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High Temperature Heat Exchanger Project (Hthx) Project Quarterly Report, University Of Nevada, Las Vegas. Research Foundation

Publications (NSTD)

On October 24, 2003, the University of Nevada, Las Vegas (UNLV) hosted an all-day HTHX Kickoff Meeting attended by all participating institutional representatives and researchers. Objectives of this meeting were to identify near-term research objectives, coordinate collaborative activities, and identify required urgent action items.

Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase Iii Second Quarterly Report, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Niobium cavities are important parts of the integrated NC/SC high-power linacs. Over the years, researchers in several countries have tested various cavity shapes. They concluded that elliptically shaped cells are the most appropriate shape for superconducting cavities. The need for very clean surfaces lead to the use of a buffered chemical polishing produce for surface cleaning to get good performance of the cavities. The third phase concludes the experimental a fluid flow study and optimization study. The first quarter and second quarter of phase three also begins the experimental set-up of secondary emission studies from niobium in superconducting mode. This …

Mapping Surface Polarization In Thin Films Of The Ferroelectric Polymer P(Vdf-Trfe)., Bradley W. Peterson, Stephen Ducharme, Vladimir M. Fridkin, Timothy J. Reece

Stephen Ducharme Publications

Pyroelectric Scanning Microscopy (PSM) has been developed to enable mapping of surface polarization in ferroelectric thin films, in particular the copolymer polyvinylidene fluoride trifluororethylene, or P(VDF-TrFE). The Chynoweth method for dynamically measuring pyroelectric current is employed in conjunction with a micropositioning system to construct two-dimensional images of the film polarization. These images have revealed enhancement of the polarization near the edges of the film below the average coercive field, with the center's polarization increasing thereafter to meet the edge value at saturation.

Electron Irradiation Effects On Ferroelectric Copolymer Langmuir-Blodgett Films, Christina M. Othon, Stephen Ducharme

Stephen Ducharme Publications

The effect of irradiation on the ferroelectric properties of Langmuir-Blodgett films of the copolymer poly(vinylidene fluoride-trifluorethelene) is investigating using 1.26 MeV electrons with dosages from 16 to 110 Mrad. Irradiation causes a systematic decrease in the phase transition temperature, coercive field and polarization of these thin films.

Ferroelectricity At Molecular Level, L. M. Blinov, A. V. Bune, Peter A. Dowben, Stephen Ducharme, Vladimir M. Fridkin, S. P. Palto, K. A. Verkhovskaya, G. V. Vizdrik, S. G. Yudin

Stephen Ducharme Publications

he synthesis of ultrathin ferroelectric nanostructures by the Langmuir-Blodgett method and their properties are reviewed. It is shown that ferroelectricity exists in one monolayer of the ferroelectric P(VDF-TrFE) copolymer, i.e., at the molecular level. The specific characteristics of switching of ultrathin ferroelectric films are established.

Joining Challenges In The Packaging Of Biomems, Hans Herfurth, Reiner Witte, S. Heinemann, Golam Newaz, Ahsan Mian, Daniel Georgiev, Greg Auner

Mechanical and Materials Engineering Faculty Publications

Micro-joining and hermetic sealing of dissimilar and biocompatible materials is a critical issue for a broad spectrum of products such as micro -electronical, micro -optical and biomedical products and devices. Novel implantable microsystems currently under development will include functions such as localized sensing of temperature and pressure, electrical stimulation of neural tissue and the delivery of drugs. These devices are designed to be long-term implants that are remotely powered and controlled. The development of new, biocompatible materials and manufacturing processes that ensure long-lasting functionality and reliability are critical challenges. Important factors in the assembly of such systems are the small …

High Gradient Multilayer Insulator Technology, Harlan U. Anderson, Stephen E. Sampayan, G. J. Caporaso, W. C. Nunnally, D. M. Sanders, J. A. Watson, Mike L. Krogh

Materials Science and Engineering Faculty Research & Creative Works

We are investigating a novel insulator concept that involves the use of alternating layers of conductors and insulators with periods less than 1 mm. These structures perform 1.5 to 4 times better than conventional insulators in long pulse, short pulse, and alternating polarity applications. We have surveyed our ongoing studies by investigating the performance under long pulse electron beam, short pulse, and full reversing conditions.

Characterization And Modeling Of Local Electromechanical Response In Stress-Biased Piezoelectric Actuators, N. Navapan-Traiphol, Robert W. Schwartz, Daniel S. Stutts, J. Wood

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Numerous investigators have explored the factors that contribute to the high electromechanical performance of stress-biased actuators with particular attention being given to the importance of the extrinsic (domain wall translation) response mechanism. Based on the variation in lateral stress through the thickness of the piezoelectric layer within these devices, it has been suggested that the piezoelectric coefficient varies as a function of position within the layer, though no direct evidence has been previously presented. In this study, the results of Moire interferometry investigations of local strains within these devices are reviewed. The technique permits effective depth-profiling of local deformations at …

Cfd Analysis Of Unsteady Separated Transonic Oscillation Cascade Aerodynamics, Xuedong Zhou, J. Mitch Wolff

Mechanical and Materials Engineering Faculty Publications

With an improved algebraic mesh-deforming algorithm, STAR-CD, a commercial computational fluid dynamics (CFD) solver is employed for the numerical analysis of a transonic oscillating linear cascade of advanced design blades. The center blade oscillates 0.6-degrees about the middle cord. The numerical simulation is conducted for a frequency range from 200 Hz to 500 Hz. A hybrid grid, which utilizes a structured O-grid around the airfoil and an unstructured grid everywhere else is employed. The Spalart-Allmaras (S-A), one equation turbulence model, along with other two equation k-ε models, are also utilized for the steady state simulation. The S-A turbulence …

Microwave Induced Preparation Of A-Axis Oriented Double-Ended Needle-Shaped Zno Microparticles, Suresh Pillai, John Kelly, Graeme Watson, Deirdre Ledwith

Articles

Microwave irradiation of solutions of Zn(NO₃)₂ and urea provides a straightforward route to a-axis oriented crystals of needle-like morphology.

Low-Temperature Crystallization Of Sol–Gel Processed Pb0.5ba0.5tio3: Powders And Oriented Thin Films, Suresh Pillai, Stacey Boland, Sossina Haile

Articles

A novel sol– gel process suitable for depositing thin-film lead
barium titanate has been developed. X-ray diffraction analysis
showed perovskite phase crystallization to occur at a temperature
as low as 400°C with single-phase Pb0.5Ba0.5TiO3 (PBT)
resulting at a temperature as low as 500°C. Small concentrations
of barium carbonate were evident by X-ray diffraction at
400°C, and indications of minor, carbonate-containing phases
were evident by FTIR at 600°C. Deposition of the sol by spin
coating on single-crystal and thin-film MgO on silicon resulted
in highly oriented PBT films after calcination at 600°C. Mixed
(100)/(001) films were obtained on single-crystal MgO,
whereas …

Preparation And Characterization Of Thermally Stabilized Ceria And Ceria Containing Materials, Leena Ali Rashid Al-Kaabi

Theses

Ceria, CeO₂, is one of the most important catalytic materials that can play multiple roles owing to its ability to release and uptake oxygen under catalytic reaction conditions with the preservation of it fluorite structure. Textural and thermal stability is a critical issue in determining the promoting and metal supporting functions of CeO₂ in its catalytic applications in the three way catalysis. Therefore, significant efforts have been made by industry on finding ways to improve the thermal stability of ceria both by modification of the synthesis of CeO₂ and by looking at possible stabilizers.

In the …

Material Selection For A Composite Hip Joint, Ahmed Abdullah Ali Al-Hosani

Theses

The use of biomaterials in orthopedic surgery has been successfully acceptable in the current medical practice. Total hip joint replacement (THR) is one of the most popular and successful operations in orthopedics. Total hip replacement (THR) has been using metal prosthesis for many years. However, the use of metal implants has two major disadvantages. The first disadvantage is that the stiffness of the metallic prosthesis is relatively high compared to the surrounding, load carrying bone. The elastic moduli of titanium and cobalt-chromium alloy are 110 and 210 GPa, respectively. Whereas the elastic modulus of cortical bone ranges from 15 to …

The Role Of The Solid Substrate On The Spreading Kinetics Of A Liquid Droplet, Bashar Jalal Sasa

Theses

Classic hydrodynamic wetting theory leads to a linear relationship between spreading speed and the capillary force, being determined only by the surface tension of the liquid and its viscosity.

The theory appears in good agreement with results generated from experiments conducted on the spreading of Polydimethylsiloxanes (PDMS) on soda-lime glass substrate and fails to account for the behavior of other liquids. This thesis examines the role played by the solid substrate on the spreading kinetics of liquid droplets. The set of experiments whose results are presented below used different types of liquids with various properties of surface tension and viscosity …

Chemical Solution Deposition Of Electronic Oxide Films, Robert W. Schwartz, Theodor Schneller, Rainer Waser

Materials Science and Engineering Faculty Research & Creative Works

The chemical solution deposition (CSD) technique as a highly flexible method for the fabrication of electronic oxide thin films is reviewed. Various chemical aspects of different approaches are discussed, including sol-gel, hybrid, and metallo-organic decomposition (MOD) routes, which all have been successfully applied for the deposition of this class of materials. Principles of the selection and properties of the educts, the mechanism of film crystallization, and tailoring of microstructure through manipulation of deposition parameters are reported. the role of thermodynamics on the phase transformation process is also reviewed. Finally, some of the applications for chemical solution-derived thin films currently under …

Optical Characterization Of Ceramic Thin Films: Applications In Low-Temperature Solid Oxide Fuel-Cell Materials Research, B. P. Gorman, V. Petrovsky, Harlan U. Anderson, T. Petrovsky

Materials Science and Engineering Faculty Research & Creative Works

Characterization of thin film solid oxide fuel-cell materials can be difficult due to the range of porosities in electrodes and electrolytes as well as the nano-sized pores and particles. in this study, optical characterization techniques such as ultraviolet-visible transmission and reflection spectrophotometry are illustrated as methods for achieving information about the film density from the film refractive index as well as the film thickness. These techniques were used to investigate the sintering process of colloidal CeO₂ on sapphire substrates and polymeric precursor-derived ZrO₂:16%Y (YSZ) thin films on silicon over the temperature range 400-1000 °C, and the results …

Thermal Efficiency Of Steel Melting, Kent D. Peaslee, Semen Naumovich Lekakh, Bradley Randall

Materials Science and Engineering Faculty Research & Creative Works

This paper presents the results of energy consumption measurements at steel foundries using induction and/or electric arc furnace melting. Statistical methods, infrared thermography, and numerical investigations were used for analysis of heat losses. The influence of different melting practices on energy losses was examined. Industrial experiments in isothermal holding of liquid steel in induction furnaces under different power inputs were used for evaluation of the real values of heat losses by radiation from liquid steel and conductivity through lining. Average values and statistical distributions of energy consumptions for melting steel are presented in this article.

Evaluation Of Microstructure And Superplasticity In Friction Stir Processed 5083 Al Alloy, Indrajit Charit, Rajiv S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Friction stir processing (FSP) has been developed as a potential grain refinement technique. In the current study, a commercial 5083 Al alloy was friction stir processed with three combinations of FSP parameters. Fine-grained microstructures with average grain sizes of 3.5-8.5 µm were obtained. Tensile tests revealed that the maximum ductility of 590 was achieved at a strain rate of 3 x 10^-3 s^-1 and 530 °C in the 6.5-µm grain size FSP material, whereas for the material with 8.5-µm grain size, maximum ductility of 575 was achieved at a strain rate of 3 x 10^-4 s^{-1 …}

Preparation Of (Pb,Ba)Tio3 Powders And Highly Oriented Thin Films By A Sol-Gel Process, Stacey Boland, Suresh Pillai, Wein-Duo Yang, Sossina Haile

Articles

Solid solution Pb1-xBaxTiO3, with particular emphasis on Pb0.5Ba0.5TiO3, was prepared
using a sol-gel process incorporating lead acetate trihydrate, barium acetate, and
titanium isopropoxide as precursors, acetylacetone (2,4 pentanedione) as a chelating
agent, and ethylene glycol as a solvent. The synthesis procedure was optimized by
systematically varying acetylacetone: Ti and H2O:Ti molar ratios and calcination
temperature. The resulting effects on sol and powder properties were studied using
thermogravimetric analysis/differential scanning calorimetry, Fourier transform infrared
spectroscopy, Brunauer-Emmett-Teller analysis, and x-ray diffraction (XRD).
Crystallization of the perovskite structure occurred at a temperature as low as 450 °C.
Thin films were prepared by spin …

Etching With Electron Beam Generated Plasmas, D. Leonhardt, Scott G. Walton, Christopher Muratore, Richard F. Fernsler, R. A. Meger

Chemical and Materials Engineering Faculty Publications

A modulated electron beam generated plasma has been used to dry etch standard photoresist materials and silicon. Oxygen–argon mixtures were used to etch organic resist material and sulfur hexafluoride mixed with argon or oxygen was used for the silicon etching. Etch rates and anisotropy were determined with respect to gas compositions, incident ion energy (from an applied rf bias) and plasma duty factor. For 1818 negative resist and i-line resists the removal rate increased nearly linearly with ion energy (up to 220 nm/min at 100 eV), with reasonable anisotropic pattern transfer above 50 eV. Little change in etch rate was …

Effect Of Plasma Flux Composition On The Nitriding Rate Of Stainless Steel, Christopher Muratore, Scott G. Walton, D. Leonhardt, Richard F. Fernsler, David D. Blackwell, R. A. Meger

Chemical and Materials Engineering Faculty Publications

The total ion flux and nitriding rate for stainless steel specimens exposed to a modulated electron beam generated argon-nitrogen plasma were measured as a function of distance from the electron beam axis. The total ion flux decreased linearly with distance, but the nitriding rate increased under certain conditions, contrary to other ion flux/nitriding rate comparisons published in the literature. Variation in ion flux composition with distance was explored with a mass spectrometer and energy analyzer as a possible explanation for the anomalous nitriding rate response to ion flux magnitude. A transition in ion flux composition from mostly N2 1 to …

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry, Morphology, And Surface Preparation: Quarterly Report, Allen L. Johnson, John Farley, Dale L. Perry

Transmutation Sciences Materials (TRP)

This project has four components:

(1) the fabrication of a materials test apparatus with unique capabilities,

(2) comparative studies of steel corrosion under gas phase conditions comparable to the Lead Bismuth Eutectic (LBE) oxygen control conditions,

(3) isotope labeling studies, and

(4) collaborative efforts with other workers in the field.

Development Of Titanium Nitride/Molybdenum Disulphide Composite Tribological Coatings For Cryocoolers, Anil Pai

Electronic Theses and Dissertations

Hydrogen is a clean and sustainable form of carrier of energy that can be used in mobile and stationary applications. At present hydrogen is produced mostly from fossil sources. Solar photoelectrochemical processes are being developed for hydrogen production. Storing hydrogen can be done in three main ways: in compressed form, liquid form and by chemical bonding. Near term spaceport operations are one of the prominent applications for usage of large quantities of liquid hydrogen as a cryogenic propellant. Efficient storage and transfer of liquid hydrogen is essential for reducing the launch costs. A Two Stage Reverse Turbo Brayton Cycle (RTBC) …

Phenomenology And Experimental Observations In High Temperature Ternary Interdiffusion, Abby Lee Elliott

Electronic Theses and Dissertations

A new method to extract composition dependent ternary interdiffusion coefficients from a single diffusion couple experiment is presented. The calculations involve direct determination of interdiffusion fluxes from experimental concentration profiles and local integration and differentiation of Onsager's formalism. This new technique was applied to concentration profiles obtained from selected semi-infinite, single-phase diffusion couple experiments in the Cu-Ni-Zn, Fe-Ni-Al, and Ni-Cr-Al systems. These couples exhibit features such as uphill diffusion and zero flux planes. The interdiffusion coefficients from the new technique along with coefficients reported from other methods are graphed as functions of composition. The coefficients calculated from the new technique …

Modeling, Fabrication, And Optimization Of Niobium Cavities, Robert A. Schill Jr., Mohamed Trabia, William Culbreth

Transmutation Sciences Materials (TRP)

One of the key technologies for the deployment of acceleratordriven transmutation systems is the accelerator itself. Elliptical superconducting niobium cavities are used to increase the efficiency of the high-power accelerators needed to support the transmutation mission.

One of the major sources of energy loss from a superconducting accelerator cavity is a process known as multiple impacting (or “multipacting”) of electrons. This phenomenon limits the maximum amount of energy and power that the niobium cavity can store. As a result, the maximum power available for accelerating the desired charge, as well as the overall performance of the accelerator is reduced. Furthermore, …

Synthysis Of Polymer/Nano-Droplet Composites From Reverse Microemulsion Polymerization, Liehui Ge

Master's Theses and Doctoral Dissertations

L₁ and L₂ domains of the water/AOT/MMA ternary system were investigated at 22±1°C. Free radical polymerizations were conducted in L₂ domain. Only opaque polymer rods were obtained. Acrylamide, a water soluble monomer, plays a role of co-surfactant which greatly expands the L₂ domain. However, polymerizations only yielded opaque material. SEM showed images of phase separation.

MDOS (2-Methacryloyloxy)ethyl trimethylammonium bis(2-ethylhexyl) sulfosuccinate, was synthesized by ion exchange method. L₁ and L₂ domains of the water/MDOS/MMA ternary system were also investigated at 22±1°C. Free radical polymerizations were conducted in L₂ domain. Transparent polymer was produced. The …

Exploration Of Artificial Multiferroic Thin-Film Heterostructures Using Composition Spreads, K.-S. Chang, M. A. Aronova, C.-L. Lin, M. Murakami, M.-H. Yu, Jason R. Hattrick-Simpers, O. O. Famodu, S. Y. Lee, R. Ramesh, M. Wuttig, I. Takeuchi, C. Gao, L. A. Bendersky

Faculty Publications

We have fabricated a series of composition spreads consisting of ferroelectric BaTiO₃ and piezomagnetic CoFe₂O₄ layers of varying thicknesses modulated at nanometer level in order to explore artificial magnetoelectricthin-film heterostructures. Scanning microwavemicroscopy and scanning superconducting quantum interference device microscopy were used to map the dielectric and magnetic properties as a function of continuously changing average composition across the spreads, respectively. Compositions in the middle of the spreads were found to exhibit ferromagnetism while displaying a dielectric constant as high as ≈120.

Processing, Microstructural And Mechanical Characterization Of Mechanically Alloyed Al-Al2o3 Nanocomposites, Pushkar Katiyar

Electronic Theses and Dissertations

Aluminum-alumina nanocomposites were synthesized using mechanical alloying of blended component powders of pure constituents. This study was performed on various powder mixtures with aluminum as the matrix and alumina as the reinforcement with volume fractions of 20, 30, and 50 % and Al2O3 particle sizes of 50 nm, 150 nm, and 5 µm. X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques were used for the crystal structure and microstructural characterization of the powders at different stages of milling. Al2O3 powders with 50 nm and 150 nm particle size were predominantly of γ-type, while Al2O3 of 5 µm size was …

Corrosion Of Steel By Lead Bismuth Eutectic, John Farley, Allen L. Johnson, Dale L. Perry

Transmutation Sciences Materials (TRP)

There is an active international interest in lead-bismuth eutectic and similar liquid lead systems because of the relevance to the transmutation of nuclear waste, fast reactors, and spallation neutron sources. A successful program in nuclear waste processing that includes transmutation in accelerator-driven systems and fast reactors, would significantly decrease the space requirements for geological repositories.

Materials in these systems must be able to tolerate high neutron fluxes, high temperatures, and chemical corrosion. For lead bismuth eutectic (LBE) systems, there is an additional challenge because the corrosive behaviors of materials in LBE are not well understood. Most of the available information …

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials, Ajit K. Roy

Transmutation Sciences Materials (TRP)

The primary objective of this task is to evaluate the effect of environmental and mechanical parameters on environment induced degradations of candidate target structural materials for applications in spallation-neutron-target systems, such as accelerator-driven systems for the transmutation of waste. The materials selected for evaluation and characterization are martensitic stainless steels including Alloys HT-9, EP-823 and Type 422 stainless steel (SS).

More recently, this experimental program has been expanded to evaluate the effect of molten lead-bismuth eutectic (LBE) on the corrosion behavior of target structural materials in the presence of oxygen. Since the Materials Performance Laboratory (MPL) at UNLV currently cannot …