Materials Science and Engineering Commons^™

Improved Gas Sensing Performance Of Ald Azo 3-D Coated Zno Nanorods, P. Lin, X. Chen, K. Zhang, H. Baumgart

Electrical & Computer Engineering Faculty Publications

This paper reports an enhancement on the sensing performance of ZnO nanorod ethanol sensors with a new approach by utilizing nested coatings of Aluminum doped ZnO (AZO) thin films by Atomic Layer Deposition (ALD) technology. ZnO nanorods were grown by the hydrothermal method with the ZnO seed layer synthesized on Silicon wafers by ALD. To enhance the sensing performance of ZnO nanorod ethanol sensors, multiple coated AZO thin film 3-D coatings were deposited on the surface of the intrinsic ZnO nanorods by ALD.To investigate the sensing performance of the ZnO nanorods sensor for the detection of ethanol vapor, a gas …

Pneumatospinning Of Collagen Microfibers From Benign Solvents, Seth Polk, Nardos Sori, Nick Thayer, Yas Maghdouri-White, Anna A. Bulysheva, Michael P. Francis

School of Medical Diagnostics & Translational Sciences Publications

Introduction. Current collagen fiber manufacturing methods for biomedical applications, such as electrospinning and extrusion, have had limited success in clinical translation, partially due to scalability, cost, and complexity challenges. Here we explore an alternative, simplified and scalable collagen fiber formation method, termed 'pneumatospinning,' to generate submicron collagen fibers from benign solvents. Methods and results. Clinical grade type I atelocollagen from calf corium was electrospun or pneumatospun as sheets of aligned and isotropic fibrous scaffolds. Following crosslinking with genipin, the collagen scaffolds were stable in media for over a month. Pneumatospun collagen samples were characterized using Fourier-transform infrared spectroscopy, circular dichroism, …

No2- And No3- Enhance Cold Atmospheric Plasma Induced Cancer Cell Death By Generation Of Onoo-, Dehui Xu, Qingjie Cui, Yujing Xu, Zhijie Liu, Zeyu Chen, Wenjie Xia, Hao Zhang, Dingxin Liu, Hailan Chen, Michael G. Kong

Bioelectrics Publications

Cold atmospheric plasma (CAP) is a rapidly developed technology that has been widely applied in biomedicine especially in cancer treatment. Due to the generation of various active species in plasma, CAP could induce various tumor cells death and showed a promising potential in cancer therapy. To enhance the biological effects of gas plasma, changing the discharging parameters is the most commonly used method, yet increasing discharging power will lead to a higher possibility of simultaneously damage surrounding tissues. In this study, by adding nontoxic concentration of additional nitrite and nitrate in the medium, we found that anti-tumor effect of CAP …

Current-Driven Production Of Vortex-Antivortex Pairs In Planar Josephson Junction Arrays And Phase Cracks In Long-Range Order, Francisco Estellés-Duart, Miguel Ortuño, Andrés M. Somoza, Valerii M. Vinokur, Alex Gurevich

Physics Faculty Publications

Proliferation of topological defects like vortices and dislocations plays a key role in the physics of systems with long-range order, particularly, superconductivity and superfluidity in thin films, plasticity of solids, and melting of atomic monolayers. Topological defects are characterized by their topological charge reflecting fundamental symmetries and conservation laws of the system. Conservation of topological charge manifests itself in extreme stability of static topological defects because destruction of a single defect requires overcoming a huge energy barrier proportional to the system size. However, the stability of driven topological defects remains largely unexplored. Here we address this issue and investigate numerically …

Optimization Of Top Contact For Cu(In,Ga)Se2 Solar Cells, Grace Cherukara Rajan

Electrical & Computer Engineering Theses & Dissertations

As world energy demands continue to increase, the need to generate electricity from a broader variety of sources, including renewables, is more critical than ever. With costs still 30% higher than those of natural gas, solar energy is a viable contender, but more progress is needed to level the playing field with other forms of energy generation. The overall energy security can be enhanced by diversifying the energy supply. Among them, Cu(In,Ga)Se₂ (CIGS) has gained significant momentum as a possible high efficiency and low cost thin film solar cell material. The capacity to scale up any photovoltaic technology is …

Non-Destructive Evaluation For Composite Material, Desalegn Temesgen Delelegn

Electrical & Computer Engineering Theses & Dissertations

The Nondestructive Evaluation Sciences Branch (NESB) at the National Aeronautics and Space Administration (NASA) Langley Research Center (LaRC) has conducted impact damage experiments over the past few years with the goal of understanding structural defects in composite materials. The Data Science Team within the NASA LaRC Office of the Chief Information Officer (OCIO) has been working with the Non-Destructive Evaluation (NDE) subject matter experts (SMEs), Dr. Cheryl Rose, from the Structural Mechanics & Concepts Branch and Dr. William Winfree, from the Research Directorate, to develop computer vision solutions using digital image processing and machine learning techniques that can help identify …

Effects Of Automated Fiber Placement On High Strain Rate Compressive Response Of Advanced Composites, Alexander Trochez

Mechanical & Aerospace Engineering Theses & Dissertations

Automated Fiber Placement (AFP) technology shows great promise in manufacturing carbon fiber composite structures. However, intermittent defects occur in the process that can affect the overall mechanical performance of the structure. The aim of this work is to investigate the effects of deliberately placed principal defects (Gap, Overlap, and Fold) on the compressive response under quasistatic (strain rate ~10^-3 s^-1) and dynamic (strain rate ~10³ s-1) loading conditions. The controlled defects were placed at the laminate level in different orientations and depths. High strain rate compression experiments were conducted using a split Hopkinson pressure bar (SHPB) …

Characterization And Analysis Of Ultrathin Cigs Films And Solar Cells Deposited By 3-Stage Process, Grace Rajan, Krishna Aryal, Shankar Karki, Puruswottam Aryal, Robert W. Collins, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

In view of the large-scale utilization of Cu(In,Ga)Se₂ (CIGS) solar cells for photovoltaic application, it is of interest not only to enhance the conversion efficiency but also to reduce the thickness of the CIGS absorber layer in order to reduce the cost and improve the solar cell manufacturing throughput. In situ and real-time spectroscopic ellipsometry (RTSE) has been used conjointly with ex situ characterizations to understand the properties of ultrathin CIGS films. This enables monitoring the growth process, analyzing the optical properties of the CIGS films during deposition, and extracting composition, film thickness, grain size, and surface roughness which …

New Method Of Nickel Oxide As Hole Transport Layer And Characteristics Of Nickel Oxide Based Perovskite Solar Cell, Loi Nguyen

Electrical & Computer Engineering Theses & Dissertations

For perovskite solar cells, poly (2,3-dihydrothieno-1, 4-dioxin)-poly (styrenesulfonate) (PEDOT:PSS) is a common hole transport layer. However, PEDOT:PSS has a lot of drawbacks, such as irregular quality from distributors, poor electron blocker, and hygroscopic nature. On the other hand, NiOx has been reported that it can provide good stability and carrier mobility. From literature, NiOx was used to replace PEDOT:PSS as a hole transport layer with positive results since it is transparent as a thin film and also possesses compatible work function in perovskite solar cell bandgap alignment. In depositing NiOx as a thin film, many approaches have been developed. However, …

Development And Evaluation Of Post-Production Oxygenation Techniques For The Augmentation Of Biochar, Matthew David Huff

Chemistry & Biochemistry Theses & Dissertations

Biochar is the carbon rich solid by-product of biomass pyrolysis. Interest in biochar can be broken down to several main categories: use as a carbon sequestration agent, use as a medium for the removal via adsorption of unwanted materials in wastewater, and as a soil amendment for the increase of cation exchange capacity (CEC). In order to generate a biochar which is stable enough for carbon sequestration, higher temperature pyrolysis must be used in order to ensure a lower O:C ratio in order to increase the half-life of biochar in soil. This dissertation addresses the evaluation of biochars made from …

Effects Of Protein-Coated Nanofibers On Conformation Of Gingival Fibroblast Spheroids: Potential Utility For Connective Tissue Regeneration, Gili Kaufman, Ryan A. Whitescarver, Laiz Nunes, Xavier-Lewis Palmer, Drago Skrtic, Wojtek Tutak

Engineering Technology Faculty Publications

Deep wounds in the gingiva caused bytrauma or surgery require a rapid and robust healing of connective tissues. Wepropose utilizing gas-brushed nanofibers coated with collagen and fibrin for that purpose. Our hypotheses are that protein-coated nanofibers will: (i) attract and mobilize cells in various spatial orientations, and (ii) regulate the expression levels ofspecific extracellular matrix (ECM)-associated proteins, determining the initial conformational nature ofdense and soft connective tissues. Gingival fibroblast monolayers and3D spheroids were cultured onECMsubstrate and covered with gas-blown poly-(DL-lactide-co-glycolide)(PLGA) nanofibers (uncoated/coated with collagen and fibrin). Cell attraction and rearrangement was followed byF-actin staining and confocal microscopy. Thicknesses ofthe cell …

Effect Of Curing Rate On The Microstructure And Macroscopic Properties Of Epoxy Fiberglass Composites, Ammar Patel, Olesksandr Kravchenko, Ica Manas-Zloczower

Mechanical & Aerospace Engineering Faculty Publications

Curing rates of an epoxy amine system were varied via different curing cycles, and glass-fiber epoxy composites were prepared using the same protocol, with the aim of investigating the correlation between microstructure and composite properties. It was found that the fast curing cycle resulted in a non-homogenous network, with a larger percentage of a softer phase. Homogenized composite properties, namely storage modulus and quasi-static intra-laminar shear strength, remained unaffected by the change in resin microstructure. However, fatigue tests revealed a significant reduction in fatigue life for composites cured at fast curing rates, while composites with curing cycles that allowed a …

Novel Contact Materials For Improved Performance Cdte Solar Cells, Angus Rocket, Robert Collins, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

This program has explored a number of novel materials for contacts to CdTe solar cells in order to reduce the back contact Schottky barrier to zero and produce an ohmic contact. The project tested a wide range of potential contact materials including TiN, ZrN, CuInSe₂:N, a-Si:H and alloys with C, and FeS₂. Improved contacts were achieved with FeS₂. As part of understanding the operation of the devices and controlling the deposition processes, a number of other important results were obtained. In the process of this project and following its conclusion it led to research …

Direct Strength Approach To Predict The Flexural Strength Of Cold-Formed Z-Section Purlins On Sloped Roofs, Ali Parva, Michael W. Seek

Engineering Technology Faculty Publications

In this study, the strength of cold-formed Z-section purlins is predicted considering the effects of roof slope in real roof systems. The study applies to simple span purlins with torsion restraints at support locations and at paired locations along the length of the member. A previously developed method has shown through comparisons to base tests that when the biaxial bending and torsion stresses are incorporated into the analysis, the Direct Strength Method can accurately predict the strength of a purlin. These stress distributions can deviate substantially from the constrained bending approximation typically assumed in analysis and therefore impacts the local …

A Scientific Approach To Understanding The Head Trauma Endured By A Mixed Martial Arts Fighter, John William Michael Sorbello

Mechanical & Aerospace Engineering Theses & Dissertations

The purpose of this research is to gain some insight on the type of head trauma an athlete may encounter during mixed martial arts (MMA) competition. These athletes endure continuous blows to the head throughout their training and fighting career. The knowledge obtained from this research may assist MMA athletes and trainers in assessing the way they train, how they compete and, more importantly, how long they choose to compete in their amateur or professional MMA career.

The analysis is performed by first creating a three-dimensional solid model of the human head based on geometric coordinates originally obtained from a …

Behavior And Strength Of Rc Spandrel Members Under Unsymmetrical Bending And Torsion Including Cfrp Retrofitting, Muhammad Fahim

Civil & Environmental Engineering Theses & Dissertations

This dissertation presents the outcome of an experimental and theoretical investigation of the behavior and strength of reinforced concrete spandrel members both with and without carbon fiber reinforced polymer (CFRP) retrofitting. Both isolated spandrel members with L-shaped cross section as well as those integrated with reinforced concrete slabs are studied. A series of isolated spandrel members were tested under separate and combined actions of unsymmetrical bending and torsion. Six of these specimens were retrofitted externally with high-strength CFRP strips. Materially nonlinear analysis procedures are also formulated and programmed for the spandrel members with and without CFRP retrofitting. Furthermore, ultimate bending-torsion …

6 Field-Observed Cracking Of Paired Lightweight And Normalweight Concrete Bridge Decks, Tara L. Cavalline, Jeremy T. Calamusa, Amy M. Kitts, Brett Q. Tempest

Engineering Technology Faculty Publications

Research has suggested that conventional lightweight concrete can offer durability advantages due to reduced cracking tendency. Although a number of publications exist providing the results of laboratory-based studies on the durability performance of lightweight concrete (with lightweight coarse aggregate) and internally cured concrete (using prewetted lightweight fine aggregate), far fewer field studies of durability performance of conventional lightweight concrete bridge decks in service have been performed. This study was commissioned to provide insight to a highway agency on whether enhanced durability performance, and therefore reduced maintenance and longer lifecycles, could be anticipated from existing lightweight concrete bridge decks that were …

Light Soaking Phenomena In Organic-Inorganic Mixed Halide Perovskite Single Crystals, Hye Ryung Byun, Dae Young Park, Hye Min Oh, Gon Namkoong, Mun Seok Jeong

Electrical & Computer Engineering Faculty Publications

Recently, organic inorganic mixed halide perovskite (MAPbX₃; MA = CH₃NH₃^+, X = Cl^-, Br^-, or I^-) single crystals with low defect densities have been highlighted as candidate materials for high-efficiency photovoltaics and optoelectronics. Here we report the optical and structural investigations of mixed halide perovskite (MAPbBr_3-xI_x) single crystals. Mixed halide perovskite single crystals showed strong light soaking phenomena with light illumination conditions that were correlated to the trapping and detrapping events from defect sites. By systematic investigation with optical analysis, we found that the …

Impact Of Trucking Network Flow On Preferred Biorefinery Locations In The Southern United States, Timothy M. Young, Lee D. Han, James H. Perdue, Stephanie R. Hargrove, Frank M. Guess, Xia Huang, Chung-Hao Chen

Electrical & Computer Engineering Faculty Publications

The impact of the trucking transportation network flow was modeled for the southern United States. The study addresses a gap in existing research by applying a Bayesian logistic regression and Geographic Information System (GIS) geospatial analysis to predict biorefinery site locations. A one-way trucking cost assuming a 128.8 km (80-mile) haul distance was estimated by the Biomass Site Assessment model. The "median family income," "timberland annual growth-to-removal ratio," and "transportation delays" were significant in determining mill location. Transportation delays that directly impacted the costs of trucking are presented. A logistic model with Bayesian inference was used to identify preferred site …

Impact Of Clip Connection And Insulation Thickness On Bracing Of Purlins In Standing Seam Roof Systems, Michael W. Seek, Daniel Mclaughlin

Engineering Technology Faculty Publications

The flexural strength of purlins in standing seam roof systems is highly dependent upon the extent to which the sheathing provides lateral and torsional restraint. Typical models to predict the restraint provided by the sheathing assume that the plane of lateral resistance occurs at the top flange of the purlin. In reality, depending on the configuration of the clip and the amount of insulation located between the purlin and the clip, the plane of lateral resistance and corresponding center of rotation shifts above the top flange. This distance, referred to as the effective standoff, is important to evaluate the effectiveness …

Imaging Of Super-Fast Dynamics And Flow Instabilities Of Superconducting Vortices, L. Embon, Y. Anahory, Ž L. Jelić, E. O. Lachman, Y. Myasoedov, M. E. Huber, G. P. Mikitik, A. V. Silhanek, M. V. Milošević, A Gurevich, E. Z. Zeldov

Physics Faculty Publications

Quantized magnetic vortices driven by electric current determine key electromagnetic properties of superconductors. While the dynamic behavior of slow vortices has been thoroughly investigated, the physics of ultrafast vortices under strong currents remains largely unexplored. Here, we use a nanoscale scanning superconducting quantum interference device to image vortices penetrating into a superconducting Pb film at rates of tens of GHz and moving with velocities of up to tens of km/s, which are not only much larger than the speed of sound but also exceed the pair-breaking speed limit of superconducting condensate. These experiments reveal formation of mesoscopic vortex channels which …

Preface-Jes Focus Issue On Electrolysis For Increased Renewable Energy Penetration, B. Pivovar, M. Carmo, K. Ayers, X. Zhang, J. O'Brien

Mechanical & Aerospace Engineering Faculty Publications

(First paragraph) Today represents a particularly exciting time, as our planet’s energy system is undergoing major changes due to dramatically decreasing renewable energy prices and increasing societal concerns over greenhouse gas emissions, criteria pollutants (arsenic, mercury, NOx, particulate matter), and climate change. These factors are pushing society toward deep decarbonization of our energy system, perhaps the most challenging issue facing the planet today. Unfortunately, wind and solar energy, while both promising generation sources, come with intermittency challenges and have limitations in their abilities to impact industrial and transportation sector demands where fossil fuel energy carriers based on chemical bonds have …

An Examination Of The Indentation Size Effect In Fcc Metals And Alloys From A Kinetics Based Perspective Using Nanoindentation, David Earl Stegall

Mechanical & Aerospace Engineering Theses & Dissertations

The indentation size effect (ISE) in metals is described as the rise in hardness with decreasing depth of indentation and contradicts conventional plasticity behavior. The goal of this dissertation is to further examine the fundamental dislocation mechanisms that may be contributing to the so-called indentation size effect. In this work, we examined several metals and alloys including 99.999% Aluminum (SFE ~200 mJ/m²), 99.95% Nickel (SFE ~125 mJ/m²), 99.95% Silver (SFE ~22 mJ/m²⁾, and three alloys, alpha brass 70/30 (SFE >10 mJ/m²), 70/30 nickel copper (SFE ~100 mJ/ …

A Comparison Of Microstructure And Uniaxial Compressive Response Of Ice-Templated Porous Alumina Scaffolds Fabricated From Two Different Particle Sizes, Nikhil D. Dhavale

Mechanical & Aerospace Engineering Theses & Dissertations

Development of bio-inspired highly porous (>50 vol.%) cellular ceramics is crucial to meet the demand of high-performance lightweight and damage-tolerant materials for a number of cutting-edge applications including impact energy absorption, biomedical implants, and energy storage. A key design feature that is observed in many natural materials (e.g., nacre, bamboo, wood, etc.) is the presence of hierarchical microstructure that results in an excellent synergy of various material properties, which are otherwise considered as mutually exclusive in current paradigm of materials design. To this end, development of multilayered, interconnected and anisotropic cellular ceramics could benefit the aforementioned applications. However, mimicking …

Plasma Processing Of Superconducting Radio Frequency Cavities, Janardan Upadhyay

Physics Theses & Dissertations

The development of plasma processing technology of superconducting radio frequency (SRF) cavities not only provides a chemical free and less expensive processing method, but also opens up the possibility for controlled modification of the inner surfaces of the cavity for better superconducting properties. The research was focused on the transition of plasma etching from two dimensional flat surfaces to inner surfaces of three dimensional (3D) structures. The results could be applicable to a variety of inner surfaces of 3D structures other than SRF cavities. Understanding the Ar/Cl₂ plasma etching mechanism is crucial for achieving the desired modification of Nb …

Secondary Electron Emission From Plasma Processed Accelerating Cavity Grade Niobium, Miloš Bašović

Mechanical & Aerospace Engineering Theses & Dissertations

Advances in the particle accelerator technology have enabled numerous fundamental discoveries in 20th century physics. Extensive interdisciplinary research has always supported further development of accelerator technology in efforts of reaching each new energy frontier.

Accelerating cavities, which are used to transfer energy to accelerated charged particles, have been one of the main focuses of research and development in the particle accelerator field. Over the last fifty years, in the race to break energy barriers, there has been constant improvement of the maximum stable accelerating field achieved in accelerating cavities. Every increase in the maximum attainable accelerating fields allowed for higher …

Thin Film Studies Toward Improving The Performance Of Accelerator Electron Sources, Md Abdullah Al Mamun

Mechanical & Aerospace Engineering Theses & Dissertations

Future electron accelerators require DC high voltage photoguns to operate beyond the present state of the art to conduct new experiments that require ultra-bright electron beams with high average current and higher bunch charge. To meet these demands, the accelerators must demonstrate improvements in a number of photogun areas including vacuum, field emission elimination in high voltage electrodes, and photocathodes. This dissertation illustrates how these improvements can be achieved by the application of suitable thin-films to the photogun structure for producing ultra-bright electron beams.

This work is composed of three complementary studies. First, the outgassing rates of three nominally identical …

Uv Light-Induced Aggregation Of Titania Submicron Particles, Can Zhou, Yashar Bashirzadeh, Timothy A. Bernadowsky Jr., Xiaoyu Zhang

Mechanical & Aerospace Engineering Faculty Publications

In this study, aggregation of TiO₂ (rutile and anatase) submicron particles in deionized (DI) water under ultra-violet (UV) light irradiation was investigated. While no aggregation was observed in the dark, rutile and anatase submicron particles started aggregating upon application of UV light and ceased aggregation in about 2 and 8.4 h, respectively. It has been demonstrated that UV light directly mitigated the particle mobility of TiO₂, resulting in a neutralization effect of the Zeta potential. It was also observed that rutile particles aggregated much faster than anatase particles under UV radiation, indicating that the Zeta potential of …

The Role Of Microbial Exopolymers In Determining The Fate Of Oil And Chemical Dispersants In The Ocean, Antonietta Quigg, Uta Passow, Wei-Chun Chin, Chen Xu, Shawn Doyle, Laura Bretherton, Manoj Kamalanathan, Alicia K. Williams, Jason B. Sylvan, Zoe V. Finkel, Anthony H. Knap, Kathleen A. Schwehr, Saijin Zhang, Luni Sun, Terry L. Wade, Wassim Obeid, Patrick G. Hatcher, Peter H. Santschi

Chemistry & Biochemistry Faculty Publications

The production of extracellular polymeric substances (EPS) by planktonic microbes can influence the fate of oil and chemical dispersants in the ocean through emulsification, degradation, dispersion, aggregation, and/or sedimentation. In turn, microbial community structure and function, including the production and character of EPS, is influenced by the concentration and chemical composition of oil and chemical dispersants. For example, the production of marine oil snow and its sedimentation and flocculent accumulation to the seafloor were observed on an expansive scale after the Deepwater Horizon oil spill in the Northern Gulf of Mexico in 2010, but little is known about the underlying …

Improving Response Characteristics Of Split Ring Resonators Using Experimental Designs, Omer Faruk Keskin

Engineering Management & Systems Engineering Theses & Dissertations

The purpose of this thesis is to investigate the application of design of experiments approaches in the analysis of split ring resonators, and to compare two different approaches. The design parameters of the meta-material device are examined to study all the main effects, the two factor interactions, and the curvature effects. A full factorial design and a central composite design is utilized for the study. The results in improving split ring resonator design are discussed.

This study shows that the design of experiments approaches can effectively be utilized to examine the effects on the response values of a specific type …