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Materials Science and Engineering Faculty Research & Creative Works

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Full-Text Articles in Materials Science and Engineering

Elevated Temperature Microstructure Stability Of Slm 304l Stainless Steel, Tarak Amine, Joseph William Newkirk Aug 2016

Elevated Temperature Microstructure Stability Of Slm 304l Stainless Steel, Tarak Amine, Joseph William Newkirk

Materials Science and Engineering Faculty Research & Creative Works

With time at temperature, changes in metallurgical structure can be expected for almost any steel or alloy. In stainless steels, the changes can be grain growth, carbide precipitation, ferrite decomposition, or embrittlement. These phenomena can significantly effect the properties of the steel and would potentially change the functionality of the component. Therefore, to determine component stability, the elevated temperature microstructure stability of additive manufacturing materials was studied. This work investigates the influence of different aging times of additive material stainless steels (304L) fabricated with the Selective Laser Melting (SLM) process on microstructure and mechanical properties. Microstructure and mechanical properties were …

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Simulation Of Cooling Rate Effects On Ti-48al-2cr-2nb Crack Formation In Direct Laser Deposition, Lei Yan, Wei Li, Xueyang Chen, Yunlu Zhang, Joseph William Newkirk, Frank W. Liou, David Dietrich Aug 2016

Simulation Of Cooling Rate Effects On Ti-48al-2cr-2nb Crack Formation In Direct Laser Deposition, Lei Yan, Wei Li, Xueyang Chen, Yunlu Zhang, Joseph William Newkirk, Frank W. Liou, David Dietrich

Materials Science and Engineering Faculty Research & Creative Works

Transient temperature history is vital in direct laser deposition (DLD) because it reveals the cooling rate at specific temperatures, which directly relates to phase transformation and types of microstructure formed in deposit. FEA simulation was employed to study the transient temperature history and cooling rate at different experimental setups in Ti-48Al-2Cr-2Nb DLD process. In this paper, an innovative model was described, which combines a moving Gaussian distribution heat source and element birth and death technology in ANSYS, help to analysis cooling rate control method and guide crack-free deposits build process.

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Preface To The Special Issue On Advanced Microstructural Characterization Of Materials, Haiming Wen Aug 2016

Preface To The Special Issue On Advanced Microstructural Characterization Of Materials, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Microstructural characterization is a vital part in materials science, as it plays a key role in understanding the structure-property relationship in materials. Various advanced microstructural characterization techniques have emerged, for example, scanning electron microscopy, transmission electron microscopy, scanning transmission electron microscopy, high resolution (scanning) transmission electron microscopy, electron backscatter diffraction, energy dispersive x-ray spectroscopy, electron energy loss spectroscopy, precession electron diffraction, energy-filtered transmission electron microscopy, and atom probe tomography. The applications of these techniques have greatly advanced the understanding of material microstructures on different scales from micrometer to atomic scale. Advanced microstructural characterization can be applied to a variety of …

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Stability Of The M2 Phase Of Vanadium Dioxide Induced By Coherent Epitaxial Strain, N. F. Quackenbush, Yijia Gu, For Full List Of Authors, See Publisher's Website. Aug 2016

Stability Of The M2 Phase Of Vanadium Dioxide Induced By Coherent Epitaxial Strain, N. F. Quackenbush, Yijia Gu, For Full List Of Authors, See Publisher's Website.

Materials Science and Engineering Faculty Research & Creative Works

Tensile strain along the cR axis in epitaxial VO2 films raises the temperature of the metal insulator transition and is expected to stabilize the intermediate monoclinic M2 phase. We employ surface-sensitive x-ray spectroscopy to distinguish from the TiO2 substrate and identify the phases of VO2 as a function of temperature in epitaxial VO2/TiO2 thin films with well-defined biaxial strain. Although qualitatively similar to our Landau-Ginzburg theory predicted phase diagrams, the M2 phase is stabilized by nearly an order of magnitude more strain than expected for the measured temperature window. Our results reveal that the …

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A Dissolution-Precipitation Mechanism Is At The Origin Of Concrete Creep In Moist Environments, Isabella Pignatelli, Aditya Kumar, R. Alizadeh, Yann Le Pape, Mathieu Bauchy, Gaurav Sant Aug 2016

A Dissolution-Precipitation Mechanism Is At The Origin Of Concrete Creep In Moist Environments, Isabella Pignatelli, Aditya Kumar, R. Alizadeh, Yann Le Pape, Mathieu Bauchy, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

Long-term creep (i.e., deformation under sustained load) is a significant material response that needs to be accounted for in concrete structural design. However, the nature and origin of concrete creep remain poorly understood and controversial. Here, we propose that concrete creep at relative humidity ≥ 50%, but fixed moisture content (i.e., basic creep), arises from a dissolution-precipitation mechanism, active at nanoscale grain contacts, as has been extensively observed in a geological context, e.g., when rocks are exposed to sustained loads, in liquid-bearing environments. Based on micro-indentation and vertical scanning interferometry data and molecular dynamics simulations carried out on calcium-silicate-hydrate (C-S-H), …

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Management Of A Sever Degloving Foot Injury: A Rare Presentation Of Food Injury In Emergency Department, Ugur Lok, Hasan Buyukaslan, Umut Gulacti, Fatih Dogan, Irfan Aydin Apr 2016

Management Of A Sever Degloving Foot Injury: A Rare Presentation Of Food Injury In Emergency Department, Ugur Lok, Hasan Buyukaslan, Umut Gulacti, Fatih Dogan, Irfan Aydin

Materials Science and Engineering Faculty Research & Creative Works

Occupational crash injuries of the foot present a significant reconstructive challenge due to the superficial location of structures such as tendon, joint and neurovascular network essential for proper acceptance of weight bearing and shear forces associated with bipedal gait. We discussed here a rare case in which an extensive degloving injury of the foot and combined with knee traumatic dislocation and proximal fibula tip fracture that underwent amputation. The authors suggested that none of treatment modalities of degloving are entirely satisfactory, so that each case must be considered independently with cons and pros

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The Anisotropy Of Hexagonal Close-Packed And Liquid Interface Free Energy Using Molecular Dynamics Simulations Based On Modified Embedded-Atom Method, Ebrahim Asadi, Mohsen Asle Zaeem Apr 2016

The Anisotropy Of Hexagonal Close-Packed And Liquid Interface Free Energy Using Molecular Dynamics Simulations Based On Modified Embedded-Atom Method, Ebrahim Asadi, Mohsen Asle Zaeem

Materials Science and Engineering Faculty Research & Creative Works

This work aims to comprehensively study the anisotropy of the hexagonal close-packed (HCP)-liquid interface free energy using molecular dynamics (MD) simulations based on the modified-embedded atom method (MEAM). As a case study, all the simulations are performed for Magnesium (Mg). The solid-liquid coexisting approach is used to accurately calculate the melting point and melting properties. Then, the capillary fluctuation method (CFM) is used to determine the HCP-liquid interface free energy (γ) and anisotropy parameters. In CFM, a continuous order parameter is employed to accurately locate the HCP-liquid interface location, and the HCP symmetry-adapted spherical harmonics are used to expand γ …

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Ceramic-Ceramic Welds, Greg Hilmas, William Fahrenholtz, Jeremy Lee Watts, Derek Scott King, Sean Landwehr Mar 2016

Ceramic-Ceramic Welds, Greg Hilmas, William Fahrenholtz, Jeremy Lee Watts, Derek Scott King, Sean Landwehr

Materials Science and Engineering Faculty Research & Creative Works

A method of producing a ceramic weld, including identifying a ceramic first surface an a ceramic second surface to he bonded together, maintaining a non-oxidizing atmosphere over the first and second surfaces, and engaging the first and second surfaces to define a joint, An arc is generated between an electrode and the joint to create a liquid phase, and the liquid phase is cooled to yield a solid fusion layer, wherein the first and second surfaces are joined in the fusion layer.

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Glass Derived Nanoparticles For Nerve Tissue Repair, D. E. Day, Ali Mohammadkah, Amy Beth Harkins, Laura Marquardt Mar 2016

Glass Derived Nanoparticles For Nerve Tissue Repair, D. E. Day, Ali Mohammadkah, Amy Beth Harkins, Laura Marquardt

Materials Science and Engineering Faculty Research & Creative Works

A biocompatible, biodegradable composite material, and method of using nanoparticles formed within the composite material for nerve repair are disclosed. The nanoparticles may not be formed until the glass degrades upon contact with a fluid in vivo or in vitro.

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Erratum: "Composition- And Pressure-Induced Ferroelectric To Antiferroelectric Phase Transitions In Sm-Doped Bifeo₃ System" [Appl. Phys. Lett. 106, 012903 (2015)], Fei Xue, Linyun Liang, Yijia Gu, Ichiro Takeuchi, Sergei V. Kalinin, Long-Qing Chen Feb 2016

Erratum: "Composition- And Pressure-Induced Ferroelectric To Antiferroelectric Phase Transitions In Sm-Doped Bifeo₃ System" [Appl. Phys. Lett. 106, 012903 (2015)], Fei Xue, Linyun Liang, Yijia Gu, Ichiro Takeuchi, Sergei V. Kalinin, Long-Qing Chen

Materials Science and Engineering Faculty Research & Creative Works

In the acknowledgement of the original article, the Award No. DMR-0820404 should be replaced by DMR-1420620.

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Erratum: Orientations Of Low-Energy Domain Walls In Perovskites With Oxygen Octahedral Tilts (Physical Review B - Condensed Matter And Materials Physics (2014) 90 (220101)), Fei Xue, Yijia Gu, Linyun Liang, Yi Wang, Long-Qing Chen Feb 2016

Erratum: Orientations Of Low-Energy Domain Walls In Perovskites With Oxygen Octahedral Tilts (Physical Review B - Condensed Matter And Materials Physics (2014) 90 (220101)), Fei Xue, Yijia Gu, Linyun Liang, Yi Wang, Long-Qing Chen

Materials Science and Engineering Faculty Research & Creative Works

In the Acknowledgment of the original article, the Award No. DMR-0820404 should be replaced by DMR-1420620.

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Coupled Crystal Orientation-Size Effects On The Strength Of Nano Crystals, Rui Yuan, Irene J. Beyerlein, Caizhi Zhou Jan 2016

Coupled Crystal Orientation-Size Effects On The Strength Of Nano Crystals, Rui Yuan, Irene J. Beyerlein, Caizhi Zhou

Materials Science and Engineering Faculty Research & Creative Works

We study the combined effects of grain size and texture on the strength of nanocrystalline copper (Cu) and nickel (Ni) using a crystal-plasticity based mechanics model. Within the model, slip occurs in discrete slip events exclusively by individual dislocations emitted statistically from the grain boundaries. We show that a Hall-Petch relationship emerges in both initially texture and non-textured materials and our values are in agreement with experimental measurements from numerous studies. We find that the Hall-Petch slope increases with texture strength, indicating that preferred orientations intensify the enhancements in strength that accompany grain size reductions. These findings reveal that texture …

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Refractive Index And Thermo-Optic Coefficients Of Ge-As-Se Chalcogenide Glasses, Benn Gleason, Kathleen Richardson, Laura Sisken, Charmayne Smith (Lonergan) Jan 2016

Refractive Index And Thermo-Optic Coefficients Of Ge-As-Se Chalcogenide Glasses, Benn Gleason, Kathleen Richardson, Laura Sisken, Charmayne Smith (Lonergan)

Materials Science and Engineering Faculty Research & Creative Works

Seventeen glasses in the Ge-As-Se ternary glass-forming region have been fabricated and analyzed to provide input for optical design data and to establish composition- and structure-based relationships to aide development of novel chalcogenide glasses with tailored optical functionality. While known that Ge addition to binary As-Se glasses enhances the mean coordination number (MCN) of the network and results in increased Tg and decreased CTE, this work highlights the impact on optical properties, specifically mid-wave (λ = 4.515 μm) index and thermo-optic coefficient (dn/dT). Trends in property changes were correlated with an excess or deficiency of chalcogen content in the glassy …

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Antibody Targeting Facilitates Effective Intratumoral Sirna Nanoparticle Delivery To Her2-Overexpressing Cancer Cells, Maria C. Palanca-Wessels, Garrett Booth, Anthony J. Convertine, Brittany B. Lundy, Geoffrey Y. Berguig, Michael F. Press, Patrick S. Stayton, Oliver W. Press Jan 2016

Antibody Targeting Facilitates Effective Intratumoral Sirna Nanoparticle Delivery To Her2-Overexpressing Cancer Cells, Maria C. Palanca-Wessels, Garrett Booth, Anthony J. Convertine, Brittany B. Lundy, Geoffrey Y. Berguig, Michael F. Press, Patrick S. Stayton, Oliver W. Press

Materials Science and Engineering Faculty Research & Creative Works

The therapeutic potential of RNA interference (RNAi) has been limited by inefficient delivery of short interfering RNA (siRNA). Tumor-specific recognition can be effectively achieved by antibodies directed against highly expressed cancer cell surface receptors. We investigated the utility of linking an internalizing streptavidinconjugated HER2 antibody to an endosome-disruptive biotinylated polymeric nanocarrier to improve the functional cytoplasmic delivery of siRNA in breast and ovarian cancer cells in vitro and in an intraperitoneal ovarian cancer xenograft model in vivo, yielding an 80% reduction of target mRNA and protein levels with sustained repression for at least 96 hours. RNAi-mediated site specific cleavage …

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Direct Experimental Evidence For Differing Reactivity Alterations Of Minerals Following Irradiation: The Case Of Calcite And Quartz, Isabella Pignatelli, Aditya Kumar, Kevin G. Field, Bu Wang, Yingtian Yu, Yann Le Pape, Mathieu Bauchy, Gaurav Sant Jan 2016

Direct Experimental Evidence For Differing Reactivity Alterations Of Minerals Following Irradiation: The Case Of Calcite And Quartz, Isabella Pignatelli, Aditya Kumar, Kevin G. Field, Bu Wang, Yingtian Yu, Yann Le Pape, Mathieu Bauchy, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

Concrete, used in the construction of nuclear power plants (NPPs), may be exposed to radiation emanating from the reactor core. Until recently, concrete has been assumed immune to radiation exposure. Direct evidence acquired on Ar+-ion irradiated calcite and quartz indicates, on the contrary, that, such minerals, which constitute aggregates in concrete, may be significantly altered by irradiation. More specifically, while quartz undergoes disordering of its atomic structure resulting in a near complete lack of periodicity, calcite only experiences random rotations, and distortions of its carbonate groups. As a result, irradiated quartz shows a reduction in density of around …

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Structure And Corrosion Behavior Of Sputter Deposited Ce-Al-O Coating On Al 2024-T3 Alloy Substrates, Yuanyuan Liu, Jiamu Huang, James B. Claypool, Matthew J. O'Keefe Jan 2016

Structure And Corrosion Behavior Of Sputter Deposited Ce-Al-O Coating On Al 2024-T3 Alloy Substrates, Yuanyuan Liu, Jiamu Huang, James B. Claypool, Matthew J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Deposition of Ce-Al-O coatings on Al 2024-T3 alloy substrates was conducted by magnetron co-sputtering of CeO2 and Al targets. The incorporation of Al into the CeO2 film resulted in an amorphous or nanocrystalline structure with binding energy states different from Al, Al2O3, and CeO2. Electrochemical measurements indicated that the amorphous or nanocrystalline Ce-Al-O coating increased the corrosion resistance of bare Al 2024-T3 substrates by more than three orders of magnitude and exhibited a very different cathodic and anodic protective mechanism compared to Al and CeO2 coated and as-polished Al 2024-T3 samples. …

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Evolution Of Non-Metallic Inclusions In Foundry Steel Casting Processes, Marc Harris, Von Richards, Ronald J. O'Malley, Semen Naumovich Lekakh Dec 2015

Evolution Of Non-Metallic Inclusions In Foundry Steel Casting Processes, Marc Harris, Von Richards, Ronald J. O'Malley, Semen Naumovich Lekakh

Materials Science and Engineering Faculty Research & Creative Works

The evolution of nonmetallic inclusions was examined for 4320 steel at an industrial steel foundry. The steel was followed from electric arc furnace melting through ladle refining to final casting. Timed sampling was performed at all stages of the process. Samples were analyzed using an automated SEM/EDS system. The overall evolution of oxide inclusions in terms of nucleation, growth, and flotation during liquid processing was studied using area fraction and average diameter. Chemical composition evolution was observed using a joint ternary plotting tool developed under this program. It was found that the use of zirconium as an addition for nitrogen/oxygen …

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Structure And Corrosion Behavior Of Sputter Deposited Cerium Oxide Based Coatings With Various Thickness On Al 2024-T3 Alloy Substrates, Yuanyuan Liu, Jiamu Huang, James B. Claypool, Carlos E. Castano, Matthew J. O'Keefe Nov 2015

Structure And Corrosion Behavior Of Sputter Deposited Cerium Oxide Based Coatings With Various Thickness On Al 2024-T3 Alloy Substrates, Yuanyuan Liu, Jiamu Huang, James B. Claypool, Carlos E. Castano, Matthew J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Cerium oxide-based coatings from ∼100 to ∼1400 nm in thickness were deposited onto Al 2024-T3 alloy substrates by magnetron sputtering of a 99.99% pure CeO2 target. The crystallite size of CeO2 coatings increased from 15 nm to 46 nm as the coating thickness increased from ∼100 nm to ∼1400 nm. The inhomogeneous lattice strain increased from 0.36% to 0.91% for the ∼100 nm to ∼900 nm thick coatings and slightly decreased to 0.89% for the ∼1400 nm thick coating. The highest adhesion strength to Al alloy substrates was for the ∼210 nm thick coating, due to a continuous …

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Evolution Of The Statistical Distribution In A Topological Defect Network, Fei Xue, Xueyun Wang, Ion Socolenco, Yijia Gu, Longqing Chen, Sang-Wook Cheong Nov 2015

Evolution Of The Statistical Distribution In A Topological Defect Network, Fei Xue, Xueyun Wang, Ion Socolenco, Yijia Gu, Longqing Chen, Sang-Wook Cheong

Materials Science and Engineering Faculty Research & Creative Works

The complex networks of numerous topological defects in hexagonal manganites are highly relevant to vastly different phenomena from the birth of our cosmos to superfluidity transition. The topological defects in hexagonal manganites form two types of domain networks: type-I without and type-II with electric self-poling. A combined phase-field simulations and experimental study shows that the frequencies of domains with N-sides, i.e. of N-gons, in a type-I network are fitted by a lognormal distribution, whereas those in type-II display a scale-free power-law distribution with exponent ~ 2. A preferential attachment process that N-gons with a larger N have higher probability of …

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High-Frequency Electromagnetic Purification Of Silicon, Lucas Nana Wiredu Damoah, Lifeng Zhang Sep 2015

High-Frequency Electromagnetic Purification Of Silicon, Lucas Nana Wiredu Damoah, Lifeng Zhang

Materials Science and Engineering Faculty Research & Creative Works

The effect of a high-frequency electromagnetic (EM) field on the removal of nonmetallic inclusions from molten silicon was experimentally investigated. Inclusion separation efficiencies of up to 99 pct were reached. The separation efficiency was independent of the particle concentration in the melt and increased significantly with increases in the frequency, separation time, and coil current. Particles were separated from the silicon matrix and relocated to the top, bottom, and side walls of the crucible due to the effect of three mechanisms: induced secondary fluid flow which carried particles from the bulk of the melt; EM body force which worked in …

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A Microstructure And Hardness Study Of Functionally Graded Materials Ti6al4v/Tic By Laser Metal Deposition, Jingwei Zhang, Yunlu Zhang, Frank W. Liou, Joseph William Newkirk, Karen M. Brown Taminger, William J. Seufzer Aug 2015

A Microstructure And Hardness Study Of Functionally Graded Materials Ti6al4v/Tic By Laser Metal Deposition, Jingwei Zhang, Yunlu Zhang, Frank W. Liou, Joseph William Newkirk, Karen M. Brown Taminger, William J. Seufzer

Materials Science and Engineering Faculty Research & Creative Works

Crack free functionally graded material (FGM) Ti6Al4V-TiC has been fabricated by laser metal deposition (LMD) using TiC and Ti6Al4V powder which were premixed for different ratios. This study focuses on the influence of laser processing parameters and TiC compositional distribution on microstructure, Vickers hardness and phase. The microstructure is analyzed by scanning electron microscopy (SEM), x-ray diffraction (XRD) and hardness tests. Primary carbide, eutectic carbide and unmelted carbide are found in the deposit area. When laser power increased, the primary and secondary dendrite arm spacing increased. The laser power and scanning speed did not influence the Vickers hardness distribution significantly.

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Burner, Emitter, And Recuperator Development For Lightweight Thermophotovoltaic Power Supply, Lewis Fraas, Leonid Minkin, J. Avery, Hui She, L. Ferguson, Fatih Dogan Jun 2015

Burner, Emitter, And Recuperator Development For Lightweight Thermophotovoltaic Power Supply, Lewis Fraas, Leonid Minkin, J. Avery, Hui She, L. Ferguson, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Like batteries, thermophotovoltaic generators produce DC electricity quietly. TPV uses infrared photovoltaic cells to convert infrared radiation from a combustion heated ceramic IR emitter. However, because the specific energy in a hydrocarbon fuel like propane or butane is 12,900 Wh/kg, much larger than the specific energy of 145 Wh/kg for a Li-ion battery, TPV is very promising as a lightweight DC power supply. A portable cylindrical thermophotovoltaic (TPV) battery replacement concept has been previously described. It consists of a cylindrical TPV receiver assembly using simple diffused junction GaSb IR cells along with a novel omega recuperator and a novel doped …

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Impact Of Stoichiometry On Structural And Optical Properties Of Sputter Deposited Multicomponent Tellurite Glass Films, Okechukwu Ogbuu, Qingyang Du, Hongtao Lin, Lan Li, Yi Zou, Erick Koontz, Charmayne Smith (Lonergan), Sylvain Danto, Kathleen Richardson, Juejun Hu Jun 2015

Impact Of Stoichiometry On Structural And Optical Properties Of Sputter Deposited Multicomponent Tellurite Glass Films, Okechukwu Ogbuu, Qingyang Du, Hongtao Lin, Lan Li, Yi Zou, Erick Koontz, Charmayne Smith (Lonergan), Sylvain Danto, Kathleen Richardson, Juejun Hu

Materials Science and Engineering Faculty Research & Creative Works

Multicomponent TeO2-Bi2O3-ZnO (TBZ) glass thin films were prepared using RF magnetron sputtering under different oxygen flow rates. The influences of oxygen flow rate on the structural and optical properties of the resulting thin films were investigated. We observed that thin films sputtered in an oxygen-rich environment are optically transparent while those sputtered in an oxygen-deficient environment exhibit broadband absorption. The structural origin of the optical property variation was studied using X-ray diffraction, X-ray photoelectron spectroscopy, Raman Spectroscopy, and transmission electron microscopy which revealed that the presence of under-coordinated Te leads to the observed optical …

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Chemical Oxidative Polymerization, Optical, Electrochemical And Kinetic Studies Of 8-Amino-2-Naphthol, Fatih Dogan, Ismet Kaya, Ali Bilici, Mehmet Yildirim Jun 2015

Chemical Oxidative Polymerization, Optical, Electrochemical And Kinetic Studies Of 8-Amino-2-Naphthol, Fatih Dogan, Ismet Kaya, Ali Bilici, Mehmet Yildirim

Materials Science and Engineering Faculty Research & Creative Works

Here the polymerization of 8-amino-2-naphthol (AN) is reported without use of an additional external template, surfactants or functional dopants. For this, NaOCl and hydrochloride acid solution (1.0 M) were used as oxidant and reaction medium, respectively. The structure of oligomer was elucidated by FT-IR, UV–vis and 1 H-NMR techniques. The number average molecular weight of oligomer was found to be 2200Da with a polydispersity index of 1.4 by size exclusion chromatography. This oligomer exhibited a multicolor emission behavior as it was excited at different wavelengths. Redox states were clarified by cyclic voltammetry (CV) technique and the relationship between anodic/cathodic peak …

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Electrolytic Recovery Of Bismuth And Copper As A Powder From Acidic Sulfate Effluents Using An Emew® Cell, Wei Jin, Paul I. Laforest, Alex Luyima, Weldon Read, Luis M. Navarro, Michael S. Moats Jun 2015

Electrolytic Recovery Of Bismuth And Copper As A Powder From Acidic Sulfate Effluents Using An Emew® Cell, Wei Jin, Paul I. Laforest, Alex Luyima, Weldon Read, Luis M. Navarro, Michael S. Moats

Materials Science and Engineering Faculty Research & Creative Works

Effective removal of bismuth is a primary concern during copper electrorefining. A novel electrowinning process using an emew® cell was developed to recover bismuth and copper from a copper electrorefining waste stream. Significant removal and co-deposition of copper and bismuth were achieved from a highly acidic sulfate industrial effluent using a current density of 350 A m-2, but the current efficiency was low (27%). Operating at a lower current density (75 A m-2) facilitated the preferred removal of Cu, while increasing current efficiency to 67.4% due to the decrease of aside-reaction. Consequently, a two-stage process was …

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Enhancing Grain Refinement Of Austenitic Steel With Ti Additions By Melt Treatment Sequence Optimization, Gun Ge, Semen Naumovich Lekakh, Ronald J. O'Malley May 2015

Enhancing Grain Refinement Of Austenitic Steel With Ti Additions By Melt Treatment Sequence Optimization, Gun Ge, Semen Naumovich Lekakh, Ronald J. O'Malley

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

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Origin Of Interfacial Polar Order In Incipient Ferroelectrics, Yijia Gu, Nan Wang, Fei Xue, Long-Qing Chen May 2015

Origin Of Interfacial Polar Order In Incipient Ferroelectrics, Yijia Gu, Nan Wang, Fei Xue, Long-Qing Chen

Materials Science and Engineering Faculty Research & Creative Works

There are ample experimental evidences indicating that the ferroelastic domain walls of incipient ferroelectrics, such as SrTiO3 and CaTiO3, are polar. The emergence of such interfacial polar order at a domain wall is exciting and believed to arise from the coupling between a primary order parameter, such as a strain or an antiferrodistortive (AFD) order parameter, and polarization. There have been several mechanisms proposed to explain the emergence of interfacial polar order, including biquadratic coupling, AFD-antiferroelectric coupling, and flexoelectric coupling. Using CaTiO3 as an example, we demonstrate, using both asymptotic analytics and numerical calculation, that the …

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Erratum: "Impact Of Symmetry On The Ferroelectric Properties Of Catio₃ Thin Films" (Applied Physics Letters 106:162904 (2015)), Michael D. Biegalski, Liang Qiao, Yijia Gu, Apurva Mehta, Qian He, For Full List Of Authors, See Publisher's Website. May 2015

Erratum: "Impact Of Symmetry On The Ferroelectric Properties Of Catio₃ Thin Films" (Applied Physics Letters 106:162904 (2015)), Michael D. Biegalski, Liang Qiao, Yijia Gu, Apurva Mehta, Qian He, For Full List Of Authors, See Publisher's Website.

Materials Science and Engineering Faculty Research & Creative Works

There is a typo of the space group. All the Pnmb should be Pbnm (or Pnma). So the Glazer notation should be changed to (a-a-c+) for Pbnm space group on page 4 of the article. We have also noticed that the thermodynamic analysis of CaTiO3 thin film is not correct. The films are (001)PC-oriented or (101)-oriented. Therefore, there is no need to rotate the coordinate system (on page 4 of the article). By applying the thin film boundary condition, i.e., ε11 = ε22 = εs, ε …

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Kinetics Of Corrosion Of Bn-Zro2-Sic Ceramics In Contact With Si-Killed Steel, Abhishek Kumar, Vivek Thapliyal, David G.C. Robertson, Jeffrey D. Smith May 2015

Kinetics Of Corrosion Of Bn-Zro2-Sic Ceramics In Contact With Si-Killed Steel, Abhishek Kumar, Vivek Thapliyal, David G.C. Robertson, Jeffrey D. Smith

Materials Science and Engineering Faculty Research & Creative Works

The mechanism and kinetics of corrosion of BN-ZrO2-SiC (MYCROSINT®SO43) by molten Si-killed steel was studied. Isothermal corrosion tests were performed for duration between 2 and 8 h. Refractory and steel composition and morphology changes were investigated. A kinetic model using process simulation software METSIM and thermochemical software FactSage was developed to understand refractory-steel interactions. The corrosion process showed a deviation from parabolic kinetics and was fitted by a combination of linear and parabolic terms. It was determined that corrosion of the BN-ZrO2-SiC refractory was governed by dissolution of SiC and BN and removal of ZrO2 …

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Focus On Properties And Applications Of Perovskites, Fatih Dogan, Hong Lin, Maryline Guilloux-Viry, Octavio J. Pena Apr 2015

Focus On Properties And Applications Of Perovskites, Fatih Dogan, Hong Lin, Maryline Guilloux-Viry, Octavio J. Pena

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

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