Materials Science and Engineering Commons^™

Effect Of Dspp Al2O3 On Electrical Properties Of Polymer Electrolyte, Hai-Fen Xie, Xiao-Xiang Sun, Yi-Pin Wang, Guang-Yuan Li

Journal of Electrochemistry

The PEO-NaSCN polymer solid electrolytes by adding dispersed second phase particles (DSPP) of Al₂O₃ were studied. The characteristics of solid electrolytes and conductivity values are dependent on DSPP Al₂O₃ sizes and its contents. It was found that when the Al₂O₃ sizes are less than 1 μm, which is a criticle size, the sample conductivities were larger than those of the pure PEO-NaSCN samples and when the Al₂O₃ sizes are larger than 1 μm then the sample conductivities are less then those of the pure samples. The maximum conductivity …

Study On Degradation Of Phenol By Electrochemical Oxidation, Yue-Li Liu, Hong-Hua Ge

Journal of Electrochemistry

Electrochemical oxidation of phenol was carried out by the Dimensionally Stable Anodes (DSA) electrode, which has been discarded as waste by alkali chloride factory. The result indicates that a good phenol removal can be obtained under certain phenol concentration by the DSA electrode. The key factor in effecting phenol removal of electrochemical oxidation is applied current density, the following factors are pH, electrolyte concentration and phenol concentration. After experiments, the optimal test conditions are 30 mA/cm², pH 10, electrolyte concentration 10 mg/L, phenol concentration 10 mg/L.67% CODcr removal and 90% absorbance removal are gained by electrochemical oxidation for …

Adsorption And Oxidation Of Phenol Electrode Processes, Bao-Cheng Wang, Yan-Ping Sun, Jin-Hua Zhu

Journal of Electrochemistry

The electrochemical behaviors of platinum electrode were studied by cyclic voltammetry in 1mol/L sulfuric acid solution and 1mol/L sulfuric acid solution contained phenol. The adsorption characteristics of phenol and the intermediat on electrode surface have been discussed. The reactive reversibility and oxidation mechanism of phenol on electrode process have been investigated.The potential of characteristic adsorption was suggested. The various products woud be formed when the electrode potential was greater than the one of characteristic adsorption.

Riser Design For Green Sand And Ductile Iron Castings, K. Michael Kuebler

Graduate Research Papers

Shrinkage defects in ductile iron riser contacts has long been one of the most frustrating defects to eliminate for the foundry engineer. While process variation can definitively contribute to the occurrence of these defects most can be prevented if the risers are properly designed and/or applied to the castings to be fed. There are several proven methods for the designing risers some of which go back over 40 years ago. There are also new methods available today with the advancements of simulation software. Four of these riser design methods were evaluated for their ability to produce an internally sound casting …

An Examination Of The Relationship Between Academic Dishonesty And Professional Behavior, Trevor S. Harding, Honor J. Passow, Donald D. Carpenter, Cynthia J. Finelli

Materials Engineering

A number of recent studies have found correlations between academic dishonesty in higher education and unethical behavior in the work settings. However, these studies have not explored the causal relationship between the underlying factors that lead to this dishonesty. This realization, and apparently high levels of cheating among engineering students, has lead us to a research hypothesis that decision making patterns about academic cheating among engineering students are positively correlated with those individuals' decision making patterns about work place ethics and responsibility. To test our hypothesis, we have developed an exploratory survey that asks questions about the respondent's decisions during …

Effects Of Intermetallic Morphology At The Metallic Particle/Solder Interface On Mechanical Properties Of Sn-Ag-Based Solder Joints, H. Rhee, F. Guo, J. G. Lee, Katherine C. Chen, K. N. Subramanian

Materials Engineering

Mechanical incorporation of metallic particles in the Sn-Ag-based solder resulted in various intermetallic compound (IMC) morphologies around these particles during reflow. Unlike with the Ni particles, the IMCs formed around Cu and Ag particles are relatively insensitive to reflow profiles employed. The IMC formed around the Ni particles ranges from “sunflower” morphology to “blocky” morphology with increasing time and temperature above liquidus during the heating part of the reflow profile. Mechanical properties, such as simple shear strength and creep behavior, of these composite solders were affected by the IMC morphologies in the composite solders investigated. Sunflower-shaped IMC formed around an …

Formation And Growth Of Intermetallics Around Metallic Particles In Eutectic Sn-Ag Solder, J. G. Lee, Katherine C. Chen, K. N. Subrmanian

Materials Engineering

Incorporation of metallic particulate reinforcements in eutectic Sn-Ag solder results in the formation of intermetallic compounds (IMCs) along particulate/ solder interfaces with different morphologies. For instance, “sunflower” and “blocky faceted” IMC shapes have been observed around Ni particle reinforcements incorporated in the eutectic Sn-Ag solder matrix. The time and temperature above solder liquidus during the heating stage of the reflow process has been found to play a significant role in determining the IMC morphology in these Ni particulate-reinforced solders. Similar studies were carried out with Cu and Ag particulate reinforcements using the same solder matrix. The amount of heat input …

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials: Quarterly Progress Report (June 1 – August 31, 2003), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

As indicated in the original proposal, the primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate target materials for applications in spallationneutron- target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The materials selected for evaluation and characterization are martensitic stainless steels including Alloy HT-9, Alloy EP 823 and Type 422 stainless steel. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement (HE) of these materials are being evaluated in aqueous environments of interest using tensile specimens under constant load and slow-strain-rate (SSR) conditions. …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications: Quarterly Progress Report (June 01 – Aug 31, 2003), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. This Alloy has been proven to be an excellent structural material to contain the lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. Very little data exist in the open literature on the tensile properties of this Alloy. The test material will be thermally treated prior to the evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by surface …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements: Quarterly Progress Report (June 01 – August 31, 2003), Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this collaborative research project involving the University of Nevada Las Vegas (UNLV), the Idaho State University (ISU), and the Los Alamos National Laboratory (LANL) is to evaluate the feasibility of determining residual stresses in cold-worked, plastically-deformed (bent), and welded materials using a nondestructive method based on positron annihilation spectroscopy (PAS). This technique uses γ-rays from a small MeV electron Linac to generate positrons inside the sample via pair production. This method is known to have capabilities of characterizing defects in thick specimens that could not be accomplished by conventional positron technique or other nondestructive methods. The generated …

Temperature, Stress, And Corrosive Sensing Apparatus Utilizing Harmonic Response Of Magnetically Soft Sensor Element (S), Craig A. Grimes, Keat Ghee Ong

Chemical and Materials Engineering Faculty Patents

A temperature sensing apparatus including a sensor element made of a magnetically soft material operatively arranged within a first and second time-varying interrogation magnetic field, the first time-varying magnetic field being generated at a frequency higher than that for the second magnetic field. A receiver, remote from the sensor element, is engaged to measure intensity of electromagnetic emissions from the sensor element to identify a relative maximum amplitude value for each of a plurality of higher-order harmonic frequency amplitudes so measured. A unit then determines a value for temperature (or other parameter of interst) using the relative maximum harmonic amplitude …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications: Annual Progress Report (September 2002 – August 2003), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading structural target material for accelerator-driven waste transmutation applications. This alloy has been proven to be an excellent structural material to contain the molten lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. Very little data exist in the open literature on the tensile properties of this martensitic alloy. Three different heats of this material, produced by vacuum induction melting, were thermally treated to produce fully-tempered martensitic microstructure without any retained austenite (Table I). Cylindrical specimens were fabricated from the heat-treated round bars …

Spin Blockade In Ferromagnetic Nanocontacts, M. Ye Zhuralev, Evgeny Y. Tsymbal, Sitaram Jaswal, A.V. Vedyayev, B. Dieny

Materials Research Science and Engineering Center: Faculty Publications

Using a free-electron model and a linear response theory we investigate spin-dependent electronic transport in magnetic nanocontacts in the ballistic regime of conduction. We emphasize the fact that in atomic-size ferromagnetic contacts it is possible to achieve the conductance value of e²/h, which implies a fully spin-polarized electric current. We explore some consequences of this phenomenon. In particular, we show that the presence of a nonmagnetic region in the nanocontact separating two ferromagnetic electrodes can lead to a spin blockade resulting in very large values of magnetoresistance.

External And Intrinsic Anchoring In Nematic Liquid Crystals: A Monte Carlo Study, Nikolai V. Priezjev, G. Skacej, R. A. Pelcovits, S. Zumer

Mechanical and Materials Engineering Faculty Publications

We present a Monte Carlo study of external surface anchoring in nematic cells with partially disordered solid substrates, as well as of intrinsic anchoring at free nematic interfaces. The simulations are based on the simple hexagonal lattice model with a spatially anisotropic intermolecular potential. We estimate the corresponding extrapolation length b by imposing an elastic deformation in a hybrid cell-like nematic sample. Our estimates for b increase with increasing surface disorder and are essentially temperature independent. Experimental values of b are approached only when both the coupling of nematic molecules with the substrate and the anisotropy of nematic-nematic interactions are …

Surface Structure Of Ultrathin Copolymer Films Of Ferroelectric Vinylidene Fluoride (70%) With Trifluoroethylene (30%) On Graphite, Lei Cai, Hongwei Qu, Chenxi Lu, Stephen Ducharme, Peter A. Dowben, Jiandi Zhang

Materials Research Science and Engineering Center: Faculty Publications

The structure and local structural distortions, through the polarization manipulation, of crystalline films of ferroelectric vinylidene fluoride (70%) with trifluoroethylene (30%) [P(VDF-TrFE)] copolymer on graphite were studied by scanning tunneling microscopy (STM). A quasispiral twist in C[Single Bond]C bonds with rotations about the polymer chain axis was observed by high-resolution STM, indicating a surface relaxation of the strained copolymer films. Such a relaxation behavior appears to be linked to the observed local dipole rotations accompanied by the reversal of the local polarization with biasing the STM tip. A structure model is proposed based upon the observations.

Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase Iii Quarterly Report, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Niobium cavities are important parts of the integrated NC/SC high-power linacs. Over the years, researchers in several countries have tested various cavity shapes. They concluded that elliptically shaped cells are the most appropriate shape for superconducting cavities. The need for very clean surfaces lead to the use of a buffered chemical polishing produce for surface cleaning to get good performance of the cavities. The third phase concludes the experimental a fluid flow study and optimization study. The first quarter and second quarter of phase three also begins the experimental set-up of secondary emission studies from niobium in superconducting mode. This …

Identification Of Dynamic Properties Of Materials For The Nuclear Waste Package, Brendan O'Toole, Mohamed Trabia, Amy J. Smiecinski

Publications (YM)

Stainless steel 316L, titanium alloy grade 7, and alloy C22 are currently under consideration as candidate materials for use in various components associated with the spent nuclear fuel package, which must be designed to withstand structural deformation caused by static, thermal, and handling loads. In addition, it has to maintain its integrity in case of accidents, where it may be subjected to high loads over a very short period of time. Mechanical characteristics of these three materials under dynamic loading are not well documented. This paper describes the procedures and results obtained from experiments performed over a range of slow …

Self-Consistent Modification To The Electron Density Of States Due To Electron-Phonon Coupling In Metals, Fatih Dogan, Frank Marsiglio

Materials Science and Engineering Faculty Research & Creative Works

The "standard" theory of a normal metal consists of an effective electron band which interacts with phonons and impurities. The effects due to the electron-phonon interaction are often delineated within the Migdal approximation; the properties of many simple metals are reasonably well described with such a description. On the other hand, if the electron-phonon interaction is sufficiently strong, a polaron approach is more appropriate. The purpose of this paper is to examine to what degree the Migdal approximation is self-consistent, as the coupling strength increases. We find that changes in the electron density of states become significant for very large …

A Mushy-Zone Rayleigh Number To Describe Interdendritic Convection During Directional Solidification Of Hypoeutectic Pb-Sb And Pb-Sn Alloys, Surendra N. Tewari, R. Tiwari

Chemical & Biomedical Engineering Faculty Publications

Based on measurements of the specific dendrite surface area (S-nu), fraction of interdendritic liquid (phi), and primary dendrite spacing (lambda(1)) on transverse sections in a range of directionally solidified hypoeutectic Pb-Sb and Pb-Sn alloys that were grown at thermal gradients varying from 10 to 197 K cm(-1) and growth speeds ranging from 2 to 157 mum s(-1), it is observed that S-nu = lambda(1)(-1) S*(-0.33) (3.38 - 3.29 phi + 8.85 phi(2)), where S* = D-l G(eff)/V m(1) C-o (k - 1)/k, with D-l being the solutal diffusivity in the melt, G(eff) being the effective thermal gradient, V being the …

Corrosion And Mass Transport Processes In Carbon Steel Miniature Waste Packages, James Cizdziel, Kaveh Zarrabi, Susan Lestrange, Amy J. Smiecinski

Publications (YM)

In this study, we have systematically investigated corrosion and mass transport processes in carbon steel miniature waste packages (MWP) in dynamic systems (water in, water out) under varying chemical conditions. The MWP were fabricated to have similar configuration to the DOE Spent Nuclear Fuel (SNF) waste package and that individual components to be in scale with each other compare to the SNF waste package. Two MWP configurations were studied: a "bathtub" model and a "flow-through" model. By slowly dripping 4 different solutions (groundwater obtained from well water J-13 located near Yucca Mountain, and J-13 water adjusted to low-pH, high-salinity, and …

Task 32 Delayed Hydride Cracking Of Spent Fuel Cladding Under Repository Conditions, Ajit K. Roy, Anthony Hechanova, Amy J. Smiecinski

Publications (YM)

The objective of this quality-affecting task is to evaluate the susceptibility of spent nuclear fuel cladding materials (zirconium alloys) to stress corrosion cracking (SCC), delayed hydride cracking (DHC) and localized corrosion (pitting/crevice) in simulated repository environments. During the first year of this project, major efforts were focused on developing the infrastructure for performing the desired testing involving two highly corrosion-resistant alloys namely, zircaloy-2 (Zr-2) and zircaloy-4 (Zr-4) in simulated concentrated acidic water (SAW) and modified SAW (SAWM). Modification of the SAW chemistry was done by adding hydrochloric acid (HC1) to achieve lower pH. The construction of the "Materials Performance Laboratory …

On Friction And Surface Cracking During Sliding Of Ice On Ice, Maurine Montagnat, Erland M. Schulson

Dartmouth Scholarship

As a complement to earlier measurements on the friction of both granular fresh-water ice and S2 columnar salt-water ice, new experiments were performed on the friction of S2 columnar fresh-water ice sliding against itself at low velocities (5 × 10−7 to 5 × 10−1 m s−1) and at −10°C, using the same double-shear device as was used earlier. The results showed that under a given set of experimental conditions the kinetic coefficient of friction of S2 fresh-water ice compares favorably with that of the other two variants.The experiments also revealed friction-induced surface cracks and recrystallized grains.These deformation features are explained, …

Effect Of Different Supplementary Cementitious Material On The Microstructure And Its Resistance Against Chloride Penetration Of Concrete, Vinay S. Nikam , Vikram Y. Tambvekar

Advanced Materials for Construction of Bridges, Buildings, and Other Structures III

Various research programes on long term durability of concrete are going on through -out the world. An attempt is made to study the microstructure of the concrete with the addition of different SCM like fly ash, GGBS, metakaolin, silica fume, and rice husk ash. In this paper, data is presented in a simplified manner for the sake of convenience. Hydration is a continuous process and so microstructure of HPC and interfacial zone (ITZ) can change with age and effect of environment by the influencing agents present in it.

Rapid chloride permeability test (RCPT) is carried out on the various samples …

Design Of A Pultruded Gfrp Deck For Highway Bridges, Hyeong-Yeol Kim, Sun-Myung Kim, Yoon-Koog Hwang

Advanced Materials for Construction of Bridges, Buildings, and Other Structures III

This paper deals with the design and analysis of a GFRP deck for the highway bridges. Several cellular tube sections are assessed to obtain a viable cross-sectional profile of the deck. Two GFRP patterns are proposed and tested. Using the proposed deck profile and GFRP patterns, a GFRP deck for a prototype steel I-girder bridge is designed and presented in this paper.

Development Of Space Truss Structure Using Glass Fiber Reinforced Plastics, Hiroya Hagio, Yoshikazu Utsumi, Kohzo Kimura, Koichiro Takahashi, Go Itohiya, Hitoshi Tazawa

Advanced Materials for Construction of Bridges, Buildings, and Other Structures III

This paper describes the development of a space truss structure using Glass Fiber Reinforced Plastic (GFRP) pipe that decreases life cycle cost and enhances construction efficiency. Material tests, structural experiments and FEM analysis verify the practicality of this structural system.

Reliability Analysis On Flexural Behavior Of Frp Bridge Decks, Sang-Mo Jeong, Sang-Jin Kim, Young-Bum Kim, Hyeong-Yeol Kim, Ki-Tae Park

Advanced Materials for Construction of Bridges, Buildings, and Other Structures III

Design codes for the design of FRP bridge decks shall be established to promote the use of such innovative materials. For the purpose of preparing code provisions, reliability analyses were conducted to evaluate proper levels of safety and serviceability. Based on the results, several guidelines on design codes are suggested.

Optimum Design Of A Pultruded Frp Bridge Deck., Hyeong-Yeol Kim, Young-Min Choi, Yoon-Koog Hwang, Hyo-Nam Cho

Advanced Materials for Construction of Bridges, Buildings, and Other Structures III

In this paper, an optimum design of GFRP bridge deck having a pultruded cellular cross-section is presented. The optimization process utilizes a modified genetic algorithm with the index technique. Based on the optimum design, viable cross-sectional dimension, volumes of fibers and matrix, fiber orientation, and stacking sequence for GFRP decks suitable for the pultrusion process are proposed.

The Evolution Of Best Practices With High Performance Steel For Bridges, Edward P. Wasserman, W. Henry Pate, Tim Huff

Advanced Materials for Construction of Bridges, Buildings, and Other Structures III

High Performance Steel, grade 70 (HPS-70W) became available for use in early 1996 for fabrication and testing in bridges. Two (2) states, Nebraska and Tennessee agreed to be the first to implement usage. This paper provides a discussion of 3 Tennessee case histories in which high performance steel has been used to achieve weight and cost economies.

Variable Engagement Model For The Design Of Fibre Reinforced Concrete Structures, Jackie Yen Lei Voo, Stephen J. Foster

Advanced Materials for Construction of Bridges, Buildings, and Other Structures III

In this paper a model is developed to describe the behaviour of randomly orientated discontinuous fibres in reinforced composites subject to uniaxial tension. The model is built by integrating the behaviour of single, randomly oriented, fibres over 3D space and is capable of describing the peak and post-peak response of fibre-cement-based composites in tension. The model is used to form a constitutive law for use in finite element analysis of reactive powder concrete members with a prestressed reactive powder beam failing in shear analysed. A good correlation between the theoretical and experimental results attained.

The Effect Of Aggregate Particle Size On Formation Of Geopolymeric Gel, Christine Isabella , Grant C. Lukey, Hua Xu, Jannie S.J. Van Deventer

Advanced Materials for Construction of Bridges, Buildings, and Other Structures III

Due to enhanced mechanical and chemical properties, geopolymeric materials are a potential alternative to ordinary Portland cement and high-strength cement for the construction industry. The effects of aggregate particle size on the formation and the mechanical properties of geopolymeric materials are investigated in the current work. The addition of soluble silicates to the alkaline activator was found to increase the dissolution of silicate ions from the aggregate into the geopolymer binder phase. The results indicate that the surface area of aggregate influences the strength development of a geopolymer.