Materials Science and Engineering Commons^™

Electrochemical Performance Of Li(1-X)MXFepo4 Cathode Materials Synthesized By Polymer Pyrolysis Route, Ting Li, Jiang-Feng Qian, Yu-Liang Cao, Han-Xi Yang, Xin-Ping Ai

Journal of Electrochemistry

Olivine Li_1-xM_xFePO₄(M=Cr³⁺, Mg²⁺, Mn²⁺, Ni²⁺) were synthesized by a polyacrylates-pyrolysis route. The structural and electrochemical properties of the as-synthesized cathode materials were investigated by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrochemical charge/discharge cycling. The results indicate that the metallic ions doped at low concentration do not affect the crystalline structure of the material, but considerably improve the rate capability and cycle performance of LiFePO₄ at high rate.

Rate-Dependent Slip Boundary Conditions For Simple Fluids, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

The dynamic behavior of the slip length in a fluid flow confined between atomically smooth surfaces is investigated using molecular dynamics simulations. At weak wall-fluid interactions, the slip length increases nonlinearly with the shear rate provided that the liquid/solid interface forms incommensurable structures. A gradual transition to the linear rate-dependence is observed upon increasing the wall-fluid interaction. We found that the slip length can be well described by a function of a single variable that in turn depends on the in-plane structure factor, contact density and temperature of the first fluid layer near the solid wall. Extensive simulations show that …

Life Cycle Greenhouse Gas Emission Comparison Of Steel Products With Other Materials, Christopher P. Buterbaugh, Meghan C. Mcgrath, Justin K. Novotny, Zane T. Voss, Joseph M. Brunner, Kent D. Peaslee

Materials Science and Engineering Faculty Research & Creative Works

This paper outlines the background of Life-Cycle Inventory/ Life-Cycle Assessment (LCI/LCA) and reviews an undergraduate design project in progress at the University of Missouri - Rolla (UMR) comparing LCI/LCA of steel products with similar products produced from competing materials. GaBi 4 LCI/LCA software is being used to model LCI/LCA with a demonstration of the use of the software for a typical steelmaking operation.1 Future research utilizing the LCI/LCA methodology is being applied to compare the environmental impact of steel products to other alternative engineering materials. This work involves 13 undergraduate students working in four design teams under a FeMET design …

Order-Disorder Transformations In Sm–Co And Sm–Co–Zrc Systems With 2-17 Stoichiometry, Y.Y. Kostogorova-Beller, Jeffrey E. Shield, Matthew J. Kramer

Materials Research Science and Engineering Center: Faculty Publications

This work investigates the order-disorder transformations utilizing time-resolved x-ray diffraction at the Advanced Photon Source. The metastable phases that can form during the order-disorder transformations in the Sm–Co intermetallics have the potential to produce materials with enhanced permanent magnetic properties. The high-temperature experiments transformed the disordered alloys with the TbCu₇-type structure obtained by rapid solidification into the mixture of the hexagonal and rhombohedral ordered structures at 1375 K. The ordering process and the role of the ZrC alloying on the phase formation and ordering transformations were examined. The results showed the formation of shoulders of the fundamental peaks …

Development And In Vitro Examination Of Materials For Osseointegration, Sahil Jalota

All Dissertations

Bone is a connective tissue with nanosized particles of carbonated apatitic calcium phosphate dispersed in a hydrated collagen matrix. With the ageing of the baby boomer population, an increasing number of people sustain bone fractures and defects. Hence, efforts are underway to develop materials to hasten the healing and repairing of such defects. These materials are termed as artificial bone substitutes.
This study represents innovative techniques for development of bone implant materials and improving the existing substitute materials. Emphasis was on three different kinds of materials: Metals (titanium and alloys), Ceramics (calcium phosphates), and Polymers (collagen). The bioactivity of titanium …

The Mechanical And Thick Section Bending Behavior Of Friction Stir Processed Aluminum Plate, D. Hilbert, C. Fuller, M. Mahoney, B. London

Materials Engineering

Friction stir processing (FSP) 2519-T87 aluminum plate results in enhanced ductility, 25% strain at fracture. However, the yield strength in the FSP zone drops to 175 MPa from ~400 MPa. Actively cooling the plate during FSP increases the yield strength to 185 MPa and decreases ductility to 20% strain at fracture. Thick bending of a plate of the alloy was demonstrated after the surface was subjected to FSP.

An Experimental Evaluation Of Performance Variance For Internally Threaded Geometry Related To Extended Tap Wear In Low Carbon Steel, Todd E. Alberts

All-Inclusive List of Electronic Theses and Dissertations

The development of internal threads in a manufactured part is in many cases one of the final operations in the production workflow. Quality issues in thread form development can destroy a part that has previously undergone expensive machining. The issue of tap wear is one of the multi-faceted elements that have a direct correlation on the quality of threaded components. The purpose of this research centers on resultant mechanical pull performance for the stripping of internally threaded geometry in low carbon steel as measured over various increments of the tap cutting life cycle.

Synthesis And Characterization Of Polythiophene Derivatives, Xin Chen

Material Science and Engineering Dissertations - Archive

In Chapter 1, the history of conducting polymers, especially polythiophene and its derivatives, was briefly reviewed. Different approaches of structural modifications to afford small bandgap polythiophene derivatives were discussed. The emergence of metal-containing polymers (metallopolymers) as functional materials has attracted tremendous attention around the world. Introducing metals into thiophene-based oligomers and polymers, whether the backbone or the side chain of the p-conjugated framework, the electronic, optical, or magnetic properties of the material are expected to by significantly affected by metals through various mechanisms. Synthesis methods to prepare poly(thienylene vinylene) were also briefly reviewed in this chapter. In Chapter 2, the …

Experimental Study Of Laminated Composite Tubes Under Bending, Puneet Saggar

Material Science and Engineering Theses - Archive

Bending stiffness of laminated composite tubes was determined experimentally using four-point bending test. The experimental results were compared with the results obtained by the laminated plate and smear property approaches. The results indicate that experimental values are closer to prediction of the laminated plate approach compared to smear property approach. Effects of tube radius and stacking sequence and fiber orientation of the walled thickness laminate on bending stiffness and strength of composite tubes were studied. Fracture analysis was conducted to investigate the failure process of the tube. Both techniques of x-ray radiography and optical microscopy were used in this study. …

High Temperature Heat Exchanger Project: Quarterly Progress Report January 1, 2007 Through March 31, 2007, Anthony Hechanova

Publications (NSTD)

• The variation of sulfur dioxide production (throughput) of the baseline design of the Ceramatec sulfuric acid decomposer with total mass flow rate of reacting flow has been calculated. According to the calculations, the sulfur dioxide production increases as the total mass flow rate of reacting flow increases regardless of the fact that decomposition percentage of sulfuric trioxide decreases. A parametric study of the baseline design of the Ceramatec sulfuric acid decomposer was performed.

• The thermal performance using various channel geometries for the decomposer was studied. The baseline design (straight channels) has 89.5% thermal efficiency while the thermal efficiency …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 11, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic and immersion tests to determine the corrosion rates of rock bolts. In this quarter: Potentiodynamic tests were performed to determine corrosion rates (CR) of 4340 Steel …

A Finite Difference Method For Studying Thermal Deformation In Two-Dimensional Micro Scale Metal Thin Films Exposed To Ultrashort Pulsed Lasers, Haojie Wang

Doctoral Dissertations

Ultrashort-pulsed lasers have been attracting worldwide interest in science and engineering because the lasers with pulse durations on the order of sub-picoseconds to femtoseconds possess capabilities in limiting the undesirable spread of the thermal process zone in a heated sample during material processing at the microscale. Prevention of thermal damage is an important factor for success of ultrashort-pulsed lasers in real applications. The thermal damage induced by ultrashort pulses is intrinsically different from that induced by long-pulse or continuous lasers. It occurs after the heating pulse is over and involves the shattering of thin metal layers (without a clear signature …

Growth And Behavior Of Chondrocytes On Nano Engineered Surfaces And Construction Of Micropatterned Co-Culture Platforms Using Layer-By-Layer Platforms Using Layer -By -Layer Assembly Lift-Off Method, Jameel Shaik

Doctoral Dissertations

Several approaches such as self-assembled monolayers and layer-by-layer assembled multilayer films are being used as tools to study the interactions of cells with biomaterials in vitro. In this study, the layer-by-layer assembly approach was used to create monolayer, bilayer, trilayer, five, ten and twenty-bilayer beds of eleven different biomaterials. The various biomaterials used were poly(styrene-sulfonate), fibronectin, poly-L-lysine, poly-D-lysine, laminin, bovine serum albumin, chondroitin sulfate, poly(ethyleneimine), polyethylene glycol amine, collagen and poly(dimethyldiallyl-ammonium chloride) with unmodified tissue-culture polystyrene as standard control. Three different cell lines—primary bovine articular chondrocytes, and two secondary cell lines, human chondrosarcoma cells and canine chondrocytes were used in …

Biodesulphurization Within Natural Gas In Oil And Gas Field, Sri Astuti Rahayu, M. Fierdaus, Syafrizal Syafrizal, M. Udiharto

Makara Journal of Technology

The presence of sulphur compounds in natural gas can interfere to the quality of natural gas. The decline of combustion gas capacity, metal instrument corrosion in gas piping, and the environmental pollution from gas emission can affect by their presence. Bio-filter is one of the methods that selected to reduce sulphur content in natural gas. A lab scale study of hydrogen sulphide reduction in natural gas had conducted in oil and gas field using bio-filter method. The bio-filter system (±1 L volume) contains an active carbon and thiosulphide medium as a substrate, Thiobacillus thioparus as a single culture of sulphur …

Band Gap Engineering Of Two Dimensional Silicon Photonic Crystals By Oxidation And Oxide Etching, Makhin Thitsa

Electrical & Computer Engineering Theses & Dissertations

In this thesis a thorough analysis is presented on the effects of oxidation and oxide etching on the band structure of two dimensional silicon photonic crystals (2 D Si PC's). By using the plane wave expansion method (PWM), two structures of triangular lattice, namely, air cylinders embedded in a silicon background and silicon cylinders embedded in an air background are modeled. The thesis focuses on triangular lattice arrangement because for certain parameter values such a lattice can give rise to absolute band gap, which prohibits the propagation of either transverse electric (TE) or transverse magnetic (TM) polarizations.

During oxidation three …

Mechanical Study On Using Of Accr Thermal Conductor At 500 Kv Sutet, Suprihadi Prasetyono

Makara Journal of Technology

Mechanical Study on using of ACCR Thermal Conductor at 500 kV SUTET. At the height of electricity demand increasing recently, circumstance of environment more limited and also expense of high investment, making thermal conductor (conductor thermal resistance) considered to be one of alternative in the electricity transmission bottlenecks. These days it has been developed thermal conductor ACCR (Aluminium Conductor Composite Reinforced) which can operate with temperature up to 240oC, so that making the current carrying capacity being higher than conventional conductor. This research aimed to study load current leading to mechanical characteristic ACCR conductor included tension, length of elongation and …

Behaviour Of Reinforced Self-Consolidating Concrete Frames, Aly Said, Moncef Nehdi

Civil and Environmental Engineering and Construction Faculty Research

Multi-storey reinforced concrete (RC) structural frames represent some of the most congested structural elements. Placing and consolidating concrete in such structural frames imposes substantial challenges. This offers a unique area of application for self-consolidating concrete (SCC) because of its inherent ability to flow under its own weight and fill congested sections, complicated formwork and hard-to-reach areas. Research is, however, needed to demonstrate the ability of SCC structural frames adequately to resist vertical and lateral loads. In the present study, full-scale 3 m high beam-column joints reinforced as per the Canadian Standards CSA A23·3-94 and ACI-352R-02 were made with normal concrete …

Production Of Medium Chain Length Polyhydroxyalkanoates From Oleic Acid Using Pseudomonas Putida Pga1 By Fed Batch Culture, Sidik Marsudi, Irene K.P. Tan, Seng Neon Gan, K. B. Ramachandran

Makara Journal of Technology

Bacterial polyhydroxyalkanoates (PHAs) are a class of polymers currently receiving much attention because of their potential as renewable and biodegradable plastics. A wide variety of bacteria has been reported to produce PHAs including Pseudomonas strains. These strains are known as versatile medium chain length PHAs (PHAs-mcl) producers using fatty acids as carbon source. Oleic acid was used to produce PHAs-mcl using Pseudomonas putida PGA 1 by continuous feeding of both nitrogen and carbon source, in a fed batch culture. During cell growth, PHAs also accumulated, indicating that PHA production in this organism is growth associated. Residual cell increased until the …

Simple: System Automatic Essay Assessment For Indonesian Language Subject Examination, Anak Agung Putri Ratna, Bagio Budiardjo, Djoko Hartanto

Makara Journal of Technology

SIMPLE: System Automatic Essay Assessment for Indonesian Language Subject Examination. Evaluation of study of a student is a very important aspect of an educational process. Evaluation is aimed at measuring the level of student understanding of the given lecture materials. Measuring student understanding of the course material, using essay-type exam, is generally used as the evaluation tool. In this essay-type exam, the student has to answer questions using sentences, whereby choices of possible answers are not indicated. The student has to answer the questions with his/her sentences. The answers may vary, since it reflects the student’s best thoughts of the …

Utilization Of Bagasse Cellulose For Ethanol Production Through Simultaneous Saccharification And Fermentation By Xylanase, M. Samsuri, Misri Gozan, R. Mardias, M. Baiquni, Heri Hermansyah, Anondho Wijanarko, Bambang Prasetya, M. Nasikin

Makara Journal of Technology

Utilization of Bagasse Cellulose for Ethanol Production through Simultaneous Saccharification and Fermentation by Xylanase. Bagasse is a solid residue from sugar cane process, which is not many use it for some product which have more added value. Bagasse, which is a lignosellulosic material, be able to be use for alternative energy resources like bioethanol or biogas. With renewable energy resources a crisis of energy in Republic of Indonesia could be solved, especially in oil and gas. This research has done the conversion of bagasse to bioethanol with xylanase enzyme. The result show that bagasse contains of 52,7% cellulose, 20% hemicelluloses, …

Construction Of Short-Length High-Rates Ldpc Codes Using Difference Families, Deny Hamdani, Ery Safrianti

Makara Journal of Technology

Low-density parity-check (LDPC) code is linear-block error-correcting code defined by sparse parity-check matrix. It is decoded using the massage-passing algorithm, and in many cases, capable of outperforming turbo code. This paper presents a class of low-density parity-check (LDPC) codes showing good performance with low encoding complexity. The code is constructed using difference families from combinatorial design. The resulting code, which is designed to have short code length and high code rate, can be encoded with low complexity due to its quasi-cyclic structure, and performs well when it is iteratively decoded with the sum-product algorithm. These properties of LDPC code are …

Kinetic Model For Triglyceride Hydrolysis Using Lipase:Review, Heri Hermansyah, A. Wijanarko, Dianursanti Dianursanti, Misri Gozan, Praswasti P. D.K Wulan, Rita Arbianti, Roekmijati W. Soemantojo, Tania Surya Utami, Yuliusman Yuliusman, Momoji Kubo, Naomi Shibasaki Kitakawa, Toshiy Yonemoto

Makara Journal of Technology

Triglyceride hydrolysis using lipase has been proposed as a novel method to produce raw materials in food and cosmetic industries such as diacylglycerol, monoacylglycerol, glycerol and fatty acid. In order to design a reactor for utilizing this reaction on industrial scale, constructing a kinetic model is important. Since the substrates are oil and water, the hydrolysis takes place at oil-water interface. Furthermore, the triglyceride has three ester bonds, so that the hydrolysis stepwise proceeds. Thus, the reaction mechanism is very complicated. The difference between the interfacial and bulk concentrations of the enzyme, substrates and products, and the interfacial enzymatic reaction …

Sulfonation Of Cptfe Film Grafted Styrene For Proton Exchange Membrane Fuel Cell, Yohan Yohan

Makara Journal of Technology

Sulfonation of cPTFE Film grafted Styrene for Proton Exchange Membrane Fuel Cell. Sulfonation of γ-ray iradiated and styrene-grafted crosslinked polytetrafluoroethylene film (cPTFE-g-S film) have been done. The aim of the research is to make hydropyl membrane as proton exchange membrane fuel cell. Sulfonation was prepared with chlorosulfonic acid in chloroethane under various conditions. The impact of the percent of grafting, the concentration of chlorosulfonic acid, the reaction time,and the reaction temperature on the properties of sulfonated film is examinated. The results show that sulfonation of surface-grafted films is incomplete at room temperature. The increasing of concentration of chlorosulfonic acid and …

Optical Parametric Oscillation In Orientation-Patterned Gallium Arsenide, Scott A. Shell

Theses and Dissertations

Tunable laser sources in the mid-infrared (MIR) spectral range are required for several Air Force applications. Existing lasers with output in the near-infrared can be converted to more desirable MIR by using nonlinear effects. Orientation patterned gallium arsenide (OPGaAs) is a promising nonlinear conversion material because it has broad transparency and can be engineered for specific pump laser and output wavelengths using quasi-phase matching techniques. This research examines optical parametric oscillation (OPO) of several OPGaAs samples using a 2.052 micrometers wavelength Tm, Ho:YLF pump laser. Of the seven samples available the five that were capable of getting OPO output with …

Cobalt Doping Of Semiconducting Boron Carbide Using Cobaltocene, Lonnie Carlson

Theses and Dissertations

The decomposition of cobaltocene and metacarborane (closo-1,7-dicarba-decaborane) under low energy electron irradiation at about 200 K results in a material with the Fermi level closer to the valence band than the material resulting from the decomposition of metacarborane alone. This indicates that cobaltocene provides a relatively p-type dopant as seen in ultraviolet photoemission spectroscopy/inverse photoemission spectroscopy. Upon warming to room temperature, however, the Fermi level shifts towards the conduction band, suggesting an n-type dopant. This temperature dependent surface photovoltage effect is not compelling evidence for the majority carrier type but does suggest an increase in the carrier concentration …

Characterization Of Intercalated Graphite Fibers For Microelectromechanical Systems (Mems) Applications, Bryan W. Winningham

Theses and Dissertations

Research was accomplished to characterize the electrical and physical characteristic changes of the Thornel® P-100 carbon fiber and five variants when intercalated with 96% sulfuric acid and incorporated the use of Microelectromechanical Systems (MEMS) structures for testing purposes. The five fiber variants were oxidized in 1 M nitric acid at 0.5 A for 30 seconds, 1 and 2 minutes, the last two samples were detreated at 1150 °C for one hour prior to the nitric acid treatment. The fibers were mounted onto a MEMS die, placed into a chip carrier, sulfuric acid added, the chip carrier sealed and testing accomplished. …

Dielectric Response Of Sr Doped Cacu₃Ti₄O₁₂ Ceramics, Wei Li, Robert W. Schwartz, Aiping Chen, Jinsong Zhu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Ca1−xSrxCu3Ti4O12 (x=0, 0.1, and 0.2) ceramics were fabricated and their dielectric properties were investigated. It was found that the dielectric constant significantly decreased with the increase of Sr content at low temperature region (<250 K) and remained almost unchanged at high temperature region (>250 K). Three sets of relaxation peaks were observed in electric modulus plots, which were considered to be associated with grains, domain boundaries, and grain boundaries, respectively. Through the analysis of the heights and calculated activation energies of the relaxation peaks, it is strongly believed that the suppressed dielectric constant is related to the change of domain boundaries with Sr doping. ©2007 American Institute of Physics

Mwnts Modified Gc Electrode For Hydrogen Peroxide Determination, Hong-Juan Wang, Chun-Mei Zhou, Hao Yu, Feng Peng, Jin-Kun Fang

Journal of Electrochemistry

A MWNTs modified GC electrode was constructed successfully to be used to detect hydrogen peroxide.Two methods of maximum anodic current of cyclic voltommogram and chronoamperometry were adopted to measure the concentration of hydrogen peroxide.The results show that the MWCNTs can enlarge the effective surface area of GC electrode and can enormously enhance the electron transfer.The sensitivity and correlation coefficient for hydrogen peroxide detection are 2.84 μA/mmol·L^-1,0.997 and 1.5 μA/mmol·L^-1,0.971 for cyclic voltammetry and chronoamperometry,respectively.The procedure of the two methods to detect hydrogen peroxide is simple,and the results obtained are satisfied.

Influence Of Electrolyte On The Preparation And Electrocatalytic Properties Of Pt/Gc Electrodes, Sheng-Pei Chen, Yan-Xin Chen, Tao Huang, Xiao-Wen Hou, Shi-Gang Sun

Journal of Electrochemistry

Influence of electrolyte on the electrocatalytic properties of Pt/GC electrodes for formic acid oxidation were studied by using cyclic voltammetry, SEM and electrochemical in situ FTIR spectroscopy. It has demonstrated that the surfaces of Pt/GC electrodes prepared in H₂SO₄ (Pt/GC1) or in HClO₄(Pt/GC2) are all composed of platinum particles, but which crystals are some differences in size and shape.Diameters of platinum particles on the surface Pt/GC1 are of 100~200 nm, and with spheral shape in the majority. The sizes of platinum particles on the Pt/GC2 electrode are larger in general,part of particles is of cube …

Electrochemical Characteristics Of La0.7-XCeXMg0.3Ni2.4Co0.6(X=0～0.4) Hydrogen Storage Alloys, Ling-Ling Xiao, Yi-Jing Wang, Yi Liu, Jian-Sheng Cao, Da-Wei Song, Li-Fang Jiao, Hua-Tang Yuan

Journal of Electrochemistry

The effect of partial substitution of Ce for La on the structure and the electrochemical properties of the La_0.7-xCe_xMg_0.3Ni_2.4Co_0.6(x=0～0.4)hydrogen storage alloys have been investigated systematically.The result of X-ray powder diffraction(XRD) show that the alloys are all consisted of the LaNi₃ phase and the LaNi₅ phase.The maximum discharge capacity is decreased gradually with increase of the Ce contents,but the cycling life is improved obviously.