Materials Science and Engineering Commons^™

Investigation Of Electrochemical Noise In The Crevice Corrosion Of Q235 Carbon Cteel, Qian Hu, Yu-Bing Qiu, Xing-Peng Guo

Journal of Electrochemistry

The crevice corrosion behavior of Q235 carbon steels in a NaHCO₃+NaCl solution was investigated by electrochemical noise(EN) and electrochemical impedance spectroscopy(EIS).Three stages of crevice corrosion including the induction,the rapid transform and the stable development could be clearly distinguished.The characteristics of the electrochemical noise and the noise resistance Rn showed remarkable differences at each stage.The electrode area ratio(r) of outside to inside the crevice had a significant influence in the development of crevice corrosion.The time of the induction stage increased with increasing r.However,under the stable development stage of the crevice corrosion,the surface outside the crevice was at an active …

Effect Of Naphthalene Water Reducer On Corrosion Behavior Of Reinforcing Steel In Concrete, Yu-Ming Tang, Jie Zhang, Yu Zuo

Journal of Electrochemistry

The influence of naphthalene water reducer on corrosion behavior of reinforcing steel in concrete was studied by the methods of corrosion potential measurement,linear polarization and EIS test.The values of concrete resistance(Rc) and polarization resistance(Rp) of the samples with naphthalene water reducer were higher than those without naphthalene water reducer,especially in the concrete with 0.2 percent naphthalene water reducer.A suitable amount of water reducer can improve the pore structures of concrete,increase the concrete compactness and impermeability,and decrease corrosion rate of rebars in concrete.

Effect Of Electrochemical Property Of Uns J91450 Stainless Steel On Stress Corrosion Cracking In Hydrogen Sulfide Solutions, Zhi-Yong Liu, Chao-Fang Dong, Xiao-Gang Li, Li-Xian Wang

Journal of Electrochemistry

Effect of electrochemical behaviours on stress corrosion cracking(SCC) of UNS J91450 stainless steel in hydrogen sulfide environment was investigated using slow-strain-rate test(SSRT) and electchemial techniques.Results show that UNS J91540 stainless steel was susceptible to SCC in varying H₂S solutions,and the SCC susceptibility reduced with the increase of pH value.The electrochemical property plays an important role in the SCC occurrence,as a combined effect of hydrogen embritlement and anodic dissolution at SCC cracktip at open circuit potential.In the solution with a lower pH the hydrogen revolution was intensive and the cracktip anodic dissolution was weaker,however,in the higher pH solution the …

Developments Of Scanning Electrochemical Probes And Their Applications In Studying Of Localized Corrosions, Chang-Jian Lin, Yan Li, Bin Lin, Rong-Gang Hu, Min Zhang, Xiang-Dong Zhuo, Rong-Gui Du

Journal of Electrochemistry

The electrochemical inhomogeneities always exist at the interface of metal/solution,and play an important and often controlling role in localized corrosion of metals in a given environment.It is necessary to develop in situ imaging techniques for further studying the electrochemical and environmental inhomogeneities at the interface of metal/solution for the localized corrosion system.In this paper,various techniques with spatial resolution,such as scanning micro reference electrode(SMET),scanning electrochemical microscope(SECM),atomic force microscope(AFM),and scanning Kelvin probe(SKP),and their applications in corrosion studies were briefly reviewed.The chemical probes and array electrode have been developed.It was concentrated to describe our newly developed techniques of the scanning electrochemical probes,including SMET …

Preparation And Electrochemical Properties Of Layered Manganese Oxide(Li-Birnessite Type), Xing-Kang Huang, Hai-Tao Chang, Jian-Long Gan, Qing-Shun Zhang, Hong-Jun Yue, Dong-Ping Lv, Yong Yang

Journal of Electrochemistry

Layered Li-birnessite was prepared by means of oxidizing Mn²⁺ with O₂ gas in alkaline media.The as-prepared sample was characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD), BET and thermogravimetric/diffenential thermal analysis(TG/DTA) techniques. The electrochemical properties of the material were also investigated. The results show that such a Li-birnessite consists of well-crystallized spherical particles with an interlayer distance of 0.70 nm. The Li-birnessite delivered a high discharge capacity of 203 mAh/g at a rate of 0.2 C(40 mA/g), and had good rate capability as well.

Electrochemical Behavior Of Mg-Li Electrodes In Nacl Solution, Lin Wu, Yan-Zhuo Lv, Xue Cao, Gui-Ling Wang, Dian-Xue Cao

Journal of Electrochemistry

The Mg-Li electrodes containing 8.5% and 14% Li were prepared using an induction melting method. Their electrochemical behavior in NaCl solution was investigated by means of potentiodynamic polarization, potentiostatic oxidation,electrochemical impedance technique and mass-loss measurements. The morphology of the electrodes after discharge was examined using scanning electron microscopy. The Mg-14Li electrode showed more negative open circuit potential and higher discharge current density than Mg-8.5Li electrode. The oxidation products of Mg-14Li loosely attached on the electrode surface and peeled off easily. The Mg-8.5Li exhibited higher utilization efficiency. Both electrodes gave higher utilization efficiencies when discharged at lower anodic potential.

Electrochemical Performance Of The Exfoliated Graphite Containing Sulfur Cathode Material For Lithium Sulfur Battery, Ke-Guo Yuan, Wei-Kun Wang, Zhong-Bao Yu, An-Bang Wang

Journal of Electrochemistry

The exfoliated graphite containing sulfur cathode material was prepared by the high temperature sulfur gas diffusion adsorption method.This cathode material could obtain an initial discharge specific capacity 972 mAh·g^-1,capacity retention ratio 78% and cycling efficiency above 80%,respectively.The exfoliated graphite containing sulfur cathode could decrease the reaction interphase charge transfer impedance,and restrain the sulfur or polysulfide shuttle phenomenon during the charge-discharge process through improving the diffusion impedance.

Effects Of Kscn On Kinetic Characters Of The Positive Couple And Performance For Vanadium Redox Flow Battery, Jian-Guo Liu, Dong Shi, Yue Men, Chuan-Wei Yan

Journal of Electrochemistry

In order to improve the reaction activity of VO²⁺/VO²⁺ and the battery performance of Vanadium redox flow battery,different concentration of potassium sulfocyanates KSCN were added into 0.1mol/L VOSO₄/ H₂SO₄ solution,and the kinetic characters of electrochemical reaction of VO²⁺/VO²⁺ was studied by CV and EIS.The results showed that the addition of KSCN could improve the oxidative peak current value of positive couple VO²⁺/VO²⁺ reaction,but had little influence in the reductive peak.The addition of KSCN decreased the impedance at 1.0 V.And the value of standard rate constant k0 …

Effect Of Impurity Cu(2+) On Oxygen Electrode In Pemfc, Xiao Jie, Jun-Bo Hou, Zhi-Gang Shao, Bao-Lian Yi

Journal of Electrochemistry

Rotating disk electrode was adopted in this paper to simulate the cathode in PEMFC.In the Cu²⁺ electrolyte,the influence of impurity Cu²⁺ on Carbon-Supported Pt Catalysts was investigated by using electrochemical measurements such as chronocoulometry,cyclic voltammetry and linear sweep.Experimental results showed that,after constant voltage at 0.49 V,the ECA of Pt/C decreased dramatically,it's perhaps under potential deposition of Cu might occur on the substrate.Meanwhile the change of ORR Tafel scope reaction is very large.It might be because oxygen adsorption sites are occupied by Cu atoms after they under potential deposit on surface of Pt/C catalyst,and the adsorption of oxygen on …

Electro-Oxidation Of Methanol On Fe-Doped Pt-Zro2/C Catalyst, Mao-Cai Lin, Dong-Dong Liu, Qing-Chun Yu, Ming-Ruo Hu, Heng-Yong Tu

Journal of Electrochemistry

The Fe-doped ZrO₂ powders were prepared by so-gel method.After that,Pt-Zr_1-xFe_xO₂/C catalysts were made by reducing platinum salts with ethylene glycol.The physical property of the catalyst was characterized by XRD and TEM.It was found that the distribution of the catalyst was narrow,the particle sizes of Pt and ZrO₂ particles were 2~4 nm and 3~7 nm,respectively.The Cyclic Voltammetry and Chronoamperometry testing indicated that the electro-catalytic activity for methanol electro-oxidation on Pt-ZrO₂/C catalyst increased when ZrO₂ was doped with Fe.And Pt-Zr_0.95Fe_0.05O₂/C catalyst showed the highest activity …

The Effective Slip Length And Vortex Formation In Laminar Flow Over A Rough Surface, Anoosheh Niavarani, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

The flow of viscous incompressible fluid over a periodically corrugated surface is investigated numerically by solving the Navier–Stokes equation with the local slip and no-slip boundary conditions. We consider the effective slip length which is defined with respect to the level of the mean height of the surface roughness. With increasing corrugation amplitude the effective no-slip boundary plane is shifted toward the bulk of the fluid, which implies a negative effective slip length. The analysis of the wall shear stress indicates that a flow circulation is developed in the grooves of the rough surface provided that the local boundary condition …

Droplet Assisted Self-Assembly Of Semiconductor Nanostructures, Kimberly Annosha Sablon

Graduate Theses and Dissertations

There is increasing interest in quantum dot (QD) structures for a plethora of applications, including optoelectronic devices, quantum computing and energy harvesting. While strain driven surface diffusion via stranski-krastanow (SK) method has been commonly used to fabricate these structures, a more recent technique, droplet epitaxy (DE) does not require mismatch strain and is therefore much more flexible in the combination of materials utilized for the formation of QDs.

As reported in this work, a hybrid approach that combines DE and SK techniques for realizing lateral ordering of QDs was explored. First, the droplet formation of various materials was discussed and …

Design And Fabrication Of A Small Prototype Airframe Structure, Kimberly Lynn Clark

UNLV Theses, Dissertations, Professional Papers, and Capstones

This project called for a first-generation prototype aircraft with hovering capabilities that was lightweight. The focus of this study was to design a small low-cost prototype composite airframe that meets specified requirements, analyze structures using finite element analysis and mechanical testing, and construct a prototype using proven composite manufacturing techniques. One fuselage, one wing, and several engine nacelles were designed and fabricated. Several design and fabrication methods and materials were analyzed, with focus given to the nacelles, and recommendations were provided for the manufacture of the first generation airframe based on time, weight, and cost.

Modulated Nanopores Using Pulse Anodization On Thin Aluminum, Mahesh Babu Gunukula

UNLV Theses, Dissertations, Professional Papers, and Capstones

Nanoporous anodic aluminum oxide has traditionally been made in one of two ways: "Mild Anodization (MA)" or "Hard Anodization (HA)". The former method produces self-ordered pore structures but it is slow and only works for a narrow range of processing conditions; the latter method, which is widely used in the aluminum industry, is faster but it produces films with disordered pore structures. Here we report a novel approach termed "pulse anodization" that combines the advantages of the MA and HA processes. By designing the pulse sequences it is possible to control both the composition and pore structure of the anodic …

Freeze-Spray Deposition Of Layered Alumina/Zirconia Composites, Qiang Fu, Oratai Jongprateep, Ashlee Abbott, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Freeze-spray deposition (FSD) method is described for rapid fabrication of layered composites with controlled layer thickness and uniform microstructure. The graded alumina/zirconia composites are fabricated by FSD of ceramic slurries followed by freeze drying. Aqueous slurries with glycerol addition are sprayed on a cooled substrate using an automated 3D gantry system. Processing parameters such as viscosity of the ceramic slurries, composition and thickness of deposited layers as well as sintering conditions are investigated to optimize the fabrication process. Microstructural analysis of the fabricated composites revealed uniform and crack-free transitional layers indicating a strong interfacial bonding between the layers.

Gossamer Albatross, Steve Elliott

ERAU Prescott Aviation History Program

Steve Elliott was active in the hobby of hang gliding, and was invited to join the Gossamer Albatross team in 1979. He assisted in its development and testing, and was there in a Zodiac raft when it became the first human powered aircraft to cross the English Channel and win the £100,000 Kremer Prize.

Computational Study Of Pristine And Titanium-Doped Sodium Alanates For Hydrogen Storage Applications, Gopi Krishna Phani Dathar

Doctoral Dissertations

The emphasis of this research is to study and elucidate the underlying mechanisms of reversible hydrogen storage in pristine and Ti-doped sodium aluminum hydrides using molecular modeling techniques. An early breakthrough in using complex metal hydrides as hydrogen storage materials is from the research on sodium alanates by Bogdanovic et al., in 1997 reporting reversible hydrogen storage is possible at moderate temperatures and pressures in transition metal doped sodium alanates. Anton reported titanium salts as the best catalysts compared to all other transition metal salts from his further research on transition metal doped sodium alanates. However, a few questions remained …

Characterizing Twin Structure And Magnetic Domain Structure Of Ni-Mn-Ga Through Atomic Force, Matthew Reinhold

McNair Scholars Research Journal

Ni-Mn-Ga is a ferromagnetic shape memory alloy that deforms by twin boundary motion. The magneto-mechanical properties depend strongly on the twin microstructure. A thermomechanical treatment was applied to a Ni-Mn-Ga single crystal with coexisting 10M and 14M martensite structures to create twin boundaries and align the short crystallographic c direction preferentially perpendicular to the surface. The resulting twin structure was characterized using atomic force microscopy (AFM) to obtain the surface relief caused by twinning. Magnetic force microscopy (MFM) was used to find the direction of easy magnetization (which coincides with the crystallographic c direction) of each twin. Among 18 possible …

Shielding Effectiveness Of Superalloy, Aluminum, And Mumetal Shielding Tapes, Cindy Suit Cheung

Master's Theses

Using MIL-HDBK-419A, MATLAB and Nomographs, Shielding Effectiveness for the Magnetic Field, Electric Field, and Plane Wave were calculated over a frequency range from 10 Hz to 1 GHz. The three shielding tapes used included superalloy, aluminum, and mumetal. Calculations for Shielding Effectiveness involve the computation of Absorption Loss, Reflection Loss, and Re-Reflection Correction Factor. From the outcome of the calculations, it was suitable to conclude that all three metals fulfill the 40 dB Shielding Effectiveness requirements for SGEMP fields for frequencies greater or equal to 1 MHz. Accordingly, all three shielding tapes provide at least 40 dB of shielding to …

Neutron Structural Studies On The Superconducting (Nd₁₋ₓcax)(Ba₁.₆La₀.₄)Cu₃Oz System, Amish G. Joshi, R. G. Kulkarni, William B. Yelon, Ram Prasad, M. R. Gonal

Physics Faculty Research & Creative Works

We have investigated the influence of Ca ion substitution on the structural and superconducting properties of (Nd1−xCax)(Ba1.6La0.4)Cu3Oz system. Magnetization, x-ray diffraction, and neutron diffraction studies have been carried out on a series of compounds with x=0.0-0.6. The superconducting transition temperature Tc, determined from magnetization measurements, increases with increasing Ca2+ substitution. Neutron diffraction studies reveal that these compounds crystallize in a tetragonal structure (space group P4/mmm). A detailed analysis of the neutron diffraction data reveals that Ca and La ions are intermixed at the nominal Ba and Nd sites. While a major fraction of Ca ions occupy the usual Nd site, …

Improved Predictive Power Control Of Cdma System In Rayleigh Fading Channel, Adit Kurniawan, Iskandar Iskandar, Sayid Machdar

Makara Journal of Technology

In this paper an improved prediction-based power control is proposed for code division multiple access (CDMA) systems in Rayleigh fading channel environments. One of the most serious problems which degrades the performance of power control algorithm is the effect of feedback delay. To overcome the effect of feedback delay, power control needs to employ prediction algorithm which utilises the correlation property of the past channel samples measurements to predict the future sample values. In CDMA power control, however, the correlation property of channel measurements is destroyed because the transmit power is continuously updated for each power control interval. The prediction …

On The Performance Of Svd-Dwt Based Digital Video Watermarking Technique With Semi-Blind Detector, Tarzan Basaruddin, Della Maulidiya

Makara Journal of Technology

On the Performance of SVD-DWT Based Digital Video Watermarking Technique with Semi-Blind Detector. This paper presents a watermarking technique for digital video. The proposed scheme is developed based on the work of Ganic and Chan which took the virtue of SVD and DWT. While the previous works of Chan has the blind detector property, our attempt is to develop a scheme with semi-blind detector, by using the merit of the DWT-SDV technique proposed by Ganic which was originally applied to still image. Overall, our experimental results show that our proposed scheme has a very good imperceptibility and is reasonably robust …

Lipid Production From Microalgae As A Promising Candidate For Biodiesel Production, Arief Widjaja

Makara Journal of Technology

Recently, several strains of microalgae have been studied as they contain high lipid content capable to be converted to biodiesel. Fresh water microalgae Chlorella vulgaris studied in this research was one of the proof as it contained high triacyl glyceride which made it a potential candidate for biodiesel production. Factors responsible for good growing of microalgae such as CO2 and nitrogen concentration were investigated. It was found that total lipid content was increased after exposing to media with not enough nitrogen concentration. However, under this nitrogen depletion media, the growth rate was very slow leading to lower lipid productivity. The …

Gravity Effects On Capillary Flows In Sharp Corners, Enrique Ramé, Mark M. Weislogel

Mechanical and Materials Engineering Faculty Publications and Presentations

We analyze the effect of gravity on capillary flows in sharp corners. We consider gravity perpendicular and parallel to the channel axis. We analyze both steady and unsteady flows. In the steady analysis the main result is a closed form expression for the flow rate as a function of the two gravity components. Good agreement with steady experiments is offered as support of the model. The unsteady analysis is restricted to “small” values of the two gravity parameters and is accomplished using a similarity formulation. The similarity coefficients of the gravity corrections are fully determined by the coefficients of the …

Environmental Remediation Full-Scale Implementation: Back To Simple Microbial Massive Culture Approaches, Agung Dhamar Syakti, Mohamad Yani

Makara Journal of Technology

Using bioaugmentation and biostimulation approach for contaminated soil bioremediation were investigated and implemented on field scale. We combine those approaches by culturing massively the petrophilic indigenous microorganisms from chronically contaminated soil enriched by mixed manure. Through these methods, bioremediation performance revealed promising results in removing the petroleum hydrocarbons comparatively using metabolite by product such as biosurfactant, specific enzymes and other extra-cellular product which are considered as a difficult task and will impact on cost increase.

Preparation Of Radioactive Gold Nanoparticle By Neutron Activation, Rohadi Awaludin

Makara Journal of Technology

Preparation of Radioactive Gold Nanoparticle by Neutron Activation. It was reported that gold nanoparticle could be used for cancer therapy using thermal effect. It is possible to kill cancer cells using radiation of radioisotope. Study on preparation of radioactive gold by neutron activation at central irradiation position (CIP) of G.A. Siwabessy reactor with neutron flux 1.26 x 1014 neutron s-1cm-2 has been carried out. It was revealed that a radioisotop of gold (198Au) was produced by neutron activation from natural gold. Calculation results showed that 198Au with radioactivity of 0.366 Bq, 2.93 Bq, 9.90 Bq and 23.4 Bq was produced …

Implementation Of Web Cam As Motion Detector With Directshow Interfacing, Yonatan Santoso, Iwan Setiyawan, Victor N. Papilaya

Makara Journal of Technology

Implementation of Web Cam as Motion Detector with DirectShow Interfacing. One of many ways to take control a web cam is by using DirectShow which is integrated in DirectX. DirectShow acts like an API therefore it is easier to use. Afterwards, web cam will be implemented to detect object’s motion as well as camera surveillance. The method is by comparing a reference image with other image which is taken lately. If there are differences between those image it means motion has been detected.

Thermal Stability Of Clay's Galleries In Polypropylene - Clay (Montmorillonite) Nanocomposites Using Polypropylene-Gmaleic Anhydride As Compatibilizer, Sotya Astutiningsih, Pandu Lanang Kinasih, Arief Cahyo Wibowo

Makara Journal of Technology

Thermal Stability of Clay's Galleries in Polypropylene - Clay (montmorillonite) Nanocomposites using Polypropylene-g- Maleic Anhydride as Compatibilizer. Superior properties of food packaging can be achieved using nanocomposite technology. However, fabrication of this materials are complex and expensive. Long term objectives of this research is the synthesis of low cost polypropylene clay nanocomposites (PPCN) via a short-cut method known as ‘cascade engineering’. Cascade engineering principle in PPCN fabrication is performed by using compatibilizer (to enable the mixing of PP and clay) masterbatch, and PPCN in one pot process using melt mixer. This paper present the experimental results using small-angle x-ray diffraction …

Induction And Conduction Electromagnetic Waves Caused By Lightning Strike On The Low Voltage Network, Reynaldo Zoro

Makara Journal of Technology

Induction and Conduction Electromagnetic Waves Caused by Lightning Strike on the Low Voltage Network. Direct and indirect lightning strikes can disturb and induce low voltage overheadlines and it can produced overvoltage due to traveling waves along the lines. This overvoltage can damage the equipments connected to it. It was recorded that there were already a lot of damages of electronic equipments and arrestesr located inside the building of Lightning Measurement Station at Mnt. Tangkuban Perahu. Most of the overvoltage which was developed on the low voltage lines were coming from indirect lightning strike nearby due to the fact that most …

Muara Bekasi – Muara Tawar Offshore Transmission Pipeline Routing And Economic Analysis., Asep Handaya Saputra, Ardiansyah Ardiansyah

Makara Journal of Technology

Muara Bekasi – Muara Tawar Offshore Transmission Pipeline Routing and Economic Analysis. Power plant Muara Tawar will substitute the need of oil fuel to gas as form of economizing and energy conservation. The nearest supply point to fulfill natural gas needed on Muara Bekasi. So that Power Plant Company needed to develop gas pipeline infrastructure to joining the point.The purpose of this study is to create a system of gas transmission pipeline from gas supply point at Muara Bekasi to Power Plant Muara Tawar trough to offshore area. Design of gas transmission pipeline is started with technical data collection and …