Materials Science and Engineering Commons^™

Polyethyleneimine-Based High Yield Fluorescent Soluble Covalent Organic Framework, Haonan Wang

USF Tampa Graduate Theses and Dissertations

In this thesis, we report a novel covalent organic framework (COF) with fluorescence and water-soluble features, F-COF-PT with high gravimetric yield (~ 89%), that was generated by the reactions of branched polyethyleneimine (PEI) and 1,3,6,8-Tetrabromopyrene (TBP). The surface area and pore volume were about up to 63.2 m2/g and 0.41 m3/g. The prepared COFs maintained the TBP fluorescent performance in water solutions at 440-460 nm. Furthermore, Cu(II) ion solution would impact the quenching activity with F-COF-PT3, and NaOH treated F-COF-PT3 has the 5.6 m2/g capacity of uptake CO2. Finally, the zeta potential and particle diameter of original and treated F-COF-PT3s …

Material And Topographically Optimized Thermal Dissipation For High-Performance Electronic Devices Utilizing Vapor Chambers, Derek Joseph Daniels

USF Tampa Graduate Theses and Dissertations

Advances in materials science and engineering in the field of thermal transport and dissipation enable the use of higher-performance electronic devices that are smaller and generate more heat. Phase change thermal transport systems such as heat pipes and vapor chambers enable passive dissipation from devices that generate excessive heat without the need for actively pumped cooling systems. Properly designed vapor chamber enabled systems easily exceed the thermal conductivity of manufactured diamond at a small fraction of the cost.[1][2][3] While heat pipe phase change systems are generally one-dimensional with a limited cross section, vapor chambers are generally two-dimensional with a small …

Texturing In Bi2Te3 Alloy Thermoelectric Materials: An Applied Physics Investigation, Oluwagbemiga P. Ojo

USF Tampa Graduate Theses and Dissertations

Thermoelectric devices provide the means for direct conversion between heat and electricity. The device conversion efficiency, or performance, is directly related to the thermoelectric figure of merit, ZT, of the working materials. Bismuth telluride alloys are the materials currently in use in most thermoelectric devices for near room temperature solid-state refrigeration and power conversion applications. The vast majority of publications in the literature on thermoelectricity report on investigations towards developing new materials with enhanced thermoelectric properties, however Bi₂Te₃ alloys have been used in thermoelectric devices for decades.

In this thesis, an investigation of crystallographic texturing on large …

Development Of Carbon And Silicon Carbide Based Microelectrode Implantable Neural Interfaces, Chenyin Feng

USF Tampa Graduate Theses and Dissertations

The use of neural modulation techniques to treat nervous system disorders, as well as neural recording to study brain function, continues to be of intense interest around the world. Due to the need to treat diseases such as Parkinson’s, dementia, depression and return normal function to patients suffering from nervous system damage and trauma, neural implants continue to be developed globally. One of these devices, the microelectrode implantable neural interface (mINI), has been rapidly developed, thanks to advanced semiconductor fabrication processes. However, the long-term reliability of present-day devices has still to be demonstrated and is delaying the application of this …

Preparation And Characterization Of Single Layer Conducting Polymer Electrochromic And Touchchromic Devices, Sharan Kumar Indrakar

USF Tampa Graduate Theses and Dissertations

Electrochromic devices (ECDs) have triggered great interest because of their potential applicability in energy-efficient buildings and low power display systems, including reflective type smart windows/mirrors and wearable-flexible devices. In the past decades, electrochromic technologies with different device structures and materials have been proposed. The idea of employing a simple device structure with a durable, cost effective electrolyte is crucial to designing and manufacturing high-performance ECDs. With this idea in mind, this thesis describes the various efforts to develop a simple ECD comprising of a composite single active layer gel electrolyte, sandwiched between two transparent conducting electrodes, lasting over 10,000 cycles …

Corrosion Propagation Of Stainless Steel Reinforced Concrete, Nelly Sofía Orozco Martínez

USF Tampa Graduate Theses and Dissertations

Structural durability is a growing concern in global infrastructure. The infrastructure report card released by the American Society of Civil Engineers (ASCE) indicates that approximately 9.1% of the total bridges in the United States were structurally deficient in 2016. In addition, it suggests that about 40% of the total bridges in the country are now 50 years or older. This issue becomes even more critical in structures exposed to aggressive environments such as marine structures. Thus, federal and regional efforts are now being directed towards infrastructural durability improvement to improve the long-term cost-efficiency of civil infrastructure.

Corrosion prevention strategies may …

Sulfate Optimization In The Cement-Slag Blended System Based On Calorimetry And Strength Studies, Mustafa Fincan

USF Tampa Graduate Theses and Dissertations

Optimization of sulfur trioxide (SO³) content is typically conducted for plain cements (OPC-based) paste or mortar systems using compressive strength testing and isothermal calorimetry for quality control. The objective of these procedures is to ensure adequate strength and set properties by controlling the time of occurrence of the aluminate peak by adjusting the SO³ content by incremental addition of sulfate in the form of hemihydrate at three or more levels, at the same time attempting to maximize either strength or heat of hydration at 1 and 3 days. The inclusion of supplementary cementitious materials such as blast …

Fabrication And Characterization Methods Of Self-Cleaning Coatings For Solar Panels Application, Mohammed Khaleel M Alhussain

USF Tampa Graduate Theses and Dissertations

Transparent self-cleaning coatings with superhydrophobic and superhydrophilic behavior are of great interest in a wide range of industrial applications such as automotive, solar panels, windows, and optical devices. Each has its uses, properties, and characteristics. For the use of these coatings on solar panels, certain features are important in maintaining the efficiency of the panels in different weather conditions and reducing the operation and maintenance cost, such as self-cleaning, high transparency, antifouling, anti-fogging, and anti-icing. Herein, we have investigated the fabrication of self-cleaning coatings using two simple methods and ways to improve their characteristics. In the first method, a hydrophobic …

The Effect Of Cement And Blast Furnace Slag Characteristics On Expansion Of Heat-Cured Mortar Specimens, Jair G. Burgos

USF Tampa Graduate Theses and Dissertations

Delayed ettringite formation (DEF) is a durability issue that typically occurs in concrete exposed to high temperatures at an early age such as precast elements and massive concrete structural elements. There are many advantages to precast concrete such as its quality control, better safety control, and reusable forms, which make them cheaper than casting on site [1]. Heat curing of precast concrete is conducted to obtain high early-strength. However, in doing so, durability issues can arise in the form of internal sulfate attack also known as DEF, if the internal temperature of concrete exceeds 70°C. Past this threshold, ettringite decomposes …

Conversion From Metal Oxide To Mof Thin Films As A Platform Of Chemical Sensing, Meng Chen

USF Tampa Graduate Theses and Dissertations

Chemical sensor is working as a widely used device which can be applied to the detection of specific chemicals that are existing in the environment especially in gas phase. The detection of combustible and toxic chemicals can be extremely important in the field of both industrial and civil activities. The chemical sensor is commonly operating by utilizing a chemical or physical interaction between the specific chemical compound and the sensing functional unit, to obtain an electronic signal caused by the property change and realize the chemical detection. Traditional chemical gas sensors such as catalytic gas sensor, thermal conductivity gas sensor, …

Tuning Degradation And Cell Adhesion In Next Generation Resorbable Implants, Ufuomaroghene Ikoba

USF Tampa Graduate Theses and Dissertations

Osteoarthritic and bone degenerative diseases are expected to grow immensely as the aging population, 65 years and older increases. Orthopedic implants are one sub-class of medical devices that are used to treat bone breaks and fractures. Traditionally, internal fixation implants are manufactured using titanium or stainless steel. Magnesium, a bioresorbable and biodegradable material, has been proposed as an alternative to titanium and stainless steel. The goal of this research is to control the degradation behavior of magnesium implants by developing crystallized thin poly(lactic acid) copolymer films as protective coatings. To do this, this work was divided into two aims. Aim …

Urine Volume Reduction During Long-Duration Cave Exploration By A Light-Weight And Portable Forward Osmosis System, Sebastian Engelhardt, Katey E. Bender, Jörg Vogel, Stephen E. Duirk, Francisco B. Moore, Hazel A. Barton

International Journal of Speleology

The preservation of caves is a challenge during long-duration cave expeditions where human waste can add significant nitrogen to the cave ecosystem. Since the removal of urine that accumulates during a multi-day caving trip is not always feasible due to weight and volume constraints, a light-weight and portable filtration system that is capable of reducing urine volume would be desirable. In this study we tested the Aquaporin Inside hollow fiber membrane in a forward osmosis (FO) setup to evaluate its capability to reduce urine volume while rejecting nitrogenous compounds using different draw solution chemistries and water recovery rates. As a …

Laser-Induced Modifications In Two-Dimensional Materials, Tariq Afaneh

USF Tampa Graduate Theses and Dissertations

Atomically thin two-dimensional (2D) materials have attracted a growing interest in the lastdecade from the fundamental point of view as well as their potential applications in functional devices. Due to their high surface-to-volume ratio, the physical properties of 2D materials are very sensitive to the environmental factor such as surrounding media and illumination conditions (e.g. light-mater interaction). In the first part of this dissertation I will present recent advances in developing laser-assisted methods to tune the physical properties of 2D transition metal dichalcogenides (TMDs). We demonstrate laser-assisted chemical modification ultrathin TMDs, locally replacing selenium by sulfur atoms. The photo-conversion process …

Sustainable Non-Noble Metal Based Catalysts For High Performance Oxygen Electrocatalysis, Swetha Ramani

USF Tampa Graduate Theses and Dissertations

Current energy crisis has dramatically shifted the focus of technological advancements towards clean and renewable forms of energy. Continued dependence and utilization of fossil fuels has created global awareness on harmful greenhouse gas emissions and climate change. A need for sustainable technology has gained a lot of significance in the recent years. This has led to the development of devices and technologies that rely on environmentally friendly electrochemical conversion and storage of energy. One such advancement that generates electrical energy from chemical reactions is known as fuel cell technology. While fuel cells have demonstrated potential in replacing the conventional technologies …

Additive Manufactured And Laser Enhanced Optical Fiber On Flexible Kapton Substrate, Dianhao Hou

USF Tampa Graduate Theses and Dissertations

This thesis mainly focuses on the realization of laser enhancing additive manufactured optical fibers on the flexible substrate based on previous work on the rigid surface, and the exploration of their loss at different bend status by optical transmission test. Optical fibers are successfully fabricated using polymethyl methacrylate by fused deposition modeling technology within Norland Optical Adhesive 1369 which is chosen as the cladding material and micro-dispensed on the Kapton substrate. The Laser cutting technology and scanning electron microscope have been used to enhance and characterize the flatness of two end facets of samples, respectively. The optical adhesive and PMMA …

Van Der Waals Epitaxy Of Ultrathin Early Transition Metal (Ti & V) (Di)Selenides: Charge And Magnetic Order In The Ultrathin Limit, Manuel Bonilla Lopez

USF Tampa Graduate Theses and Dissertations

Since the isolation of graphene in 2004, two-dimensional (2D) layered materials, specially the transition metal dichalcogenides (TMDs), have attracted immense interest from theoreticians and experimentalist due to the diversity of properties presented in this family of materials. The main reason for the interest in such materials has been the observation of emergent properties as a consequence of the reduced dimensions, i.e. the monolayer regime. Initially the monolayer regime was obtained via the scotch-tape method. The implementation of exfoliation techniques was successful since layered 2D materials are composed of stacked layers held together by weak van der Walls forces that permits …

Cancer Biomarker Detection In Human Plasma By Integrating Surface Acoustic Wave And Metal-Enhanced Fluorescence, Yuqi Huang

USF Tampa Graduate Theses and Dissertations

This thesis includes data and discussion about the technique of metal-enhanced fluorescence (MEF) to lower the detection limit of carcinoembryonic antigen (CEA). The detection limit goes down to 100pg/mL level when using MEF substrate made by rapid thermally annealed silver film covered by silica, which has great promise in diagnosing certain types of cancer that uses CEA as detection biomarker, such as pancreatic cancer and colon cancer. To further address the issue of background noises from non-specifically bound proteins (NSB) in complex media, such as plasma, serum, urine and blood, MEF is integrated with surface acoustic wave (SAW) streaming in …

Laser Micropatterning Effects On Corrosion Resistance Of Pure Magnesium Surfaces, Yahya Efe Yayoglu

USF Tampa Graduate Theses and Dissertations

Magnesium and its alloys are good candidates to manufacture medical implants. They have excellent biocompatibility and because they biodegrade secondary surgical operation to remove the implant could be eliminated. However, in aqueous environments, magnesium alloys rapidly corrode, resulting in premature degradation of the implant along with biologically intolerable hydrogen gas generation. In literature, there are multiple studies focused on creating water repelling hydrophobic magnesium surfaces in order to decrease corrosion rates. Hydrophobic properties can be achieved by creation of a roughness profile on an initially smooth surface combined with a treatment that reduces the free surface energy. In theory, hydrophobic …

Growth And Characterization Of 2d Layered Materials, Algene Fryer Ii

USF Tampa Graduate Theses and Dissertations

2D layered materials are becoming an important area of research due to their exceptional electrical and optical properties. Specifically, 2D layered monochalcogenides are known for their high carrier motilities, whereas layered metal halides have been shown to have noteworthy photoresponsivity. Despite the assortment of 2D layered materials, the search for reliable and scalable synthesis methods is still a challenge in this family of materials. Often a certain growth technique will compromise a desirable trait needed for further fabrication, such as the quality of the crystal or its coverage on a substrate. In this study, two growth techniques that incorporate changeable …

Influence Of Glass Fiber Reinforced Polymer Wraps On Corrosion Progression Of Bridge Piles In Marine Environments, Shayan Yazdani

USF Tampa Graduate Theses and Dissertations

The Friendship Trail Bridge connecting Tampa to St. Petersburg was demolished in 2016. Thirteen 20 inches. by 20 inches. reinforced concrete piles supporting its superstructure were part of research studies conducted between 2004 and 2008 to explore the role of glass fiber reinforced polymers (GFRP) in corrosion repair. During demolition, piles were typically cut at the pile cap and in the splash zone. The resulting segments varied in length between 3 to 4 ft. These remnants were transported to the University of South Florida (USF) campus for postmortem analysis. The overarching goal was to establish the role of GFRP in …

Low-Grade Kaolin Clay Natural Resource For Use As A Supplementary Cementitious Material In Structural Concrete Elements, Brandon X. Lorentz

USF Tampa Graduate Theses and Dissertations

At the turn of the century, low-grade kaolin clay (LGK) was presented as a widely available and potential natural resource of supplementary cementitious materials (SCM) for producing high performance concretes. In using LGK as an SCM, clinker production is reduced, aiding environmental concerns with associated CO2 emissions. These types of clays have very heterogeneous mineralogy and microstructural characteristics, causing unique influences on concrete structural and flow performance, although these influences are not well understood. This research studies LGK natural to the state of Florida and assesses their potential use as high performance SCM.

Ten kaolin clays were obtained through a …

First-Principles Simulations Of Materials Under Extreme Conditions, Kien Nguyen Cong

USF Tampa Graduate Theses and Dissertations

The investigation of materials at extreme conditions of high pressure and temperature (high-PT), has been one of the greatest scientific endeavors in condensed mater physics, chemistry, astronomy, planetary, and material sciences. Being subjected to high-PT conditions, materials exhibit dramatic changes in both atomic and electronic structure resulting in an emergence of exceptionally interesting phenomena including structural and electronic phase transitions, chemical reactions, and formation of novel compounds with never-previously observed physical and chemical properties. Although new exciting experimental developments in static and dynamic compression combined with new diagnostics/characterization methods allow to uncover new processes and phenomena at high P-T conditions, …

Fabrication And Characterization Of Electrical Energy Storage And Harvesting Energy Devices Using Gel Electrolytes, Belqasem Aljafari

USF Tampa Graduate Theses and Dissertations

Redox-active materials in the bulk of gel electrolytes are unquestionably holding the primary roles in developing energy harvesting and storage technology. Both technologies are necessary in order to cope with the current challenges of the environmental crises of global warming and finite non-renewable sources while the demand for energy modern societies have been speedily increased. One of the most challenges of making a hybrid device of energy conversion and storage is the cost of the fabrication process. Therefore, gel electrolyte-based materials with redox-active properties can potentially be a promising solution to improve the performance of electrochemical and photoelectrochemical devices for …

Sorption Of Benzene, Toluene, Ethylbenzene And Different Ratios Of Mixture Solvent By Plasticized Pema Films Using A Qcm Sensor, Xinpeng Li

USF Tampa Graduate Theses and Dissertations

VOCs (volatile organic compounds) can cause great harm to human health especially benzene, toluene and ethylbenzene. In this work a Quartz Crystal Microbalance (QCM) sensor with a polymer/plasticizer film was developed to quantify the VOCs both in air and water. QCM is an acoustic wave sensor that can be used well in detecting the aromatic compounds in the film. Because more than one VOC is present in the air, this thesis focuses on finding the sorption of different ratios of VOCs (benzene, toluene, ethylbenzene) using a polymer/plasticizer film in QCM. Poly (ethyl methacrylate) (PEMA) was used as the polymer because …

Extrusion Of Perovskite Oxide/ Silica Composites For Thermochemical Carbon Dioxide Conversion, Qian Li

USF Tampa Graduate Theses and Dissertations

In order to solve the increasing greenhouse effect problem, perovskite-type oxides have been used to convert CO2 to CO in a reverse water-gas shift chemical looping (RWGS-CL) process. Currently, the process is at the micro-reactor scale and used catalyst in powder form. However, formed materials are needed if the scale is to be increased.

Our research focus is on increasing the conversion yield of perovskite oxides with SiO2 support and scaling up the powder form perovskite-type oxides to pellet by extrusion. The binder added during the extrusion process must be removed to avoid affecting the performance of the catalyst and …

Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations, Yasin Kocak

USF Tampa Graduate Theses and Dissertations

High density polyethylene (HDPE) geomembrane is most common geomembrane which is mainly used for civil engineering applications. However, HDPE geomembrane loses its properties under oxidative degradation progress. This study aims to assess geomembranes which have different percentage of phenolic antioxidant and hindered amine light stabilizer (HALS) with under the six months of the thermal-oxidative degradation. The interactions between phenolic antioxidant, HALS and carbon black can affect the mechanical, physical and chemical properties. To monitor these properties, Differential Scanning Calorimetry (DSC), Fourier-transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy coupled with Energy Dispersive X-ray spectroscopy (SEM/EDX), Melt Index tests, …

Study Of Transition Metal Dichalcogenides Via Linear And Non-Linear Spectroscopy, Christopher E. Stevens

USF Tampa Graduate Theses and Dissertations

Beginning with the discovery of graphene, two-dimensional materials have amassed a strong interest. Like graphene, transition metal dichalcogenides (TMDs) can be coaxed into atomically thin sheets which have some impressive properties. Unlike graphene, TMDs also has a change in their electronic band structure causing an indirect band gap to a direct gap transition in its monolayer form. Additionally, these materials lose their inversion symmetry as a monolayer. These unique properties make TMDs a strong candidate for being used in optoelectronic and valleytronic devices. In order for these devices to be successful, the optical properties of TMDs must be thoroughly understood. …

Encapsulation Of Organic Thermochromic Materials With Silicon Dioxide, Mingyang Huang

USF Tampa Graduate Theses and Dissertations

Currently, functional materials are attracting considerable attention in the effort to solve some tough challenges the world is faced with. Thermochromic (TC) materials have the potential to make buildings more energy efficient because of their ability to change color (i.e black to white) at specific temperatures. Using this property, TC materials can reflect solar radiation in the summer, to keep a building cool during daytime hours, and absorb solar radiation in the winter to keep the building warm when their color is dark. Very often, to increase their durability, thermochromic materials are encapsulated. In this work, a new process has …

Phase Evolution And Dynamic Behavior In Materials With Noncollinear Spin Textures, Eleanor M. Clements

USF Tampa Graduate Theses and Dissertations

Noncentrosymmetric magnetic materials have gained special attention due to their ability to stabilize topologically nontrivial magnetic states via the competition between symmetric exchange and the antisymmetric Dzyaloshinskii-Moriya (DM) interaction. The spin struc- tures in these materials have become a center of interest for spintronics applications due to their stable, particle-like properties, and high degree of tunability via control of external parameters, such as magnetic and/or electric field and temperature. Understanding how these robust magnetic structures stabilize, evolve, dynamically respond, and adhere to existing models, all in the presence of external stimuli, are topics of fundamental interest. In this dissertation, the …

Synthesis And Characterization Of Molybdenum Disulfide/Conducting Polymer Nanocomposite Materials For Supercapacitor Applications, Turki S. Alamro

USF Tampa Graduate Theses and Dissertations

The needs for energy storage devices have kindled researchers desire to explore and synthesize nanocomposite materials. Storing energy efficiently, effectively and sustainably are the science and engineering communities’ highest priorities to develop electrochemical energy storage devices. Supercapacitors have become power solution not only because supercapacitors can bridge the gap between the traditional capacitors and rechargeable batteries but also because of many other advantages which include extraordinary electrochemical properties, wide working-temperature range, cost effective, safe operation and long/stable cycle life. They have higher current pules than batteries due to the mechanism of charging and discharging. Batteries charging and discharging via chemical …