Materials Science and Engineering Commons^™

Revealing Student Misconceptions And Instructor Blind Spots With Muddiest Point Formative Feedback, Cindy Waters, Stephen J. Krause, Janet Callahan, Barry Dupen, Mary B. Vollaro, Peggie Weeks

Materials Science and Engineering Faculty Publications and Presentations

Of interest to all engineering disciplines, well-designed formative feedback has the potential to enhance both instructor teaching and student learning. Delivering fundamental courses year after year, can ultimately lead faculty to use stale notes or slides from past years. This approach may save time, but does not meet the shifting needs of our students who have high expectations from their instructors. One simple method to improve teaching is to employ muddiest point reflections. Muddiest point reflections involve simply asking students to anonymously reflect on what was “muddy”, i.e. confusing, during class and to rank their level of confusion which not …

Micro/Nano-Structural Examination And Fission Product Identification In Neutron Irradiated Agr-1 Triso Fuel, I. J. Van Rooyen, T. M. Lillo, H. M. Wen, C. M. Hill, T. G. Holesinger, Y. Q. Wu, J. A. Aguiar

Materials Science and Engineering Faculty Publications and Presentations

Advanced electron microscopic and micro-analysis techniques were developed and applied to study irradiation effects and fission-product behavior in selected low-enriched uranium-oxide/uranium-carbide tristructural-isotropic (TRISO)-coated particles from fuel compacts in four capsules irradiated to burnups of 11.2 to 19.6% fissions per initial metal atom (FIMA) consisting of Baseline, Variant 1, and Variant 3 fuel types. Trend analysis shows precipitates were mostly random in their distribution along the perimeter of the inner pyrolytic carbon-silicon carbide (IPyC-SiC) interlayer with only weak association with kernel protrusion and buffer fractures. Pd is dominantly found in most precipitates in both intra and intergranular locations. Nano-sized Ag is …

Integrating Computational Modeling Modules Into Undergraduate Materials Science And Engineering Education, Lan (Samantha) Li

Materials Science and Engineering Faculty Publications and Presentations

To meet national workforce need, we integrated computational modeling training into undergraduate materials science and engineering (MSE) courses, including Thermodynamics, and Structure of Materials. We also flipped the courses, requiring students to self-study topics outside the class. In the class, the instructors focused on demonstrating real-world materials problems and guiding the students to solve the problems using different computational modeling techniques. Learning the computational modeling concepts within a short period of time was challenging to the students. Another challenge was that the students had various STEM backgrounds, such as MSE, mechanical engineering, and physics. In order to foster student learning, …

An Open-Source, Automated Chemical Vapor Deposition System For The Production Of 2d Materials, Dale Brown

Boise State University Theses and Dissertations

While interest in two-dimensional materials has exploded in recent years, the high cost of chemical vapor deposition (CVD) systems can act as a barrier to entry for some researchers interested in studying these materials. This thesis presents an open-source design for an automated CVD that can be built for a fraction of the cost of similarly capable commercial systems and that can easily be customized and expanded.With a CVD built as described,growth of high quality graphene and graphene foam is demonstrated.These results highlight the flexibility of the open-source design in producing a variety of nanomaterials, which are at the forefront …

Plastic Deformation And Effective Strain Hardening Coefficient Of Irradiated Fe-9wt%Cr Ods Alloy By Nano-Indentation And Tem, Corey Kenneth Dolph

Boise State University Theses and Dissertations

The objective of this study is to characterize changes in the yielding, and effective strain hardening coefficient of an oxide dispersion strengthened (ODS) alloy upon exposure to irradiation. It is well known that irradiation produces a supersaturation of defects, which alters the mechanical properties of a material. In order to engineer materials for use in advanced nuclear reactors, the long-term effects of neutron irradiation on mechanical performance must be understood. However, high-dose neutron exposure is often simulated using ion bombardment. Unfortunately, ion irradiation results in a shallow damage layer that prevents traditional bulk mechanical characterization methods from being utilized. A …

Electrolyte Optimization Study For Tio2 Nanotube Electrode In Sodium Ion Batteries, Richard Wendel Cutler

Boise State University Theses and Dissertations

Batteries are ubiquitous in daily life. Sodium-ion batteries have the potential to become inexpensive alternatives to the current market products such as Lithium-ion batteries. TiO₂ nanotubes have proven potential as an anode for Na-ion batteries. Electrolytes made by NaClO₄ salt and carbonate-based solvents make up commonly used electrolytes in sodium ion battery research. We used electrochemical and physical characterization tests to evaluate the optimum electrolyte for this anode material in the Na system. We determined that the ClO₄^- ion decomposes at the TiO₂ surface and promotes the formation of an unstable solid electrolyte interphase. A …

Determining Hydrodynamic Forces In Bursting Bubbles Using Dna Nanotube Mechanics, Rizal F. Hariadi, Erik Winfree, Bernard Yurke

Materials Science and Engineering Faculty Publications and Presentations

Quantifying the mechanical forces produced by fluid flows within the ocean is critical to understanding the ocean’s environmental phenomena. Such forces may have been instrumental in the origin of life by driving a primitive form of self-replication through fragmentation. Among the intense sources of hydrodynamic shear encountered in the ocean are breaking waves and the bursting bubbles produced by such waves. On a microscopic scale, one expects the surface-tension–driven flows produced during bubble rupture to exhibit particularly high velocity gradients due to the small size scales and masses involved. However, little work has examined the strength of shear flow rates …

Dna-Mediated Excitonic Upconversion Fret Switching, Donald L. Kellis, Sarah M. Rehn, Brittany L. Cannon, Paul H. Davis, Elton Graugnard, Jeunghoon Lee, Bernard Yurke, William B. Knowlton

Materials Science and Engineering Faculty Publications and Presentations

Excitonics is a rapidly expanding field of nanophotonics in which the harvesting of photons, ensuing creation and transport of excitons via Förster resonant energy transfer (FRET), and subsequent charge separation or photon emission has led to the demonstration of excitonic wires, switches, Boolean logic and light harvesting antennas for many applications. FRET funnels excitons down an energy gradient resulting in energy loss with each step along the pathway. Conversely, excitonic energy upconversion via upconversion nanoparticles (UCNPs), although currently inefficient, serves as an energy ratchet to boost the exciton energy. Although FRET-based upconversion has been demonstrated, it suffers from low FRET …

The Decision, Implementation And Assessment Of A Credit-Bearing Activity Class By Faculty In Residence: A Case Study, Janet Callahan, Geoff Harrison, Michael Humphrey, Cala Sielaff, Melissa Wintrow

Materials Science and Engineering Faculty Publications and Presentations

This case study reports on a programmatic decision to require a credit-bearing course that was made by Faculty in Residence (FIR), including its implementation and results over a two-year period from 2010-2012. The focus is on FIR and on the impact of their decision upon the students enrolled in their Living Learning Communities (LLCs). The credit-bearing course was a Kinesiology Activities class taken by all seven LLCs at Boise State University. Anonymous feedback from students was obtained via end of semester surveys; results were used to improve the course. Survey feedback was analyzed to assess the value students perceived to …

High Temperature Oxidation Kinetics Of Dysprosium Particles, Brian J. Jaques, Darryl P. Butt

Materials Science and Engineering Faculty Publications and Presentations

Rare earth elements have been recognized as critical materials for the advancement of many strategic and green technologies. Recently, the United States Department of Energy has invested many millions of dollars to enhance, protect, and forecast their production and management. The work presented here attempts to clarify the limited and contradictory literature on the oxidation behavior of the rare earth metal, dysprosium. Dysprosium particles were isothermally oxidized from 500 to 1000 °C in N₂–(2%, 20%, and 50%) O₂ and Ar–20% O₂ using simultaneous thermal analysis techniques. Two distinct oxidation regions were identified at each isothermal temperature …

Stability And Decomposition Of Ca-Substituted Lanthanum Ferrite In Reducing Atmospheres, Patrick M. Price, Darryl P. Butt

Materials Science and Engineering Faculty Publications and Presentations

Calcium-substituted lanthanum ferrites (La_1–xCa_xFeO_3–δ x = 0, 0.1, 0.2, 0.3, 0.4) were synthesized in air and subsequently decomposed in reducing atmospheres. The partial pressure of oxygen (P_O2) was controlled by varying the H₂/H₂O ratio by bubbling hydrogen/argon mixtures through water baths at controlled temperatures. Three regions of mass loss were identified as the P_O2 was reduced, two of which were determined to be associated with decomposition reactions. Calcium was shown to decrease the thermal stability of the perovskite compound, but rather …

Carbon Dioxide Sorption In A Nanoporous Octahedral Molecular Sieve, Izaak Williamson, Eric B. Nelson, Lan Li

Materials Science and Engineering Faculty Publications and Presentations

We have performed first-principles density functional theory calculations, incorporated with van der Waals interactions, to study CO₂ adsorption and diffusion in nanoporous solid – OMS-2 (Octahedral Molecular Sieve). We found the charge, type, and mobility of a cation, accommodated in a porous OMS-2 material for structural stability, can affect not only the OMS-2 structural features but also CO₂ sorption performance. This paper targets K⁺, Na⁺, and Ba²⁺ cations. First-principles energetics and electronic structure calculations indicate that Ba²⁺ has the strongest interaction with the OMS-2 porous surface due to valence electrons donation to …

Atom Probe Study Of Irradiation-Enhanced Α′ Precipitation In Neutron-Irradiated Fe–Cr Model Alloys, Yaqiao Wu

Materials Science and Engineering Faculty Publications and Presentations

Atom probe tomography (APT) was performed to study the effects of Cr concentrations, irradiation doses and irradiation temperatures on α′ phase formation in Fe–Cr model alloys (10–16 at.%) irradiated at 300 and 450 °C to 0.01, 0.1 and 1 dpa. For 1 dpa specimens, α′ precipitates with an average radius of 1.0–1.3 nm were observed. The precipitate density varied significantly from 1.1 × 10²³ to 2.7 × 10²⁴ 1/m³, depending on Cr concentrations and irradiation temperatures. The volume fraction of α′ phase in 1 dpa specimens qualitatively agreed with the phase diagram prediction. For 0.01 dpa …

First-Principles Studies Of Perovskite Compounds For Thermoelectric Applications, Penelope E. Ackerman, Lan Li (Mentor)

Idaho Conference on Undergraduate Research

Computational modeling techniques have been used to provide detailed insights into the structure-property relationships of materials. We have collaborated with the National Institute of Standards and Technology to develop various perovskite compounds with desired thermoelectric properties. We have used density functional theory-based approaches to study structural stability and electrical properties of R₂(FeCo)O₆ perovskite compounds (R = Pr, Nd, Sm, Eu and Gd), for which Fe and Co randomly occupy the B-site. Vienna ab-initio simulation package (VASP) has been performed to optimize geometry and structure. Superlattice and locally disordered phases have been compared through a total energy minimization …

On The Fe Enrichment During Anodic Polarization Of Mg And Its Impact On Hydrogen Evolution, D. Lysne, S. Thomas, M. F. Hurley, N. Birbilis

Materials Science and Engineering Faculty Publications and Presentations

Iron (Fe) is an unintentional impurity present in pure magnesium (Mg) and Mg alloys, albeit nominally in low and innocuous concentrations (< 100 ppmw). Since Fe, like most metals, is more noble than Mg, the presence of Fe impurities can serve as cathodic sites within the Mg matrix. During anodic polarization of Mg, incongruent dissolution can lead to undissolved Fe impurities accumulating upon the Mg surface, permitting an increase in the overall rate of hydrogen evolution. The experimental manifestation of the incongruent dissolution of Mg, has not yet been clarified, wherein, the extent and efficiency of Fe enrichment during anodic polarization is not known, and also the increase in the hydrogen evolution rate due to Fe enrichment has not been quantified. In this work, Mg specimens with Fe concentration between 40 to 13,000 ppmw were examined in 0.1 M NaCl to obtain a quantitative relation between the Fe concentration and the rate of cathodic hydrogen evolution. These base-line alloys were then anodically polarized to facilitate surface Fe enrichment, and subsequently again cathodically polarized to determine the impact of prior dissolution and Fe enrichment on the subsequent hydrogen evolution. A simple model to predict Fe enrichment was used to analyze the electrochemical data and predict the extent and efficiency of Fe enrichment.

Characterization Of Microstructure And Property Evolution In Advanced Cladding And Duct: Materials Exposed To High Dose And Elevated Temperature, Janelle P. Wharry

Materials Science and Engineering Faculty Publications and Presentations

Designing materials for performance in high-radiation fields can be accelerated through a carefully chosen combination of advanced multiscale modeling paired with appropriate experimental validation. The studies reported in this work, the combined efforts of six universities working together as the Consortium on Cladding and Structural Materials, use that approach to focus on improving the scientific basis for the response of ferritic–martensitic steels to irradiation. A combination of modern modeling techniques with controlled experimentation has specifically focused on improving the understanding of radiation-induced segregation, precipitate formation and growth under radiation, the stability of oxide nanoclusters, and the development of dislocation networks …

Reaction Kinetics Of Rare Earth And Actinide Materials, Brian Jon Jaques

Boise State University Theses and Dissertations

This dissertation presents the effects of atmosphere, time, and energy input (thermal and mechanical) on the kinetics of gas-solid and solid-solid reactions in systems of dysprosium, uranium, oxygen, and nitrogen. Accordingly, Chapter Two presents a novel synthesis technique used to form DyN via a gas-solid reaction between dysprosium and nitrogen. DyN was rapidly formed through a mechanochemical process in a high energy ball mill at ambient temperatures. The progress of the reaction was quantified using in situ temperature and pressure measurements coupled with microscopy and x-ray diffraction. It was found that the rate of the nitridation reaction is controlled by …

Resurrecting “Poor Man’S Purple”: A Transdisciplinary Study Of Color-Shifted Pigments Used In An Encaustic Fayum Mummy Portrait Of Ancient Egypt, Brittany Archuleta, Alaggio B. Laurino, Cameron E. Quade, John-Paul D. Stroud, Jared L. Talley, Brittany L. Cannon, Ron Garnys, Darryl P. Butt, Glenn Gates, Janice Neri

College of Engineering Presentations

During the Coptic period in Fayum Egypt, encaustic (i.e. wax) mummy portraits were painted onto wooden panels or linen and attached to the mummy trappings of the deceased. One such portrait, “32.6: The Bearded Man” (c. 170-180 AD), features an unidentified Roman-Egyptian displaying a purple clavi. The trace swath of purple in the portrait provides evidence as to the origins of the painting and the identity of the man. Nanoscale analysis of the pigment suggests a red organic material was color shifted using a metal salt to produce a “poor man’s purple” as opposed to the expensive murex purple traditionally …

Towards Molecular Modification Of Carbon Nanotube Junctions In Thin Film Transistors, Noelia Caloca, A. Nicole Chang, Kari Mclaughlin, David Estrada

College of Engineering Presentations

Carbon nanotube thin film transistors have recently been used on flexible and transparent substrates for applications in integrated circuits and display drivers. Such networks are of interest due to their relatively high carrier mobility and mechanical flexibility. However, the I_ON/I_OFF ratio of these networks varies inversely with the carrier mobility, and advances in reducing the electrical and thermal resistance of nanotube junctions are needed to improve the device performance and reliability. The objective of this work is create a process to improve CNT TFT device performance by using 0-dimensional molecules to modify the physical properties of the …

Oxide Dispersion Strengthened Nickel Based Alloys Via Spark Plasma Sintering, Somayeh Pasebani, Aniket K. Dutt, Jatuporn Burns, Indrajit Charit, Rajiv S. Mishra

Materials Science and Engineering Faculty Publications and Presentations

Oxide dispersion strengthened (ODS) nickel based alloys were developed via mechanical milling and spark plasma sintering (SPS) of Ni–20Cr powder with additional dispersion of 1.2 wt% Y₂O₃ powder. Furthermore, 5 wt% Al₂O₃ was added to Ni–20Cr–1.2Y₂O₃ to provide composite strengthening in the ODS alloy. The effects of milling times, sintering temperature, and sintering dwell time were investigated on both mechanical properties and microstructural evolution. A high number of annealing twins was observed in the sintered microstructure for all the milling times. However, longer milling time contributed to improved hardness and narrower …

Tip-Based Nanofabrication Of Arbitrary Shapes Of Graphene Nanoribbons For Device Applications, Huan Hu, Shouvik Banerjee, David Estrada, Rashid Bashir, William P. King

Materials Science and Engineering Faculty Publications and Presentations

Graphene nanoribbons (GNRs) have promising applications in future nanoelectronics, chemical sensing and electrical interconnects. Although there are quite a few GNR nanofabrication methods reported, a rapid and low-cost fabrication method that is capable of fabricating arbitrary shapes of GNRs with good-quality is still in demand for using GNRs for device applications. In this paper, we present a tip-based nanofabrication method capable of fabricating arbitrary shapes of GNRs. A heated atomic force microscope (AFM) tip deposits polymer nanowires atop a CVD-grown graphene surface. The polymer nanowires serve as an etch mask to define GNRs through one step of oxygen plasma etching …

Reference Diffraction Patterns, Microstructure, And Pore-Size Distribution For The Copper (Ii) Benzene-1,3,5-Tricarboxylate Metal Organic Framework (Cu-Btc) Compounds, L. Li, I. Williamson

Materials Science and Engineering Faculty Publications and Presentations

No abstract provided.

A Transdisciplinary Approach To Determining The Provenience Of A Distorted, Pre-Columbian Skull Recovered In Rural Idaho, Jennifer K. Watkins, Gordon A. Alanko, Samantha H. Blatt, Cynthia A. Bradbury, Matthew J. Kohn, Marion Lytle, Deborah Lacroix, Joanna Taylor, John Dudgeon, Rebecca E. Hazard, Erin O’Leary-Jepsen, Darryl P. Butt

College of Engineering Presentations

Transdisciplinary research involves cooperation, exchange of information, sharing of resources and integration of disciplines to achieve a common scientific goal. In this study, collaborators utilized tools and knowledge of materials science, anthropology, archaeology, geosciences and biology in an attempt to determine the provenience of skeletal remains of unknown origin. The exchange of ideas and skills along with the crossing of disciplines in this study sucessfully allowed the incorporation of expertise from many team members. This transdisciplinary approach to research provided a more comprehensive and detailed analysis than any one field alone could provide. An archaeological assessment of a human skull …

Investigation Of Fatigue Life And Fracture Mechanics Of Unconstrained Ni-Mn-Ga Single Crystals, Theodore Bryson Lawrence

Boise State University Theses and Dissertations

Ni-Mn-Ga is a magnetic shape memory alloy (MSMA) that exhibits large recoverable strains. The magnetic field induced strain (MFIS) occurs through twin boundary motion resulting in reorientation of the crystal structure, which is coupled to the magnetic moment of the material. The shape memory capabilities of the material make it promising for applications including microactuators, sensors, microfluid pumps, refrigeration, energy harvesting, and data storage.

In order for Ni-Mn-Ga to become a viable option for use in commercial applications the performance and reliability must be on par with industry standards. Ni‑Mn-Ga has been shown to achieve high cycles at low strains, …

The Electronic And Thermodynamic Properties Of Ca Doped Lafeo3: A First Principles Study Using Density Functional Theory, Davis George Daniel

Boise State University Theses and Dissertations

Density functional theory (DFT) was used to evaluate the electronic and thermodynamic properties of Ca-doped LaFeO₃ (La_1-xCa_xFeO_3-y). La_1-xCa_xFeO_3-y exhibits ionic (O^2- anions) and electronic conductivity at high temperatures and has potential applications in gas separation, syngas production and solid oxide fuel cell cathodes. DFT is a computational technique based on the First Principles of physics, derived from the theory of quantum mechanics. DFT approximates the ground state energy of a system and can subsequently determine many bulk properties such as lattice constants, magnetic states, band gap, density …

Creating A Stem Identity: Investment With Return, Janet Callahan, Patricia Pyke, Susan Shadle, R. Eric Landrum

Materials Science and Engineering Faculty Publications and Presentations

Establishing a strong STEM (science, technology, engineering and mathematics) identity at Boise State University, a metropolitan campus with approximately 3,655 undergraduate STEM students and a total undergraduate enrollment of approximately 19,042 (16,136 FTE) has been an important step toward creating a climate conducive to facilitating fundamental change. Examples of such change include building collaborations among faculty within and across departments, establishing the identity of students as part of a community beyond their chosen major, improving the efficiency and effectiveness of university systems, and perhaps most importantly, developing a framework to think deliberately about ways to effect change. This paper is …

Thermodynamics And Reaction Kinetics During Mechanochemical Synthesis And Environmental Testing Of Lanthanide And Actinide Refractory Materials, Gordon Andrew Alanko

Boise State University Theses and Dissertations

High energy ball milling is a broad family of well-known techniques for materials processing that includes mechanochemical synthesis, in which the milled materials react during milling. The latter may involve components reacting in the solid, liquid, or gas phases, and the operative kinetics have hardly been studied. Several manufacturers of high energy ball mills have recently made available instrumented milling vessel lids. These lids are able to monitor the temperature of the lid and the gas pressure within the vessel in situ during milling experiments. This ability is a significant improvement over the ad hoc instrumentation setups sometimes discussed in …

Phase Transformations In Calcium Substituted Lanthanum Ferrite, Patrick M. Price

Boise State University Theses and Dissertations

Increasing world energy demands are still heavily dependent on fossil fuels. To meet these demands, crude oil is increasingly being extracted from remote locations where natural gas pipelines do not exist. It is not profitable for oil and gas companies to transport natural gas by ship or truck from these remote locations so it is combusted on site in the form of gas flares. Critics oppose this practice due to the environmental impact from pollution and carbon emissions created during the flaring process. Oil and gas companies are eager to find profitable ways to eliminate natural gas lines in order …

Magnetic Shape Memory Micro-Pump For Intra-Cranial Drug Delivery, Sam Barker, Eric Rhoads, Andrew Morrison, Miranda Buttram, Paul Lindquist

College of Engineering Presentations

Magnetic shape-memory alloys exhibit strong magneto-structural coupling enabling large magnetic-field-induced deformation. Local control of twinning via variable inhomogeneous magnetic fields initiates local reversible deformation. Previous work produced a valve-less micropump consisting of a Ni-Mn-Ga single crystal, a casing, and a rod magnet. The micropump successfully pumped fluid in opposite directions when the magnet was turned clockwise and counter clockwise. Our current work modifies this micropump for application in rat a head stage, which would simultaneously monitor electroencephalograph data and deliver 0.5-5.0 μl of a drug solution at 100-500 nl/min directly to the rat’s brain. These improvements and the application of …

Molecular Modification Of Cnt Junctions, Kari Mclaughlin*, Hanna Meinikheim*, Angela "Nikki" Chang

College of Arts and Sciences Presentations

Carbon nanotube networks (CNNs) are increasingly finding applications as thin film transistors (TFTs), integrated circuits, and display drivers on flexible, transparent substrates. This is attributed to the higher carrier mobility of CNNs as compared to amorphous silicon and organic TFTs [1,2]. However, high electrical [3-5] and thermal [6,7] resistances at individual nanotube junctions (NJs) limit the performance of CNN devices. The resistances of the junctions are no less than an order of magnitude higher than those of individual carbon nanotubes (CNTs). This causes high power dissipation at the NJs. In the end this causes degradation of the overall device performance …