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Materials Science and Engineering Faculty Research & Creative Works

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Full-Text Articles in Materials Science and Engineering

Calibration Of The Johnson–Cook Model At High Temperatures For An Ultra-High Strength Crnimov Steel, Mario F. Buchely, S. Chakraborty, V. Athavale, Laura Bartlett, Ronald J. O'Malley, D. Field, K. Limmer, K. Sebeck Jul 2023

Calibration Of The Johnson–Cook Model At High Temperatures For An Ultra-High Strength Crnimov Steel, Mario F. Buchely, S. Chakraborty, V. Athavale, Laura Bartlett, Ronald J. O'Malley, D. Field, K. Limmer, K. Sebeck

Materials Science and Engineering Faculty Research & Creative Works

This paper presents a study on the thermo-mechanical behavior of an ultra-high strength CrNiMoV steel at high temperatures and medium strain rates through hot tensile tests. The material was examined in two conditions: as-cast/heat-treated (AC/HT) and as-rolled (AR). Tensile tests were conducted at temperatures of 800,900,1000,1100, and 1200°C, and strain rates of 0.1,1, and 10s−1. Inclusion and porosity analysis was also performed on the tensile specimens. The results revealed that the flow stress decreased by approximately 70% on average from 800°C to 1200°C, while increasing by approximately 32% on average from 0.1s−1 to 10s−1 in strain rate. The elongation exhibited …

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A Strong And Ductile Cobalt-Free Solid-Solution Fe30ni30mn30cr10 Multi-Principal Element Alloy From Hot Rolling, Hans Pommerenke, Jiaqi Duan, Nathan Curtis, Victor Delibera, Adam Bratten, Andrew Hoffman, Mario F. Buchely, Ronald J. O'Malley, Haiming Wen Jul 2023

A Strong And Ductile Cobalt-Free Solid-Solution Fe30ni30mn30cr10 Multi-Principal Element Alloy From Hot Rolling, Hans Pommerenke, Jiaqi Duan, Nathan Curtis, Victor Delibera, Adam Bratten, Andrew Hoffman, Mario F. Buchely, Ronald J. O'Malley, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Most of the Face-Centered Cubic (FCC) Multi-Principal Element Alloys (MPEAs) Developed Thus Far Contain Cobalt. for Many Applications, it is Either required or Beneficial to Avoid Cobalt, Since Cobalt Has Long-Term Activation Issue (For Nuclear Applications), is Expensive, and is Considered a Critical Material. in Addition, FCC Structured Solid-Solution MPEAs Tend to Have Relatively Low Strength. a FCC Solid-Solution Fe30Ni30Mn30Cr10 (At %) MPEA Was Fabricated Via Arc Melting, Followed by Homogenization at 1100 °C for 12 H. the Alloy Was Hot Rolled at 1100 °C with a Total Reduction of Up to 97 %. the Microstructure Was Characterized and Mechanical …

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A Strong And Ductile Cobalt-Free Solid-Solution Fe30ni30mn30cr10 Multi-Principal Element Alloy From Hot Rolling, Hans Pommerenke, Jiaqi Duan, Nathan Curtis, Victor Delibera, Adam Bratten, Andrew Hoffman, Mario Buchely, Ronald O'Malley, Haiming Wen Jul 2023

A Strong And Ductile Cobalt-Free Solid-Solution Fe30ni30mn30cr10 Multi-Principal Element Alloy From Hot Rolling, Hans Pommerenke, Jiaqi Duan, Nathan Curtis, Victor Delibera, Adam Bratten, Andrew Hoffman, Mario Buchely, Ronald O'Malley, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Most of the face-centered cubic (FCC) multi-principal element alloys (MPEAs) developed thus far contain cobalt. for many applications, it is either required or beneficial to avoid cobalt, since cobalt has long-term activation issue (for nuclear applications), is expensive, and is considered a critical material. in addition, FCC structured solid-solution MPEAs tend to have relatively low strength. an FCC solid-solution Fe30Ni30Mn30Cr10 (at %) MPEA was fabricated via arc melting, followed by homogenization at 1100 °C for 12 h. the alloy was hot rolled at 1100 °C with a total reduction of up to 97 %. the microstructure was characterized, and mechanical …

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Engineering Heterogeneous Nucleation During Solidification Of Multiphase Cast Alloys: An Overview, Simon (Semen) N. Lekakh, Jingjing Qing Jul 2023

Engineering Heterogeneous Nucleation During Solidification Of Multiphase Cast Alloys: An Overview, Simon (Semen) N. Lekakh, Jingjing Qing

Materials Science and Engineering Faculty Research & Creative Works

The theory of heterogeneous nucleation was initially developed as a part of condensed matter physics, and later it was used as an important engineering tool to design metallurgical processes. This success has led to wide applications of the theory in metallurgical practice. For example, engineering heterogeneous nucleation in ductile iron has been used to reduce shrinkage defects, suppress cementite formation, and modify the size and shape of microstructural constituencies. This demonstrates how theoretical knowledge could benefit industry practice. This overview aims to summarize the authors' published studies in co-authorship with colleagues and students, which covers different aspects of engineering heterogeneous …

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Unlocking Road Stability: Machine Learning-Powered Prediction Of Bitumen Distortion Under Traffic Flow Influence, Sabahudin Vrtagic, Milan Dordevic, Fatih Dogan, Muhammed Codur, Mario Hoxha, Edis Softic Jun 2023

Unlocking Road Stability: Machine Learning-Powered Prediction Of Bitumen Distortion Under Traffic Flow Influence, Sabahudin Vrtagic, Milan Dordevic, Fatih Dogan, Muhammed Codur, Mario Hoxha, Edis Softic

Materials Science and Engineering Faculty Research & Creative Works

Road intersections are made of asphalt pavement, a popular road surface material used worldwide. The pavement may suffer deformities and deterioration, resulting in higher maintenance expenses and an elevated likelihood of road accidents, due to factors such as heavy vehicles and environmental variables like temperature and rainfall. To tackle these obstacles, researchers have devised several machine-learning algorithms and optimization techniques. These tools aim to forecast and scrutinize pavement deformation, with the goal of refining pavement design and maintenance approaches, as well as obtaining a more comprehensive comprehension of the factors that impact pavement effectiveness. This paper shows that heavy vehicles …

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Dissolution Rates Of Borophosphate Glasses In Deionized Water And In Simulated Body Fluid, Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow Jun 2023

Dissolution Rates Of Borophosphate Glasses In Deionized Water And In Simulated Body Fluid, Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

Particles of Borophosphate Glasses with the Nominal Molar Compositions 16Na2O-(24-Y)CaO-YSrO-XB2O3-(60-X)P2O5 (Mol%), Where 0 ≤ X ≤ 60 and Y = 0, 12, and 24, Were Reacted in Deionized Water and in Simulated Body Fluid (SBF) at 37 °C. for the Dissolution Experiments in Water, the PH of the Solution at the Conclusion of the Experiments Increased Systematically, from 2.1 to 9.5, for Y = 0 Glasses When 'x' Increased from 0 to 60. the Reaction Rates over the First 8–24 H of Dissolution in Both SBF and Deionized Water Followed Linear …

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Erratum To “Structure Of Tin Phosphate Glasses By Neutron And X-Ray Diffraction” [Journal Of Non Crystalline Solids:X 2c (2019) 100017] (Journal Of Non-Crystalline Solids: X (2019) 2, (S2590159119300305), (10.1016/J.Nocx.2019.100017)), U. Hoppe, Richard K. Brow, A. C. Hannon, M. V. Zimmermann Jun 2023

Erratum To “Structure Of Tin Phosphate Glasses By Neutron And X-Ray Diffraction” [Journal Of Non Crystalline Solids:X 2c (2019) 100017] (Journal Of Non-Crystalline Solids: X (2019) 2, (S2590159119300305), (10.1016/J.Nocx.2019.100017)), U. Hoppe, Richard K. Brow, A. C. Hannon, M. V. Zimmermann

Materials Science and Engineering Faculty Research & Creative Works

The publisher regrets the following conflict of interest text was not published. • All the authors listed in this article have made Substantial contributions to the conception or design of the work; or the acquisition, analysis, or interpretation of data for the work; AND drafting the work or revising it critically for important intellectual content; AND Final approval of the version to be published. • I also undertake that the article represents valid work. Neither this article nor any part of it has been copied or plagiarized from other works. • That the article has not been published so far …

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Effect Of Cr And Ni Concentrations On Resilience Of Cast Nb-Alloyed Heat Resistant Austenitic Steels At Extreme High Temperatures, Simon N. Lekakh, Mario F. Buchely, Mei Li, Larry Godlewski May 2023

Effect Of Cr And Ni Concentrations On Resilience Of Cast Nb-Alloyed Heat Resistant Austenitic Steels At Extreme High Temperatures, Simon N. Lekakh, Mario F. Buchely, Mei Li, Larry Godlewski

Materials Science and Engineering Faculty Research & Creative Works

Austenitic Cr–Ni Alloyed Heat Resistant Steels with Nb Additions Are Used for Intensively Thermo-Mechanically Loaded Cast Components Working in Extreme High Temperature Oxidizing Environment. their Performance during Static Oxidation and Transient Thermo-Mechanical Loading Was Investigated to Recommend an Optimal Cost-Effective Cr/Ni Composition of Nb-Alloyed Austenitic Class Steels. the Static Oxidation and Transient Thermo-Mechanical Behavior of Three Austenitic Steels with Different Cr/Ni Alloying Levels Were Investigated and Compared for Variety of Working Conditions. Static Oxidation Was Performed between 900 °C and 1000 °C in Air for 400 H. the Critical Temperature Which Increases Spallation during Static Oxidation Was Determined for Each …

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A Prediction Of Young's Modulus For Tin Containing Phosphate Glasses Using Quantitative Structural Information, Tatsuki Shimizu, Akira Saitoh, Uwe Hoppe, Grégory Tricot, Richard K. Brow May 2023

A Prediction Of Young's Modulus For Tin Containing Phosphate Glasses Using Quantitative Structural Information, Tatsuki Shimizu, Akira Saitoh, Uwe Hoppe, Grégory Tricot, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

A Rigid Unit Packing Fraction (RUPF) Model Was Used to Better Understand the Influence of Local Structural Units on the Young's Elastic Modulus (E) of Binary and Ternary Tin Phosphate Glasses. Quantitative Analyses of the Units that Constitute the Glass Structure, Obtained from X-Ray/neutron Diffraction and 31P MAS-NMR Spectroscopy, Were Used to Calculate Polyhedral Packing Fractions that, with Tabulated Bond Dissociation Energies, Were Used to Predict E based on a Modification of the Makashima-Mackenzie Relationship, Which Uses Ion Sizes to Calculate Packing Fractions. Predictions based on the RUPF Model Are Better Than Those based on Ion Sizes, and Extending the …

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Review Of Magnetic Properties And Texture Evolution In Non-Oriented Electrical Steels, Yizhou Du, Ronald J. O'Malley, Mario F. Buchely May 2023

Review Of Magnetic Properties And Texture Evolution In Non-Oriented Electrical Steels, Yizhou Du, Ronald J. O'Malley, Mario F. Buchely

Materials Science and Engineering Faculty Research & Creative Works

Electrical steels can be classified into two groups: grain-oriented (GO) and non-oriented (NGO) electrical steel. NGO electrical steels are mainly considered as core materials for different devices, such as electric motors, generators, and rotating machines. The magnetic properties and texture evolution of NGO electrical steels depend on multiple factors (such as chemical content, heat-treatment, and rolling process) making the development of new products a complex task. In this review, studies on the magnetic properties of NGO electrical steels and the corresponding texture evolution are summarized. The results indicate that further research is required for NGO electrical steels to ensure high …

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A Hyperbaric Aerodynamic Levitator For Containerless Materials Research, Sydney E. Boland, Stephen K. Wilke, Jonathan A. Scott, Sarah M. Schlossberg, Alex Ivaschenko, Richard J.K. Weber, David W. Lipke May 2023

A Hyperbaric Aerodynamic Levitator For Containerless Materials Research, Sydney E. Boland, Stephen K. Wilke, Jonathan A. Scott, Sarah M. Schlossberg, Alex Ivaschenko, Richard J.K. Weber, David W. Lipke

Materials Science and Engineering Faculty Research & Creative Works

A hyperbaric aerodynamic levitator has been developed for containerless materials research at specimen temperatures exceeding 2000 °C and pressures up to 10.3 MPa (1500 psi). This report describes the prototype instrument design and observations of the influence of specimen size, density, pressure, and flow rate on levitation behavior. The effect of pressure on heat transfer was also assessed by studying the heating and cooling behavior of levitated Al2O3 liquids. A threefold increase in the convective heat transfer coefficient was estimated as pressure increased to 10.3 MPa. The results demonstrate that hyperbaric aerodynamic levitation is a promising technique for containerless materials …

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A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario F. Buchely, Haiming Wen Apr 2023

A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario F. Buchely, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Recent Studies on Precipitation-Hardened High-Entropy Alloys (HEAs) Demonstrate their High Strength and Thermal Stability, Making Them Promising Materials for High-Temperature Structural Applications Such as Nuclear Reactors. However, Many Existing HEAs Contain Cobalt (Co), Which is Unsuitable for Nuclear Applications Because of the Long-Term Activation Issue of Co. Co is Also Expensive and Considered a Critical Material for Other Applications. Therefore, It is Desired to Exclude Co from the Composition. a Co-Free (Fe0.3Ni0.3Mn0.3Cr0.1)88Ti4Al8 HEA Was Developed and Studied in This Work. in Contrast to Previous Co-Free HEAs, This Alloy is …

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A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario Buchely, Haiming Wen Apr 2023

A High-Strength Precipitation Hardened Cobalt-Free High-Entropy Alloy, Matthew Luebbe, Jiaqi Duan, Fan Zhang, Jonathan Poplawsky, Hans Pommeranke, Maalavan Arivu, Andrew Hoffman, Mario Buchely, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Recent studies on precipitation-hardened high-entropy alloys (HEAs) demonstrate their high strength and thermal stability, making them promising materials for high-temperature structural applications such as nuclear reactors. However, many existing HEAs contain cobalt (Co), which is unsuitable for nuclear applications because of the long-term activation issue of Co. Co is also expensive and considered a critical material for other applications. Therefore, it is desired to exclude Co from the composition. a Co-free (Fe0.3Ni0.3Mn0.3Cr0.1)88Ti4Al8 HEA was developed and studied in this work. in contrast to previous Co-free HEAs, this alloy is close to Equi atomic in its composition and promises a more …

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Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang Mar 2023

Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang

Materials Science and Engineering Faculty Research & Creative Works

Ceramic On-Demand Extrusion (CODE) is a direct ink writing process which allows for the creation of near theoretically dense ceramic components with large cross-sections due to oil-assisted drying. Yttria-stabilized zirconia (YSZ) colloidal pastes (∼d50 ≲ 1 µm) were used in CODE to produce dense (multi-road infill and ≳ 98% relative density), large continuous volume (> 1 cm3), and high fidelity (nozzle diameters ≲ 1 mm) structural ceramic components. However, many of these printed components underwent significant particle migration after forming. The reason for this particle migration defect was investigated using the coffee-ring effect for dilute solutions and rheological methods for …

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Novel Effects Of Grain Size And Ion Implantation On Grain Boundary Segregation In Ion Irradiated Austenitic Steel, Andrew K. Hoffman, Yongfeng Zhang, Maalavan Arivu, Li He, Kumar Sridharan, Yaqiao Wu, Rinat K. Islamgaliev, Ruslan Z. Valiev, Haiming Wen Mar 2023

Novel Effects Of Grain Size And Ion Implantation On Grain Boundary Segregation In Ion Irradiated Austenitic Steel, Andrew K. Hoffman, Yongfeng Zhang, Maalavan Arivu, Li He, Kumar Sridharan, Yaqiao Wu, Rinat K. Islamgaliev, Ruslan Z. Valiev, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Nuclear Reactor Environments Are Extreme in Nature Due to the Combination of Exposure to Corrosive Coolant, Mechanical Stresses, and Neutron Irradiation Damage. This Combination of Environments Can Lead to Irradiation Induced/assisted Precipitation, Segregation, and Embrittlement Coupled with Enhanced Creep and Stress Corrosion Cracking. While Nanostructured Materials Are of Interest in a Variety of Applications Due to their Unique Properties Including High Mechanical Strength, for Nuclear Applications Nanostructured Materials Have the Added Benefit of Irradiation Resistance Due to the High-Volume Density of Sinks for Irradiation-Induced Defects. in This Study, We Show Unique Radiation-Induced Segregation (RIS) Behavior in Nanocrystalline 304 Stainless Steel …

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Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas Mar 2023

Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas

Materials Science and Engineering Faculty Research & Creative Works

High-entropy (HE) ultra-high temperature ceramics have the chance to pave the way for future applications propelling technology advantages in the fields of energy conversion and extreme environmental shielding. Among others, HE diborides stand out owing to their intrinsic anisotropic layered structure and ability to withstand ultra-high temperatures. Herein, we employed in-situ high-resolution synchrotron diffraction over a plethora of multicomponent compositions, with four to seven transition metals, with the intent of understanding the thermal lattice expansion following different composition or synthesis process. As a result, we were able to control the average thermal expansion (TE) from 1.3 x 10−6 to …

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Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang Mar 2023

Particle Migration In Large Cross-Section Ceramic On-Demand Extrusion Components, Austin J. Martin, Wenbin Li, Jeremy Lee Watts, Gregory E. Hilmas, Ming-Chuan Leu, Tieshu Huang

Materials Science and Engineering Faculty Research & Creative Works

Ceramic On-Demand Extrusion (CODE) is a direct ink writing process which allows for the creation of near theoretically dense ceramic components with large cross-sections due to oil-assisted drying. Yttria-stabilized zirconia (YSZ) colloidal pastes (∼d50 ≲ 1 µm) were used in CODE to produce dense (multi-road infill and ≳ 98% relative density), large continuous volume (> 1 cm3), and high fidelity (nozzle diameters ≲ 1 mm) structural ceramic components. However, many of these printed components underwent significant particle migration after forming. The reason for this particle migration defect was investigated using the coffee-ring effect for dilute solutions and rheological methods for …

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Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas Mar 2023

Anisotropic Thermal Expansion In High-Entropy Multicomponent Alb2-Type Diboride Solid Solutions, Frédéric Monteverde, Mattia Gaboardi, Federico Saraga, Lun Feng, William Fahrenholtz, Gregory Hilmas

Materials Science and Engineering Faculty Research & Creative Works

High-entropy (HE) ultra-high temperature ceramics have the chance to pave the way for future applications propelling technology advantages in the fields of energy conversion and extreme environmental shielding. Among others, HE diborides stand out owing to their intrinsic anisotropic layered structure and ability to withstand ultra-high temperatures. Herein, we employed in-situ high-resolution synchrotron diffraction over a plethora of multicomponent compositions, with four to seven transition metals, with the intent of understanding the thermal lattice expansion following different composition or synthesis process. As a result, we were able to control the average thermal expansion (TE) from 1.3 x 10−6 to 6.9 …

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Synthesizing Ti–Ni Alloy Composite Coating On Ti–6al–4v Surface From Laser Surface Modification, Yitao Chen, Joseph William Newkirk, Frank W. Liou Feb 2023

Synthesizing Ti–Ni Alloy Composite Coating On Ti–6al–4v Surface From Laser Surface Modification, Yitao Chen, Joseph William Newkirk, Frank W. Liou

Materials Science and Engineering Faculty Research & Creative Works

In This Work, a Ni-Alloy Deloro-22 Was Laser-Deposited on a Ti–6Al–4V Bar Substrate with Multiple Sets of Laser Processing Parameters. the Purpose Was to Apply Laser Surface Modification to Synthesize Different Combinations of Ductile TiNi and Hard Ti2Ni Intermetallic Phases on the Surface of Ti–6Al–4V in Order to Obtain Adjustable Surface Properties. Scanning Electron Microscopy, Energy Dispersion Spectroscopy, and X-Ray Diffraction Were Applied to Reveal the Deposited Surface Microstructure and Phase. the Effect of Processing Parameters on the Resultant Compositions of TiNi and Ti2Ni Was Discussed. the Hardness of the Deposition Was Evaluated, and Comparisons with …

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Methods For Determining The Infrared Complex Refractive Indices N(Λ) And K(Λ) From Organic Solid Powders: Comparison Of A Sucrose Single Crystal And A Pressed Pellet, Michael O. Yokosuk, Danielle L. Saunders, Charles Tom Resch, Jeremy D. Erickson, Charmayne E. Lonergan, Sarah D. Burton, Mark E. Bowden, Kelly A. Peterson, Timothy J. Johnson, Tanya L. Myers Jan 2023

Methods For Determining The Infrared Complex Refractive Indices N(Λ) And K(Λ) From Organic Solid Powders: Comparison Of A Sucrose Single Crystal And A Pressed Pellet, Michael O. Yokosuk, Danielle L. Saunders, Charles Tom Resch, Jeremy D. Erickson, Charmayne E. Lonergan, Sarah D. Burton, Mark E. Bowden, Kelly A. Peterson, Timothy J. Johnson, Tanya L. Myers

Materials Science and Engineering Faculty Research & Creative Works

There exists a need to measure optical constants n and k for many materials, especially organic solids in the infrared spectral region, but at present, there are only two established methods for making such measurements: single-angle (SA) reflectance and infrared spectroscopic ellipsometry (IRSE). the former derives the n/k vectors via measurement of the change in the amplitude of light reflected from the sample and then uses the Kramers-Kronig transform, while the latter measures the change in polarization of the reflected light from the sample to derive n/k. Here we make a direct comparison between the n/k vectors derived from SA …

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The Effects Of Phosphorus Pentoxide Additions On The Thermal, Rheological, And Structural Properties Of Sodium Borosilicate Glass, K. L. Skerratt-Love, J. L. George, A. M.T. Bell, F. Sweeney, D. Cutforth, C. (Charmayne) E. Lonergan, D. R. Dixon, A. A. Kruger, P. A. Bingham Jan 2023

The Effects Of Phosphorus Pentoxide Additions On The Thermal, Rheological, And Structural Properties Of Sodium Borosilicate Glass, K. L. Skerratt-Love, J. L. George, A. M.T. Bell, F. Sweeney, D. Cutforth, C. (Charmayne) E. Lonergan, D. R. Dixon, A. A. Kruger, P. A. Bingham

Materials Science and Engineering Faculty Research & Creative Works

This research has characterized the effects of P2O5 additions on the physical, chemical, thermal, rheological properties and the structure of SiO2-B2O3-Na2O glasses relevant to radioactive waste immobilization. Properties analyzed include high-temperature viscosity, glass transition temperature (Tg) and structure. X-ray diffraction (XRD) confirmed a solubility limit of between 3.0 and 4.0 mol% P2O5 for the onset of crystallinity with formation of Na3PO4 and Na4P2O7 in annealed bulk glasses; and between 4.0 and 5.0 mol% P2O …

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Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow Jan 2023

Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

Borophosphate glasses were prepared with the nominal molar compositions 16Na2O-(24-y)CaO-ySrO-xB2O3-(60-x)P2O5 (mol%), where 0≤x≤60 and y=0, 12, and 24. Information about the compositional dependence of borate and phosphate site speciation and next nearest neighbor linkages was obtained by 11B and 31P MAS NMR and Raman spectroscopies, and by high pressure liquid chromatography (HPLC). With the initial replacement of P2O5 by B2O3, tetrahedral borate sites linked to four phosphate anions, B(ØP)4, are created in the glass structure, and the average phosphate anion becomes smaller as bridging PØP bonds are replaced by bridging PØB bonds. With further increases in the B2O3 content, borate …

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Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow Jan 2023

Network Structures And The Properties Of Na-Ca-Sr-Borophosphate Glasses, Parker T. Freudenberger, Rebekah L. Blatt, Randall E. Youngman, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

Borophosphate glasses were prepared with the nominal molar compositions 16Na2O-(24-y)CaO-ySrO-xB2O3-(60-x)P2O5 (mol%), where 0≤x≤60 and y=0, 12, and 24. Information about the compositional dependence of borate and phosphate site speciation and next nearest neighbor linkages was obtained by 11B and 31P MAS NMR and Raman spectroscopies, and by high pressure liquid chromatography (HPLC). With the initial replacement of P2O5 by B2O3, tetrahedral borate sites linked to four phosphate anions, B(ØP)4, are created in the glass structure, and the average phosphate anion …

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Temperature Monitoring In The Refractory Lining Of A Continuous Casting Tundish Using Distributed Optical Fiber Sensors, Muhammad Roman, Hanok Tekle, Dinesh Reddy Alla, Farhan Mumtaz, Jeffrey D. Smith, Laura Bartlett, Ronald J. O'Malley, Rex E. Gerald, Jie Huang Jan 2023

Temperature Monitoring In The Refractory Lining Of A Continuous Casting Tundish Using Distributed Optical Fiber Sensors, Muhammad Roman, Hanok Tekle, Dinesh Reddy Alla, Farhan Mumtaz, Jeffrey D. Smith, Laura Bartlett, Ronald J. O'Malley, Rex E. Gerald, Jie Huang

Materials Science and Engineering Faculty Research & Creative Works

This Article Explores the Prospects of using Spatially Distributed Optical Fiber Temperature Sensors based on Rayleigh Optical Frequency Domain Reflectometry (OFDR) Technology in the Continuous Casting of Molten Steel. the Measurement Capability of the Optical Fiber Sensors in a Simulated Steelmaking Environment Was Demonstrated using a Mock Refractory-Lined Tundish, Which Was Fabricated In-House. Single-Mode Optical Fibers, Contained in Protective Stainless-Steel Tubing, Were Embedded in the Refractory Lining of the Mock Tundish. the Instrumented Tundish Was Preheated Up to a Temperature of 960 °C (Recorded at the Surface of the Working Lining) Before the Molten Steel Pour. a Low-Alloy Steel (AISI …

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Effect Of Mechanical Activation On Carbothermal Synthesis And Densification Of Zrc, Nina Obradović, Lun Feng, Suzana Filipović, Miljana Mirković, Darko Kosanović, Jelena Rogan, William Fahrenholtz Jan 2023

Effect Of Mechanical Activation On Carbothermal Synthesis And Densification Of Zrc, Nina Obradović, Lun Feng, Suzana Filipović, Miljana Mirković, Darko Kosanović, Jelena Rogan, William Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

Zirconium carbide ceramics were prepared by carbothermal reduction of ZrO2 and C that were mixed by high-energy ball milling. Powders were milled for times from 0 to 120 min in air. As milling time increased, the surface area of the powders increased, indicating significant particle size reduction. Milled powders were reacted at 1600 °C and then densified by spark plasma sintering at 2000 °C, which was sufficient to convert the starting powders to zirconium carbide. Unmilled powders did not reach full density. Milled powders reached full density, but ZrO2 impurities were found for specimens prepared from powders milled …

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Effect Of Annealing Time On Texture Evolution Of Fe–3.4 Wt% Si Nonoriented Electrical Steel, Yizhou Du, Ronald J. O'Malley, Mario F. Buchely, Paul Kelly Jan 2023

Effect Of Annealing Time On Texture Evolution Of Fe–3.4 Wt% Si Nonoriented Electrical Steel, Yizhou Du, Ronald J. O'Malley, Mario F. Buchely, Paul Kelly

Materials Science and Engineering Faculty Research & Creative Works

Herein, the Effect of Annealing Time on the Texture Evolution in Fe–3.4 Wt.% Si Non-Oriented Electrical Steel is Investigated. Strip Samples Are Cast using a Vacuum Sampling Method, Which Simulate the Solidification Conditions of an Industrial Twin Roll Thin Strip Casting (TRSC) Process. As-Cast Samples with Different Carbon and Sulfur (C&S) Levels Are Hot Rolled (HR) with Varying Levels of Hot Deformation, Cold Rolled (CR) to 0.35 Mm Thickness, and Then Annealed at 1050 °C for Different Holding Times (1, 6, 24 H). to Fe–3.4 Wt.% Si Non oriented Electrical Steel, the Observed Texture Evolution Can Be Divided into Different …

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Advancing Aluminum Casting Optimization With Real-Time Temperature And Gap Measurements Using Optical Fiber Sensors At The Metal-Mold Interface, Bohong Zhang, Abhishek Prakash Hungund, Dinesh Reddy Alla, Deva Prasaad Neelakandan, Muhammad Roman, Ronald J. O'Malley, Laura Bartlett, Rex E. Gerald, Jie Huang Jan 2023

Advancing Aluminum Casting Optimization With Real-Time Temperature And Gap Measurements Using Optical Fiber Sensors At The Metal-Mold Interface, Bohong Zhang, Abhishek Prakash Hungund, Dinesh Reddy Alla, Deva Prasaad Neelakandan, Muhammad Roman, Ronald J. O'Malley, Laura Bartlett, Rex E. Gerald, Jie Huang

Materials Science and Engineering Faculty Research & Creative Works

Accurate measurement of interfacial heat transfer during casting solidification is crucial for optimizing metal solidification processes. The gap between the mold wall and the casting surface plays a significant role in heat transfer and cooling rates. In this study, two innovative fiber-optic sensors are employed to measure real-time mold gaps and thermal profiles during the solidification of A356 aluminum in a permanent mold casting. The experimental setup consists of a specially designed mold system made of unheated, uncoated tool steel, which facilitates easy installation of the fiber-optic sensors. An Extrinsic Fabry-Perot interferometric (EFPI) sensor is utilized to monitor the evolving …

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Microstructure Evolution And Austenitic Grain Refinement Of Ti-Modified High Mn Steels During Solution Annealing Heat Treatment, Abhinav Karanam, Arnab Sarkar, Erik Nenzen, Viraj Ashok Athavale, Mark Watson, Laura Nicole Bartlett, Lukas Bichler Jan 2023

Microstructure Evolution And Austenitic Grain Refinement Of Ti-Modified High Mn Steels During Solution Annealing Heat Treatment, Abhinav Karanam, Arnab Sarkar, Erik Nenzen, Viraj Ashok Athavale, Mark Watson, Laura Nicole Bartlett, Lukas Bichler

Materials Science and Engineering Faculty Research & Creative Works

Austenitic high manganese (Mn) steels are often used in harsh environments due to their high toughness and wear resistance. Heat treatments are performed to engineer the microstructure of the steels and optimize their performance for the desired service conditions. This study investigated the effect of titanium (Ti) and heat treatment on the microstructure of cast high Mn steel (HMS) alloys. The results reveal that Ti addition contributed to grain refinement in the as cast and heat-treated conditions. In-situ observation of microstructure evolution up to 1125 °C confirmed the stability of precipitated TiC particles, while revealing a new mechanism of grain …

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In Situ High-Temperature Raman Spectroscopy Via A Remote Fiber-Optic Raman Probe, Bohong Zhang, Hanok Tekle, Ronald J. O'Malley, Jeffrey D. Smith, Rex E. Gerald, Jie Huang Jan 2023

In Situ High-Temperature Raman Spectroscopy Via A Remote Fiber-Optic Raman Probe, Bohong Zhang, Hanok Tekle, Ronald J. O'Malley, Jeffrey D. Smith, Rex E. Gerald, Jie Huang

Materials Science and Engineering Faculty Research & Creative Works

This Study Demonstrated for the First Time an in Situ High-Temperature Fiber-Optic Raman Probe to Study the Structure of Glass and Slag Samples at Temperatures Up to 1400 °C. a Customized External Telescope Was Integrated into a Portable Fiber-Optic Raman Probe to Extend the Optical Working Distance to Allow the Probe to Work in a High-Temperature Environment. Three Samples Were Evaluated to Demonstrate the Functionality of the High-Temperature Fiber-Optic Raman Probe. Room Temperature and High-Temperature Raman Spectra Were Successfully Collected and Analyzed. in Addition, a Deconvolution Algorithm Was Used to Identify Peaks in the Spectrum that Could Then Be Related …

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High Temperature Confocal Scanning Laser Microscopy Analysis Of Dead-Burned Magnesia Aggregates, Tyler Richards, Viraj Athavale, Jeffrey D. Smith, Ronald J. O'Malley Jan 2023

High Temperature Confocal Scanning Laser Microscopy Analysis Of Dead-Burned Magnesia Aggregates, Tyler Richards, Viraj Athavale, Jeffrey D. Smith, Ronald J. O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Dead-Burned Magnesia is a Commonly Used Material in the Manufacturing of Refractories for the Steelmaking Industry. Aggregates of Dead-Burned Magnesia Contain Secondary Phases Due to the Impurities within the Magnesite Rock Used in its Production. While These Phases Can Aid in Sintering Magnesia, They May Have Some Impact on the High-Temperature Performance of the Refractory Product. High-Temperature Confocal Scanning Laser Microscopy Was Utilized to Observe the Behavior of Dead-Burned Magnesia Aggregates at Elevated Temperatures (Up to 1550°C). Liquid Formation Was Detected Even at Temperatures Below 1350°C. in Some Cases, This Liquid Quickly Exuded from the Aggregate Surface. This Liquid Phase …

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