Materials Science and Engineering Commons^™

Loading Direction Dependence Of Asymmetric Response Of < C+A > Pyramidal Slip In Rolled Az31 Magnesium Alloy, Yuzhi Zhu, Dewen Hou, Kaixuan Chen, Zidong Wang

Materials Science and Engineering Faculty Publications and Presentations

No abstract provided.

Heterostructure Engineering In Electrode Materials For Sodium-Ion Batteries: Recent Progress And Perspectives, Eric Gabriel, Chunrong Ma, Kincaid Graff, Angel Conrado, Dewen Hou, Hui Xiong

Materials Science and Engineering Faculty Publications and Presentations

Sodium-ion batteries (SIBs) have stepped into the spotlight as a promising alternative to lithium-ion batteries for large-scale energy storage systems. However, SIB electrode materials, in general, have inferior performance than their lithium counterparts because Na⁺ is larger and heavier than Li⁺. Heterostructure engineering is a promising strategy to overcome this intrinsic limitation and achieve practical SIBs. We provide a brief review of recent progress in heterostructure engineering of electrode materials and research on how the phase interface influences Na⁺ storage and transport properties. Efficient strategies for the design and fabrication of heterostructures (in situ methods) …

High-Sensitivity Electronic Stark Spectrometer Featuring A Laser-Driven Light Source, J. S. Huff, K. M. Duncan, C. J. Van Galen, M. S. Barclay, W. B. Knowlton, B. Yurke, P. H. Davis, D. B. Turner, R. J. Stanley, R. D. Pensack

Materials Science and Engineering Faculty Publications and Presentations

We report developmental details of a high-sensitivity Stark absorption spectrometer featuring a laser-driven light source. The light source exhibits intensity fluctuations of ∼0.3% over timescales ranging from 1 min to 12 h, minimal drift (≤ 0.1%/h), and very little 1/f noise at frequencies greater than 200 Hz, which are comparable to or better than an arc-driven light source. Additional features of the spectrometer include balanced detection with multiplex sampling, which yielded lower noise in A, and constant wavelength or wavenumber (energy) spectral bandpass modes. We achieve noise amplitudes of ∼7 × 10⁻⁴ and ∼6 × 10^{−6 …}

Correlative Imaging Of Three-Dimensional Cell Culture On Opaque Bioscaffolds For Tissue Engineering Applications, Mone’T Sawyer, Josh Eixenberger, Olivia Nielson, Jacob Manzi, Cadré Francis, Raquel Montenegro-Brown, Harish Subbaraman, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Three-dimensional (3D) tissue engineering (TE) is a prospective treatment that can be used to restore or replace damaged musculoskeletal tissues, such as articular cartilage. However, current challenges in TE include identifying materials that are biocompatible and have properties that closely match the mechanical properties and cellular microenvironment of the target tissue. Visualization and analysis of potential 3D porous scaffolds as well as the associated cell growth and proliferation characteristics present additional problems. This is particularly challenging for opaque scaffolds using standard optical imaging techniques. Here, we use graphene foam (GF) as a 3D porous biocompatible substrate, which is scalable, reproducible, …

Investigation Of Deformation Behavior Of Additively Manufactured Aisi 316l Stainless Steel With In Situ Micro-Compression Testing, Fei Teng, Ching-Heng Shiau, Cheng Sun, Robert C. O'Brien, Michael D. Mcmurtrey

Materials Science and Engineering Faculty Publications and Presentations

Additive manufacturing techniques are being used more and more to perform the precise fabrication of engineering components with complex geometries. The heterogeneity of additively manufactured microstructures deteriorates the mechanical integrity of products. In this paper, we printed AISI 316L stainless steel using the additive manufacturing technique of laser metal deposition. Both single-phase and dual-phase substructures were formed in the grain interiors. Electron backscatter diffraction and energy-dispersive X-ray spectroscopy indicate that Si, Mo, S, Cr were enriched, while Fe was depleted along the substructure boundaries. In situ micro-compression testing was performed at room temperature along the [001] orientation. The dual-phase substructures …

Intrinsic And Atomic Layer Etching Enhanced Area-Selective Atomic Layer Deposition Of Molybdenum Disulfide Thin Films, Jake Soares, Wesley Jen, John D. Hues, Drew Lysne, Jesse Wensel, Steven M. Hues, Elton Graugnard

Materials Science and Engineering Faculty Publications and Presentations

For continual scaling in microelectronics, new processes for precise high volume fabrication are required. Area-selective atomic layer deposition (ASALD) can provide an avenue for self-aligned material patterning and offers an approach to correct edge placement errors commonly found in top-down patterning processes. Two-dimensional transition metal dichalcogenides also offer great potential in scaled microelectronic devices due to their high mobilities and few-atom thickness. In this work, we report ASALD of MoS₂ thin films by deposition with MoF₆ and H₂S precursor reactants. The inherent selectivity of the MoS₂ atomic layer deposition (ALD) process is demonstrated by growth …

Leveraging Steric Moieties For Kinetic Control Of Dna Strand Displacement Reactions, Drew Lysne, Tim Hachigian, Chris Thachuk, Jeunghoon Lee, Elton Graugnard

Materials Science and Engineering Faculty Publications and Presentations

DNA strand displacement networks are a critical part of dynamic DNA nanotechnology and are proven primitives for implementing chemical reaction networks. Precise kinetic control of these networks is important for their use in a range of applications. Among the better understood and widely leveraged kinetic properties of these networks are toehold sequence, length, composition, and location. While steric hindrance has been recognized as an important factor in such systems, a clear understanding of its impact and role is lacking. Here, a systematic investigation of steric hindrance within a DNA toehold-mediated strand displacement network was performed through tracking kinetic reactions of …

Thermomechanical Properties Of Neutron Irradiated Al3Hf-Al Thermal Neutron Absorber Materials, Donna Post Guillen, Mychailo B. Toloczko, Ramprashad Prabhakaran, Yuanyuan Zhu, Yu Lu, Yaqiao Wu

CAES Energy Policy Institute Faculty Publications and Presentations

A thermal neutron absorber material composed of Al₃Hf particles in an aluminum matrix is under development for the Advanced Test Reactor. This metal matrix composite was fabricated via hot pressing of high-purity aluminum and micrometer-size Al₃Hf powders at volume fractions of 20.0, 28.4, and 36.5%. Room temperature tensile and hardness testing of unirradiated specimens revealed a linear relationship between volume fraction and strength, while the tensile data showed a strong decrease in elongation between the 20 and 36.5% volume fraction materials. Tensile tests conducted at 200 °C on unirradiated material revealed similar trends. Evaluations were then …

Photophysical Studies Of Electronic Structure And Excited-State Dynamics Of Dna-Templated Cyanine Dye Aggregates, Jonathan Samuel Huff

Boise State University Theses and Dissertations

The invention and widespread adoption of the digital computer in the last century has led to an era of rapid technological advancement that has continued to the present day. This advancement has been sustained to a large degree by continued miniaturization of the electronic components in microprocessors, which results in increased computing power and energy efficiency. In recent years, this strategy has produced diminishing returns because the cost for each incremental size reduction increases as engineers approach the fundamental scaling limits of silicon-based semiconductor devices. Meanwhile, breakthroughs in DNA nanotechnology hold great promise for a new generation of self-assembled nanodevices …

Transformation Pathways Of Lanthanide-Free Mn-Al-Ga-X Alloys Where X = Co, Fe, And Ni, Shane L. Palmer

Boise State University Theses and Dissertations

Ubiquitous rare-earth, (i.e. lanthanide) permanent magnets (PMs) composed of Nd-Fe-B are the strongest PMs on the market. However, limited mineral sources, complex elemental separation, and supply chain volatility have shifted the lanthanides to critical material status. Inexpensive, readily available materials are sought to fill an energy product performance gap to reduce dependency on lanthanide PMs. Frequently, lanthanide PMs are used in applications where their energy products are excessively high. Mn-Al based permanent magnets offer a potential substitute for PM applications which do not require the high energy product of a lanthanide PM. MnAl alloys form a metastable ferromagnetic tetragonal …

Poly(Alkyl Aldehyde)S: A New Class Of Closed-Loop Recyclable Plastics, Kyle Arnold Nogales

Boise State University Theses and Dissertations

This dissertation will describe a new class of closed-loop recyclable, self-immolative polymers that undergo selective, complete, and rapid depolymerization in the solid state when triggered. Self-immolative poly(alkyl aldehyde)s are synthesized efficiently in approximately 60% yield using anionic polymerization, which provides access to polymers in accessible lengths ranging from short (M_n value of 2 kDa) to long polymers (M_n value of 5,000 kDa). The physical and thermal properties of the polymers can be tuned rationally by appropriate choice of the aldehyde monomer, with some of the polymers displaying mechanical properties that are similar to traditional plastics. The polymers depolymerize …

Catalyzed Oxidation Of Ig-110 Nuclear Graphite By Simulated Fission Products Ag And Pd Nanoparticles, Junhua Jiang, John Stempien, Yaqiao Wu

Materials Science and Engineering Faculty Publications and Presentations

To evaluate the stability of nuclear materials in high temperature gas reactors under air ingress conditions, catalytic oxidation of IG-110 graphite by two simulated fission products, metallic Pd and Ag, was studied in oxidative atmosphere and at temperatures up to 1000 °C using an integrated furnace, mass spectroscopy and infrared spectroscopy system. Transmission electron microscopy and X-ray diffraction studies show that Pd and Ag nanoparticles were successfully introduced onto powdery IG-110 graphite through an impregnation and subsequent heat-treatment process. The combined mass spectroscopy and infrared spectroscopy methods allow simultaneous analysis of two gaseous products, CO and CO₂, and …

Mechanical Testing Data From Neutron Irradiations Of Pm-Hip And Conventionally Manufactured Nuclear Structural Alloys, Yaqiao Wu

Materials Science and Engineering Faculty Publications and Presentations

This article presents the comprehensive mechanical testing data archive from a neutron irradiation campaign of nuclear structural alloys fabricated by powder metallurgy with hot isostatic pressing (PM-HIP). The irradiation campaign was designed to facilitate a direct comparison of PM-HIP to conventional casting or forging. Five common nuclear structural alloys were included in the campaign: 316L stainless steel, SA508 pressure vessel steel, Grade 91 ferritic steel, and Ni-base alloys 625 and 690. Irradiations were carried out in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) to target doses of 1 and 3 displacements per atom (dpa) at target temperatures …

Decoding The Hydrodynamic Properties Of Microscale Helical Propellers From Brownian Fluctuations, Bernard Yurke

Materials Science and Engineering Faculty Publications and Presentations

The complex motility of bacteria, ranging from single-swimmer behaviors such as chemotaxis to collective dynamics, including biofilm formation and active matter phenomena, is driven by their microscale propellers. Despite extensive study of swimming flagellated bacteria, the hydrodynamic properties of their helical-shaped propellers have never been directly measured. The primary challenges to directly studying microscale propellers are 1) their small size and fast, correlated motion, 2) the necessity of controlling fluid flow at the microscale, and 3) isolating the influence of a single propeller from a propeller bundle. To solve the outstanding problem of characterizing the hydrodynamic properties of these propellers, …

Black Phosphorus Ink Formulation For Aerosol Jet Printing, Florent Muramutsa

Boise State University Theses and Dissertations

As the demand for data-driven technologies such as cloud computing, artificial intelligence, and the Internet of Things increases, the value of data centers rises. However, the cost of optical interconnects that convert optical signals to electrical signals and vice versa limits the bandwidth in these data centers. Historically the optoelectronic materials of group III–V semiconductor materials are grown using epitaxy and transferred to silicon microelectronics using robotic pick-and-place technology. This costly method restricts the large-scale production of on-chip optoelectronic components such as diodes, photodetectors, and lasers. In this dissertation, we investigated the potential of black phosphorus (BP) as a material …

Structure-Property-Processing Analysis Of Graphene Bioscaffolds For Viability And Differentiation Of C2c12 Cells, Lynn Karriem

Boise State University Theses and Dissertations

We investigated the structure – property – processing correlation of graphene bioscaffolds produced using three different methods. Bioscaffolds were prepared by chemical vapor deposition (CVD), sublimation of Silicon Carbide (SiC), and printed solvent assisted exfoliated graphene ink. To gain insight into the roughness and topography of graphene, AFM was performed on each bioscaffold. Raman spectroscopy mapping demonstrated differences in the I_2D/I_G ratio for each scaffold. Young’s modulus was determined by nanoindentation and indicated that epitaxial graphene had the highest average stiffness, followed by CVD, with printed graphene demonstrating the lowest average stiffness. To investigate the biocompatibility of …

Kinetic Barriers For Leakage Reduction In Dna Autocatalytic Strand Displacement Networks, Drew Lysne

Boise State University Theses and Dissertations

Currently medical diagnostic methods suffer from the need for skilled labor, bulky, sophisticated and expensive equipment, ideal lab environments and ample time. A point-of-care biosensor can alleviate these problems and allow for more mobile disease detection. To meet this need, researchers have looked to DNA strand displacement networks to perform molecular level computation through a series of DNA strand displacement reactions in which disease associated biomarker inputs can trigger a cascaded signal to produce a readable output downstream in a matter of minutes. Such quick readable outputs require signal amplification. While amplification can be achieved through enzymatic activity, enzymes introduce …

Closed-Loop, Recyclable Plastics From Ethyl Cyanoacrylate, Allison Joy Christy

Boise State University Theses and Dissertations

Ethyl cyanoacrylate, commonly known as super glue, has held a prominent role as an adhesive for decades due to its propensity to rapidly polymerize into poly(ethyl cyanoacrylate) (PECA) under ambient conditions. Ethyl cyanoacrylate monomers and their resulting PECA polymers are bio-friendly, which has allowed them to be used as medical adhesives and to be applied to drug delivery systems. However, PECA has not been used as a plastic material due to the perceived difficulty of handling the ethyl cyanoacrylate monomer. Here, we present a novel PECA plastic that displays thermal stability and tensile strength values that are comparable to atactic …

Closed-Loop Recyclable Plastics From Poly(Ethyl Cyanoacrylate), Allison J. Christy, Scott T. Phillips

Materials Science and Engineering Faculty Publications and Presentations

Ethyl cyanoacrylate is a highly reactive monomer that has been used nearly exclusively to make Super Glue and related fast-setting adhesives. Here, we describe transformation of this highly abundant, readily available monomer into a closed-loop recyclable plastic that could supplant currently used (and often unrecycled/unrecyclable) plastics, such as poly(styrene). We report polymerization conditions, plastic-processing methods, and plastic-recycling protocols for poly(ethyl cyanoacrylate) plastics that make the Super Glue monomer a viable starting material for a next generation of closed-loop recyclable plastics. The processes described are scalable, and the plastics can be recycled in a closed-loop process with >90% yields, even when …

Effect Of Substituent Location On The Relationship Between The Transition Dipole Moments, Difference Static Dipole, And Hydrophobicity In Squaraine Dyes For Quantum Information Devices, Maia Ketteridge, Austin Biaggne, Ryan Rau, German Barcenas, Olga A. Mass, William B. Knowlton, Bernard Yurke, Lan Li

Materials Science and Engineering Faculty Publications and Presentations

Aggregates of organic dyes that exhibit excitonic coupling have a wide array of applications, including medical imaging, organic photovoltaics, and quantum information devices. The optical properties of a dye monomer, as a basis of dye aggregate, can be modified to strengthen excitonic coupling. Squaraine (SQ) dyes are attractive for those applications due to their strong absorbance peak in the visible range. While the effects of substituent types on the optical properties of SQ dyes have been previously examined, the effects of various substituent locations have not yet been investigated. In this study, density functional theory (DFT) and time-dependent density functional …

Impact Of Population Based Indoor Residual Spraying With And Without Mass Drug Administration With Dihydroartemisinin-Piperaquine On Malaria Prevalence In A High Transmission Setting: A Quasi-Experimental Controlled Before-And-After Trial In Northeastern Uganda, Richard C. Elliott

Materials Science and Engineering Faculty Publications and Presentations

Background: Declines in malaria burden in Uganda have slowed. Modelling predicts that indoor residual spraying (IRS) and mass drug administration (MDA), when co-timed, have synergistic impact. This study investigated additional protective impact of population-based MDA on malaria prevalence, if any, when added to IRS, as compared with IRS alone and with standard of care (SOC).

Methods: The 32-month quasi-experimental controlled before-and-after trial enrolled an open cohort of residents (46,765 individuals, 1st enumeration and 52,133, 4th enumeration) of Katakwi District in northeastern Uganda. Consented participants were assigned to three arms based on residential subcounty at study start: MDA+IRS, IRS, SOC. IRS …

Molecular Dynamic Studies Of Dye–Dye And Dye–Dna Interactions Governing Excitonic Coupling In Squaraine Aggregates Templated By Dna Holliday Junctions, German Barcenas, Austin Biaggne, Olga A. Mass, William B. Knowlton, Bernard Yurke, Lan Li

Materials Science and Engineering Faculty Publications and Presentations

Dye molecules, arranged in an aggregate, can display excitonic delocalization. The use of DNA scaffolding to control aggregate configurations and delocalization is of research interest. Here, we applied Molecular Dynamics (MD) to gain an insight on how dye–DNA interactions affect excitonic coupling between two squaraine (SQ) dyes covalently attached to a DNA Holliday junction (HJ). We studied two types of dimer configurations, i.e., adjacent and transverse, which differed in points of dye covalent attachments to DNA. Three structurally different SQ dyes with similar hydrophobicity were chosen to investigate the sensitivity of excitonic coupling to dye placement. Each dimer configuration was …

Probing Dna Structural Heterogeneity By Identifying Conformational Subensembles Of A Bicovalently Bound Cyanine Dye, Matthew S. Barclay, Azhad U. Chowdhury, Austin Biaggne, Jonathan S. Huff, Nicholas D. Wright, Paul H. Davis, Lan Li, William B. Knowlton, Bernard Yurke, Ryan D. Pensack, Daniel B. Turner

Materials Science and Engineering Faculty Publications and Presentations

DNA is a re-configurable, biological information-storage unit, and much remains to be learned about its heterogeneous structural dynamics. For example, while it is known that molecular dyes templated onto DNA exhibit increased photostability, the mechanism by which the structural dynamics of DNA affect the dye photophysics remains unknown. Here, we use femtosecond, two-dimensional electronic spectroscopy measurements of a cyanine dye, Cy5, to probe local conformations in samples of single-stranded DNA (ssDNA–Cy5), double-stranded DNA (dsDNA–Cy5), and Holliday junction DNA (HJ–DNA–Cy5). A line shape analysis of the 2D spectra reveals a strong excitation–emission correlation present in only the dsDNA–Cy5 complex, which is …

Elucidating The Synergic Effect In Nanoscale Mos2/Tio2 Heterointerface For Na-Ion Storage, Chunrong Ma, Dewen Hou, Jiali Jiang, Yanchen Fan, Xiang Li, Tianyi Li, Zifeng Ma, Haoxi Ben, Hui Xiong

Materials Science and Engineering Faculty Publications and Presentations

Interface engineering in electrode materials is an attractive strategy for enhancing charge storage, enabling fast kinetics, and improving cycling stability for energy storage systems. Nevertheless, the performance improvement is usually ambiguously ascribed to the “synergetic effect”, the fundamental understanding toward the effect of the interface at molecular level in composite materials remains elusive. In this work, a well-defined nanoscale MoS₂/TiO₂ interface is rationally designed by immobilizing TiO₂ nanocrystals on MoS₂ nanosheets. The role of heterostructure interface between TiO₂ and MoS₂ by operando synchrotron X-ray diffraction (sXRD), solid-state nuclear magnetic resonance, and density functional …

Thermal Atomic Layer Etching Of Mos2 Using Mof6 And H2O, Jake Soares, Anil U. Mane, Devika Choudhury, Steven Letourneau, Steven M. Hues, Jeffrey W. Elam, Elton Graugnard

Materials Science and Engineering Faculty Publications and Presentations

Two-dimensional (2D) layered materials offer unique properties that make them attractive for continued scaling in electronic and optoelectronic device applications. Successful integration of 2D materials into semiconductor manufacturing requires high-volume and high-precision processes for deposition and etching. Several promising large-scale deposition approaches have been reported for a range of 2D materials, but fewer studies have reported removal processes. Thermal atomic layer etching (ALE) is a scalable processing technique that offers precise control over isotropic material removal. In this work, we report a thermal ALE process for molybdenum disulfide (MoS₂). We show that MoF₆ can be used as …

Thermal Effect On Dislocation Interactions In Magnesium Alloy, Yuzhi Zhu, Yi Chen, Dewen Hou, Zidong Wang

Materials Science and Engineering Faculty Publications and Presentations

In this work, dislocation interactions are directly observed and analyzed by using in-situ transmission electron microscope during heating processes in a pre-deformed Mg-3Al-1Zn magnesium alloy. Thermodynamic behaviors of two types of dislocations are investigated, i.e., individual dislocations and low-angle grain boundary arranged by dislocations. The results show that the low-angle grain boundary remains stable as the heating temperature increases to 673 K, while most of the individual dislocations disappear until the heating temperature reaches 473 K. Furthermore, the low-angle grain boundary tends to absorb individual dislocations nearby. The stability and the annihilation of both types of dislocations are discussed.

Deep Learning Of Microstructures, Amir Abbas Kazemzadeh Farizhandi

Boise State University Theses and Dissertations

The internal structure of materials also called the microstructure plays a critical role in the properties and performance of materials. The chemical element composition is one of the most critical factors in changing the structure of materials. However, the chemical composition alone is not the determining factor, and a change in the production process can also significantly alter the materials' structure. Therefore, many efforts have been made to discover and improve production methods to optimize the functional properties of materials. The most critical challenge in finding materials with enhanced properties is to understand and define the salient features of the …

Nucleation And Growth Of Molybdenum Disulfide Grown By Thermal Atomic Layer Deposition On Metal Oxides, Jake Soares, Steven Letourneau, Matthew Lawson, Anil U. Mane, Yu Lu, Yaqiao Wu, Steven M. Hues, Lan Li, Jeffrey W. Elam, Elton Graugnard

Materials Science and Engineering Faculty Publications and Presentations

To enable greater control over thermal atomic layer deposition (ALD) of molybdenum disulfide (MoS₂), here we report studies of the reactions of molybdenum hexafluoride (MoF₆) and hydrogen sulfide (H₂S) with metal oxide substrates from nucleation to few-layer films. In situ quartz crystal microbalance experiments performed at 150, 200, and 250 °C revealed temperature-dependent nucleation behavior of the MoF₆ precursor, which is attributed to variations in surface hydroxyl concentration with temperature. In situ Fourier transform infrared spectroscopy coupled with ex situ x-ray photoelectron spectroscopy (XPS) indicated the presence of molybdenum oxide and molybdenum oxyfluoride …

Heteroepitaxy Of Gasb On Gaas (111)A For Electron Transport Studies, Madison Drake

Boise State University Theses and Dissertations

III-V semiconductors grown by molecular beam epitaxy (MBE) on (111) surfaces have some interesting electronic properties. For certain materials with a (111)-orientation, the Γ- and L-valleys are reasonably close in energy. This means that it may be possible to take advantage of electron conduction in the L- and Γ-valleys at the same time, allowing us to overcome the so-called “density-of-states bottleneck,” and enable transistors with large drive currents.¹ We have investigated this phenomenon in GaSb- and InAs-based 2D electron gases for which the electron effective masses are low.

However, growth of materials with a (111) orientation is typically more …

Atomic Layer Processing Of Molybdenum Disulfide Thin Films, Jake Alan Soares

Boise State University Theses and Dissertations

As feature sizes in semiconductor devices continue to shrink, it is of upmost importance to synthesize materials that can accommodate the drastic degree of scaling. One such material receiving great attention is molybdenum disulfide (MoS₂), which is a semiconducting two-dimensional (2D) material in its most favorable few-layer form. The distinctive electrical properties make few to single-layer MoS₂ a potential candidate to replace silicon in many microelectronic devices. MoS₂ research is commonly conducted on mechanically exfoliated films due to the high quality, low defect layers that can be prepared. However, exfoliation is not a scalable method due …