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Articles 151 - 180 of 220
Full-Text Articles in Materials Science and Engineering
Investigation Of Thermal, Elastic And Load-Biased Transformation Strains In Niti Shape Memory Alloys, Shipeng Qiu
Investigation Of Thermal, Elastic And Load-Biased Transformation Strains In Niti Shape Memory Alloys, Shipeng Qiu
Electronic Theses and Dissertations
Polycrystalline NiTi shape memory alloys have the ability to recover their original, pre-deformed shape in the presence of external loads when heated through a solid-solid phase transformation from a lower-symmetry B19' martensite phase to a higher-symmetry B2 austenite phase. The strain associated with a shape memory alloy in an actuator application typically has thermal, elastic and inelastic contributions. The objective of this work was to investigate the aforementioned strains by recourse to in situ neutron diffraction experiments during selected combinations of heating, cooling and/or mechanical loading. The primary studies were conducted on polycrystalline Ni49.9Ti50.1 specimens on the Spectrometer for MAterials …
Strengthening Potential Of Single-Walled Carbon Nanotubes In Phenolic Resin Composites, Brittany Kerr
Strengthening Potential Of Single-Walled Carbon Nanotubes In Phenolic Resin Composites, Brittany Kerr
Electronic Theses and Dissertations
Strengthening potential of single-walled carbon nanotubes (SWCNTs) in a phenolic resin composite was evaluated by characterization of purified and phenyl sulfonated SWCNTs, investigation of the load transfer capability of the purified SWCNTs, and characterization of the composites. Purified and phenyl sulfonated SWCNTs, as well as their composites, were examined by Raman spectroscopy, thermogravimetric analysis, scanning electron microscopy equipped with energy dispersive spectroscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and ultra violet-visible spectrometry. Fabrication of the SWCNT/phenolic resin composite was performed by first dispersing the SWCNTs in ethylene glycol and then homogenizing the mixture with phenolic resin. The ethylene glycol was …
Phase-Field Simulation Of Microstructural Development Induced By Interdiffusion Fluxes Under Multiple Gradients, Rashmi Mohanty
Phase-Field Simulation Of Microstructural Development Induced By Interdiffusion Fluxes Under Multiple Gradients, Rashmi Mohanty
Electronic Theses and Dissertations
The diffuse-interface phase-field model is a powerful method to simulate and predict mesoscale microstructure evolution in materials using fundamental properties of thermodynamics and kinetics. The objective of this dissertation is to develop phase-field model for simulation and prediction of interdiffusion behavior and evolution of microstructure in multiphase binary and ternary systems under composition and/or temperature gradients. Simulations were carried out with emphasis on multicomponent diffusional interactions in single-phase system, and microstructure evolution in multiphase systems using thermodynamics and kinetics of real systems such as Ni-Al and Ni-Cr-Al. In addition, selected experimental studies were carried out to examine interdiffusion and microstructure …
Vibrational And Mechanical Properties Of 10 Mol % Sc2o3-1 Mol % Ceo2- Zro2 Electrolyte Ceramics For Solid Oxide Fuel Cells, Svetlana Lukich
Vibrational And Mechanical Properties Of 10 Mol % Sc2o3-1 Mol % Ceo2- Zro2 Electrolyte Ceramics For Solid Oxide Fuel Cells, Svetlana Lukich
Electronic Theses and Dissertations
Solid Oxide Fuel Cells (SOFCs) are emerging as a potential breakthrough energy conversion technology for clean and efficient production of electricity and heat from hydrogen and hydrocarbon fuels. Sc0.1Ce0.01ZrO2 electrolytes for Solid Oxide Fuel Cells are very promising materials because their high ionic conductivity in the intermediate temperature range 700°C-800°C. The vibration response of cubic and rhombohedral (β) 10 mol%Sc2O3 - 1 mol%CeO2 - ZrO2(Sc0.1Ce0.01ZrO2 ) both at room and high-temperatures is reported. The in-situ heating experiments and ex-situ indentation experiments were performed to characterize the vibrational behavior of these important materials. A temperature and stress-assisted phase transition from cubic …
Multicomponent Interdiffusion In Austenitic Ni-, Fe-Ni-Base Alloys And L12-Ni3al Intermetallic For High-Temperature Applications, Narayana Garimella
Multicomponent Interdiffusion In Austenitic Ni-, Fe-Ni-Base Alloys And L12-Ni3al Intermetallic For High-Temperature Applications, Narayana Garimella
Electronic Theses and Dissertations
Interdiffusion in multicomponent-multiphase alloys is commonly encountered in many materials systems. The developments of multicomponent-multiphase alloys require control of microstructure through appropriate heat treatment, involving solid-state transformations, precipitation processes, and surface modification, where the interdiffusion processes play a major role. In addition, interdiffusion processes often control degradation and failure of these materials systems. Enhanced performance and reliable durability always requires a detailed understanding of interdiffusion. In this study, ternary and quaternary interdiffusion in Ni-Cr-X (X = Al, Si, Ge, Pd) at 900°C and 700°C, Fe-Ni-Cr-X (X = Si, Ge) at 900°C, and Ni3Al alloyed with Ir, Ta and Re at …
Formation Of Lyotropic Liquid Crystals Through The Self-Assembly Of Bile Acid Building Blocks, Karan Tamhane
Formation Of Lyotropic Liquid Crystals Through The Self-Assembly Of Bile Acid Building Blocks, Karan Tamhane
Electronic Theses and Dissertations
Liquid crystalline materials (LCMs) have gained much popularity over the past century. The thermotropic forms of these materials have been extensively studied and employed in a range of innovative applications. The lyotropic liquid crystal systems that have been studied in the past have often been formed by the organization of natural and synthetic small molecules in solutions. In this study, we use self-assembled supramolecular structures as building blocks to fabricate lyotropic liquid crystals. We investigate the self-assembly of a naturally occurring bile acid called lithocholic acid (LCA), to form supramolecular fibrous and tubular structures in basic aqueous solutions. We control …
Electronic Properties And Microstructures Of Amorphous Sicn Ceramics Derived From Polymer Precursors, Tao Jiang
Electronic Properties And Microstructures Of Amorphous Sicn Ceramics Derived From Polymer Precursors, Tao Jiang
Electronic Theses and Dissertations
Polymer-derived ceramics (PDCs) are a new class of high-temperature materials synthesized by thermal decomposition of polymeric precursors. These materials possess many unique features as compared with conventional ceramics synthesized by powder metallurgy based processing. For example, PDCs are neither amorphous nor crystalline. Instead, they possess nano-domain structures. Due to the direct chemical-to-ceramic processing, PDCs can be used for making components and devices with complex shapes. Thus, understanding the properties and structures of these materials are of both fundamental and practical interest. In this work, the structures and electronic behavior of polymer-derived amorphous silicon carbonitrides (SiCNs) were investigated. The materials were …
Characterization And Aqueous Colloidal Processing Of Tungsten Nano-Powders, Zhengtao Yang
Characterization And Aqueous Colloidal Processing Of Tungsten Nano-Powders, Zhengtao Yang
Electronic Theses and Dissertations
Extensive attention has been paid to consolidate nanoparticles into nanocrystalline components that possess better properties than their coarse-grained counterparts. Nanocrystalline monolithic tungsten (W) has been envisaged to possess better properties than coarse-grained tungsten and to improve the performance of many military components. Commercially available nano-W powders were characterized via X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and Brunauer, Emmett, and Teller (BET) measurement. While the bulk of nano-W powders consisted of bcc-W as confirmed by XRD and TEM, much of their surface consisted of WO3 with traces of …
Sintering Additives For Nanocrystalline Titania And Processing Of Porous Bone Tissue Engineering Scaffolds, Arun Menon
Sintering Additives For Nanocrystalline Titania And Processing Of Porous Bone Tissue Engineering Scaffolds, Arun Menon
Electronic Theses and Dissertations
Titania (Titanium dioxide, TiO2) has been researched as a promising biomaterial due to its excellent biocompatibility. However, the main limitation of titania is its poor mechanical properties which limit its use in many load-bearing applications. In this thesis report, the properties of titania were improved by doping with small quantities of MgO, ZnO and SiO2 as sintering additives. Nanocrystalline powder was selected, as it possesses outstanding properties over conventional coarse-grained powders due to reduced grain size. Nanocrystalline anatase powder of size 5-15 nm was synthesized via a simple sol-gel technique. Small quantities of dopants were introduced into pure titania powder, …
Classical Size Effect In Copper Thin Films: Impact Of Surface And Grain Boundary Scattering On Resistivity, Tik Sun
Electronic Theses and Dissertations
Surface and grain boundary electron scattering contribute significantly to resistivity as the dimensions of polycrystalline metallic conductors are reduced to, and below, the electron mean free path. A quantitative measurement of the relative contributions of surface and grain boundary scattering to resistivity is very challenging, requiring not only the preparation of suitably small conductors having independent variation of the two relevant length scales, namely, the sample critical dimension and the grain size, but also independent experimental quantification of these two length scales. In most work to date the sample grain size has been either assumed equal to conductor dimension or …
Prevention Of Environmentally Induced Degradation In Carbon/Epoxy Composite Material Via Implementation Of A Polymer Based Coati, Bradford Tipton
Prevention Of Environmentally Induced Degradation In Carbon/Epoxy Composite Material Via Implementation Of A Polymer Based Coati, Bradford Tipton
Electronic Theses and Dissertations
As the use of fiber reinforced plastics increases in such industries as aerospace, wind energy, and sporting goods, factors effecting long-term durability, such as environmental exposure, are of increasing interest. The primary objectives of this study were to examine the effects of extensive environmental exposure (specifically UV radiation and moisture) on carbon/epoxy composite laminate structures and to determine the relative effectiveness of polymer-based coatings at mitigating degradation incurred due to such exposure. Carbon/epoxy composite specimens, both coated and uncoated, were subjected to accelerated weathering in which prolonged outdoor exposure was simulated by controlling the radiation wavelength (in the UV region), …
Probing And Tuning The Size, Morphology, Chemistry And Structure Of Nanoscale Cerium Oxide, Satyanarayana Kuchibhatla
Probing And Tuning The Size, Morphology, Chemistry And Structure Of Nanoscale Cerium Oxide, Satyanarayana Kuchibhatla
Electronic Theses and Dissertations
Cerium oxide (ceria)-based materials in the nanoscale regime are of significant fundamental and technological interest. Nanoceria in pure and doped forms has current and potential use in solid oxide fuel cells, catalysis, UV- screening, chemical mechanical planarization, oxygen sensors, and bio-medical applications. The characteristic feature of Ce to switch between the +3 and + 4 oxidation states renders oxygen buffering capability to ceria. The ease of this transformation was expected to be enhanced in the nanoceria. In most the practical scenarios, it is necessary to have a stable suspension of ceria nanoparticles (CNPs) over longer periods of time. However, the …
N Multilayer Thin Film Reactions To Form L10 Fept And Exchange Spring Magnets, Bo Yao
N Multilayer Thin Film Reactions To Form L10 Fept And Exchange Spring Magnets, Bo Yao
Electronic Theses and Dissertations
FePt films with the L10 phase have potential applications for magnetic recording and permanent magnets due to its high magnetocrystalline anisotropy energy density. Heat treatment of n multilayer films is one approach to form the L10 FePt phase through a solid state reaction. This thesis has studied the diffusion and reaction of n multilayer films to form the L10 FePt phase and has used this understanding to construct exchange spring magnets. The process-structure-property relations of n multilayer films were systematically examined. The transmission electron microscopy (TEM) study of the annealed multilayers indicates that the Pt layer grows at the expense …
Development And Application Study Of Nanoscale Thin Film Materials And Polymer Nanocomposites, Hui Chen
Development And Application Study Of Nanoscale Thin Film Materials And Polymer Nanocomposites, Hui Chen
Electronic Theses and Dissertations
This dissertation demonstrated that the manipulation of substances at the molecular or nanometer level can lead to the discovery and development of new materials with interesting properties and important applications. Chapter 1 describes the development of a nanoscale molecular thin film material for corrosion protection. By using a self-assembled monolayer film with a thickness of only about 1 nanometer as a linkage, a covalent bonding was achieved between a polyurethane top coating and an aluminum alloy substrate. This covalent bonding between polymer top coating and the aluminum alloy substrate significantly improved the corrosion resistance of the substrate. Chapter 2 and …
Effect Of Composition, Morphology And Semiconducting Properties On The Efficiency Of Cuin1-Xgaxse2-Ysy Thin-Film Solar Cells Pre, Sachin Kulkarni
Effect Of Composition, Morphology And Semiconducting Properties On The Efficiency Of Cuin1-Xgaxse2-Ysy Thin-Film Solar Cells Pre, Sachin Kulkarni
Electronic Theses and Dissertations
A rapid thermal processing (RTP) reactor for the preparation of graded CuIn1-xGaxSe2-ySy (CIGSeS) thin-film solar cells has been designed, assembled and is being used at the Photovoltaic Materials Laboratory of the Florida Solar Energy Center. CIGSeS films having the optimum composition, morphology, and semiconducting properties were prepared using RTP. Initially films having various Cu/(In+Ga) ratios were prepared. In the next step selenium incorporation in these films was optimized, followed by sulfur incorporation in the surface to increase the bandgap at the surface. The compositional gradient of sulfur was fine-tuned so as to increase the conversion efficiency. Materials properties of these …
Application Of Polyelectrolyte Multilayers For Photolithographic Patterning Of Diverse Mammalian Cell Types In Serum Free Medium, Vipra Dhir
Electronic Theses and Dissertations
Integration of living cells with novel microdevices requires the development of innovative technologies for manipulating cells. Chemical surface patterning has been proven as an effective method to control the attachment and growth of diverse cell populations. Patterning polyelectrolyte multilayers through the combination of layer-by-layer self-assembly technique and photolithography offers a simple, versatile and silicon compatible approach that overcomes chemical surface patterning limitations, such as short-term stability and low protein adsorption resistance. In this study, direct photolithographic patterning of PAA/PAAm and PAA/PAH polyelectrolyte multilayers was developed to pattern mammalian neuronal, skeletal and cardiac muscle cells. For all studied cell types, PAA/PAAm …
Effects Of Internal Oxidation On Thermo-Mechanical Properties Of Atmospheric Plasma Sprayed Conicraly Coatings, Travis Patterson
Effects Of Internal Oxidation On Thermo-Mechanical Properties Of Atmospheric Plasma Sprayed Conicraly Coatings, Travis Patterson
Electronic Theses and Dissertations
Thermal barrier coatings (TBC) with MCrAlY (M=Co and/or Ni) bond coats have been widely used in hot sections of gas turbines to protect underlying superalloys from high temperatures, oxidation, and hot corrosion. Deposition of MCrAlY bond coats using atmospheric plasma spray (APS), as oppose to conventionally employed vacuum/low-pressure plasma spray and high velocity oxy-fuel deposition, allows greater flexibility in ability to coat economically and rapidly for parts with complex geometry including internal surfaces. There were three objectives of this study. First, relationships between APS spray parameters and coating microstructure was examined to determine optimum spray parameters to deposit APS CoNiCrAlY …
Quantitative Thickness Mapping In High-Angle Annular Dark-Field (Haadf) Scanning Transmission Electron Microscopy (Stem), Haritha Nukala
Quantitative Thickness Mapping In High-Angle Annular Dark-Field (Haadf) Scanning Transmission Electron Microscopy (Stem), Haritha Nukala
Electronic Theses and Dissertations
Only a few methods are currently available for the measurement of sample thicknesses in Transmission Electron Microscopy (TEM). These methods, Convergent-Beam Electron Diffraction (CBED) and thickness mapping in Energy-Filtered TEM (EFTEM), are either elaborate or complex. In this present work, I have investigated and come up with a simple straight-forward method to measure the local thickness of a TEM sample with the atomic number (Z-contrast) imaging using High-Angle Annular Dark Field (HAADF) Scanning Transmission Electron Microscopy (STEM). HAADF STEM shows atomic number contrast for high scattering angles of the electrons, owing to predominant electron scattering at the potential of the …
Production Of Bulk Ceramic Shapes From Polymer Derived Ceramics, Arnold Hill
Production Of Bulk Ceramic Shapes From Polymer Derived Ceramics, Arnold Hill
Electronic Theses and Dissertations
A method has been developed to produce bulk ceramic components from a class of ceramics known as polymer derived ceramics. In the past polymer derived ceramics have been limited to thin film applications or in the fabrication of MEMS devices. The reason being that when the polymer is into a ceramic, large quantities of gas are generated which produce internal pressure that fractures the ceramic components. The method developed here solves that issue by casting into the polymer a 3 dimensional network of polymer fibers in the form of a foam which, during pyrolysis, burns out and leaves a network …
Laser Enhanced Doping For Silicon Carbide White Light Emitting Diodes, Sachin Bet
Laser Enhanced Doping For Silicon Carbide White Light Emitting Diodes, Sachin Bet
Electronic Theses and Dissertations
This work establishes a solid foundation for the use of indirect band gap semiconductors for light emitting application and presents the work on development of white light emitting diodes (LEDs) in silicon carbide (SiC). Novel laser doping has been utilized to fabricate white light emitting diodes in 6H-SiC (n-type N) and 4H-SiC (p-type Al) wafers. The emission of different colors to ultimately generate white light is tailored on the basis of donor acceptor pair (DAP) recombination mechanism for luminescence. A Q-switched Nd:YAG pulse laser (1064 nm wavelength) was used to carry out the doping experiments. The p and n regions …
Preparation And Characterisation Of Stabilized Nafion/Phosphotungstic Acid Composite Membranes For Proton Exchange Membrane Fuel Cell (Pemfc) Automobile Engines, Rohit Agarwal
Electronic Theses and Dissertations
Membrane durability is one of the limiting factors for proton exchange membrane fuel cell (PEMFC) commercialisation by limiting the lifetime of the membrane via electrochemical / mechanical / thermal degradation. Lower internal humidity in the membrane at high temperature ( > 100 °C) and low relative humidity (25-50 %RH) operating conditions leads to increased resistance, lowering of performance and higher degradation rate. One of the promising candidates is composite proton exchange membranes (CPEMs) which have heteropoly acid (HPA) e.g. Phosphotungstic acid (PTA) doped throughout the Nafion® matrix. HPA is primarily responsible for carrying intrinsic water which reduces the external water dependence. …
Synthesis And Characterization Of Polymer-Derived Porous Sicn Ceramics, Yun Wei
Synthesis And Characterization Of Polymer-Derived Porous Sicn Ceramics, Yun Wei
Electronic Theses and Dissertations
The synthesis and characterization of porous SiCN ceramics produced by the method of polymer-derived ceramics were studied in this work. The polymer-to-ceramic conversion technique is a novel revolution in the methods for fabricating porous materials with controlled morphologies and tailored properties. The porous SiCN ceramics can be successfully prepared from thermal decomposition of polymeric precursors (polysilazane) and the pore former (polyvinyl alcohol (PVA)). The fabrication procedures involved the mixing of the pre-ceramic precursor with appropriate concentration of the PVA, curing, pyrolysis and subsequent PVA removal, leaving pores in the ceramic matrix. The material obtained revealed a homogeneous amorphous microstructure consisting …
Amorphous Phase Formation In Mechanically Alloyed Fe-Based Systems., Satyajeet Sharma
Amorphous Phase Formation In Mechanically Alloyed Fe-Based Systems., Satyajeet Sharma
Electronic Theses and Dissertations
Bulk metallic glasses have interesting combination of physical, chemical, mechanical, and magnetic properties which make them attractive for a variety of applications. Consequently there has been a lot of interest in understanding the structure and properties of these materials. More varied applications can be sought if one understands the reasons for glass formation and the methods to control them. The glass-forming ability (GFA) of alloys can be substantially increased by a proper selection of alloying elements and the chemical composition of the alloy. High GFA will enable in obtaining large section thickness of amorphous alloys. Ability to produce glassy alloys …
Thermodynamic Studies On The Synthesis Of Nitrides And Epitaxial Growth Of Ingan, Zinki Monga
Thermodynamic Studies On The Synthesis Of Nitrides And Epitaxial Growth Of Ingan, Zinki Monga
Electronic Theses and Dissertations
Nitride semiconductor materials have been used in a variety of applications, such as LEDs, lasers, photovoltaic cells and medical applications. If incandescent bulbs could be replaced by white GaN LEDs, they would not only provide compactness and longer lifetime, but this would also result in huge energy savings. A renewed interest in InGaN emerged recently after it was discovered that the band gap for InN is 0.7eV, instead of the previously published value of 1.9eV. Thus InGaN solid solutions cover almost the whole visible spectrum, from a band gap of 3.34eV for GaN and 0.7eV for InN. Hence, InGaN can …
Dimesionality Aspects Of Nano Micro Integrated Metal Oxide Based Early Stage Leak Detection Room Temperature Hydrogen Sensor, Sameer Arun Deshpande
Dimesionality Aspects Of Nano Micro Integrated Metal Oxide Based Early Stage Leak Detection Room Temperature Hydrogen Sensor, Sameer Arun Deshpande
Electronic Theses and Dissertations
Detection of explosive gas leaks such as hydrogen (H2) becomes key element in the wake of counter-terrorism threats, introduction of hydrogen powered vehicles and use of hydrogen as a fuel for space explorations. In recent years, a significant interest has developed on metal oxide nanostructured sensors for the detection of hydrogen gas. Gas sensors properties such as sensitivity, selectivity and response time can be enhanced by tailoring the size, the shape, the structure and the surface of the nanostructures. Sensor properties (sensitivity, selectivity and response time) are largely modulated by operating temperature of the device. Issues like instability of nanostructures …
Mechanisms Of Lifetime Improvement In Thermal Barrier Coatings With Hf And/Or Y Modification Of Cmsx-4 Superalloy Substrates, Jing Liu
Electronic Theses and Dissertations
In modern turbine engines for propulsion and energy generation, thermal barrier coating (TBCs) protect hot-section blades and vanes, and play a critical role in enhancing reliability, durability and operation efficiency. In this study, thermal cyclic lifetime and microstructural degradation of electron beam physical vapor deposited (EB-PVD) Yttria Stabilized Zirconia (YSZ) with (Ni,Pt)Al bond coat and Hf- and/or Y- modified CMSX-4 superalloy substrates were examined. Thermal cyclic lifetime of TBCs was measured using a furnace thermal cycle test that consisted of 10-minute heat-up, 50-minute dwell at 1135C, and 10-minute forced-air-quench. TBC lifetime was observed to improve from 600 cycles to over …
Processing And Study Of Carbon Nanotube / Polymer Nanocomposites And Polymer Electrolyte Materials, Muthuraman Harish
Processing And Study Of Carbon Nanotube / Polymer Nanocomposites And Polymer Electrolyte Materials, Muthuraman Harish
Electronic Theses and Dissertations
The first part of the study deals with the preparation of carbon nanotube/polymer nanocomposite materials. The dispersion of multi-walled carbon nanotubes (MWNTs) using trifluoroacetic acid (TFA) as a co-solvent and its subsequent use in polymer nanocomposite fabrication is reported. The use of carbon nanotube/ polymer nanocomposite system for the fabrication of organic solar cells is also studied. TFA is a strong but volatile acid which is miscible with many commonly used organic solvents. Our study demonstrates that MWNTs can be effectively purified and readily dispersed in a range of organic solvents including dimethyl formamide (DMF), tetrahydrofuran (THF), and dichloromethane when …
Low Temperature Nitife Shape Memory Alloys: Actuator Engineering And Investigation Of Deformation Mechanisms Using In Situ Neutr, Vinu Krishnan
Low Temperature Nitife Shape Memory Alloys: Actuator Engineering And Investigation Of Deformation Mechanisms Using In Situ Neutr, Vinu Krishnan
Electronic Theses and Dissertations
Shape memory alloys are incorporated as actuator elements due to their inherent ability to sense a change in temperature and actuate against external loads by undergoing a shape change as a result of a temperature-induced phase transformation. The cubic so-called austenite to the trigonal so-called R-phase transformation in NiTiFe shape memory alloys offers a practical temperature range for actuator operation at low temperatures, as it exhibits a narrow temperature-hysteresis with a desirable fatigue response. Overall, this work is an investigation of selected science and engineering aspects of low temperature NiTiFe shape memory alloys. The scientific study was performed using in …
Vacancy Engineered Doped And Undoped Nanocrystalline Rare Earth Oxide Particles For High Temperature Oxidation Resistant Coating, Ranjith Thanneeru
Vacancy Engineered Doped And Undoped Nanocrystalline Rare Earth Oxide Particles For High Temperature Oxidation Resistant Coating, Ranjith Thanneeru
Electronic Theses and Dissertations
Rare earth oxides with trivalent lattice dopants have been of great interest to researchers in the recent years due to its potential applications in catalysis and high temperature protective coatings. The ability to store oxygen in rare earths is the basis for catalysis because of the ability to change valence states which causes the presence of intrinsic oxygen vacancies in the crystal lattice. Although, several doped-rare earth oxide systems in micron scale have been investigated, the doping effect in cerium oxide nanoparticles with well characterized particle size has not been studied. The doping of ceria at that small size can …
Understanding The Low Temperature Electrical Propertiesof Nanocrystalline Sno2 For Gas Sensor Applications, Christina Drake
Understanding The Low Temperature Electrical Propertiesof Nanocrystalline Sno2 For Gas Sensor Applications, Christina Drake
Electronic Theses and Dissertations
Nanocrystalline metal/metal oxide is an important class of transparent and electronic materials due to its potential use in many applications, including gas sensors. At the nanoscale, many of the phenomena observed that give nanocrystalline semiconducting oxide enhanced performance as a gas sensor material over other conventional engineering materials is still poorly understood. This study is aimed at understanding the low temperature electrical and chemical properties of nanocrystalline SnO2 that makes it suitable for room temperature gas detectors. Studies were carried out in order to understand how various synthesis methods affect the surfaces on the nano-oxides, interactions of a target gas …