Materials Science and Engineering Commons^™

Glycan Functionalization Of Iron Oxide Nanoparticles (Ionps) As A Method Of Inactivating Antibiotic Resistant Neisseria Gonorrhoeae Via A Magnetically Mediated Energy Delivery (Magmed) System, Cedric Taylor

All Theses

With the increase of antibiotic resistant bacteria, current established therapeutic treatment methods are rapidly demonstrating decreasing efficacy. For this project, we are studying a novel alternate mechanism of treating antibiotic resistant bacteria by utilizing magnetic iron oxide nanoparticles (IONPs) coated with a heterobifunctional polyethylene glycol polymer (PEG) and functionalized with glycan structures that can interact with Neisseria gonorrhoeae FA1090. Interaction between the IONPs and bacteria is manipulated by an external alternating magnetic field (AMF) in a process known as magnetically mediated energy delivery (MagMED). Magnetic IONPs were synthesized and reacted with PEG (PEG-IONPs) and functionalized with glycans Gal(α1-3)Gal(β1-4)Glc(β1-1) (common name: …

Development Of Lambda Factors For Masonry Design With Lightweight Grout, Rumi Shrestha

All Theses

Reduction in structural mass, improvement in thermal performance, and reduction in shrinkage cracking through internal curing are some of the reasons that lightweight (LW) aggregates have been used in structures and pavements for decades. However, lightweight grout is still not permitted for use in reinforced masonry construction by the TMS 402/602-16 code. In order to realize the benefits of lightweight grout in U.S. reinforced masonry construction, a codified procedure for its use is required which must be informed by experimental testing.

This research is a pilot project directed to characterize the performance of LW grout in comparison to normal weight …

Mechanical Interfacial Locking And Multiscale Modeling Of Reinforced Thermoplastic Composites For Structural Applications, Anmol Kothari

All Dissertations

The ever-growing pressure of reducing the adverse impact of transportation systems on environment has pushed industries towards fuel-efficient and sustainable solutions. While several approaches have been used to improve fuel efficiency, the light-weighting of structural components has proven broadly effective. In this regard, reinforced thermoplastic composites (RTPC), owing to their high recyclability, higher impact strength and fast cycle times, have become competitive candidates at an industrial scale. However, to implement RTPC toward large scale structural applications several challenges pertaining to material design and manufacturing effects need to be addressed. To this end, a computational study is carried out to address …

Investigation And Characterization Of New Optically Stimulated Luminescence (Osl) Dosimetric Materials, Linyu Pan

All Dissertations

Optically stimulated luminescence (OSL) dosimeters have attracted increasing attention due to advantages over TL dosimeters, including no thermal quenching and higher sensitivity. Nevertheless, currently, there are only two commercially available OSL dosimeters, BeO and Al₂O₃:C. An OSL dosimeter requires low effective atomic number (Z_eff < 16), at least one type of recombination center and one type of trap, and UV~blue emission. In this dissertation, motivated by the search of new OSL dosimetric materials, a systematic investigation of alumina (Z_eff = 11.3) and magnesium aluminate spinel (Z_eff = 11.2) based materials was performed in terms of the engineering of the recombination centers and electronic traps. Microstructural characterization was executed by means of X-ray diffraction (XRD) and Raman spectroscopy. Luminescence was characterized under X-ray excitation (radioluminescence; RL) at ambient and …

Hydrothermal Reaction Synthesis And Characterization Of Zns:Ag Scintillator, Yuchen Shao

All Theses

Thisworkaims at the development of a reactive ultrafiltration membrane scintillator for rapid activity determination and isotopic quantification of waterborne special nuclear materials (SNMs) based on ZnS:Ag. The effects of the pH of the precursor solution on ZnS:Ag synthesized under various conditions of temperature and time by the hydrothermal reaction synthesis method (200℃ for 6 hours, pH from 1 to 12; 100℃ for 2 hours, pH from 7 to 12;60℃ for 6 hours, pH from 7 to 12) were investigated. Samples were characterized on their structure, morphology and luminescence by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), photoluminescence (PL) …

Production And Characterization Of Uranium Sol Gel Surrogates Produced With Cerium Acetate And Cerium Nitrate, Matthew Brett Alford

All Dissertations

For the production of ceramic microspheres for future space travel, new methods of processing must be explored. The sol gel method proves promising for the production of uranium-based ceramic microspheres that are consistent enough in size and shape for such an application. A process for producing these microspheres has already been established, but there are avenues for improvement.

Handling of radioactive material like uranium is not always possible or warranted. As such, a non-radioactive surrogate that greatly resembles the processing of its actual radioactive counterpart. Herein this work a cerium-based surrogate is developed to closely resemble an already established process …

Characterization Of Mechanical, Thermodynamic And Surface Properties Of The Butterfly Proboscis, Tatiana Stepanova

All Theses

The butterfly proboscis is a fascinating fiber designed to probe and transport fluids. The built-in sensors and actuators make this fiber multifunctional. The proboscis consists of 2 hollow C-shaped tubes that are united when the butterfly comes out of the pupa. A single galea consists of a solid cuticular wall, muscles, nerves, and tracheae. The proboscis cuticular wall is mainly composed of polymers and small amounts of metals and non-metals. The proboscis is a porous material, and its water content is high, up to 50%. When the butterfly is not hungry, its proboscis is tightly coiled; when the butterfly is …

Comparison Study Of Mold Growth Resistance Of Plastic Based Material Flooring (Pbm Flooring) And Ceramic Tile Flooring, Jyothi Rangineni, Jeremy Tzeng

Publications

Clemson University Department of Biological Sciences and Tile Council of North America Product Performance Testing Laboratory evaluated whether ceramic tile and Plastic Based Material (PBM¹) flooring support mold growth when exposed to fungal spores.

Mold grows in moisture-rich environments and requires only minimal sources of nutrition to support growth. It has long been identified to cause damage to buildings and construction materials and its presence in buildings has been connected to many major health concerns with various studies and reviews published on this matter.²

The method used to evaluate mold growth was ASTM G21-96 (2015).³ This …

Standardized Waterproof Testing Of Plastic Based Material Flooring (Pbm Flooring), John P. Sanders, Cody Spence

Publications

Tile Council of North America Product Performance Testing Laboratory, under the direction of Dr. John Sanders of the Bishop Materials Laboratory at Clemson University, evaluated the extent that water can leak through plastic based material (PBM)¹ floor coverings advertised as 100% waterproof. To make this assessment, product literature was examined to determine which test methods were used to support the manufacturers’² claims of products being waterproof. Neither test methods or data to justify a 100% waterproof claim were found, despite a thorough review of product literature.³

ASTM, ANSI, ISO, and CEN standards were examined for relevant test …

Wet Slip Resistance Of Plastic Based Material Flooring (Pbm Flooring), John P. Sanders, Grant Davidson

Publications

Tile Council of North America Product Performance Testing Laboratory, under the direction of Dr. John Sanders of the Bishop Materials Laboratory at Clemson University, measured the wet Dynamic Coefficient of Friction (DCOF) of 22 plastic based material (PBM¹) flooring products that manufacturers² advertise or claim to be waterproof, water resistant, or depict being used in areas where flooring gets wet.³ The claims suggest that such PBM products can be used where exposed to water. However, product literature for only five products tested in this report cautioned the products can be potentially slippery when wet, and no …

Nanoparticle Doped Optical Fibers For High Energy Lasers, Amber L. Vargas

All Theses

Fabrication of rare earth (RE) doped optical fibers for use in fiber-based lasers and amplifiers is conventionally performed using a solution doping technique where RE salts (i.e., ErCl3) are dissolved in a solvent, introduced into the porous silica soot, dried and consolidated to form the active fiber core. This process does not allow for tailoring of the chemical environment about the RE. Alternatively, nanoparticle (NP) doping is more recent approach to incorporating rare earths into an optical fiber and have been shown to permit modification of the chemical environment around the RE in ways the enhance spectroscopic performance. This is …

Non-Newtonian Fabric-Fluid Composites: Fabrication, Characterization And Testing For Anti-Ballistics Applications, Hayley M. Weir

All Theses

This thesis aims to characterize non-Newtonian suspensions for anti-ballistics applications. This involves characterizing the rheological behavior of each suspension. It also includes characterizing the interactions of the suspensions with several types of fabrics with known antiballistics properties. The study also tests the armor composites under ballistics stresses by firing on them with standardized military weaponry. This data is then compiled to determine which, if any, of the fabrics and suspensions are ultimately suitable for anti-ballistics uses.

Extended Lamer Synthesis Of Cobalt Doped Ferrite, Benjamin D. Fellows, Sarah Sandler, Jacob Livingston, Kristin Fuller, Lotanna Nwandu, Sarah Timmis, Kayla A. Lantz, Morgan Stefik, O. Thompson Mefford

Publications

Nonstoichiometric cobalt ferrite nanoparticles have drawn interest in magnetically mediated energy delivery due to their high magnetocrystalline anisotropy and their high peak loss frequency. The use of an extended LaMer synthesis allows for size control of the doped particles up to a threshold core diameter of 18 nm. Above this diameter, particles become unstable and drop out of suspension, allowing for further nucleation events to occur. This leads to a cyclic nucleation, growth, and destabilization regime seen during the course of the reaction. Using the size control of the extended LaMer synthesis technique, we examine the specific absorption rate (SAR) …

Synthesis And Characterization Of Glycidyl Methacrylate-Based Graft Copolymer Functional Interfaces, Nikolay Brordinov

All Dissertations

Modification of materials properties such as surface energy, wettability, ability to absorb, contain or release specific type of chemicals enables practical application of these materials in various scientific and engineering set-ups. However, designing protocol that could be easily adapted for different situations and simultaneously unlock multiple variations of the resulting properties is a non-trivial task. This dissertation is devoted to application of glycidyl methacrylate-based graft copolymers for the purposes of surface modification, establishing fundamental trends and dependencies of this process and exploring the possible range of applications. These materials have extremely valuable property to undergo controllable post-synthetic modifications including surface …

Lb3d: A Parallel Implementation Of The Lattice-Boltzmann Method For Simulation Of Interacting Amphiphilic Fluids, S. Schmieschek, L. Shamardin, S. Frijters, T. Krüger, U. D. Schiller, J. Harting, P. V. Coveney

Publications

We introduce the lattice-Boltzmann code LB3D, version 7.1. Building on a parallel program and supporting tools which have enabled research utilising high performance computing resources for nearly two decades, LB3D version 7 provides a subset of the research code functionality as an open source project. Here, we describe the theoretical basis of the algorithm as well as computational aspects of the implementation. The software package is validated against simulations of meso-phases resulting from self-assembly in ternary fluid mixtures comprising immiscible and amphiphilic components such as water–oil–surfactant systems. The impact of the surfactant species on the dynamics of spinodal decomposition are …

Current Understanding And Future Research Directions At The Onset Of The Next Century Of Sintering Science And Technology, Rajendra K. Bordia, Suk-Joong L. Kang, Eugene A. Olevsky

Publications

Sintering and accompanying microstructural evolution is inarguably the most important step in the processing of ceramics and hard metals. In this process, an ensemble of particles is converted into a coherent object of controlled density and microstructure at an elevated temperature (but below the melting point) due to the thermodynamic tendency of the particle system to decrease its total surface and interfacial energy. Building on a long development history as a major technological process, sintering remains among the most viable methods of fabricating novel ceramics, including high surface area structures, nanopowder-based systems, and tailored structural and functional materials. Developing new …

Quantification Of Volatile Residuals In Polydioxanone By Gas Chromatography: Method Development, Validation And Implementation, Clayton Joseph Culbreath

All Theses

Bioresorbable polymers are increasingly utilized for implantable medical devices to avoid complications related to explant and/or long term responses to foreign materials. As with all polymeric materials, residual levels of unreacted monomer, and other volatiles, drastically affect the mechanical and chemical properties as well as the parameters required to process the material into a device. The 1,4-dioxane-2-one (PDO) monomer is a six membered ring that forms an ether-ester polymer via ring-opening polymerization (ROP) with intermediate absorption rate properties that are ideal for numerous implant situations. Developing devices using poly(1,4-dioxane-2-one) (PPDO, PDO, PDX, PPDX, or PDS) is complicated by residual levels …

Rare Earth Emissions From Polyethylene Terephthalate Fiber, Joshua Jenkins Furtick

All Theses

Rare earth-polymer blends can be useful in many applications including safety, security, displays, and novelty. Polyester, specifically polyethylene terephthalate, is a ubiquitous material in the world today and offers many opportunities for the usefulness of visible light rare earth emissions.

In this work we have attempted to incorporate rare earth complexes with polyester yarn using various methods including coating, extrusion, and dyeing, with the latter having the most success. Nanoparticles were used initially for these experiments, however certain limitations of the particles could not be overcome, for example the size of the particles and the incompatibility of the inorganic matrix …

Fully Magnetic Printing By Generation Of Magnetic Droplets On Demand With A Coilgun, Vladislav Vekselman, Luke Sande, Konstantin G. Kornev

Publications

In this paper, we exhibit a coilgun-based approach to drop-on-demand printing of liquids laden with magnetic particles. In contrast to other drop-on-demand technologies designed to print droplets only in gaseous environments, this methodology allows one to print magnetic droplets inside any gaseous or liquid media using the same coilgun. Furthermore, we demonstrate the basic principles of magnetic drop-on-demand generation and show the physico-chemical parameters controlling the process.

Synthesis And Characterization Of Oleophobic Fluorinated Polyester Films, Tugba Demir

All Dissertations

The study presented in this dissertation is dedicated to the synthesis and characterization of oleophobic fluorinated polyester films. Specifically, the blending of oleophilic polyethylene terephthalate (PET) with low surface energy materials such as fluorinated polyesters has been used in order to fabricate oleophobic PET films. First, fluorinated polyesters (P(PF-oate-R)) possessing different end-groups (-COOH, -OH and -CF3) are synthesized via polycondensation reaction of isophthaloyl chloride with perfluoro ether alcohols. Then, they are solvent-blended with PET at various concentrations to obtain oleophobic polyester films of different compositions. In addition, the films are annealed to investigate the effect of annealing on surface properties …

Designing Optical Properties In Infrared Glass, Benn Gleason

All Dissertations

Chalcogenide glasses (ChGs) are well-known for their attractive optical properties, such as high refractive index and transparency in across infrared wavelengths. ChGs also possess the ability to compositionally tune properties such as the refractive index, the thermo-optic coefficient, and other non-optical properties. Chalcogenide glasses with compositionally tailored physical and optical properties will provide optical designers with new materials necessary to create novel infrared imaging systems requiring new or expanded functionality. This dissertation has evaluated the relationship between glass composition, the resulting atomic structure, and resulting optical and thermo-optical properties, with specific focus on the infrared refractive index and the thermo-optic …

Eye Tracking Consumer Purchase Behavior Within Physical And Virtual Environments, David Andrew Stone

All Theses

Understanding how consumers observe and make purchase decisions within a retail context is now both accessible and efficient through the process of eye tracking. Eye tracking package design aesthetics helps us understand and predict what consumers are looking at, and how likely a package might be selected. Typically, this research is conducted in an immersive retail setting where consumers can shop as they would in a normal store-shopping context. A store is stocked with products where a participant in the study shops throughout while wearing an eye tracker to gather data on what their attention fixates on within a given …

Microanalysis Of Polymer Chain Diffusion In Heat Seals, Russell Cooper

All Theses

Heat sealing is an integral method for the closure and protection of packaging. Previous work has shown that seal strength is developed by the interdiffusion of polymer chains within heat seals. Heat seals were made between two dissimilar materials. Poly(ethylene-co-acrylic acid) (EAA) was heat sealed to ionomer. Diffusion within the EAA-ionomer heat seals was estimated. The diffusion estimates were then related to resulting seal strength in the EAA-ionomer sealant system. Heated tooling sealing was utilized to make heat seals at 40 psi (275.79 kPa), 0.5 seconds, and a range of temperatures between 180˚F (82.22˚C) and 300˚F (148.89˚C). Scanning electron microscopy …

Fabrication And Characterization Of Magnetic Nanoparticle Composite Membranes, Akeem Cruickshank

All Theses

To effectively and accurately deliver drugs within the human body, both new designs and components for implantable micropumps are being studied. Designs must ensure high biocompatibility, drug compatibility, accuracy and small power consumption. The focus of this thesis was to fabricate a prototype magnetic nanoparticle membrane for eventual incorporation into a biomedical pump and then determine the relationship between this membrane deflection and applied pneumatic or magnetic force. The magnetic nanoparticle polymer composite (MNPC) membranes in this study were composed of crosslinked polydimethylsiloxane (PDMS) and iron oxide nanoparticles (IONPs). An optimal iron oxide fabrication route was identified and particle size …

Relationship Between Peel Force, Opening Force, And Burst Force For A Semi-Rigid Cup And Lid, Pre- And Post-Retort, Raj Navalakha

All Theses

This research determines if there is any relationship between the peel force, the opening force and the burst force for a semi-rigid cup and lid system, for pre- and post-retort conditions. It also compares the relationship (regression lines) between these forces pre- and post-retort. These seal results were studied by varying the sealing parameters of dwell time and temperature while keeping the pressure constant. Polypropylene cups and a peelable barrier retort lidding were used in this study. As compared to past research, a different peel testing technique was used to measure the peel and the opening force. The entire lid …

Composite Films With Magnetic Nanorods: Fundamentals, Processing And Applications, Yu Gu

All Dissertations

This Dissertation is centered on studying the composite films with magnetic nanorods. In recent years, one-dimensional magnetic nanostructures, such as magnetic nanorods, chains of magnetic nanoparticles, and nanotubes filled with magnetic nanoparticles have caught great attentions due to the breadth of applications. Their unique magnetic and geometrical features open new avenues of studies in medicine, sensors, optofluidics, magnetic swimming, and microrheology. In particular, they offered great opportunities for design of multifunctional devices and for manufacturing of anisotropic nano- and microstructures with unprecedented magnetic and mechanical properties. However, the strategy for nanorod alignment in both Newtonian and complex fluids has not …

Earth Abundant Thin Film Technology For Next Generation Photovoltaic Modules, Githin Alapatt

All Dissertations

With a cumulative generation capacity of over 100 GW, Photovoltaics (PV) technology is uniquely poised to become increasingly popular in the coming decades. Although, several breakthroughs have propelled PV technology, it accounts for only less than 1% of the energy produced worldwide. This aspect of the PV technology is primarily due to the somewhat high cost per watt, which is dependent on the efficiency of the PV cells as well as the cost of manufacturing and installing them. Currently, the efficiency of the PV conversion process is limited to about 25% for commercial terrestrial cells; improving this efficiency can increase …

Synthesis And Characterization Of Chemically Functionalized Shape Memory Nanofoams For Unattended Sensing Applications, Anna Paola Soliani

All Dissertations

The work in this dissertation is devoted to the synthesis and characterization of novel materials for off-line unattended sensing: shape-memory grafted nanofoams. The fabrication process and characterization of highly efficient, polymeric nanosensor element with the ability to selectively detect analytes and retain memory of specific exposure events is reported. These shape memory nanofoams could potentially act as efficient and highly sensitive coatings for evanescent waveguide-based optical monitoring systems. On exposure to specific analytes, the polymeric coatings locally change their internal structure irreversibly at the nanolevel, affecting the local optical properties such as refractive index. Currently, enrichment polymer layers (EPLs) are …

High-Productivity Membrane Adsorbers: Polymer Surface-Modification Studies For Ion-Exchange And Affinity Bioseparations, Heather Chenette

All Dissertations

This Dissertation centers on the surface-modification of macroporous membranes to make them selective adsorbers for different proteins, and the analysis of the performance of these membranes relative to existing technology. Traditional chromatographic separations for the isolation and purification of proteins implement a column packed with resin beads or gel media that contain specific binding ligands on their exposed surface area. The productivity of this process is balanced by the effective use of the binding sites within the column and the speed at which the separation can take place, in addition to the need to maintain sufficient protein purity and bioactivity. …

Synthesis Of Silicon Carbide Fibers From Polycarbosilane By Electrospinning Method, Yuan Yue

All Theses

Silicon carbide (SiC) is widely used in many fields due to its unique properties. Bulk SiC normally has a flexural strength of 500 - 550 MPa, a Vickers hardness of ~27 GPa, a Young's modulus of 380 - 430 GPa, and a thermal conductivity of approximately 120 W/mK. SiC fibers are of great interest since they are the good candidates for reinforcing ceramic matrix composites (CMCs) because of the weavability and high temperature strength of about two to three GPa at about 1000 °C. Silicon carbide fibers have been synthesized from polycarbosilane (PCS) with ~25 μm diameter using the melt-spinning …