Materials Science and Engineering Commons^™

A Study Of Protein And Peptide-Directed Nanoparticle Synthesis For Catalytic Materials, Abdollah Mosleh

Graduate Theses and Dissertations

Nanoparticles have received much attentions due to their unique properties that makes them suitable candidates for a broad range of applications. As the size of particles decreases, their surface area-to-volume ratio would increase which is the main cause of much attention. In addition to the size, their morphologies and compositions may also play important roles for defining unique properties. Nanoparticle synthesis include both bottom-up and top-down strategies. To control the process of inorganic nanoparticles synthesis one could follow the bottom-up approach to have atom-level control over their compositions, morphologies, phases, and sizes which is the subject of this work. Due …

Switching Trajectory Control For High Voltage Silicon Carbide Power Devices With Novel Active Gate Drivers, Shuang Zhao

Graduate Theses and Dissertations

The penetration of silicon carbide (SiC) semiconductor devices is increasing in the power industry due to their lower parasitics, higher blocking voltage, and higher thermal conductivity over their silicon (Si) counterparts. Applications of high voltage SiC power devices, generally 10 kV or higher, can significantly reduce the amount of the cascaded levels of converters in the distributed system, simplify the system by reducing the number of the semiconductor devices, and increase the system reliability.

However, the gate drivers for high voltage SiC devices are not available on the market. Also, the characteristics of the third generation 10 kV SiC MOSFETs …

Growth Of Indium Nitride Quantum Dots By Molecular Beam Epitaxy, Steven P. Minor

Graduate Theses and Dissertations

Over the last decade, the evolution of the global consciousness in response to decreasing environmental conditions from global warming and pollution has led to an outcry for finding new alternative/clean methods for harvesting energy and determining ways to minimize energy consumption. III-nitride materials are of interest for optoelectronic and electronic device applications such as high efficiency solar cells, solid state lighting (LEDs), and blue laser (Blu-ray Technology) applications. The wide range of direct band gaps covered by its alloys (0.7eV-6.2eV) best illustrates the versatility of III-nitride materials. This wide range has enabled applications extending from the ultraviolet to the near …

Silicone Tadpole: Research Into Soft Bodies, Danielle Fernandez

Mechanical Engineering Undergraduate Honors Theses

In this thesis, research is conducted in the area of soft robotics by building a soft tadpole that can deform with a specific air pressure. The goal is to mimic the motion of an organic tadpole in respect to its S-shaped tail movement. The angle of deformation, derived from material mechanic theories, ranges from 45 to 80 degrees for this type of movement. The design includes a head compartment which acts as a tank to transfer nitrogen pressure and a tail section that receives the said pressure and bends as a result. The tail section was designed with two rows …

Methods To Remotely Eliminate Biofilm From Medical Implants Using 2.4 Ghz Microwaves, Brett Glenn

Mechanical Engineering Undergraduate Honors Theses

Infections associated with biofilm growth are usually challenging to eradicate due to their high tolerance toward antibiotics [11, 12]. Biofilms often form on the inert surfaces of medically implanted devices [13]. No matter the sophistication, microbial infections can develop on all medical devices and tissue engineering constructs [12]. Related infections lead to 2 million cases annually in the U.S., costing the healthcare system over $5 billion in additional healthcare expenses [12].

Novel solutions to biofilm’s microbial colonization span the spectrum of engineering and science disciplines. Yet a practical solution still does not exist. The research presented here will explore a …

Modelling Palladium Decorated Graphene Using Density Functional Theory To Analyze Hydrogen Sensing Application, Sameer Kulkarni

Mechanical Engineering Undergraduate Honors Theses

Graphene is an exciting new material with many promising applications. One such application of graphene is gas sensing, when adsorbed with transition metals, notably Palladium. Therefore, it is of paramount importance to have appropriate ab initio calculations to calculate the various properties of graphene under different adsorbates and gasses. The first step in these calculations is to have a functioning base Density Functional Theory (DFT) model of pristine graphene decorated with Palladium. The computational methods described in this paper has yielded results for pristine graphene that have been confirmed many times in previous experimental and theoretical studies. Future work needs …

Bgaas Alloy Semiconductors For Lasers On Silicon, Joshua Mcarthur

Mechanical Engineering Undergraduate Honors Theses

In the world of semiconductors today, there is a large dissonance between optical devices and electrical application. Due to the limitations of electron transport, photonic integrated circuits are soon-to-be vital in fields like telecommunications and sensing. Right now, these PIC’s are mostly made from indium phosphide. Due to its ubiquitous nature, however, there is a huge push to integrate efficient optics with silicon. It’s cheap, abundant, dope-able, and our electronic infrastructure is based on it. The reason why silicon photonics aren’t already commercialized is because of silicon’s indirect bandgap—it is inefficient with optical applications. The problem with combining direct gap …

Structural Design Guidelines For Pervious Concrete Pavements, April Smith

Civil Engineering Undergraduate Honors Theses

Pervious pavements have gained popularity in recent years as the transportation industry focuses on sustainability and environmental impact. This research investigated the structural design of pervious concrete pavements. There is no standard design method; therefore, the goal was to lessen ambiguity surrounding the use of pervious concrete for pavement structures. By characterization of the rigid pavement design equation from the 1993 AASHTO Structural Design Guide for Design of Pavement Structures through laboratory exploration and review of existing literature, a guide was created to assist engineers in the design of pervious concrete pavements.

A Silicon Germanium Cmos Linear Voltage Regulator For Wireless Agricultural Applications, Aminta Naidili Castillo Robles

Graduate Theses and Dissertations

This thesis presents the design, simulation and test results of a silicon germanium (SiGe) complementary metal-oxide-semiconductor (CMOS) linear regulator. The objective of the circuit is to power other analog devices regardless of the load current and input voltage changes. The application of this regulator is to be part of a project developing a miniaturized semiconductor platform that can be inserted into stems of crops in order to measure data inside the plant and then send it wirelessly to the user. The linear regulator was designed on a BiCMOS SiGe 0.13µm which is a GlobalFoundries process. It has been tested at …

Plasmonic Properties Of Nanoparticle And Two Dimensional Material Integrated Structure, Desalegn Tadesse Debu

Graduate Theses and Dissertations

Recently, various groups have demonstrated nano-scale engineering of nanostructures for optical to infrared wavelength plasmonic applications. Most fabrication technique processes, especially those using noble metals, requires an adhesion layer. Previously proposed theoretical work to support experimental measurement often neglect the effect of the adhesion layers. The first finding of this work focuses on the impact of the adhesion layer on nanoparticle plasmonic properties. Gold nanodisks with a titanium adhesion layer are investigated by calculating the scattering, absorption, and extinction cross-section with numerical simulations using a finite difference time domain (FDTD) method. I demonstrate that a gold nanodisk with an adhesive …

Investigation Of Critical Technologies Of Chemical Vapor Deposition For Advanced (Si)Gesn Materials, Joshua Matthew Grant

Graduate Theses and Dissertations

The development of new materials for efficient optoelectronic devices from Group IV elements is the heart of Group IV photonics. This has direct ties to modern technology as the foundation for the electronics industry is silicon. This has driven the development of silicon-based optoelectronics using these other Group IV materials as silicon is a poor optical material due to its indirect band gap when compared to the III-V semiconductors that are used by most of the optoelectronics industry. While efforts have been made to integrate III-V materials onto silicon substrates, the incompatibility with the complementary metal oxide semiconductor process has …

Optical Enhancement In Periodic Plasmonic Gratings For Sers And Metal-Semiconductor-Metal Photodetectors (Msm-Pds) Applications, Ahmad Aziz Darweesh

Graduate Theses and Dissertations

This dissertation is aimed to numerically study the effect of plasmonic grating electrodes on the efficiency of metal-semiconductor-metal photodetectors (MSM PDs) and the sensitivity of Surface Enhanced Raman Spectroscopy (SERS). This research can benefit many areas of nanoscience and optics, including plasmonic applications, such as, super lenses, nano-scale optical circuits, optical filters, surface plasmon enhanced photo-detectors solar cells, imaging sensors, charge-coupled devices (CCD), and optical-fiber communication systems. Several parameters, wire widths and thickness, gap space, taper angle, and the incident wavelength and angle, were investigated. The goal of this research is to utilize the plasmonic phenomenon by using plasmonic gratings …

Removal Of Synthetic Azo Dye Using Bimetallic Nickel-Iron Nanoparticles, Shelby L. Foster, Katie Estoque, Michael Voecks, Nikki Rentz, Lauren F. Greenlee

Chemical Engineering Faculty Publications and Presentations

Bimetallic nanoparticles comprised of iron (Fe) and nickel (Ni) were investigated for the removal of an azo dye contaminant in water. Morphology (core shell and alloy) and metal molar ratio (Ni2Fe10, Ni5Fe10, and Ni10Fe10) were tested as key nanoparticle properties. The shelf life of the nanoparticles was tested over a 3-week period, and the effect of initial nanoparticle concentration on dye removal was evaluated. The highest initial nanoparticle concentration (1000 mg/L) showed consistent Orange G removal and the greatest extent of dye removal, as compared to the other tested concentrations (i.e., 750 mg/L, 500 mg/L, and 250 mg/L) for the …

Cadmium Sulfide-Buffered Pv Systems: Assessing The Environmental, Health, And Economic Impacts, Maqsood Ali Mughal, Rajesh Sharma

Journal of the Arkansas Academy of Science

As the world’s population continues to grow, global energy crises are expected to rise in the future, thus accelerating the demand for renewable energy technology, particularly solar photovoltaics. The energy sector will face an increasingly complex array of interlocking challenges - technological, environmental, health, economic, and regulatory. In this paper, we study CdS, a widely used buffer material in thin film photovoltaics, to assess and monetize environmental, health, and socio-economic externalities associated with the use of the material. Currently, CdS has a significant advantage over other alternate buffer materials in terms of efficiency and low-cost production of large-area processing of …

Young’S Modulus As A Measurement To Estimate Damage Related With Alkali-Silica Reaction In Concrete., Anazaria J. Ortega Gonzalez

Civil Engineering Undergraduate Honors Theses

The main purpose of this research is to compare two nondestructive methods to assess Alkali-Silica reaction (ASR) in concrete. Fifteen concrete prisms were cast using aggregates with different Alkali-Silica reactivity such as Jobe sand and Van Buren sand. The change in strain, shear wave velocity and Young’s modulus were determined according to ASTM C129 and ASTM C215, respectively. This data was collected by Dillon K Self, who determined that the shear wave velocity and strain are inversely proportional. However, when single cracking in the concrete specimen transition to map cracking, the shear wave velocity dropped significantly, whereas the strain value …

Optimization Of The Practice Of Slow Cooling Steel Bars: A Redesign And Modernization Of Materials, Eryn Johnston

Mechanical Engineering Undergraduate Honors Theses

Throughout the process of steel making, certain grades of steel are a higher risk for defects caused by the inability to quickly diffuse hydrogen through the steel when cooled to room temperature at a normal rate based on the ambient air temperature. To reduce the hydrogen flaking defects that are caused due to hydrogen entrapment in the steel, the process of slow cooling is utilized. This process reduces the cooling rate of steel bars by keeping them at a higher temperature for extended periods and in turn gives the hydrogen a chance to fully dissipate from the steel. In many …

Growth And Characterization Of Silicon-Germanium-Tin Semiconductors For Future Nanophotonics Devices, Bader Saad Alharthi

Graduate Theses and Dissertations

The bright future of silicon (Si) photonics has attracted research interest worldwide. The ultimate goal of this growing field is to develop a group IV based Si foundries that integrate Si-photonics with the current complementary metal–oxide–semiconductor (CMOS) on a single chip for mid-infrared optoelectronics and high speed devices. Even though group IV was used in light detection, such as photoconductors, it is still cannot compete with III-V semiconductors for light generation. This is because most of the group IV elements, such as Si and germanium (Ge), are indirect bandgap materials. Nevertheless, Ge and Si attracted industry attention because they are …

Fabrication And Characterization Of Electrochemical Glucose Sensors, Mohammed Marie

Graduate Theses and Dissertations

Electrochemical sensors based on the nanostructure of the semiconductor materials are of tremendous interest to be utilized for glucose monitoring. The sensors, based on the nanostructure of the semiconductor materials, are the third generations of the glucose sensors that are fast, sensitive, and cost-effect for glucose monitoring.

Glucose sensors based on pure zinc oxide nanorods (NRs) grown on different substrates, such ITO, FTO, and Si/SiO2/Au, were investigated in this research. Silicon nanowire (NW)- based glucose sensors were also studied. First, an enzyme-based glucose sensor was fabricated out of glass/ITO/ZnO NRs/BSA/GOx/nafion membrane. The sensor was tested amperometrically at different glucose concentrations. …

Measuring Characteristic Shrinkage Variability Due To Metal Loading Effects In Low Temperature Co-Fired Ceramic Using Image Processing, John Ezekiel Zumbro

Graduate Theses and Dissertations

Low temperature co-fired ceramic (LTCC) has many benefits when it comes to electronic packaging due to the low dielectric loss, reliability in extreme environments, and high breakdown voltage. Though the ceramic has a lot of benefits it is not widely used due to the high cost and complexities associated with manufacturing. One of these issues with manufacturing is compensating for the shrinkage of the ceramic, this is accomplished by using an expansion factor, creating the “green” or manufactured design. This expansion factor is approximated through knowledge of the ceramic factors such as the metal loading, layers of ceramic tape, firing …

Growth And Behaviors Of Inn/Gan Multiple Quantum Wells By Plasma-Assisted Molecular Beam Epitaxy, Chen Li

Graduate Theses and Dissertations

Fully realizing the potential of InGaN semiconductors requires high quality materials with arbitrary In-content. To this date the growth of In-rich InGaN films is still challenging since it suffers from the low growth temperatures and many detrimental alloying problems. InN/GaN multiple quantum wells (MQWs) and super lattices (SLs) are expected to be promising alternatives to random InGaN alloys since in principle they can achieve the equivalent band gap of InGaN random alloys with arbitrarily high In-content and at the same time bypass many growth difficulties.

This dissertation focuses on studying the growth mechanisms, structural properties and energy structures of InN/GaN …

Comparative Study Of Power Semiconductor Devices In A Multilevel Cascaded H-Bridge Inverter, Kenneth Mordi

Graduate Theses and Dissertations

This thesis compares the performance of a nine-level transformerless cascaded H-bridge (CHB) inverter with integrated battery energy storage system (BESS) using SiC power MOSFETs and Si IGBTs. Two crucial performance drivers for inverter applications are power loss and efficiency. Both of these are investigated in this thesis. Power devices with similar voltage and current ratings are used in the same inverter topology, and the performance of each device is analyzed with respect to switching frequency and operating temperature. The loss measurements and characteristics within the inverter are discussed. The Saber® simulation software was used for the comparisons. The power MOSFET …

Incorporation Of Silica Nanoparticles Into The Underlayer Of Pda/Ptfe Thin Coatings, Adedoyin Abe

Mechanical Engineering Undergraduate Honors Theses

Polytetrafluoroethylene (PTFE) is one of the most low friction and corrosion resistant solid lubricants. Prior studies have shown that a polydopamine (PDA) underlayer enhances the durability of PTFE thin coating. In this study, 100, 200, and 300 µL of aqueous silica nanoparticle (NP) solutions were added to the PDA deposition solution. The durability and coefficient of friction of PDA/PTFE thin coatings on stainless steel substrates are investigated with and without incorporating the silica NPs. The coatings were tested in dry contact conditions using a Universal Mechanical Tester (UMT) with a ball-on-flat configuration in a reciprocating motion. It was found that …

Properties Of Matter, Mike Jackson, Holly Haney

High School Lesson Plans

Students will investigate the relationship(s) between thermal and electrical properties of matter. First, students will use a multimeter and temperature probe to investigate the relationship between electrical resistance and temperature of an electrical resistor composed of metals. They will then graph collected data to analyze the relationship and draw a conclusion as to their relationship. They will then perform the same investigation on a thermal resistor made of a semiconducting substance and analyze that collected data. Finally, using ClaimEvidence-Reasoning (CER) structure, students will use their experimental evidence to state the similarities and differences between the electro-thermal properties of metals and …

Mesoscale Computational Studies Of Thin-Film Bijels, Joseph M. Carmack

Graduate Theses and Dissertations

Bijels are a relatively new class of soft materials that have many potential applications in the technology areas of energy, medicine, and environmental sustainability. They are formed by the arrest of binary liquid spinodal decomposition by a dispersion of solid colloidal nanoparticles. This dissertation presents an in-depth simulation study of Bijels constrained to thin-film geometries and in the presence of electric fields. We validate the computational model by comparing simulation results with previous computational modeling and experimental research. In the absence of suspended particles, we demonstrate that the model accurately captures the rich kinetics associated with diffusion-based surface-directed spinodal decomposition. …

Effects Of Surface-Directed Spinodal Decomposition On Binary Thin-Film Morphology, Michael Brian Wise

Graduate Theses and Dissertations

Preferential wetting can have a significant impact on the kinetics of phase separation in certain systems. The depletion of the wetting component can simply alter domain growth rates or change the structure entirely. In this thesis, we employ a Cahn-Hilliard model to study the evolution of binary thin-films with symmetric surface wetting. Three possible morphologies were identified: discrete, bicontinuous, and a novel quasi-2D bicontinuous structure in which both phases retain continuity throughout the volume as well as on the center xy plane. Using a continuity factor, regions of film thickness versus blend composition were classified as producing a certain morphology. …

Phase Field Model Of Thermally Induced Phase Separation (Tips) For The Formation Of Porous Polymer Membranes, Ashley Green, Aria Green

Mechanical Engineering Undergraduate Honors Theses

Most membrane research and development has been done through experimental work, which can be costly and time consuming. An accurate computational model would greatly reduce the need for these experiments. The focus of the research presented in this paper is to create an accurate computational model for membrane formation using thermally induced phase separation (TIPS). A phase field model is employed to create this model including the Cahn Hilliard Equation and Flory Huggins Theory. This model produced computational results that correspond well with theoretical and experimental results. The model was then adapted to correspond to the PVDF/DPC polymer-solvent system by …

Surface Area And Electrocatalytic Properties Of Feni Nanoparticles For The Oxygen Evolution Reaction (Oer), James Burrow

Chemical Engineering Undergraduate Honors Theses

Iron-nickel bimetallic electrocatalysts have recently emerged as some of the best candidates for the oxygen evolution reaction (OER) in alkaline electrolyte. Understanding the effects of composition and morphology of iron-nickel nanoparticles is crucial for optimization and enhanced electrocatalyst performance. Both physical surface area and electrochemical surface area (ECSA) are functions of morphology. In this study, four different iron-nickel nanoparticle catalysts were synthesized. The catalysts were varied based on morphology (alloy versus core-shell) and composition (low, medium, and high stabilizer concentration). Brunauer-Emmett-Teller (BET) surface area analysis was conducted on three of the synthesized iron-nickel nanoparticles using a physisorption analyzer while electrochemical …

Design, Fabrication, And Characterization Of Novel Optoelectronic Devices For Near-Infrared Detection, Ahmad Nusir

Graduate Theses and Dissertations

Investigating semiconductor materials and devices at the nanoscale has become crucial in order to maintain the exponential development in today’s technology. There is a critical need for making devices lower in power consumption and smaller in size. Nanoscale semiconductor materials provide a powerful platform for optoelectronic device engineers. They own interesting properties which include enhanced photoconductivity and size-tunable interband transitions.

In this research, different types of nanostructures were investigated for optoelectronic devices: nanocrystals, nanowires, and thin-films. First, lead selenide nanocrystals with narrow bandgap were synthesized, size-tailored, and functionalized with molecular ligands for the application of uncooled near-infrared photodetectors. The devices …

Design, Fabrication, And Characterization Of All-Inorganic Quantum Dot Light Emitting Diodes, Ramesh Vasan

Graduate Theses and Dissertations

Quantum dot light emitting diodes are investigated as a replacement to the existing organic light emitting diodes that are commonly used for thin film lighting and display applications. In this, all-inorganic quantum dot light emitting diodes with inorganic quantum dot emissive layer and inorganic charge transport layers are designed, fabricated, and characterized. Inorganic materials are more environmentally stable and can handle higher current densities than organic materials. The device consists of CdSe/ZnS alloyed core/shell quantum dots as the emissive layer and metal oxide charge transport layer. The charge transport in these devices is found to occur through resonant energy transfer …

Fabrication And Characterization Of Graphene Based 2d Materials For Supercapacitors, Anishkumar Manoharan

Graduate Theses and Dissertations

Supercapacitors have attracted a lot attention due to their efficient energy storage. In comparison to batteries, supercapacitors have high capacitance, energy, and power densities per unit mass than conventional capacitors. Carbon based materials are most promising in supercapacitor application due to their outstanding physical and electrochemical behavior. In this work, a facile method to synthesize a nanocomposite electrode consisting of annealed carbon from carbon ink and MoS2 was demonstrated. Effects of various aqueous and solid electrolytes were studied. It was found that the nanocomposite electrode with 10% MoS2 and 1M Na2SO4 as the aqueous electrolyte tested using the three electrode …