Materials Science and Engineering Commons^™

The Mechanism Of Radiation-Induced Nanocluster Evolution In Oxide Dispersion Strengthened And Ferritic-Martensitic Alloys, Matthew John Swenson

Boise State University Theses and Dissertations

The objective of this study is to evaluate the mechanism of irradiation-induced nanoparticle evolution in a model Fe-9%Cr oxide dispersion strengthened steel and commercial ferritic-martensitic alloys HCM12A and HT9. Each alloy is irradiated with Fe²⁺ ions, protons, or neutrons to doses ranging from 1-100 displacements per atoms at 500°C. The morphology of nanoclusters are characterized using atom probe tomography. The evolution of clusters in each alloy are notably different with each irradiating particle, and the competing effects of ballistic dissolution and radiation-enhanced, diffusion-driven growth are attributed to the respective differences in cluster evolution. A phase evolution model, originally theorized …

Testing Our Assumptions: The Role Of First Course Grade And Course Level In Mathematics And English, Janet Callahan, Marcia Belcheir

Materials Science and Engineering Faculty Publications and Presentations

Methods that provide an early indicator of factors that affect student persistence are important to colleges and universities. This quantitative research focused on the role of level of entry mathematics and English and also on grades earned in those classes as they relate to persistence after one year. The research showed that by far, the variable most predictive of first-time, full-time students enrolling one year later was earning a grade of “A” in English. Compared to those who did not pass their first English course, students who earned an “A” were three times more likely to persist. The variables which …

Computationally Connecting Organic Photovoltaic Performance To Atomistic Arrangements And Bulk Morphology, Matthew L. Jones, Eric Jankowski

Materials Science and Engineering Faculty Publications and Presentations

Rationally designing roll-to-roll printed organic photovoltaics requires a fundamental understanding of active layer morphologies optimized for charge separation and transport, and which ingredients can be used to self-assemble those morphologies. In this review article we discuss advances in three areas of computational modeling that provide insight into active layer morphology and the charge transport properties that result. We explain the computational bottlenecks prohibiting atomistically-detailed simulations of device-scale active layers and the coarse-graining and hardware acceleration strategies for overcoming them. We review coarse-grained simulations of organic photovoltaic active layers and show that high throughput simulations of experimentally-relevant length scales are now …

Listening And Negotiation Ii, Adjo A. Amekudzi-Kennedy, Kevin D. Hall, Trevor Scott Harding, Amy J. Moll, Janet Callahan

Materials Science and Engineering Faculty Publications and Presentations

This paper is based on a panel held in June, 2017 in Columbus, Ohio, jointly sponsored by the Women in Engineering Division and by the Minorities in Engineering Division. It is focused on negotiation, with an emphasis on providing practical strategies that are relevant in an academic setting. The panel featured academic leaders at multiple levels, including professor, chair and dean, from diverse engineering institutions, ranging from teaching-centric to heavily research-focused. Panelists discussed strategies for negotiation, with an emphasis on an approach that meets the interests of both parties to the extent possible. The panel was administrated with an opening …

Establishing Doctoral Programs In Electrical Engineering, Materials Science And Engineering, And Computing In An Emerging Research Institution: Lessons Learned And Best Practices, Janet Callahan, Cheryl B. Schrader, Darryl P. Butt, Timothy Anderson, Tammi Vacha-Hasse, Amy J. Moll

Materials Science and Engineering Faculty Publications and Presentations

Over the past decade, three doctoral programs have been launched at Boise State University. The first doctoral program established was in Electrical and Computer Engineering, selected because of the need for a trained workforce in the region. The other two doctoral programs, Materials Science and Engineering, and Computing, were from the start designed as interdisciplinary degree programs. That is, they were designed for the participation of not just program faculty within the division, but for the participation of program faculty with related research interests in other departments at the university. This paper presents the steps taken to launch the programs, …

Vertically Integrated Projects (Vip) Programs: Multidisciplinary Projects With Homes In Any Discipline, Jocelyn B. S. Cullers, William L. Hughes, Donna C. Llewellyn

Materials Science and Engineering Faculty Publications and Presentations

A survey of papers in the ASEE Multidisciplinary Engineering Division over the last three years shows three main areas of emphasis: individual courses; profiles of specific projects; and capstone design courses. However, propagating multidisciplinary education across the vast majority of disciplines offered at educational institutions with varying missions requires models that are independent of the disciplines, programs, and institutions in which they were originally conceived. Further, models that can propagate must be cost effective, scalable, and engage and benefit participating faculty. Since 2015, a consortium of twenty-four institutions has come together around one such model, the Vertically Integrated Projects (VIP) …

Ten Years Later: Where Are They Now?, Janet Callahan, Donna C. Llewellyn, Vicki Stieha, Ann E. Delaney

Materials Science and Engineering Faculty Publications and Presentations

This paper explores the educational and career trajectories of the alumnae of an outreach activity for girls. The outreach activity was originally developed using an integrated marketing approach to attract girls into engineering programs.¹ The program, a two day, overnight experience for rising 9^th, 10^th and 11^th grade girls, focuses on showcasing engineering as an exciting, creative activity, including activities developed from that perspective. Started in 2005 and held annually since then, a total of over 500 girls have participated, with approximately 85% of them coming from Boise State University’s immediate metropolitan area. Facilitated by …

Effects Of Proton Irradiation On Structural And Electrochemical Charge Storage Properties Of Tio2 Nanotube Electrode For Lithium-Ion Batteries, Kassiopeia A. Smith, Andreas I. Savva, Changjian Deng, Hui Xiong

Materials Science and Engineering Faculty Publications and Presentations

The effects of proton irradiation on nanostructured metal oxides have been investigated. Recent studies suggest that the presence of structural defects (e.g. vacancies and interstitials) in metal oxides may enhance the material’s electrochemical charge storage capacity. A new approach to introduce defects in electrode materials is to use ion irradiation as it can produce a supersaturation of point defects in the target material. In this work we report the effect of low-energy proton irradiation on amorphous TiO₂ nanotube electrodes at both room temperature and high temperature (250 ˚C). Upon room temperature irradiation the nanotubes demonstrate an irradiation-induced phase transformation …

Computational Modeling Of Electrical And Phonon Properties Of Skutterudites And Two-Dimensional Transition Metal Dichalcogenides, Izaak Gene Williamson

Boise State University Theses and Dissertations

This dissertation documents the computational modeling of skutterudite and two-dimensional transition metal dichalcogenide (2D TMD) materials for energy and electronic applications by analyzing the effects of materials doping and heterostructure formation on structural, energetic, electrical, phonon, and thermal properties. These topics remain largely unexplored and can accelerate materials development by providing insight on structure-properties-performance relationships.

Skutterudites are commonly studied for thermoelectric applications because they are low-cost, easy to process, and offer good intrinsic transport properties. They also exist as large, open structures which can be altered through filler atoms or substitutional dopants. A density functional theory (DFT)-based investigation of dopant …

Assessing Time-Dependent Density Functional Theory As A Computational Tool To Model Chromophores Intercalated Into Dna Scaffolds, Eric Nelson

McNair Scholars Research Journal

Understanding first-principles energy transport in organic molecules reveals novel energy harvesting systems, quantum computing, and solar power energy transportation and production. DiSC₂(5), also named Cy5, exhibits bright fluorescence signals and has shown promising lossless exciton transport properties, as well as tunable energy absorption and emission when conjoined with DNA. This paper focuses on functional groups of organic molecules, specifically the chromophoric red dye DiSC₂(5) and its interaction with H- and J-aggregates and with DNA. Density functional theory (DFT) and time dependent density functional theory (TD-DFT) are applied to investigate the chromophore Cy5 in vertically stacked (H-aggregates) …

Liquid-Gas Surface Tension Voltage Dependence During Electrowetting On Dielectric Of 5-90 Nm Gold Nanofluids, Saeid Vafaei, Karthik Chinnathambi, Theodorian Borca-Tasciuc

Materials Science and Engineering Faculty Publications and Presentations

This article investigates the effective liquid-gas surface tension changes of water and 5-90nm gold nanofluids measured during electrowetting on dielectric experiments. The Young-Laplace equation for sessile droplets in air was solved to fit the experimental droplet shape and determine the effective liquid-gas surface tension at each applied voltage. A good agreement between experimental droplet shapes and the predictions was observed for all the liquids investigated in applied range of 0-30V. The measured liquid-gas effective surface tensions of water and gold nanofluid decreased with voltage. At a given voltage, the effective liquid-gas surface tension of gold nanofluids initially decreased as the …

Availability: A Metric For Nucleic Acid Strand Displacement Systems, Xiaoping Olson, Shohei Kotani, Jennifer E. Padilla, Natalya Hallstrom, Sara Goltry, Jeunghoon Lee, Bernard Yurke, William L. Hughes, Elton Graugnard

Materials Science and Engineering Faculty Publications and Presentations

DNA strand displacement systems have transformative potential in synthetic biology. While powerful examples have been reported in DNA nanotechnology, such systems are plagued by leakage, which limits network stability, sensitivity, and scalability. An approach to mitigate leakage in DNA nanotechnology, which is applicable to synthetic biology, is to introduce mismatches to complementary fuel sequences at key locations. However, this method overlooks nuances in the secondary structure of the fuel and substrate that impact the leakage reaction kinetics in strand displacement systems. In an effort to quantify the impact of secondary structure on leakage, we introduce the concepts of availability and …

Signal-To-Noise Ratio Enhancement Using Graphene-Based Passive Microelectrode Arrays, Sepideh Rastegar, Justin Stadlbauer, Kiyo Fujimoto, Kari Mclaughlin, David Estrada, Kurtis D. Cantley

Materials Science and Engineering Faculty Publications and Presentations

This work is aimed toward the goal of investigating the influence of different materials on the signal-to-noise ratio (SNR) of passive neural microelectrode arrays (MEAs). Noise reduction is one factor that can substantially improve neural interface performance. The MEAs are fabricated using gold, indium tin oxide (ITO), and chemical vapor deposited (CVD) graphene. 3D-printed Nylon reservoirs are then adhered to the glass substrates with identical MEA patterns. Reservoirs are filled equally with a fluid that is commonly used for neuronal cell culture. Signal is applied to glass micropipettes immersed in the solution, and response is measured on an oscilloscope from …

Application Of Artificial Neural Networks To Identify Equilibration In Computer Simulations, Michael H. Leibowitz, Evan D. Miller, Michael M. Henry, Eric Jankowski

Materials Science and Engineering Faculty Publications and Presentations

Determining which microstates generated by a thermodynamic simulation are representative of the ensemble for which sampling is desired is a ubiquitous, underspecified problem. Artificial neural networks are one type of machine learning algorithm that can provide a reproducible way to apply pattern recognition heuristics to underspecified problems. Here we use the open-source TensorFlow machine learning library and apply it to the problem of identifying which hypothetical observation sequences from a computer simulation are "equilibrated" and which are not. We generate training populations and test populations of observation sequences with embedded linear and exponential correlations. We train a two-neuron artificial network …

Nanomanufacturing Outside Of The Lab: An Academic-Industry Partnership Case Study, Ann E. Delaney

Boise State University Theses and Dissertations

In 2003, policy entrepreneur Dr. Mihail Roco wrote in Nature Biotechnology, “The key goals of nanotechnology are advances in molecular medicine, increased working productivity, extension of the limits of sustainable development and increased human potential.” From initial visions like Roco’s until now, there has been significant investment and research progress in the field of nanotechnology. According to the White House, over $20 billion has been invested in nanotechnology research and development by the United States government since 2000.¹ There is now a growing emphasis on transitioning from a focus on fundamental research towards a focus on overcoming …

Empirical Models For Structural Effects Of A-Site Point Defects And Ordering In Perovskites, Kevin Ross Tolman

Boise State University Theses and Dissertations

Composition-structure-property relationships are essential keys to unlocking the strength of predictive crystal chemistry. Awkwardly, the electroceramics industry largely relies on various time-consuming and expensive trial-and-error experiments to address new questions which often could otherwise be interpolated from published data. Indeed, predictive models, which can be derived from empirical evidence, can greatly aid the direction and support of future development in a meaningful, apt, and cost-effective way. Theory suggests that intrinsic properties on the scale of a unit cell may be estimated from the sizes and charges of the chemical constituents alone. Ultimately, researchers could be provided a compositional recipe for …

High-Temperature Corrosion Testing Of Uranium Silicide Surrogates, B. J. Jaques, G. Alanko, D. P. Butt

Materials Science and Engineering Faculty Publications and Presentations

The corrosion resistance of cerium silicide, a surrogate of uranium silicide, is investigated to gain insight into the reaction of uranium silicide with water. As-received and proton-irradiated Ce₃Si₂, CeSi₂, and CeSi_1.x monolithic pellets are subjected to corrosion tests in water at 300°C and 9 MPa for up to 48 h. Results show that an oxide layer composed of Ce_4.67 (SiO₄)₃O forms on the surface of all samples, and it grows thicker with extended exposure times. Irradiated samples corrode to a greater extent than their unirradiated counterparts, which is …

Sample Preparation Techniques For Grain Boundary Characterization Of Annealed Triso-Coated Particles, M. L. Dunzik-Gougar, I. J. Van Rooyen, C. M. Hill, T. Trowbridge, J. Madden, J. Burns

Materials Science and Engineering Faculty Publications and Presentations

Crystallographic information about layers of silicon carbide (SiC) deposited by chemical vapor deposition is essential to understanding layer performance, especially when the the layers are in nonplanar geometries (e.g., spherical). Electron backscatter diffraction (EBSD) was used to analyze spherical SiC layers using a different sampling approach that applied focused ion beam (FIB) milling to avoid the negative impacts of traditional sample polishing and address the need for very small samples of irradiated materials for analysis. The mechanical and chemical grinding and polishing of sample surfaces can introduce lattice strain and result in the unequal removal of SiC and the surrounding …

Partial Oxidation Of Surrogate Jet-A Fuel Over Sio2 Supported Moo2, Shreya Shah, Oscar G. Marin-Flores, Chinnathambi Karthik, M. Grant Norton, Su Ha

Materials Science and Engineering Faculty Publications and Presentations

A SiO₂-supported MoO₂ nanoparticle catalyst was synthesized by a sol-gel method and tested as catalytic material for the partial oxidation of n-dodecane. MoO₂ nanoparticles supported on SiO₂ are °C, which is a typical reforming temperature for n-dodecane. The formation of Mo O Si bonds at the interface between MoO₂ nanoparticles and SiO₂ support appear to be responsible for the enhanced stability to sintering displayed by the nanoparticles. As a result of this particle size stabilization, SiO₂ supported MoO₂ nanoparticles show an improved reforming activity in terms of syngas generation …

Nonlinear Machine Learning And Design Of Reconfigurable Digital Colloids, Andrew W. Long, Carolyn L. Phillips, Eric Jankowski, Andrew L. Ferguson

Materials Science and Engineering Faculty Publications and Presentations

Digital colloids, a cluster of freely rotating “halo" particles tethered to the surface of a central particle, were recently proposed as ultra-high density memory elements for information storage. Rational design of these digital colloids for memory storage applications requires a quantitative understanding of the thermodynamic and kinetic stability of the configurational states within which information is stored. We apply nonlinear machine learning to Brownian dynamics simulations of these digital colloids to extract the low-dimensional intrinsic manifold governing digital colloid morphology, thermodynamics, and kinetics. By modulating the relative size ratio between halo particles and central particles, we investigate the size-dependent configurational …

High-Performance And Flexible Thermoelectric Films By Screen Printing Solution-Processed Nanoplate Crystals, Tony Varghese, Courtney Hollar, Joseph Richardson, Nicholas Kempf, Chao Han, Pasindu Gamarachchi, David Estrada, Yanliang Zhang

Materials Science and Engineering Faculty Publications and Presentations

Screen printing allows for direct conversion of thermoelectric nanocrystals into flexible energy harvesters and coolers. However, obtaining flexible thermoelectric materials with high figure of merit ZT through printing is an exacting challenge due to the difficulties to synthesize high-performance thermoelectric inks and the poor density and electrical conductivity of the printed films. Here, we demonstrate high-performance flexible films and devices by screen printing bismuth telluride based nanocrystal inks synthesized using a microwave-stimulated wet-chemical method. Thermoelectric films of several tens of microns thickness were screen printed onto a flexible polyimide substrate followed by cold compaction and sintering. The n-type films demonstrate …

Thermoelectric Half-Heuslers: Synthesis, Processing, And Performance, Joseph Robert Croteau

Boise State University Theses and Dissertations

Thermoelectric half-Heusler compounds have potential to convert the heat wasted from industrial and transportation processes to useful electricity. Among the highest performing half-Heusler compounds are nano-structured bulk materials which have been arc-melted, pulverized into a nano-powder, and sintered by DC-hot press. High performing n- and p-type half-Heusler compounds with nominal composition of Hf_0.25Zr_0.75NiSn_0.99Sb_0.01 and Nb_0.75Ti_0.25FeSb, respectively, have been provided to us in both dense and powder form by our collaborators at the University of Houston. We consolidate these powders by SPS, refine these powders to improve both particle size …

Cermet Development For High Temperature And High Pressure Applications, Beatriz Justus Ferez, Samantha Guthrie, Brian J. Jaques (Mentor), Darryl P. Butt (Mentor)

Idaho Conference on Undergraduate Research

Many traditionally used low cost alloys are easily corroded in steam or supercritical CO₂. An effective solution is to utilize ceramic heat exchangers that are often integrated with metallic components which result in a significant thermal expansion mismatch. The goal of this project is to develop a sealing method to create a hermetic joint between the ceramic and metal alloy. Proposed is a seal ring containing a cermet powder with a coefficient of thermal expansion (CTE) higher than the ceramic and metal to produce a high temperature compressive seal. Cermets of Ag and MgO have been selected to …

Computational Studies Of Grain Boundary Behavior In Uranium Dioxide Nuclear Fuels, Eric Nelson, Lan Li (Mentor), Simon C. Middleburgh (Mentor)

Idaho Conference on Undergraduate Research

Nuclear power is responsible for the production of 380,000 Megawatts of energy worldwide, which results in over 11% of the world’s energy production [world-nuclear.org]. Pellet-cladding interactions (PCI) are a key nuclear fuel failure mechanism which presents formidable challenges to researchers due to extreme nuclear fission conditions. Although PCI interactions have been reduced due to fuel additives, understandings of PCI interactions remain elusive. We propose new approaches to increase understanding of nuclear fuel interactions; specifically, uranium dioxide and the effects of dopants. This study focuses on amorphous uranium dioxide and fission products, while benchmarking new methods with previous computational studies. Results …

Verifying The Implementation Of An Anisotropic Grain Boundary Energy Model In Idaho National Lab’S Marmot, John-Michael H. Bradley, Evan D. Hansen, Jarin C. French, Yongfeng Zhang (Mentor)

Idaho Conference on Undergraduate Research

This work aims to verify the correct implementation of an anisotropic grain boundary (GB) energy model for face-centered cubic (FCC) and fluorite materials in Idaho National Laboratory’s phase field fuel performance code MARMOT. The model was recently implemented in MARMOT with the purpose of enabling higher fidelity simulations of UO₂ nuclear fuels. As part of verification, tests were performed to measure the energy dependence on misorientation of high symmetry GBs in an FCC metal (Cu). The energies of the [100], [110], and [111] twist boundaries result as predicted, as do the energies of the [111] symmetric tilt boundaries. However, …

Controlling The Corrosion And Cathodic Activation Of Magnesium Via Microalloying Additions Of Ge, R. L. Liu, M. F. Hurley, A. Kvryan, G. Williams, J. R. Scully, N. Birbilis

Materials Science and Engineering Faculty Publications and Presentations

The evolution of corrosion morphology and kinetics for magnesium (Mg) have been demonstrated to be influenced by cathodic activation, which implies that the rate of the cathodic partial reaction is enhanced as a result of anodic dissolution. This phenomenon was recently demonstrated to be moderated by the use of arsenic (As) alloying as a poison for the cathodic reaction, leading to significantly improved corrosion resistance. The pursuit of alternatives to toxic As is important as a means to imparting a technologically safe and effective corrosion control method for Mg (and its alloys). In this work, Mg was microalloyed with germanium …

The Impact Of Volunteering At A Girls Outreach Activity On Community Formation, Donna C. Llewellyn, Janet Callahan, Amy J. Moll, Catherine Rose Bates

Materials Science and Engineering Faculty Publications and Presentations

This paper is focused on exploring the motivation for volunteering at an engineering outreach activity. The outreach activity itself involved a two day, overnight experience for 9th and 10th grade girls that started in 2005, and which has been held annually since that time. The outreach event takes place in Boise, Idaho, and at the time of its onset was the only outreach or camp activity in the state focused on girls or young women. Across ten years, 510 total girls have participated, with approximately 85% of them coming from the immediate metropolitan area. The program was developed with a …

Microgalvanic Corrosion Behavior Of Cu-Ag Active Braze Alloys Investigated With Skpfm, Armen Kvryan, Kari Livingston, Corey M. Efaw, Kyle Knori, Brian J. Jaques, Paul H. Davis, Darryl P. Butt, Michael F. Hurley

Materials Science and Engineering Faculty Publications and Presentations

The nature of microgalvanic couple driven corrosion of brazed joints was investigated. 316L stainless steel samples were joined using Cu-Ag-Ti and Cu-Ag-In-Ti braze alloys. Phase and elemental composition across each braze and parent metal interface was characterized and scanning Kelvin probe force microscopy (SKPFM) was used to map the Volta potential differences. Co-localization of SKPFM with Energy Dispersive Spectroscopy (EDS) measurements enabled spatially resolved correlation of potential differences with composition and subsequent galvanic corrosion behavior. Following exposure to the aggressive solution, corrosion damage morphology was characterized to determine the mode of attack and likely initiation areas. When exposed to 0.6 …

Listening And Negotiation, Janet Callahan, Mary E. Besterfield-Sacre, Jenna P. Carpenter, Kim Lascola Needy, Cheryl B. Schrader

Materials Science and Engineering Faculty Publications and Presentations

Negotiation is an important skill for faculty at all stages of their career, but one that research suggests is often uncomfortable for women faculty to employ. This paper focuses on the topic of negotiation, with an emphasis on providing practical ideas and strategies relevant to academic professionals at both entry-level and mid-career who find that they need to negotiate a career opportunity. The paper will review negotiation basics, as well as discuss what can be negotiated, how one might proceed to discuss these, and how listening is critical to negotiation. By viewing negotiation as a "wise agreement"¹ that seeks …

Support Model For Transfer Students Utilizing The Stem Scholarship Program, Lynn Olson, Amy J. Moll, Doug Bullock, Amit Jain, Janet Callahan

Materials Science and Engineering Faculty Publications and Presentations

This paper describes how the College of Engineering at Boise State University utilized a National Science Foundation S-STEM award from 2011 to 2016 to support transfer students in their path toward graduation. The need for this support was a result of both Boise State University College of Engineering’s transition from a 2-year pre-engineering program to the establishment of Bachelors of Science in Engineering Degree programs in 1997 as well as the establishment of the College of Western Idaho as a regional community college in 2007. Both of these factors led to an increase in the numbers of incoming engineering students …