To this aim, alkali-activated natural pozzolan mortars were made with concentrations of sodium …

Microwave Absorption Properties Of Tires, Yuzhe Zhang

Dissertations, Master's Theses and Master's Reports - Open

The waste tire is belonging to insoluble high polymer elastic materials. It takes hundreds of years to resolve the macromolecules of waste tire into the standard which does not pollute the environment. More and more waste tires are air stored which causes space occupation and mosquito-breeding in the places that will spread diseases. The disposal methods include landfill, stockpiles, dumping and incising into particles. However, all these methods are not technically and economically efficient. The trend for the development of waste tire treatment processes is low cost, on-site, and high product recovery at high energy efficiency. In this project, microwave …

Mse Annual Report 2014, Department Of Materials Science And Engineering, Michigan Technological University

Department of Materials Science and Engineering Annual Reports

Table of Contents

• Department Legends
• Wonder Material
• Student News
• Faculty and Staff News
• Alumni News
• Endowed Scholarships

Structure And Catalytic Properties Of Ultra-Small Ceria Nanoparticles, Xing Huang

Theses and Dissertations--Chemical and Materials Engineering

Cerium dioxide (ceria) is an excellent catalytic material due to its ability to both facilitate oxidation/reduction reactions as well as store/release oxygen as an oxygen buffer. The traditional approach to assess and improve ceria's catalytic behavior focuses on how efficiently O-vacancies can be generated and/or annihilated within the material, and how to extend established understandings of "bulk" ceria to further explain the greatly enhanced catalytic behavior of ultra-small ceria nanoparticles (uCNPs) with sizes less than 10 nm. Here, using density functional theory (DFT) calculations, we reexamine the atomic and electronic structures of uCNPs, especially their surface configurations. A unique picture …

Influence Of Ferrite Phase In Alite-Calcium Sulfoaluminate Cements, Tristana Y. Duvallet

Theses and Dissertations--Chemical and Materials Engineering

Since the energy crisis in 1970’s, research on low energy cements with low CO₂-emissions has been increasing. Numerous solutions have been investigated, and the goal of this original research is to create a viable hybrid cement with the components of both Ordinary Portland cement (OPC) and calcium sulfoaluminate cement (CSAC), by forming a material that contains both alite and calcium sulfoaluminate clinker phases. Furthermore, this research focuses on keeping the cost of this material reasonable by reducing aluminum requirements through its substitution with iron. The aim of this work would produce a cement that can use large amounts …

The Development And Biocompatibility Of Low Temperature Co-Fired Ceramic (Ltcc) For Microfluidic And Biosensor Applications, Jin Luo

Theses and Dissertations--Chemical and Materials Engineering

Low temperature co-fired ceramic (LTCC) electronic packaging materials are applied for their electrical and mechanical properties, high reliability, chemical stability and ease of fabrication. Three dimensional features can also be prepared allowing integration of microfluidic channels and cavities inside LTCC modules. Mechanical, optical, electrical, microfluidic functions have been realized in single LTCC modules. For these reasons LTCC is attractive for biomedical microfluidics and Lab-on-a-Chip systems. However, commercial LTCC systems, optimized for microelectrics applications, have unknown cytocompatibility, and are not compatible with common surface functionalization chemistries.

The first goal of this work is to develop biocompatible LTCC materials for biomedical applications. …

Nanometer-Scale Membrane Electrode Systems For Active Protein Separation, Enzyme Immobilization And Cellular Electroporation, Zhiqiang Chen

Theses and Dissertations--Chemical and Materials Engineering

Automated and continuous processes are the future trends in downstream protein purification. A functionalized nanometer-scale membrane electrode system, mimicking the function of cell wall transporters, can selectively capture genetically modified proteins and subsequently pump them through the system under programmed voltage pulses. Numerical study of the two-step pulse pumping cycles coupled with experimental His-GFP releasing study reveals the optimal 14s/1s pumping/repel pulse pumping condition at 10 mM bulk imidazole concentration in the permeate side. A separation factor for GFP: BSA of 9.7 was achieved with observed GFP electrophoretic mobility of 3.1×10^-6 cm² s^-1 V^-1 at 10 …