Materials Science and Engineering Commons^™

Chlorination And Selective Vaporization Of Rare Earth Elements, Daniel Gaede

Graduate Theses & Non-Theses

No abstract provided.

Electrochemical Characterization Of Xanthate Chemisorption On Copper And Enargite, Tyler Broden

Graduate Theses & Non-Theses

The electrochemical reactions of copper and enargite (Cu₃AsS₄) were studied in the absence and presence of xanthate by cyclic voltammetry (C.V.) using electrodes fashioned from pure copper wire obtained from the Metallurgical and Materials Engineering Department, and an enargite mineral sample obtained from the Orphan Girl mine in Butte, MT. Voltammograms were produced in buffer solutions of pH values ranging from 7-12. Electrochemical reactions were discerned by comparing E_H-pH diagrams calculated from thermodynamics using StabCal, a computer program developed by Dr. Huang at Montana Tech. The chemisorption of xanthate on the surface of copper …

Environmental Considerations For Treatment Of Effluent Waste Solutions And Solid Waste Products, Larry G. Twidwell

Metallurgy

No abstract provided.

Thermodynamic Considerations In Molten Salt Electrolysis For Rare Earth Metals, Arwin Gunawan

Graduate Theses & Non-Theses

Many applications utilize rare earths as a part of their essential composition, such as: Ni-MH batteries, glass screen, magnets, fluorescent lightning, etc. These reactive elements are normally found as an oxide compound due to their affinity with oxygen. Their oxide formation exhibits a high standard free energy, which make them really stable. Consequently, extracting rare earths cannot be easily done with a simple acid-base reaction.

It has been known that there are two reduction ways to extract rare earth, metallothermic reduction and molten salt electrolysis process. Metallothermic method is determined by standard free energy formation, melting point, boiling point, vapor …

Estimation And Thermodynamic Modeling Of Solid Iron Species In The Berkeley Pit Water, Rajesh Srivastava

Graduate Theses & Non-Theses

Since the cessation of open-pit mining activities from the Berkeley Pit located in Butte, MT in 1982, the pit had gradually filled with metal-laden acidic mine water. The purpose of this investigation was to estimate and apply thermodynamic theory to a group of iron-sulfate solids that might equilibrate with the Berkeley Pit water. Thermodynamic data was incomplete for acid mine affected water, and the effects of Cu cementation on the formation of iron oxide and sulfate solids had not been analyzed. Ferric iron compounds such as Ferrihydrite, Goethite, Schwertmannite, Potassium Jarosite and Potassium Hydronium Jarosite were modelled in Stabcal using …

Optimization Of Rare Earth Leaching From Ores And Concentrates, Grant Wallace

Graduate Theses & Non-Theses

The use of applied chemistry in the production and optimization of leach solutions from Rare Earth Element (REE) ores and concentrates was investigated. Ore and concentrate samples were characterized using scanning electron microscopy/mineral liberation analysis (SEM/MLA), X-ray Diffraction (XRD), and Inductively-coupled Plasma Atomic Emission Spectroscopy (ICP-AES). Multiple leach tests were performed to analyze the effects of temperature, residence time, and reagent concentration on the leaching of REEs. Analysis of leach solutions was carried out using ICP-AES. Modeling and statistical analysis of extraction behavior was carried out using DesignExpert 9. Modeling data for multiple REEs indicate that extraction is strongly influenced …

Voltammetric Investigation Of Xanthate Chemisorption On A Chalcopyrite Surface, Jesse Lynn Bowden

Graduate Theses & Non-Theses

Cyclic Voltammetry experiments have been conducted on copper, iron, and chalcopyrite (CuFeS2) and compared to mass-balanced EH-pH Diagrams. Potassium ethyl xanthate (KEX) was added to solution and additional voltammetry experiments were performed to determine the surface chemistry reactions of flotation collector in solution with these minerals. The ultimate goal of this research was to investigate the possibility of xanthate chemisorption onto the chalcopyrite mineral surface. Results of the copper mineral testing confirm previous literature studies and corroborate published isotherm data. Results of the iron mineral testing showed changes in surface reactions with the addition of potassium ethyl xanthate to solution, …

Thermal Processing And Mechanical Properties Of Beta Phase Titanium Alloys For Biomedical Applications, Ethan Wood

Graduate Theses & Non-Theses

The past few decades have seen an increase in the use of beta titanium alloys as structural biomaterials. Their combination of excellent mechanical properties, corrosion resistance and biocompatibility, along with a lower Young’s modulus than stainless steel, cobalt-chromium and commercially pure titanium make the beta titanium alloys ideal biomaterials. This work evaluates the use of three beta titanium alloys for biomedical applications. Three beta titanium alloys, Ti 15-3-3-3, Ti SP-700 and Ti Beta-C, underwent thermal processing to optimize mechanical properties. The alloys were subjected to tensile testing, hardness testing, fatigue testing, optical microscopy and SEM fracture analysis in order to …

Thermodynamic Analysis Of Rare Earth Chlorination And Bromination Processes, Katie Lyons, Jerome Downey, Dan Gaede, Bryce Ruffier

2015 Undergraduate Research

Research funded by the Army Research Laboratory (ARL), the Metallurgical and Materials Engineering Department at Montana Tech investigated various methods of extracting and refining rare earth elements (REEs) from mineral ores and concentrates. Extensive thermodynamic, thermogravimetric and differential thermal analyses were performed to evaluate the relative stabilities of various REE compounds in order to assess potential methods for selective separation and recovery of specific REEs. Conversion of rare earth oxides (REO) to rare earth chlorides or bromides is a possible initial step in pyrometallurgical and hydrometallurgical processing of REEs. REO can be converted to chlorides or bromides by roasting in …

Wetting And Reactivity Of Active Metal Braze Alloys On Tungsten Carbide, Hayden Peck, Alan Meier, Ph.D.

2014 Undergraduate Research

Background

Tungsten carbide is useful because of its hardness and strength. Joining of dissimilar materials especially non-metallic materials is very challenging. Active metals such as titanium can be added to a ductile filler metals such as copper to get wetting via a reduction reaction.

Conclusions

All alloy conditions wet the tungsten carbide/cobalt substrates. Two different interfacial reaction types were observed: dissolution and reduction reactions. An important issue has been identified: the braze interface reactions change the chemistry of the braze alloy which change the interaction between the braze alloy and the other material substrate.

Oxidation Kinetics Of Nicrofer-6025ht For Use In Elevated Temperature Electrochemical Devices, Tyler Cook, Alan Meier, Ph.D.

TECHxpo

Recent advances in high temperature electrochemical devices have prompted research into potential materials for component fabrication.

Wetting And Reactive Air Brazing Of Bscf For Oxygen Separation Devices, Richard Ladouceur, Alan Meier, Ph.D.

2013 Undergraduate Research

The goals of this project are to develop a Reactive Air Brazing (RAB) alloy and process for joining Barium strontium cobalt ferrite (BSCF), and to develop a fundamental understanding of the wettability and microstructral development due to reaction kinetics in BSCF/Ag-Me_xO_y systems.

Effects Of Oxygen Content Of Admitted Gases In Sulfide Flotation, Brian J. Boyle

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Methods Of Studying The Effects Of Frothers, Frank L. Bazzanella

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Studies In Modulation Of Interfacial Reactions For Certain Sulphide Minerals, Robert Owen Beyaert

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Habit Modification Of Naclo3 With Nai, William A. Coghlan

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Production Of Standard-Grade Ferromanganese In An Electric Arc Furnace, Force F. Baney Jr.

Bachelors Theses and Reports, 1928 - 1970

The investigations conducted in this project were essentially concerned with the effects of various compositions of two different slag systems upon the increased recovery of manganese in a standard-grade ferromanganese.

Investigation Of The Ternary System Silver-Aluminum-Indium (Ag-Al-In), Elvin H. Beardslee

Bachelors Theses and Reports, 1928 - 1970

This thesis paper contains material pertaining to & preliminary investigation of the ternary system Ag-Al-In. Procedures in this preliminary investigation are discussed in detail.

Preliminary Examination Of The Aluminum Corner Of The Ternary System Aluminum-Silver-Indium (A1-Ag-In), Jerome J. Blake

Bachelors Theses and Reports, 1928 - 1970

In this paper the author attempts to lay the groundwork for future work on the Al-Ag-In system.

Increased Corrosion Of A 304 Stainless Steel Upon Bending, William C. Tiddy

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Identification Of Nonmetallic Inclusions In Armco Ingot Iron With Polarized Light, Frank E. Panisko

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

The Hydrometallurgy Of Uranium, John E. Cesarani

Bachelors Theses and Reports, 1928 - 1970

No abstract provided.

Crystal Habit Modification Of Sodium Chlorate, Michael R. Keegan

Bachelors Theses and Reports, 1928 - 1970

All single crystals have a particular habit or morphology. The crystal habit refers to the relative degree of development of crystallographic planes into surfaces which make up the external appearance of the single crystal.

In this paper, NaClO3 is used as a parent crystal. Its simple cubic habit is modified to tetrahedral by the use of impurities of SO4=, S2O3=, Cr2O7=, and NO3-. The degree of habit change is studied as a function of impurity concentration and temperature. The problem and phenomena are explained in terms of surface chemistry and thermodynamics.

Physico-Chemical Principles Of Sixteenth Century Metallurgy, Robert E. Johnson

Bachelors Theses and Reports, 1928 - 1970

Following a review of sixteenth century metallurgical literature and a discussion of Gibbs free energy, this thesis discusses thermodynamic considerations of galena (PbS) reduction by iron from a lead assay of this period. The importance of fluxes in this assay is emphasized. The discussion covers both equilibrium and non-equilibrium conditions at 1100 degrees Celsius. Possible substitutes for iron are also covered.

Information from twenty-one small controlled lead assays is correlated with the thermodynamic discussion to determine the purpose of each constituent in the assay.

The Beneficiation Of Titaniferous-Magnetite Sands, Ronald Lloyd Nordwick

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation of beneficiation methods is to develop and study possible economic methods for recovering an iron-titanium concentrate of sufficient purity to meet metallurgical requirements for subsequent direct reduction to pig iron and a high titanium slag.

Stress-Corrosion Cracking Of Brass, Paul A. Fossey

Bachelors Theses and Reports, 1928 - 1970

the mechanism of stress-corrosion cracking of brass has been sought for many years. Investigators have proposed many mechanisms, but each of these mechanisms has always had several drawbacks. This paper presents an account of experimental work done in the laboratory on this subject and compares it to the work of previous investigations. It evaluates the mechanisms presented by investigators and shows the failures of these mechanisms. A theory of Nitrogen Embrittlement is presented and an evaluation of this theory with experimental work follows.

Experimental Arc Furnace Smelting Of Titaniferous Iron Sands From The Northern Oregon Coast, Allan P. Herring

Bachelors Theses and Reports, 1928 - 1970

This investigation is an attempt to experimentally smelt titaniferous iron sands from the Northern Oregon Coast in a laboratory arc furnace.

The Effect Of Ph Upon Chelation Reactions In Montmorillonite Clays, Joseph Michael Keane

Bachelors Theses and Reports, 1928 - 1970

The purpose of this thesis is to investigate several chelation reactions and determine the effect of variable pH upon these reactions.

An Investigation Of The Sintering Of Iron-Wire Compacts, George L. Vivian

Bachelors Theses and Reports, 1928 - 1970

A study of the sintering of iron has been made by observing the rate of bonding of iron wires wound on iron spools. The specimens were sintered at a constant temperature of 850c in vacuum furnaces capable of producing pressures of 10-5 to 10-4 mm of mercury, and the growth of the bond between wires was observed as a function of time.

It has been concluded that the volume-diffusion mechanism is strongly operating in the sintering of iron at 850c, but in an evacuated system, the evaporation-condensation mechanism also contributes to the sintering process.

Attempts To Grow Metal Single Crystals By Strain Anneal, Donald James Mcmillan

Bachelors Theses and Reports, 1928 - 1970

The growth of such crystals in the solid state eliminates these problems to a considerable degree. Therefore, the purpose of this study was to grow a metal single crystal of predetermined orientation in the solid state utilizing the strain-anneal method.