Materials Science and Engineering Commons^™

Simultaneous Heat And Mass Transfer To A Liquid Through Two Separated Interfaces, Ku-Il Park

Theses

The oxygenator is the main element of a heart-lung machine, which takes over the work of the lungs (adding oxygen to and removing carbon dioxide from the blood) during an operation. Oxygenators function by passing oxygen through a hollow fiber (straw-like fiber), where blood gases are exchanged via tiny pores in the fiber walls. In this study, a fiber-in-fiber technology was used to design a temperature controlled blood oxygenator membrane module. A Celgard® X-10 hollow fiber was put through the lumen of a polypropylene hollow fiber having a solid wall. Both fibers are made of polypropylene and are waterproof due …

Preparation And Characterization Of Thermally Stabilized Ceria And Ceria Containing Materials, Leena Ali Rashid Al-Kaabi

Theses

Ceria, CeO₂, is one of the most important catalytic materials that can play multiple roles owing to its ability to release and uptake oxygen under catalytic reaction conditions with the preservation of it fluorite structure. Textural and thermal stability is a critical issue in determining the promoting and metal supporting functions of CeO₂ in its catalytic applications in the three way catalysis. Therefore, significant efforts have been made by industry on finding ways to improve the thermal stability of ceria both by modification of the synthesis of CeO₂ and by looking at possible stabilizers.

In the …

Material Selection For A Composite Hip Joint, Ahmed Abdullah Ali Al-Hosani

Theses

The use of biomaterials in orthopedic surgery has been successfully acceptable in the current medical practice. Total hip joint replacement (THR) is one of the most popular and successful operations in orthopedics. Total hip replacement (THR) has been using metal prosthesis for many years. However, the use of metal implants has two major disadvantages. The first disadvantage is that the stiffness of the metallic prosthesis is relatively high compared to the surrounding, load carrying bone. The elastic moduli of titanium and cobalt-chromium alloy are 110 and 210 GPa, respectively. Whereas the elastic modulus of cortical bone ranges from 15 to …

The Role Of The Solid Substrate On The Spreading Kinetics Of A Liquid Droplet, Bashar Jalal Sasa

Theses

Classic hydrodynamic wetting theory leads to a linear relationship between spreading speed and the capillary force, being determined only by the surface tension of the liquid and its viscosity.

The theory appears in good agreement with results generated from experiments conducted on the spreading of Polydimethylsiloxanes (PDMS) on soda-lime glass substrate and fails to account for the behavior of other liquids. This thesis examines the role played by the solid substrate on the spreading kinetics of liquid droplets. The set of experiments whose results are presented below used different types of liquids with various properties of surface tension and viscosity …

Design Of Asphalt Concrete Mixtures For Pavement Maintenance And Rehabilitation, Mubarak Bakheet Gaith Al-Falahi

Theses

The main objective of the thesis is to develop a knowledge base for the design of asphalt concrete mixtures suiting various types and causes of pavement distress and to develop supporting guidelines for the selection of aggregate types, gradation and binder contents for desirable mixture properties.

To achieve this objective, a two-level model was developed. The upper-level is a Factorial Experimental Design Model (FEDM) for the pavement condition evaluation. It can be used as a prediction tool to estimate the Pavement Condition Index (PCI), and determine the percentages of the types of distresses (Load, Environmental, Others). The upper-level model was …

Assessment Of The Performance Of Shape Memory Alloys As Implant Devices, Noura Ali Al-Khalifi

Theses

Shape memory alloys are one class of the family of smart materials. They are considered as biomaterials, since they are well accepted by the human body. One special feature of shape memory alloys (SMA) is their ability to revert to their previous shape. This material is deformed at low temperature and when it is heated, it returns (remember) to its original form. Although, the implant binary NiTi SMA is particularly successful as a biomaterial, our NiTi SMA consist of more that 50% (55.7%) of nickel. The main purpose of this thesis was to evaluate the biological response of the shape …

The Effectiveness Of Sacp In Controlling Of Concrete Steel Reinforcement In Aggressive Environments, Hassan Ali Abubaker Al Jafri

Theses

The Arabian Gulf is considered to be one of the world's most aggressive environments for reinforced concrete. Traditional methods of corrosion protection may not be enough to provide the required level of corrosion control for the design life of concrete structures in such environments.

Cathodic protection has been found as a viable technique of inhibiting chloride induced corrosion of steel in concrete structures. As an alternative to impressed current cathodic protection ICCP a remarkable developments recently have been made in the application of sacrificial anode cathodic protection as a means of enhancing the performance of patch repair.

The main objective …

Paints And Their Environmental Impacts On Human Health In The U.A.E, Masara Y. Al-Ameri

Theses

This thesis records the findings of a research program related to "Paints and Their Environmental Impacts on Human Health in the U.A.E". The study recommends attempt to find out what paint types are of a less harmful influence on human health within different building types in United Arab Emirates due to environmental conditions.

According to Larry W. Canter (1997) "Environmental Impact Assessment" can be defined as "the systematic identification and evaluation of the potential impact (effects) of proposed projects, plans, programs, or legislative actions relative to the physical- chemical, biological, cultural, and socioeconomic components of the total environment. The primary …

Process-Structure-Property Relationship Of A Mesogenic Bioerodible Polyarylate, Seung Uk Yoo

Theses

Polymeric biomaterials are artificially synthesized polymers designed for in-vivo use. The material must be characterized and should satisfy the requirements suitable in human bodies.

For the proper characterization of materials, it is essential to apply specific processes, analyze thermal and mechanical properties, and understand the process effect and the morphology. Thermal analysis is one of the most sophisticated and well developed techniques for polymer characterization. Turi [ 1 ] has explained about the thermal characterization of polymeric materials. Jaffe et al [2], in the chapters of characterization of fibers and films, emphasized the effect of the process history of a …

In Situ Laser Etch-Depth Monitoring Of The Deep Reactive Ion Etching Process, Yuki Imura

Theses

A laser-based method for measuring feature thickness during the deep reactive ion etching process is investigated. Interference occurs between laser beam reflections from the mask surface, the mask/silicon interface, and the exposed silicon surface of a process wafer. Information from this interference signal allows the etch process to be characterized. Three methods are investigated: laser-on-SiO₂, laser-on-photoresist, and laser-on-both SiO₂ and silicon at a mask edge.

The measured data from these experiments are found to be in good agreement with theoretical calculations. Differences in reflected beam amplitude and interference fringe frequency represent well the differences SiO₂ and …

Characterization And Corrosion Of Bcc-Tantalum Coating Deposited On Aluminum And Steel Substrate By Dc Magnetron Sputtering, Chirag Joshi

Theses

Tantalum is one of the most versatile highly refractory corrosion-resistant metals. Tantalum coating can be used as an effective corrosion barrier if it is continuous, free from defects and it adheres well to the substrate. A DC magnetron sputtering technique was used to deposit tantalum on aluminum and steel. X-ray diffraction measurements revealed that the tantalum films produced by sputtering had two crystallographic structures: a body centered cubic α-phase and a metastable tetragonal β-phase. Tough and ductile alpha phase tantalum is preferred over the hard and brittle beta phase tantalum, as a protective coating. Alpha phase coatings were successfully deposited …

Thermal Assessment Of Silicon-Based Composite Materials Used In Photovoltaics, Pavlos K. Bataglannis

Theses

Photovoltaics are devices that convert sunlight directly to electricity. It is well established that the conversion efficiency of mono and poly-crystalline silicon-based photovoltaic modules is inversely related to their temperature. Substantial improvements in operational performance can thus be achieved if the thermal energy accumulating in the material can be effectively dissipated.

Accurate modelling of modules would allow possible methods of thermal dissipation to be evaluated, and as a crucial component of the model, the thermal properties of the constituent materials of PV modules needed to be known. Special consideration needed to be given to the interfaces between dissimilar materials and …

Electrical Properties Of Ultra Thin Al2o3 And Hfo2 Films As Gate Dielectrics In Mos Technology, Vishal R. Mehta

Theses

The rapidly evolving silicon industry demands devices with high-speed and low power consumption. This has led to aggressive scaling of the dimensions in metal oxide semiconductor field effect transistors (MOSFETs). The channel length has been reduced as a result of this scaling. The industry favorite, SlO₂, has reached limitations in the thickness regime of 1-1.5 nm as a gate dielectric. High-_κ gate dielectrics such as Al₂0₃ and HfO₂ and their silicates are some of the materials that may, probably, replace SlO₂, as gate dielectric in the next four to five years. …

Formation And Characterization Of N/P Shallow Junctions In Sub-Micron Mosfets, Sridhar Madishetty

Theses

Semiconductors are the burgeoning industries in today's information age. Silicon based microelectronic devices are shrinking day-by-day in accord with the scaling dimensions reported by the International Technology Roadmap for Semiconductors (ITRS). There have been many semiconductor models and simulation programs constantly keeping pace with the continuously evolving scaling dimensions, process technology, performance and cost. Electrical characterization plays a vital role in determining the electrical properties of materials and device structures. Silicon based Metal Oxide Semiconductor Field Effect Transistor (MOSFET) forms the basis of Complimentary Metal Oxide Semiconductor (CMOS) circuits. Today's aggressive scaling approaches in silicon Integrated Circuit (IC) technology require …

Crystallographic Structure And Mechanical Properties Of Tantalum Coatings On Steel Deposited By Dc Magnetron Sputtering, Charanjeet Singh Paur

Theses

Tantalum metal exhibits excellent erosion and corrosion resistance property. Hence, tantalum coatings are investigated for protection of steel surface exposed to mechanical stresses, high temperature, and corrosive environment. Such conditions exist inside large army gun barrels. The goal of this work was to contribute to the development of technology for tantalum coating of steel, which would replace the presently used electrochemical chromium deposition. A DC magnetron sputtering process was used to deposit tantalum coatings on steel substrates. In sputtering, tantalum is deposited in two phases: ductile, body-centered cubic (bcc) phase (a-phase) and a metastable, brittle tetragonal ß-phase. Only a-phase of …

Formation & Characterization Of P/N Shallow Junctions In Sub-Micron Mosfets, Samrat G. Chawda

Theses

The formation of shallow junctions in the source and drain regions is a major challenge to the continued success of scaling of complementary metal oxide semiconductors (CMOS) circuits. The formation of these device structures requires low-energy ion implantation and rapid thermal annealing (RTA). One of the processes which has been shown to be advantageous is spike annealing, with fast ramping and short dwell time at maximum temperature. This work is a study of the effects of implant energy, implant dose and annealing cycles on the reverse-bias leakage current in the diode junction. The reversebias leakage is the study of junction …

Crystallization Kinetics, Structural Parameters And Optical Properties Of Some Semiconducting Oxide Glasses Doped With Rare Earth And Transition Metal Ions, Khawlah Mohammad Ahmad Al-Yahyaei

Theses

No abstract provided.

Synthesis, Characterization And Applications Of Some Conducting Polymers, Fatma Yousif Mohamed Balhey

Theses

Conducting polymers emerged as a new class of materials by the end of the sixties. Since then many efforts have been made to put these materials to

industrial use. Among the achievements are their applications in the semiconductor industry, medical field, chemical and biological sensors, etc. A

different track that alleviated the prospects of the application of conducting

polymers is the modification of the polymer film, namely through the inclusion of metallic moieties for specific target usage. In this thesis the candidate aimed

to synthesis well established and extensively studied class of electrically conductive polymer, 3-methylthiophene. The polymer was then …

Investigation Of The Electronic And Optical Properties Of The Strained Cdte/Znte (001) Superlattices, Amna Abdulla Ahmed Al-Zarouni

Theses

Semiconductors are distinguished among all materials by having a non-vanishing energy band gaps. They are often used in industry in the form of alloys or heterostructures in order to tailor energy gaps suitable for the desired applications. In general, semiconductor materials have broad applications in industry, ranging from micro-electronic devices, to light emitters and detectors, to laser and solar cells. In the last two decades, particular attention has been given to the II-VI semiconductor heterostructures because of their suitability as photoelectronic devices covering from the infra-red to the ultra-violet spectral ranges. The scope of this thesis belongs to the field …

Characterization Of Alpha And Beta Phases Of Tantalum Coatings, Anto Yohannan

Theses

Sputtered tantalum forms two phases - α and β. The α and β phases have distinctly different crystalline structures and properties. The structure and the causes of formation of the β phase are still being studied by researchers. This is a study to distinguish and characterize these two phases. Samples from Bennet Labs and NJIT were characterized using techniques such as SEM, EDX, XRF, XRD, TEM and XAFS. Samples deposited at NJIT were used for an experimental study on the conditions favoring the formation of the phases, by depositing tantalum on heated steel and silicon substrates, additionally TEM analysis was …

Assessment Of The Recycled Concrete Aggregates Structural Suitability For Road Construction, Abdulla Yousef Ali Al-Ali

Theses

In most aspects of modem life, there is a consensus among practitioners and decision makers of the importance of preserving the environment, and to find alternatives to the scarce natural materials. This can be accomplished by better utilization of the natural materials and/or recycling or reclaiming their waste, specially, if they are of finite resources. The recycled material could be an attractive alternative (both environmentally and economically) if its characteristics are proven to be close to those of the natural material.

Utilizing recycled mineral aggregates in the construction field in general and in highway pavement in specific is somehow governed …

Evaluation Of Some Organic Inhibitors For Stainless Steel Corrosion Using Different Electrochemical And Surface Techniques, Maryam Hassan Saeed Al-Hassan

Theses

Stainless steels have been extensively used in automotive, industrial, electronics, etc., applications. Iron (Fe) and chromium (Cr) are the main elements with weight percentage contribution of 60-75% and 10-25% respectively. Other elements, such as Ni, Co, Mo, Mn, C etc. are also present with variable concentrations. The purpose of this work is to use different electrochemical and surface techniques to study the corrosion behavior of stainless steel type 316 (percent composition of different chemical elements are listed in table 1) in acid media in presence and absence of different thiophene derivatives (list of inhibitors in figure 1). Moreover, other important …

Impedance And Photo-Electrochemical Properties Of Oxide Films On Stainless Steel Formed By Different Polarization Techniques, Mona Salim Saleh Ai Kaabi

Theses

Stainless steel alloys have a very active and important role in industry. Because many of

These industries have to work in aggressive media; stainless steels are threatened by corrosion

Which may affect their performance and cost the manufacturers millions of dollars yearly.

Several treatments have been taken part to solve this problem; one is by forming a protective

Oxide layer on the stainless steel (SS) surface to prevent it from corrosion. In this thesis; this way of protecting SS Surface is applied to two different types of Stainless Steel, those are AISI 316 and AISI 31 0; respectively. The oxide …

Deposition Of Tantalum On Steel By Sputtering, Bhavin Shah

Theses

Recent interest in tantalum deposition comes from two different applications. One is in microelectronics where thin tantalum films (< 1 µm) are used as diffusion barrier layers for copper interconnects. The other involves its application as a material for corrosion and wear resistant coating on surfaces that are subjected to high stresses and harsh chemical and erosive environments.

This thesis is a part of the investigation done at the Ion Beam and Thin Film Research Laboratory at NJIT to study the deposition conditions and properties of tantalum thin films. It includes the design and construction of Planar D.C. Magnetron Sputtering System and Cylindrical D.C. Magnetron Sputtering System for deposition on the planar and cylindrical surfaces of steel, respectively. The electrical characteristics of the cylindrical system were tested in a range of pressures and conditions for initiation and maintaining of …

Dynamics Of Pancake Vortices In A Finite Stack Of Superconducting Copper Oxide Layers, Mariam Mustafa Ahmad Al Marzoqi

Theses

The high temperature superconductors are very promising materials in a wide range of applications, starting from the electricity power supply. They play a lifesaving function through imaging systems. Even major internet and communication advances depend on these materials.

Superconductivity in these materials occurs particularly in the copper-oxide planes. However, since these materials are type-II superconductors, magnetic fields can penetrate these materials in quantized amounts of flux called vortices without destroying completely superconductivity, but producing some resistance, due to vortex motion. In order to overcome the resistance problem, vortices must be pinned to prevent their motion and hence eliminate the resistance. …

Preparation And Properties Of Tantalum Silicide Films On Silicon Substrates, Lei Jin

Theses

Tantalum silicide (TaSi₂) thin films were sputter deposited on p- type and n- type silicon substrates using VARIAN 3125 magnetron DC sputtering system with TaSi₂ target. The thicknesses of TaSi₂ thin films considered in this study are 200Å, 600Å and 1000Å, respectively. The TaSi₂/Si wafers were annealed at temperatures in the range of 400 to 900°T. The sheet resistances of TaSi₂ thin films with various thicknesses were measured by four-point probe before and after annealing. The sheet resistance decreases with increase in annealing temperature and decreases with the increase in thickness of TaSi …

Nanoporous Sio2/Vycor Membranes For Air Separation, Mihir Tungare

Theses

Porous Vycor tubes with 40Å initial pore diameter were modified using low pressure chemical vapor deposition (LPCVD) of silicon dioxide N0₂). Diethylsilane (DES) in conjunction with nitrous oxide (N₂O) was used as a precursor to synthesize these SiO₂ films. The aim of this study was to obtain a considerable selectivity between species of comparable size and hence N₂O was used. The use of N₂O was believed to make the process self-limiting. DES was allowed to flow through the tube and N₂O on the outside in the chamber at 550°C …

Characterization Of Tantalum Coatings On Steel Substrates, Prabha Shivaramkrishnan

Theses

Sputtered tantalum can be used as an effective corrosion resistant barrier if the coating is continuous, free from defects and is adherent to the substrate it is intended to protect. For corrosion-applications 100% bcc phase tantalum is preferred. X-ray diffraction results indicate that sputtered tantalum deposits typically contain a mixture of bcc and beta phases. Depending on the deposition conditions the morphology of tantalum coatings as studied using scanning electron microscopes can vary from irregular, dendritic structure to a defined step type structure. A "cauliflower type" structure has also been observed. Extended x-ray absorption fine structure measurement was used to …

Synthesis And Characterization Of Silicon Dioxide Films Using Diethyl Silane And Oxygen, Kiran Kumar

Theses

This study focuses on producing thin and thick silicon dioxide films towards the fabrication of integrated optical sensor capable of monitoring and determining in-situ, the concentration of numerous analyze species simultaneously. In this study, diethylsilane (DES) has been used as a precursor to produce silicon dioxide films by low pressure chemical vapor deposition. The films were synthesized with two different flow ratios of oxygen to DES in the temperature range of 550°C to 800°C at a constant pressure of 200mTorr. The films deposited with lower oxygen to DES flow ratio have very high growth rate but suffer from high tensile …

Plasma Enhanced Chemical Vapor Deposition Of Diamondlike Carbon Films Using Acetylene, Sriram Vishwanathan

Theses

This study is focussed on the synthesis and characterization of diamondlike carbon (DLQ films deposited on silicon wafers and glass by plasma enhanced chemical vapor deposition (PECVD), using acetylene (C₂H₄) as a precursor. The process parameters, such as temperature, pressure, power and reactant gas flow rate have been systematically varied and their effects on the film growth rate and properties were investigated. The optimized deposition condition appeared to be at 150°C, 200mTorr, 200 Watts and flow rate = 25 sccm. For these conditions, the films were hard and found to have good adhesion to the substrate, …