Materials Science and Engineering Commons^™

Selection Of Additions In The Process Of Electrochemical Synthesizing Of K2Feo4, Wei-Hua Yang, Dong-Qin Bi, Yan Zhou, Hong-Hui Wang, Xin-Ren Lan

Journal of Electrochemistry

Some of different additions including KIO₄ was added to the anodic electrolyte for electrochemical synthesizing of K₂FeO₄,the effects of these additions on current yield were investigated.XRD and SEM were used to characterize the structure and image of K₂FeO₄.The results show that KIO₄ is a preferable addition.When the mass dosage of KIO₄ is 0.02%,electrolysis time is 1 h,the current yield is enhanced by 31.6% and the corresponding purity of the product is improved by 3.85 %.

Electrochemical Behavior Of Zinc Alloy Anode In Ca(Oh)2 Solutions Of Different Ph, Peng-Ying Ren, Ji-Quan He

Journal of Electrochemistry

The polarization curves of zinc alloy anodes in Ca(OH)₂ solutions have been measured by potentiodynamic method,and the composition of corrosion products were examined by X-ray-diffraction(XRD).The experimental results indicated that not only the electrochemical behavior of zinc alloy anodes were absolutely different in every alkaline solutions,but also many electrochemical parameters were determined,such as zero current potential(E0),the density of corrosion current(icorr),passive current density(ip),breakdown potential(Eb),and so on.There were three zero current potential when zinc alloy anodes in some Ca(OH)₂ solutions which made passive state unstable.The graphs of E-pH about zinc alloy anodes dipped in different Ca(OH)₂ solutions were drawn,and compared …

Study On Electrochemical Impedance Spectroscopy Of Carbon Steel Eroded In Methyldiethanolamine Solution, Dong-Ping Wei, Rong-Zong Hu, Dan-Mei Pan, Wei-Xiong Huang, Rui Dong

Journal of Electrochemistry

Corrosion behavior of carbon steel in methyldiethanolamine(MDEA) solution was investigated by Electrochemical Impedance Spectroscopy(EIS).The results were showed that the corrosion rate of carbon steel in solution containing dissolved oxygen is higher than that in solution removed of dissolved oxygen before cathodic activation.They were reversed after cathodic activation.The corrosion rate is increased at first and then decreased when the concentration of MDEA is increased in the blank solutions.In the simulated solutions containing quantities of!heat-stable salts(HSS),the corrosion rate is decreased monotonously with increase of the MDEA concentration.As anodic polarization potential is increased,the EIS of carbon steel in HSS simulated solution showed characteristics …

Research Of 2,2′-Dipyridine On Electroless Copper Plating Using Sodium Hypophosphite As Reductant, Bin Yang, Fang-Zu Yang, Ling Huang, Shu-Kai Xu, Guang-Hua Yao, Shao-Min Zhou

Journal of Electrochemistry

In the bath of the electroless copper plating using sodium hypophosphite as reductant, the effects of 2,2′-dipyridine on the deposition rate, anodic oxidation of sodium hypophosphite, cathodic reduction of copper ions, surface morphologies, structure and the existing status of the deposit components were examined. The results showed that, 2,2′-dipyridine hindered the electroless deposition.Experiments of liner sweep voltammetry (LSV) indicated that,as the addition of 2,2′-dipyridine to the electrolyte, the oxidation peak potential of sodium hypophosphite shifted to a more negative value but the peak current decreased; the reducing peak potential of copper ions moved to a more negative value whereas the …

Converting Traditional Materials Labs To Project-Based Learning Experiences: Aiding Students' Development Of Higher-Order Cognitive Skills, Linda Vanasupa, Katherine C. Chen, Jonathan Stolk, Richard N. Savage, Trevor S. Harding, Blair London, William L. Hughes

Materials Engineering

Against a backdrop of compelling societal needs, graduates in science and engineering now must master their disciplines and demonstrate a sophisticated level of cognitive, affective and social development. This has lead a number of national and international commissions on science and engineering to urge educators to re-think the way in which STEM disciplines are taught. We have chosen to "repackage" a traditional undergraduate materials engineering curriculum in a form designed to promote the development of higher-order cognitive skills like self-directed learning and design. Classic metallurgy experiments have been converted to project-based learning experiences where students are put in the role …

Ultrasonic Seaming Of Pet, Pet/Cotton Blend, And Spectra Fabrics, Renuka Kadiri Reddy

Master's Theses and Doctoral Dissertations

Ultrasonic seaming offers many advantages as an alternative for joining fabrics, such as efficiency, reduced cost, conservation of energy, and recyclability of the product.

The objective of this study was to investigate the effect of ultrasonic weld parameters – weld pressure, weld time, amplitude of vibration, seam design, and material properties – on seam efficiency and stiffness of a seam. This study also compares seam efficiency and stiffness of (a) ultrasonic seam to that of sewn seam and (b) ultrasonic seam from continuous mode of operation to that of plunge mode. Regression and analytical tests were used to analyze the …

Trajectory Shaping Of Surface-To-Surface Missile With Terminal Impact Angle Constraint, S. Subchan

Makara Journal of Technology

This paper presents trajectory shaping of a surface-to-surface missile attacking a fixed with terminal impact angle constraint. The missile must hit the target from above, subject to the missile dynamics and path constraints. The problem is reinterpreted using optimal control theory resulting in the formulation of minimum integrated altitude. The formulation entails nonlinear, two-dimensional missile flight dynamics, boundary conditions and path constraints. The generic shape of optimal trajectory is: level flight, climbing, diving; this combination of the three flight phases is called the bunt manoeuvre. The numerical solution of optimal control problem is solved by a direct collocation method. The …

Limiting Maximum Drag Reduction Asymptote For The Moment Coefficient Of An Enclosed Rotating Disk With Fine Spiral Grooves, Budiarso Budiarso, Keizo Watanabe, Satoshi Ogata

Makara Journal of Technology

In this study, the limiting maximum drag reduction asymptote for the moment coefficient of an enclosed rotating disk with fine spiral grooves in turbulent flow region were obtained analytically. Analysis which were based on an assumption for a simple parabolic velocity distribution of turbulent pipe flow to represent relative tangential velocity, was carried out using momentum integral equations of the boundary layer. For a certain K- parameter the moment coefficient results agree well with experimental results for maximum drag reduction in an enclosed rotating disk with fine spiral grooves and drag reduction ratio approximately was 15 %. Additionally, the experimental …

Co2 Absorption From Its Mixture With Ch4 Or N2 Through Hollow Fiber Membrane Contactor Using Water As Solvent, Sutrasno Kartohardjono, Anggara Anggara, Subihi Subihi, Yuliusman Yuliusman

Makara Journal of Technology

CO2 Absorption from Its Mixture with CH4 or N2 through Hollow Fiber Membrane Contactor using Water as Solvent. Hollow fiber membrane contactors have been widely used as gas-liquid contactors recently such as in the CO2 absorption process from gas stream. This research aims to evaluate the effectiveness of hollow fiber membrane contactor to absorb CO2 from its mixture with CH4 or N2 using water through mass transfer and hydrodynamic tests. There are 3 membrane modules used in this research with shell diameter of 1.9 cm, length of 40 cm, outer fiber diameter of 2.7 mm and fiber number in the …

Reverse Link Cdma System Capacity Evaluation For Stratospheric Platform Mobile Communications, Iskandar Iskandar

Makara Journal of Technology

We propose an analysis of reverse link CDMA multispot beam stratospheric platforms (SPF) in this paper. The SPF is currently proposed as a novel wireless technology for the development of the next generation fixed and mobile communications. The geometry of this technology is different from that of the terrestrial but rather similar to the satellite based cellular system. However, evaluation on the CDMA system capacity of this technology has not been much reported. This paper addresses all possible multiple access interference analyses including the effects of channel fading and shadowing in order to evaluate the system capacity. Single SPF and …

The Potency Of Fire And Explosion Hazard On Premium Oil Storage Tank At Depot X 2007, Fatma Lestari, Warid Nurdiansyah

Makara Journal of Technology

The Potency of Fire and Explosion Hazard on Premium Oil Storage Tank at Depot X 2007. Premium oil storage tanks have fire and explosion risk because Premium oil is flammable liquid. Because of that, fire and explosion risk assessment on Premium oil storage tank at Depot X is needed as foundation to fire and explosion risk management, and comply with regulations. Method of this research is Dow’s Fire and Explosion Index. This research indicate that F&EI value for Premium oil storage tank is 118,82. Based on that F&EI value, level of risk at Premium oil storage tank is intermediate risk.

Analysis Of Three Phase Controlled Rectifier With The Same Distance Control As Compared To The Same Angle Control, Sudirman S., Sri Kurniati A.

Makara Journal of Technology

Analysis of three phase controlled rectifier with the same distance control as compared to the same angle control. This research aim to compare the firing of the same distance and the same angle control at three phase controlled rectifier with seen generated harmonic at input (AC side). Then calculate of rectifier efficiency and power factor comparison from both the control type. The rectifier use passive filter with resistance 11 ohm and is analysed with program simulation using PSPICE version 7.1. Result of research indicate that use of the same distance control generates the 5th and 7th harmonics, while the same …

The Use Of Red Cabbage’S Anthocyanine Extract As A Photosensitizer On A Dye-Sensitized Nanocrystalline Tio2 Solar Cell, Akhiruddin Maddu, Mahfuddin Zuhri, Irmansyah Irmansyah

Makara Journal of Technology

The use of Red Cabbage’s anthocyanine extract as a photosensitizer on a Dye-Sensitized Nanocrystalline TiO2 Solar Cell. A solid-state dye-sensitized nanocrystalline TiO2 solar cell utilizing anthocyanin extract form red cabbage as photosensitizer was fabricated. The solar cell was formed in sandwich structure, which two electrodes sandwiching polymer electrolyte containing a redox couple (I-/I3 -). One of the electrodes, namely working electrode, TiO2 layer on TCO (transparent conducting oxide) coated glass substrate was sensitized with anthocyanin dye as electron donor in the system. Another electrode was a carbon sheet as a counter electrode. Gel electrolyte based on PEG (polyethylene glycol) containing …

Effect Of Contact Time On Interface Reaction Between Aluminum Silicon (7% And 11%) Alloy And Steel Dies Skd 61, Bambang Suharno, Neni Octapiani Nurhayati, Bustanul Arifin, Sri Harjanto

Makara Journal of Technology

Effect of Contact Time on Interface Reaction between Aluminum Silicon (7% and 11%) Alloy and Steel Dies SKD 61. Die soldering (die sticking) is a defect of metal casting in which molten metal “welds” to the metallic die mold surface during casting process. Die soldering is the result of an interface reaction between the molten aluminum and the die material. Aluminum alloy with 7 and 11% silicon and SKD 61 die steel are the most common melt and die material used in aluminum die casting. This research is done to study the morphology and the characteristics of the formed AlxFeySiz …

High Temperature Heat Exchanger Project: Quarterly Progress Report July 1, 2007 Through September 30, 2007, Anthony Hechanova

Publications (NSTD)

• Ceramatec Sulfuric Acid Decomposer. The numerical model of a SiC ceramic coupon with two layers of microchannels was developed. Calculations of the factor of safety and probability of failure for the case of a straight channel were performed. Results for a pressure of 7.5 MPa were performed. The thermal and mechanical stress analyses of the Ceramatec HTHX and decomposer were completed.

• Bayonet Heat Exchanger. The thermal and mechanical stress analyses of the bayonet type HTHX and decomposer (Sandia design) were completed. Temperature profiles obtained from thermocouples measured from the Sandia experiments have been applied to the whole packed …

Effect Of Tip Resonances On Tunnelling Anisotropic Magnetoresistance In Ferromagnetic Break Junctions: A First-Principles Study, John D. Burton, Renat F. Sabirianov, Julian P. Velev, O. N. Mryasov, Evgeny Y. Tsymbal

Materials Research Science and Engineering Center: Faculty Publications

First-principles calculations of electron tunneling transport in nanoscale Ni and Co break-junctions reveal strong dependence of the conductance on the magnetization direction, an effect known as tunneling anisotropic magnetoresistance TAMR. An important aspect of this phenomenon stems from resonant states localized in the electrodes near the junction break. The energy and broadening of these states is strongly affected by the magnetization orientation due to spin-orbit coupling, causing TAMR to be sensitive to bias voltage on a scale of a few millivolts. Our results bear a resemblance to recent experimental data and suggest that TAMR driven by resonant states is a …

Work-In-Progress - Self-Directed Learning And Motivation In A Project-Based Learning Environment, Trevor S. Harding, Linda Vanasupa, Richard N. Savage, Jonathan D. Stolk

Materials Engineering

Self-directed learning is a key competency in life-long learning, an outcome often cited for engineering education, and is dependent on students' motivation, meta-cognition, and self-regulation with regards to a learning task. Few studies have addressed the aspects of engineering learning environments that promote the development of self-directed learning abilities. The goal of this study was to identify relationships between students' perceptions of their self-directed learning ability and their learning motivation within a project-based learning environment. Junior engineering students in a test cohort with heavy emphasis on project-based learning completed surveys on self-directed learning aptitude and learning motivation. Responses were compared …

Effect Of Surface Roughness On Rate-Dependent Slip In Simple Fluids, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

Molecular dynamics simulations are used to investigate the influence of molecular-scale surface roughness on the slip behavior in thin liquid films. The slip length increases almost linearly with the shear rate for atomically smooth rigid walls and incommensurate structures of the liquid/solid interface. The thermal fluctuations of the wall atoms lead to an effective surface roughness, which makes the slip length weakly dependent on the shear rate. With increasing the elastic stiffness of the wall, the surface roughness smoothes out and the strong rate dependence is restored again. Both periodically and randomly corrugated rigid surfaces reduce the slip length and …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 13, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic and immersion tests to determine the corrosion rates of rock bolts. In this quarter: Potentiodynamic tests were performed to determine corrosion rates (CR) of 4340 Steel …

Simulation Of Plasticity In Nanocrystalline Silicon, M. J. Demkowicz, A. S. Argon, D. Farkas, Megan Frary

Materials Science and Engineering Faculty Publications and Presentations

Molecular dynamics investigation of plasticity in a model nanocrystalline silicon system demonstrates that inelastic deformation localizes in intergranular regions. The carriers of plasticity in these regions are atomic environments that can be described as high-density liquid-like amorphous silicon. During fully developed flow, plasticity is confined to system-spanning intergranular zones of easy flow. As an active flow zone rotates out of the plane of maximum resolved shear stress during deformation to large strain, new zones of easy flow are formed. Compatibility of the microstructure is accommodated by processes such as grain rotation and formation of new grains. Nano-scale voids or cracks …

Correlation-Space Description Of The Percolation Transition In Composite Microstructures, Megan E. Frary, Christopher A. Schuh

Materials Science and Engineering Faculty Publications and Presentations

We explore the percolation threshold shift as short-range correlations are introduced and systematically varied in binary composites. Two complementary representations of the correlations are developed in terms of the distribution of phase bonds or, alternatively, using a set of appropriate short-range order parameters. In either case, systematic exploration of the correlation space reveals a boundary that separates percolating from nonpercolating structures and permits empirical equations that identify the location of the threshold for systems of arbitrary short-range correlation states. Two- and three-dimensional site lattices with two-body correlations, as well as a two-dimensional hexagonal bond network with three-body correlations, are explored. …

Enhanced Shrinkage Of Lanthanum Strontium Manganite (La0.90sr0.10mno3+Δ) Resulting From Thermal And Oxygen Partial Pressure Cycling, Benjamin P. Mccarthy, Larry R. Pederson, Harlan U. Anderson, Xiao Dong Zhou, Prabhakar Singh, Gregory W. Coffey, Edwin C. Thomsen

Materials Science and Engineering Faculty Research & Creative Works

Exposure of (La_0.90Sr_0.10)_0.98MnO_3+δ (LSM-10) to repeated oxygen partial pressure cycles (air/10 ppm O₂) resulted in enhanced densification rates, similar to behavior shown previously due to thermal cycling. Shrinkage rates in the temperature range 700°-1000°C were orders of magnitude higher than Makipirtti-Meng model estimations based on stepwise isothermal dilatometry results at a high temperature. a maximum in enhanced shrinkage due to oxygen partial pressure cycling occurred at 900°C. Shrinkage was the greatest when LSM-10 bars that were first equilibrated in air were exposed to gas flows of lower oxygen fugacity than in …

Signaling Pathways Activated By Interleukin-2 And Interluekin-4 Receptors Mediate T Lymphocyte Clonal Expansion, Kristen K. Comfort

Chemical and Materials Engineering Faculty Publications

Cells sense and respond to chemical and physical stimuli through signal transduction pathways, which mediate cell proliferation, differentiation, migration, and survival. The cytokines interleukin-2 (IL-2) and interleukin-4 (IL-4) are key regulators of the adaptive immune system, particularly influencing the clonal expansion and differentiation of T cells. At least in culture, both synergistic and antagonistic effects of IL-2 and IL-4 co-stimulation have been reported; the antagonism, when observed, is thought to arise from the utilization of a common subunit shared by IL-2 and IL-4 receptors. We have sought to characterize IL-2 and IL-4 signaling at the level of intracellular pathways activated …

The Urban Heat Island Mitigation Impact Screening Tool (Mist), David J. Sailor, Nikolaas Dietsch

Mechanical and Materials Engineering Faculty Publications and Presentations

A web-based software tool has been developed to assist urban planners and air quality management officials in assessing the potential of urban heat island mitigation strategies to affect the urban climate, air quality, and energy consumption within their cities. The user of the tool can select from over 170 US cities for which to conduct the analysis, and can specify city-wide changes in surface reflectivity and/or vegetative cover. The Mitigation Impact Screening Tool (MIST) then extrapolates results from a suite of simulations for 20 cities to estimate air temperature changes associated with the specified changes in surface characteristics for the …

Electroactive Polymers (Eap): Simulation Studies Of The Actuation Mechanisms In A Cantilever Cellulose Electroactive Paper, Fatim A. Mbaye

Electrical & Computer Engineering Theses & Dissertations

Electroactive polymers (EAPs) exhibit large strain in response to an external electric field and have attracted a great deal of attention in recent years for sensor and actuator applications. Favorable properties include soft actuation, ease and simplicity in manufacturing, being light-weight, low power consumption, and the ability to withstand harsh environments. However, this is an emerging material, and several aspects, including the fundamental mechanisms for piezoelectric deflections, remain unclear. This project studies the internal electromechanical factors that contribute to the voltage induced deflections of electro-active paper (EAPap). Experimental measurements of bias dependent deflections and water absorption as a function of …

Bulk Behavior Of Nanostructured Aluminum: Nanocrystalline Powders Compaction, Canning And Consolidation Via Intense Plastic Straining, Mohamed Mahmoud Hamed Shamma

Archived Theses and Dissertations

No abstract provided.

Light Beam Targeting And Positioning System For A Paint Or Coating Removal Blasting System, Richard J. Klein Ii, Christopher A. Lampe

Patents (University of Northern Iowa)

A blasting system for the removal of coatings or paint from an underlying surface uses an optical device to position the blasting nozzle an appropriate stand-off distance from the surface. The blasting media can use a variety of blasting media including abrasives, water, and various specialty blasting media. The preferred optical system is mounted to or integral with the blasting nozzle, and uses a diode laser, a beam splitter and a reflecting mirror to generate a reference beam and a gauge beam. Alternatively, two diode lasers can be used to generate the reference beam and gauge beam respectively. The reference …

Unlv Research Foundation High Temperature Heat Exchanger Development: 9/08, Anthony Hechanova

Publications (NSTD)

Barriers addressed:

Nuclear Hydrogen Initiative R&D Plan – Material performance and component design and testing for the intermediate heat exchanger and high-temperature thermochemical water splitting (H₂SO₄ decomposition and HI decomposition). Improved materials for High Temperature Electrolysis.

The Theory Of Planned Behavior As A Model Of Academic Dishonesty In Engineering And Humanities Undergraduates, Trevor S. Harding, Mathew J. Mayhew, Cynthia J. Finelli, Donald D. Carpenter

Materials Engineering

This study examines the use of a modified form of the Theory of Planned Behavior in understanding the decisions of undergraduate students in engineering and humanities to engage in cheating. We surveyed 527 randomly selected students from three academic institutions. Results supported the use of the model in predicting ethical decision-making regarding cheating. In particular, the model demonstrated how certain variables (gender, discipline, high school cheating, education level, international student status, participation in Greek organizations or other clubs) and moral constructs related to intention to cheat, attitudes toward cheating, perceptions of norms with respect to cheating, and ultimately, cheating behaviors. …

Quantum Mechanics Of Spin Transfer In Coupled Electron-Spin Chains, C. Y. Kim, Lucian Covaci, Fatih Dogan, Frank Marsiglio

Materials Science and Engineering Faculty Research & Creative Works

The manner in which spin-polarized electrons interact with a magnetized thin film is currently described by a semi-classical approach. This in turn provides our present understanding of the spin transfer, or spin torque phenomenon. However, spin is an intrinsically quantum-mechanical quantity. Here, we make the first strides towards a fully quantum-mechanical description of spin transfer through spin currents interacting with a Heisenberg-coupled spin chain. Because of quantum entanglement, this requires a formalism based on the density matrix approach. Our description illustrates how individual spins in the chain time-evolve as a result of spin transfer.