Materials Science and Engineering Commons^™

Effects Of Hydrogen On The Phases And Transition Temperatures Of Niti, Amanda Runciman, Katherine C. Chen, Alan R. Pelton, Christine Trepanier

Materials Engineering

Austenitic (B2) NiTi samples were cathodically charged with various amounts of hydrogen. Trends are tracked based on temperature, time and voltage throughout the process to establish consistent and predictive hydrogen charging procedures. The effect of hydrogen on the austenitic structure and the formation of hydrides are studied with x-ray diffraction (XRD). An increase in the austenite lattice parameter with increased hydrogen content is observed up to a hydrogen solubility limit of approximately 85 wppm. At greater hydrogen concentrations, additional XRD peaks appear, suggesting possible hydride formation. Differential scanning calorimetry (DSC) results show a decrease in both the austenitic and martensitic …

Simulations Of A New Continuous Steelmaking Process, Jorg Annie Peter, Kent D. Peaslee, D. G. C. Robertson

Materials Science and Engineering Faculty Research & Creative Works

A new continuous steelmaking process has been designed in an effort to reduce meltshop costs and increase productivity beyond the possibilities of current EAF-LMF-CC meltshops. This paper discusses possible operational performance based on industrially-verified kinetic, thermodynamic, and heat-transfer models. Dynamic simulations predict variations in steel chemistry and temperature, resulting from steel treatment and upsets. Savings in costs are projected because of increased metallic yield, lower energy requirements, more efficient use of deoxidants and alloys, fewer man-hours per ton, and decreased capital investment.

The Implications Of Academic Dishonesty In Undergraduate Engineering On Professional Ethical Behavior, Donald D. Carpenter, Trevor S. Harding, Cynthia J. Finelli

Materials Engineering

Student academic dishonesty, commonly referred to as cheating, has become a serious problem at institutions of higher education. This is particularly true of engineering students who, according to previous research, are among the most likely to cheat in college. In addition, research on college students in all fields has indicated that such behavior is more common among students who participate in academic dishonesty at the high school level and that it is correlated with other deviant or unethical behaviors, such as petty theft and lying. If, in fact, such correlations do exist, one might hypothesize that there is also a …

High Temperature Heat Exchanger Project: Quarterly Progress Report January 1, 2006 Through March 31, 2006, Anthony Hechanova

Publications (NSTD)

Quarterly Collaboration Meeting. The UNLVRF HTHX Project quarterly meeting was held in Albuquerque, NM, March 16 and 17, 2006. The purpose of the meeting was to promote collaboration and communication among the UNLV Research Foundation partners. A tour of Sandia National Laboratory was also provided that included a visit to their sulfuric acid decomposition test apparatus. There were 24 attendees from universities, national laboratories, and private industry. Collaborators discussed their research progress. The next meeting will be in July in Salt Lake City, UT.

Unlv Research Foundation High Temperature Heat Exchanger Development, Anthony Hechanova

Publications (NSTD)

Barriers addressed:

Nuclear Hydrogen Initiative R&D Plan – Material performance and component design and testing for: intermediate heat exchanger and high-temperature thermochemical water splitting (H2SO4 decomposition and HI decomposition). Improved materials for High Temperature Electrolysis.

Effect Of Silicon Content On The Corrosion Resistance And Radiation-Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems: Quarterly Progress Report (November 2005 – January 2006), Ajit K. Roy

Transmutation Sciences Materials (TRP)

This task is intended to study the effect of Si content not only on the corrosion resistance but also on the radiation-induced embrittlement of martensitic stainless steels. The susceptibility of these alloys with different Si content to stress corrosion cracking, general corrosion and localized corrosion will be evaluated in the molten LBE and aqueous environments of different pH values using state-of-the-art testing techniques. Testing in the aqueous media is intended to develop baseline data for comparison purpose. Radiation-induced embrittlement of these alloys will initially be studied by irradiating the test specimens with bremmstrahlung gamma radiation from 20-40 MeV electron beams …

2nd Annual Undergraduate Research Conference Abstract Book, University Of Missouri--Rolla

Undergraduate Research Conference at Missouri S&T

No abstract provided.

Method And Apparatus For Solder-Less Attachment Of An Electronic Device To A Textile Circuit, James A. Zollo, Bonnie Bachman, Alan R. Beatty, Stephen O. Bozzpme, Nitin B. Desai, Ronald J. Kelley, Rami C. Levy

Economics Faculty Research & Creative Works

A method and apparatus form electrical connections between electronic circuits and conductive threads (102, 104, 106, 108) that are interwoven into textile material (130). Electronic circuits (128), such as semiconductor dies, are connected to a carrier (132) and electrical connections (136) are made to conductive connection areas (110, 112, 114, 116) on the carrier (132). Conductive stitching (202, 204, 206, 208) provides electrical contacts for both the conductive connection areas (110, 112, 114, 116) on the carrier (132) and the conductive threads (102, 104, 106, 108) that are interwoven into the textile material (130). Optionally, a thin, flexible substrate material …

Method For Preparation Of Nanometer Cerium-Based Oxide Particles, X.-D. Zhou, Wayne Huebner, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

The invention comprises novel undoped and doped nanometer-scale CeO₂ particles as well as a novel semi-batch reactor method for directly synthesizing the novel particles at room temperature. The powders exhibited a surface area of approximately 170 m²/g with a particle size of about 3-5 nm, and are formed of single crystal particles that are of uniform size and shape. The particles’ surface area could be decreased down to 5 m²/g, which corresponds to a particle size of 100 nm, by thermal annealing at temperatures up to 1000° C. Control over the particle size, size distribution …

The Phase Stability Of Cerium Species In Aqueous Systems Iii. The Ce(Iii/Iv)-H2o-H2o2/O2 System Dimeric Ce(Iv) Species, Pu Yu, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Equilibria and thermodynamic data for cerium dimer species were calculated for both the Ce-H₂O-O₂ and Ce-H₂O-H₂O₂ systems. It was found that Ce (IV) has a tendency to form dimers, especially when the total cerium concentration is higher than 0.001 M. There are three major soluble dimer forms considered in this paper: (CeOCe)⁶⁺,(CeOCe)(OH)⁵⁺, and (CeOCe)(OH)²⁴⁺, all having very similar standard potentials (E⁰ _{Ce(IV)dimer/Ce(III)}01.66∀0.02V). When they coexist in solution, the concentration ratio of the Ce (IV) dimer to Ce3+ depends on the total cerium concentrations, the …

Global Challenges As Inspiration: A Classroom Strategy To Foster Social Responsibility, Linda Vanasupa, Lynn Slivovsky, Katherine C. Chen

Materials Engineering

Social responsibility is at the heart of the Engineer’s Creed embodied in the pledge that we will “dedicate [our] professional knowledge and skill to the advancement and betterment of human welfare...[placing] public welfare above all other considerations.” However, half century after the original creed was written, we find ourselves in a world with great technological advances and great global-scale technologically-enabled peril. These issues can be naturally integrated into the engineering curriculum in a way that enhances the development of the technological skill set. We have found that these global challenges create a natural opportunity to foster social responsibility within the …

Nanotechnology, Biology, Ethics And Society: Overcoming The Multidisciplinary Teaching Challenges, Linda Vanasupa, Matthew Ritter, Barbara Schader, Katherine C. Chen, Richard N. Savage, Peter Schwartz, Lynne Slivovsky

Materials Engineering

One of the inherent challenges of teaching any emerging technology like nanotechnology, is the fact that its core competencies flux in the new disciplines' early stages. Nanotechnology presents an additional challenge in that its underpinnings cross multiple traditional disciplinary boundaries. We have designed a course that aims to address some of these challenges through a handful of structural features: team-based learning; a "reverse of the learning pyramid" approach; team-teaching; embedded information literacy techniques; and application-centered content. Our course is organized around four applications that are in their developmental stages: gold nanoshells for cancer treatment; molecular manufacturing; tissue engineering of a …

Structural And Magnetic Properties Of La Mn₁₋ₓfeₓo₃ (0 < X < 1.0), X.-D. Zhou, L. R. Pederson, Qingsheng Cai, Jinbo Yang, B. J. Scarfino, M. Kim, William B. Yelon, William Joseph James, Harlan U. Anderson, C. Wang

Materials Science and Engineering Faculty Research & Creative Works

Electronic, structural, and magnetic properties of Mn-doped lanthanum ferrites were studied by neutron diffraction, superconducting quantum interference device, and impedance spectroscopy. Neutron diffraction refinements were performed with the constraint of full La occupancy, which showed the presence of excess oxygen when x < 0.4. Mixed valent Mn cations and cation vacancies, therefore, exist in all the samples. The samples with x > 0.7 are magnetically ordered at room temperature with orthorhombic symmetry (Pbnm). When x < 0.3 the structure is rhombohedral and magnetically disordered above 16 K. The majority carriers, electron holes, correspond to high oxidation states of Mn. The carrier concentration is determined from the Seebeck coefficients, and is a function of temperature and Fe concentration. The measurements of conductivity and Seebeck coefficients show polaron hopping at elevated temperatures.

Freeze-Spray Processing Of Layered Ceramic Composites (Preprint), Oratai Jongprateep, Q. Fu, A. Abbott, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Thermal gradients and associated stresses are critical in designing with ceramic composites having low thermal conductivity. In order to reduce the stresses from thermal gradients, compositional gradients are employed in designing of composite structures. This study addresses development of freeze-spray process to fabricate layered ceramic structures with controlled layer thickness and microstructural development. The composites were processed by spraying of ceramic slurries with low binder content and relatively high solids loadings up to 40 vol on a cooled substrate. The frozen parts were freeze-dried and sintered at elevated temperatures. The relationship between microstructural development and thermal expansion behavior of Al …

Effect Of Firing Temperature And Holding Time On Characterization Of Al/Sic Metal Matrix Composites Produced By Pressureless Infiltration., Anne Zulfia, Myrna Ariati

Makara Journal of Technology

Effect of Firing Temperature and Holding Time on Characterization of Al/SiC Metal Matrix Composites Produced by Pressureless Infiltration. The production of Al-SiC metal matrix composite can be carried out by pressureless metal infiltration processs (PRIMEX). The experiment was conducted using aluminium AC2B ingot as a matrix and 50%Vf SiC powder as a reinforcement which is mixed with 10% Mg powder for wetting agent. The variables of this experiment are holding time and firing temperature to investigate the effect of these conditions on mechanical properties of Al-SiC metal matrix composites. Holding time was conducted for 2,5,8,10,12 hours and firing temperatures was …

Modification Of Bonding Strength Test Of Wc Hvof Thermal Spray Coating On Rocket Nozzle, Bondan T. Sofyan, Haposan J. Pardede, Marizki Stefano, Edi Sofyan

Makara Journal of Technology

Modification of Bonding Strength Test of WC HVOF Thermal Spray Coating on Rocket Nozzle. One way to reduce structural weight of RX-100 rocket is by modifying the nozzle material and processing. Nozzle is the main target in weight reduction due to the fact that it contributes 30 % to the total weight of the structur. An alternative for this is by substitution of massive graphite, which is currently used as thermal protector in the nozzle, with thin layer of HVOF (High Velocity Oxy-Fuel) thermal spray layer. This paper presents the characterization of nozzle base material as well as the modification …

Development Of Fiber-Optic Humidity Sensor Probe With Gelatin Cladding, Akhiruddin Maddu, Kun Modjahidin, Sar Sardy, Hamdani Zain

Makara Journal of Technology

Development of Fiber-Optic Humidity Sensor Probe with Gelatin Cladding. Humidity sensor based on optical fiber with gelatin cladding has been developed. In this humidity sensor probe, the origin cladding of optical fiber is replaced by gelatin coating as humidity sensitive cladding. Testing of the optical fiber sensor probe was conducted by measuring of light intensity transmitted on the optical fiber probe for each variation of different humidity treatments. Response of the optical fiber sensor probe measured from 42%RH to 99%RH, the results show an optical transmission curve varied with relative humidity (RH). Optical transmission in the optical fiber probe increase …

On The Performance Of Imt-2000 Communication Link Based On Stratospheric Platforms, Iskandar Iskandar, Shigeru Shimamoto

Makara Journal of Technology

A new means for providing wireless communication has been currently proposed. It is based on aerial vehicle known as High Altitude Platform or Stratospheric Platforms (SPF). The SPF will be operated at an altitude of 17-22 km above the ground. Therefore, the channel condition may be different compared with those of the conventional terrestrial or satellite wireless channel. In this paper, the channel propagation characteristic of such a system is firstly investigated by means of ray tracing algorithm. We emphasize our investigation in a typical urban environment, in which the mobile users mostly exist. We developed building block model for …

Analysis Of Technical Energy Losses By Using Simulation, Betrianis Betrianis, Randite Herawan

Makara Journal of Technology

Model is a representation of a system. Through model, it can be easier to forecast and control the changing of each element system. Electricity distribution is also a system. Losses are general problem that exist in a distribution network system. But with the right methods, specifically technical energy losses can be reduced in order to increase the efficiency. By making model of the distribution network, the value of technical energy losses in the whole network as well as in every line can be observed. Simulation can also be used to see all losses reduction alternatives. By comparing results from each …

Modeling Of Coupled-Tank System Using Fuzzy Takagi-Sugeno Model, Aries Subiantoro

Makara Journal of Technology

Modeling of Coupled-Tank System Using Fuzzy Takagi-Sugeno Model. This paper describes modeling of coupledtank system based on data measurement using fuzzy Takagi-Sugeno model. The fuzzy clustering method of Gustafson- Kessel algorithm is used to classify input-output data into several clusters based on distance similarity of a member of input-output data from center of cluster. The formed clusters are projected orthonormally into each linguistic variables of premise part to determine membership function of fuzzy Takagi-Sugeno model. By estimating data in each cluster, the consequent parameters of fuzzy Takagi-Sugeno model are calculated using weighted least-squares method. The resulted fuzzy Takagi-Sugeno model is …

Design Of Induction Motor Drive Without Velocity Sensor Using Current Vector Controller With Full And Reduced Observer Moving To Dq Axis, Ridwan Gunawan, Feri Yusivar, Wahidin Wahab, Zuhal A. Kadir

Makara Journal of Technology

Design of Induction Motor Drive Without Velocity Sensor Using Current Vector Controller with Full and Reduced Observer Moving to DQ Axis. The observer is used in estimation velocity sensor usually in α-β axis, therefore this situation will need an extra transformation when we want to add compensator because the flux model is in direct and quadrature-axis dq. Every used the transformation to make possible emerge an error. So in this simulation is used a method to estimate the velocity of induction motor drive with observer that is moved to dq-axis. The model of actual motor used is in alfa-beta axis, …

Hybrid Identification System With Arx And Fast Fourier Transform In Application Of A Quarter Of Vehicle Half Active Suspension, Noveri Lysbetti M, Antonius R.

Makara Journal of Technology

Hybrid Identification System with ARX and Fast Fourier Transform in Application of a Quarter of Vehicle Half Active Suspension. In a control system problem, identification system mechanism is a absolute thing, especially in adaptation controlling to disturbance changing. For that case, is needed an identification method which can identify the changing of disturbance in that system. The aim of this research is to give an alternative in system/plant identification which is a combination (hybrid) of ARX and Fast Fourier Transform. So, it is needed an algorithm design for identification process. In this case, the designed algorithm will be implemented in …

Theoretical Modeling Of Protective Oxide Layer Growth In Non-Isothermal Lead-Alloys Coolant Systems: Quarterly Progress Report (01/01/06- 03/31/06), Yitung Chen

Transmutation Sciences Materials (TRP)

Research highlights:

• A cellular automaton model using method of global restructuring on the growth and corrosion during the formation of the passive layer has been developed.

• A stochastic model, which combines the surface growth and internal oxidation, has been developed to explain the oxidation mechanism of steels in liquid lead alloys.

• Two conference papers have been accepted and will be presented in 2006 International Congress on the Advances in Nuclear Power Plants (ICAPP '06).

Optical Characterization Of Thick Growth Orientation-Patterned Gallium Arsenide, Joshua W. Meyer

Theses and Dissertations

Tunable laser sources in the mid-infrared (MIR) spectral range are required for several Air Force applications. Existing lasers with output in the near-infrared can be converted to more desirable MIR by using nonlinear effects. Orientation patterned gallium arsenide (OPGaAs) is a promising nonlinear conversion material because it has broad transparency and can be engineered for specific pump laser and output wavelengths using quasi-phase matching techniques. This research examines the optical quality of seven OPGaAs crystal samples and explores the design of an optical parametric oscillator (OPO) device. The Air Force Research Laboratory Electro-Optical Countermeasures Technology Branch obtained the samples from …

Co2-Selective Membranes Containing Amino Groups, W.S. Winston Ho

Chemical and Materials Engineering Faculty Patents

Novel compositions suitable for fabrication of CO₂-selective membranes are disclosed. In one aspect, the present invention is directed to compositions comprising polyimide/polyamine blends and copolymers, and to compositions comprising interfacially polymerized polyamides. In another aspect this invention is directed to novel CO₂-selective membranes comprising such polyimide/polyamine blends and copolymers, and to novel CO₂-selective membranes comprising interfacially polymerized polyamides. In yet another aspect, the present invention is directed to a novel water-gas-shift (WGS) reactor comprising the novel CO₂-selective membranes. Advantageously, the use of the novel CO₂-selective membrane allows alteration of the …

Characterization Of Stress In Gan-On-Sapphire Microelectromechanical Systems (Mems) Structures Using Micro-Raman Spectroscopy, Francisco E. Parada

Theses and Dissertations

Micro-Raman (µRaman) spectroscopy is an efficient, non-destructive technique widely used to determine the quality of semiconductor materials and microelectromechanical systems. This work characterizes the stress distribution in wurtzite gallium nitride grown on c-plane sapphire substrates by molecular beam epitaxy. This wide bandgap semiconductor material is being considered by the Air Force Research Laboratory for the fabrication of shock-hardened MEMS accelerometers. µRaman spectroscopy is particularly useful for stress characterization because of its ability to measure the spectral shifts in Raman peaks in a material, and correlate those shifts to stress and strain. The spectral peak shift as a function of stress, …

Passive Multiple Beam Combination In Optical Fibers Via Stimulated Brillouin Scattering, Kirk C. Brown

Theses and Dissertations

Many active methods of scaling laser brightness have been demonstrated in recent years. The goal of this research was to demonstrate the feasibility of passively combining multiple laser beams using Stimulated Brillouin Scattering (SBS) in a long multimode optical fiber. This method of combination employed a “Gatling gun” fiber array that allowed several collimated beams to be focused by a lens into an optical fiber. The retroreflected Stokes beam is passed through the center of the beam combiner for analysis. In addition to experimental methodology and equipment used, the theoretical and historical background of SBS in optical fibers is provided. …

Analysis Of Photoconductive Properties In Ge2Sb2Te5 (Gst) Chalcogenide Films For Applications In Novel Electronics, John R. V. Chezem

Theses and Dissertations

This thesis investigated the thermal phase-change properties in Ge₂Sb₂Te₅ (GST) chalcogenide-based films and determined the feasibility of coupling the GST with photosensitive DNA material for novel optical device applications. Modeling and testing of GST were researched with the approach that GST would react as a resistive mechanism through thermal manipulation. A test structure was fabricated with a 2-micronmeter MEMS fabrication process. GST material was deposited (by RF sputtering) on the surface of the test structures. The GST was analyzed primarily in the amorphous to crystalline transition states due to more distinct changes in the resistance …

Between Microscopic And Mesoscopic Descriptions Of Twin-Twin Interaction, Peter Müllner

Materials Science and Engineering Faculty Publications and Presentations

On a microscopic scale, deformation twinning is carried by the motion of twinning disconnections. A disconnection is an interfacial line defect characterized by a Burgers vector, a line vector, and a step vector. The Burgers vector (dislocation component of the disconnection) carries the deformation while the step vector (ledge component) carries the transformation from one twin variant to the other. On a mesoscopic scale, the deformation produced by twinning is a simple shear. A moving disclination dipole provides a mesoscopic model accounting for the twinning shear. Twin – twin interaction processes including the intersection of twins, the formation of structured …

Correlations Beyond The Nearest-Neighbor Level In Grain Boundary Networks, C. A. Schuh, M. Frary

Materials Science and Engineering Faculty Publications and Presentations

Correlations among 'special' and 'general' grain boundaries are studied on two-dimensional networks, by examining the configurational entropy of boundary structures as well as percolation thresholds. Consideration of crystallographic constraints at various length scales reveals that higher-order constraints play a role in boundary connectivity and network structure. Implications for grain boundary engineering are discussed and directions for future work highlighted.