Materials Science and Engineering Commons^™

Evaluation Of Unified Interaction Parameter Model Parameters For Calculating Activities Of Ferromanganese Alloys: Mn-Fe-C, Mn-Fe-Si, Mn-C-Si, And Mn-Fe-C-Si Systems, L. I. Hongjie, Arthur E. Morris

Materials Science and Engineering Faculty Research & Creative Works

Interaction parameters for Mn-based alloys were evaluated using both carbon solubility and activity data for species in binary and ternary manganese alloys. The parameters at 1400 °C are the following εcc = -4.5; εccc = 58.8; εFeCC = 1.5; εFeCC = 2.5; In γC0 = -1.15 . εsisi = 15.5; εsisisi = 2.69; εFeSi = 2.5; εcsi = 12.4; εccsi = 27.5; In γSi0 = -7.46 The unified interaction parameter model (UIPM) was used to calculate the activity coefficients of species and the solubility of carbon in ferromanganese alloys (up to quaternary Mn-Fe-C-Si). The results were in good agreement with …

Mechanical And Tribological Properties Of Composites Of Recycled High Density Polyethylene And Recycled Rubber, Jason G. Boulanger

Masters Theses

This thesis presents a study on the mechanical and tribological properties of composite materials of recycled high density polyethylene (HDPE) and recycled rubber tire particles. The materials were compounded by extrusion and formed into test specimens by injection molding.

The first experiment studied the effect of recycled rubber percentage on mechanical properties of composites of recycled HDPE and recycled rubber. The mechanical properties included tensile strength, percent elongation, hardness, and impact resistance. Recycled rubber concentrations of 0, 5, 10, 15, 20, 25, and 30 percent were tested. The second experiment investigated the tribological properties of recycled HDPE and recycled rubber …

Newspaper Recycling And Deinking, Reem Adel Fahmy Baher

Archived Theses and Dissertations

No abstract provided.

Scaling Parallels In The Non-Debye Dielectric Relaxation Of Ionic Glasses And Dipolar Supercooled Liquids, David L. Sidebottom, Peter F. Green, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

We compare the dielectric response of ionic glasses and dipolar liquids near the glass transition. Our work is divided into two parts. In the first section we examine ionic glasses and the two prominent approaches to analyzing the dielectric response. The conductivity of ion-conducting glasses displays a power law dispersion σ(ω)∞ωn, where n≈0.67, but frequently the dielectric response is analyzed using the electrical modulus M*(ω) = 1/ε*(ω), where ε*(ω) = ε(ω) - iσ(ω)/ω is the complex permittivity. We reexamine two specific examples where the shape of M*(ω) changes in response to changes in (a) temperature and (b) ion concentration, to …

Ferroelectric Films As A Fashion Object For Polycrystalline Film Investigation, V. Petrovsky, Harlan U. Anderson, M. Shumsky

Materials Science and Engineering Faculty Research & Creative Works

BaxSr1-xTiO3 (BST), PbZrxTi1-xO3 (PZT) and two-layer PZT-BST films were prepared on Pt, Si(100) and Si(111) substrates by a sol-gel method. XRD analysis shows that the PZT films on the Si(111) substrates tended to be preferentially oriented in the (110) direction. The nondestructive readout of the state of ferroelectric polarization was investigated by three methods: the pyroelectric effect, the non-linearity of the capacitance and the field effect in MOS structures. It is shown that all three methods provide nondestructive readout, and the choice between them depends on the intended use.

Chemical Durability Of Lead-Oxide-Based, Thick-Film Binder Glasses, Douglas M. Mattox, Joshua H. Robinson

Materials Science and Engineering Faculty Research & Creative Works

Lead-oxide-bearing glasses are incompatible with aluminum nitride metallization's, and federal legislation is recommending their replacement in thick-film electronics and labeling. To evaluate alternatives, the benchmark chemical durability's of the lead borosilicate and lead aluminate thick-film binder glasses have been determined. Aluminum oxide (Al2O3) benefits water durability moderately, acid durability substantially, and basic durability indistinguishably. The rate of attack in water is approximately two orders of magnitude greater than for soda-lime glass. The thermal contractions of the glasses are compatible. An apparent, spontaneous phase separation in the Al2O3-free glass is suppressed by Al2O3 that is included as a batch component.

Optical And Electrical Properties Of Cualse² Thin Films Obtained By Selenization Of Cu/Al/Cu... Al/Cu Layers Sequentially Deposited, J. C. Bernède, S. Marsillac, C. El Moctar, A. Conan

Electrical & Computer Engineering Faculty Publications

Optical and electrical properties of CuAlSe₂ thin films obtained by selenization of Cu/Al/Cu...Al/Cu layers sequentially deposited have been investigated. It is shown that the expected energy gap (2.67 eV) is measured for well crystallized films, whereas a slightly higher value is measured for films not so well crystallized. Raman diffusion also shows differences between well and poorly crystallized films with peaks corresponding to the reference powder for the former samples. A p-type conductivity is found whatever the crystalline quality of the samples. The conductivity of the films depends also strongly on their crystalline properties. When the films are badly …

Cualse² Thin Films Obtained By Chalcogenization, S. Marsillac, K. Benchouk, C. El Moctar, J. C. Bernède, J. Pouzet, A Khellil, M. Jamali

Electrical & Computer Engineering Faculty Publications

CuAlSe₂ thin films have been synthesized by chalcogenization of thin Cu and Al layers sequentially deposited by evaporation under vacuum. It is shown that CuAlSe₂ films are obtained with some Cu₂-_δSe and Se phases present at the surface. These surface phases are suppressed by annealing under vacuum and by chemical etching in a KCN solution. At the end of the process, the XRD spectrum demonstrates that textured CuAlSe₂ films have been obtained with preferential orientation of the crystallites along the (112) direction. The gap of the films is 2.7 eV as expected. The …

Immobilization Of Radioactive Materials In Iron Phosphate Glass, Melissa G. Mesko

Doctoral Dissertations

"The current study investigates the feasibility of using iron phosphate glass for the immobilization of radioactive wastes considered incompatible with borosilicate glass. Wastes may be incompatible with borosilicate glass due to high phosphorus content (Hanford tank sludges), the presence of halides (CsCl and SrF₂ capsules), or large amounts of uranium (SNF).

Between 20 and 60 wt% Hanford tank sludge was vitrified with an iron phosphate glass at ≤ 1200°C in 1 hour. The chemical durability of iron phosphate glassy wasteforms was as good as, or better than a reference borosilicate glass (10^-9 g/cm²/min) in distilled water …

An Investigation On The Effect Of Aging And Fatigue Damage On The Mechanical Properties Of A Graphite/Bismaleimide Composite, William M. Johnston Jr.

Mechanical & Aerospace Engineering Theses & Dissertations

This investigation utilizes the open hole tension (OHT) specimen loaded in tension-tension fatigue under isothermal, fixed frequency conditions. A range of load levels and temperature levels where chosen to assess performance. These loads and temperatures ranged from relatively benign conditions (low stress, room temperature) up through aggressive conditions (high stress, high temperature). Measurements of stiffness, damage accumulation, residual strength, weight loss, and glass transition temperature (Tg) were made. Results from this work will help explain the roles of aging, load and fatigue in the performance of elevated temperature OHT specimens as well as provide insights to the individual and synergistic …

The Use Of Solid Waste Materials As Alternative Compositions In The Development Of Wood/Cement Blocks, Haig Mamas Vahradian

Dissertations and Theses @ UNI

As the population of the planet Earth increases, the need for affordable housing becomes a paramount issue in construction. This need is further complicated by the rising cost of basic building materials due to the depletion of natural resources throughout the world. These problems have caused the construction industry to refocus its attention on the elimination of waste through a comprehensive strategy to: (a) reclaim and recycle these resources into usable materials, and (b) develop products and markets in construction for recycled materials through research and testing to prove their integrity.

The purpose of this study is to determine the …