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Articles 4861 - 4890 of 5380

Full-Text Articles in Materials Science and Engineering

Glow-Discharge Enhanced Permeation Of Oxygen Through Silver, D. Wu, R. A. Outlaw, Robert L. Ash Jan 1993

Glow-Discharge Enhanced Permeation Of Oxygen Through Silver, D. Wu, R. A. Outlaw, Robert L. Ash

Mechanical & Aerospace Engineering Faculty Publications

The permeation of oxygen through Ag0.05Zr over the temperature range of 300-650°C under glow-discharge conditions has been studied and compared to the permeation of thermally dissociated molecular oxygen. A low-energy dc glow-discharge in O2 has been employed which produced approximately 10% atoms. The permeation rate during the glow discharge was found to be much higher (a factor of ∼10) than without the glow discharge. The small fraction of oxygen atoms generated appears to dominate the permeation because of much higher solution probabilities. Below 500°C, the activation energy for the permeation with glow discharge was found to be 15.5 kcal/mol …

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Processability Of Polythiophene Thin Films By Ultraviolet Photo Bleaching, Derek D. Fletcher Dec 1992

Processability Of Polythiophene Thin Films By Ultraviolet Photo Bleaching, Derek D. Fletcher

Theses and Dissertations

Materials possessing strong ��(3) optical properties such as Polythiophene are sought for the production of optical switches. Polythiophene thin films produced by plasma enhanced CVD show a surface rms roughness of 10-15 angstroms over single square micron areas which is acceptable for wave guiding in the near IR. This research investigates permanently changing the optical properties of such a thin film by exposure to UV radiation (254 nm, 35 mW/cm2), known as photo bleaching, in hope of creating a refractive index boundary for use in total internal reflection. After 60 minutes exposure the refractive index shows …

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Cathodoluminescence Spectroscopy Of Zinc Germanium Phosphide Zngep2, Michael R. Gregg Dec 1992

Cathodoluminescence Spectroscopy Of Zinc Germanium Phosphide Zngep2, Michael R. Gregg

Theses and Dissertations

Zinc Germanium Phosphide (ZnGeP2) is a nonlinear semiconductor suitable for use as a laser tuning element over the two to six micron wavelength range. Although this crystal has been studied in the past, its luminescent properties are not yet well understood. In this present study, ZnGeP2 has been examined using cathodoluminescence spectroscopy (CL). Specifically, the spectral dependence of the CL was obtained as a function of electron beam energy, beam current and temperature. The resulting CL was found to be polarized with a peak structure that was dependent on the polarization. This peak structure observed by CL …

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Use Of High-Energy Radiation For Degradation Of Environmental Pollutants, Robert D. Guthrie, Manjiri Patwardhan Oct 1992

Use Of High-Energy Radiation For Degradation Of Environmental Pollutants, Robert D. Guthrie, Manjiri Patwardhan

KWRRI Research Reports

The purpose of this project was to explore the advantages and/or limitations of high-energy radiation treatment as a method for degrading organic pollutants, particularly aryl halides, in an aqueous medium. We have done analyses of 60Co-irradiated samples and kinetic studies using pulsed electron beams. For aryl halides containing no more than two fused rings, the main products detected are those of simple halogen replacement by hydrogen, although the amount of aryl halide destroyed was always greater than the total amount of products detected. To accomplish halogen replacement by H, the reaction solvent may not be pure water but must …

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34th Rocky Mountain Conference On Applied Spectroscopy Aug 1992

34th Rocky Mountain Conference On Applied Spectroscopy

Rocky Mountain Conference on Magnetic Resonance

Program and registration information for the 34th annual meeting of the Rocky Mountain Conference on Applied Spectroscopy, co-sponsored by the Colorado Section of the American Chemical Society and the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 2-6, 1992.

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Prediction Of Paper Color: A Process Simulation Approach, Mayank Chaturvedi Jun 1992

Prediction Of Paper Color: A Process Simulation Approach, Mayank Chaturvedi

Masters Theses

A simulation model was developed for a dye mixing process and for the prediction of the optical properties of the paper. The model was integrated with the MAPPS (Modular Analysis of Pulp and Paper Systems) simulation software package. The model was validated using dyed handsheets made in a laboratory and dyed paper made on a pilot papermachine. Validation comprised of prediction of the optical properties of the handsheets and the machine-made paper which contained various combinations of three non-fluorescent dyes. Sheet reflectances were predicted at 20 nanometer intervals for discrete light wavelength range of 400 to 700 nanometers and verified …

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Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis Oct 1991

Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis

Chemistry & Biochemistry Theses & Dissertations

Catalysts composed of platinum and/or palladium on tin (IV) oxide supports, with and without silica gel, as well as catalysts composed of gold on manganese oxide, have been developed for the recombination of carbon monoxide and oxygen to form carbon dioxide for use in carbon dioxide lasers. A thermogravimetric method and a differential scanning calorimetric method have been developed for the thermal characterization of these catalysts. The mass loss data and the enthalpy changes determined as the catalysts lost water were then related to existing activity data for these catalysts. No relationship was found between the thermal data and the …

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33rd Rocky Mountain Conference On Applied Spectroscopy Jul 1991

33rd Rocky Mountain Conference On Applied Spectroscopy

Rocky Mountain Conference on Magnetic Resonance

Program and registration information for the 33rd annual meeting of the Rocky Mountain Conference on Applied Spectroscopy, sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, July 28 - August 1, 1991.

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Removal Of Chlorine From Chlorine-Nitrogen Mixture In A Film Of Liquid Water, Sarwan S. Sandhu Apr 1991

Removal Of Chlorine From Chlorine-Nitrogen Mixture In A Film Of Liquid Water, Sarwan S. Sandhu

Chemical and Materials Engineering Faculty Publications

In industry there are many examples of absorption of a gas with or without chemical reaction in the liquid phase. In physical absorption, a particular gaseous component is removed from a gas mixture due to its larger solubility in the liquid phase solvent. The removal of butane and pentane from a refinery gas mixture by a heavy oil in the liquid phase is an example of physical absorption. In absorption with chemical reaction, the gaseous component to be removed transfers across the gas-liquid interface due to a difference in the bulk chemical potentials or concentrations in the two phases. The …

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Magnetic-Field Distributions In Zinc-Nickel Ferrite, T. A. Dooling, Desmond C. Cook Apr 1991

Magnetic-Field Distributions In Zinc-Nickel Ferrite, T. A. Dooling, Desmond C. Cook

Physics Faculty Publications

The Mössbauer effect has been used to study the microscopic magnetic properties of the cubic microwave ferrite (Zn0.41Ni0.59)Fe2O4 at 300 K. The magnetically split spectrum is broad and unresolved due to the overlap of the hyperfine magnetic fields at the tetrahedral and octahedral sites. This is caused by a distribution of magnetic fields at each site. The distribution is especially large and asymmetric at the octahedral site and is due to the fact that the iron atoms at this site are influenced by the presence of both iron and zinc at the tetrahedral …

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Phase Changes In Plasma‐Sprayed Zinc‐Nickel Ferrite, T. A. Dooling, Desmond C. Cook Apr 1991

Phase Changes In Plasma‐Sprayed Zinc‐Nickel Ferrite, T. A. Dooling, Desmond C. Cook

Physics Faculty Publications

The magnetic and crystalline properties of a plasma‐sprayed coating of the microwave absorbing zinc‐nickel ferrite, (Zn0.41Ni0.59 )Fe2O4 have been studied at 300 K using the Mössbauer effect and x‐ray diffraction (XRD). Both techniques indicate that the plasma‐sprayed material separated into two phases. The first is a nickel‐rich phase with magnetic fields of 47.5 and 44.5 T at the tetrahedral and octahedral sites, respectively. The second is a zinc‐rich phase, zinc meta‐ferrite, having a small magnetic field of 4.2 T. The quadrupole splitting of this second phase is ΔE=0.34 mm s−1, …

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Calculated Point Defect Properties Of The Intermetallic Compounds Nickel Titanium (Niti) And Iron Titanium (Feti), Russell T. Lutton Mar 1991

Calculated Point Defect Properties Of The Intermetallic Compounds Nickel Titanium (Niti) And Iron Titanium (Feti), Russell T. Lutton

Theses and Dissertations

Atomistic simulation with a modified version of the DYNAMO code was used to calculate the point defect properties of the intermetallic compounds nickel titanium and iron titanium. The calculated energies are believed to be experimentally accurate to within ± 0.1 eV. Vacant Ni or Fe lattice sites were preferred and had energies of 6.356 eV for NiTi and 5.899 eV for FeTi. Removing a Ti atom resulted in a neighboring antisite defect caused by migration of a Ni or Fe atom into the vacant Ti site. These configurations had energies of 7.024 eV for NiTi and 6.336 eV for FeTi. …

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Properties Of Glass Fabric Reinforced Silicone Glazing For Solar Applications In Rural Areas, Mohammed A Ahmed Dabbour Jan 1991

Properties Of Glass Fabric Reinforced Silicone Glazing For Solar Applications In Rural Areas, Mohammed A Ahmed Dabbour

Archived Theses and Dissertations

No abstract provided.

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Defect Structure, Nonstoichiometry, And Phase Stability Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, M. M. Nasrallah, Don M. Sparlin Jan 1991

Defect Structure, Nonstoichiometry, And Phase Stability Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, M. M. Nasrallah, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

The dependence of the defect structure of Ca-doped YCrO3 on oxygen activity and temperature was investigated by high temperature thermogravimetric measurements. Defect models developed from electrical conductivity data obtained in a previous study were used to interpret the thermogravimetric data. A correlation was found between the electrical conductivity and the thermogravimetric data which suggested that these data were concomitantly dependent on the acceptor dopant and oxygen vacancy dependance of the thermodynamic parameters. Kröger-Vink type diagrams showing the regions of stability with respect to oxygen activity and temperature were constructed. The TGA data show that Ca-doped YCrO3 is even …

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Electrical Conductivity, Seebeck Coefficient And Defect Chemistry Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, Don M. Sparlin, M. M. Nasrallah Jan 1991

Electrical Conductivity, Seebeck Coefficient And Defect Chemistry Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, Don M. Sparlin, M. M. Nasrallah

Materials Science and Engineering Faculty Research & Creative Works

The electrical transport behavior and defect structure of Ca-doped YCrO3 were studied using electrical conductivity and Seebeck coefficient measurements as a function of oxygen activity and temperature. Defect models derived from the electrical conductivity data were found to adequately relate the concentration of charge carriers to the acceptor dopant and oxygen vacancy concentrations. Thermodynamic properties were calculated and found to be consistent with the model. Activation energy and carrier mobility data were also obtained. The analysis of the electrical conductivity, Seebeck and mobility data suggest that the conduction process in Ca-doped YCrO3 occurs via the small polaron hopping …

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Effects Of Sample Orientation On The Corrosion Of Zinc In Ammonium Sulfate And Sodium Hydroxide Solutions, D. Abayarathna, Edward Boyd Hale, Thomas J. O'Keefe, Y. M. Wang, D. Radovic Jan 1991

Effects Of Sample Orientation On The Corrosion Of Zinc In Ammonium Sulfate And Sodium Hydroxide Solutions, D. Abayarathna, Edward Boyd Hale, Thomas J. O'Keefe, Y. M. Wang, D. Radovic

Physics Faculty Research & Creative Works

The corrosion and electrochemical properties of three zinc single crystal surfaces with different orientations have been investigated. In near-neutral 1 M (NH4)2SO4, the corrosion rates on all three surfaces were found to be similar. However, the SEM morphologies of the corresponding corroded surfaces were markedly different from each other, but consistent with preferential attack of {1120} surfaces. In alkaline 0.5 N NaOH solution, the three sample orientations showed significantly different reactivities, with the (1120) surface exhibiting the highest reactivity and corrosion rate. Here, passivation ultimately occurred and the difference in the corrosion performance of …

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Fluorescent Lifetime Measurements Of Rare Earth Elements In Gallium Arsenide, Danny J. Topp Dec 1990

Fluorescent Lifetime Measurements Of Rare Earth Elements In Gallium Arsenide, Danny J. Topp

Theses and Dissertations

Lifetime measurements of the excited states of three GaAs semiconductors doped with the rare earth elements Erbium (ER), Praseodymium (Pr) , and Thulium (Tm) has been studied using a pulsed nitrogen laser and germanium detector. The measurements were made with an experimental set up with a system response time of 0.34 micro seconds. A 330 milliwatt nitrogen laser with a wavelength of 3370 angstrums was used to excite transitions of the rare earth elements.

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Characterization Of Barium Titanate As An Optical Amplifier, George A. Vogel Dec 1990

Characterization Of Barium Titanate As An Optical Amplifier, George A. Vogel

Theses and Dissertations

The introduction of two-beam coupling in photorefractive materials has resulted in an extensive amount of research into their use as optical processing/computing elements. This dissertation develops the theoretical equations for two-beam coupling in barium titanate as an optical amplifier. One of the factors which limits the optical gain in photorefractive crystals is the loss of pump beam power to the amplification of parasitic light (beam fanning). This parasitic light is produced by light scattered from the pump beam by imperfections on both the crystal face and within the crystal. Through the analysis of signal and noise amplification as functions of …

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32nd Rocky Mountain Conference Jul 1990

32nd Rocky Mountain Conference

Rocky Mountain Conference on Magnetic Resonance

Program and registration information for the 32nd annual meeting of the Rocky Mountain Conference, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, July 29 - August 3, 1990.

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Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3: Defect Structure, Electrical Conductivity, And Thermoelectric Power, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin Jan 1990

Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3: Defect Structure, Electrical Conductivity, And Thermoelectric Power, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Seebeck coefficient and electrical conductivity measurements were performed for undoped and Sr-doped LaMnO3 as a function of temperature and oxygen partial pressure. The results of electrical conductivity showed typical p-type behavior. As reduction proceeded, the electrical conductivity of these LaMnO3-based perovskites decreased with P 1 4O2. The analysis of the electrical conductivity data was performed by extending the defect model from a previous thermogravimetric (TG) study. The measured Seebeck coefficients were found to be positive except for the most reducing conditions when the decomposition into multiple phases occurred. The Heikes formula was adopted to interpret …

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Influence Of Copper Doping On The Performance Of Optically Controlled Gaas Switches, St. T. Ko, V. K. Lakdawala, K. H. Schoenbach, M. S. Mazzola Jan 1990

Influence Of Copper Doping On The Performance Of Optically Controlled Gaas Switches, St. T. Ko, V. K. Lakdawala, K. H. Schoenbach, M. S. Mazzola

Electrical & Computer Engineering Faculty Publications

The influence of the copper concentration in silicon-doped gallium arsenide on the photoionization and photoquenching of charge carriers was studied both experimentally and theoretically. The studies indicate that the compensation ratio (NCu/NSi) is an important parameter for the GaAs:Si:Cu switch systems with regard to the turn-on and turn-off performance. The optimum copper concentration for the use of GaAs:Si:Cu as an optically controlled closing and opening switch is determined.

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31st Rocky Mountain Conference Jul 1989

31st Rocky Mountain Conference

Rocky Mountain Conference on Magnetic Resonance

Program and registration information for the 31st annual meeting of the Rocky Mountain Conference, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, July 30 - August 4, 1989.

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Characterization Of Zirconia Gels And Their Selectivity Towards Metal Ions, Manal Mohamed Talaat El- Saidi Jun 1989

Characterization Of Zirconia Gels And Their Selectivity Towards Metal Ions, Manal Mohamed Talaat El- Saidi

Archived Theses and Dissertations

No abstract provided.

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High-Temperature Defect Structure Of Nb-Doped Lacro3, Chikung J. Yu, Harlan U. Anderson, Don M. Sparlin Jan 1989

High-Temperature Defect Structure Of Nb-Doped Lacro3, Chikung J. Yu, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Electrical conductivity and Seebeck measurements on LaCr0.98Nb0.02CrO3 show that the defect structure of the material is mainly controlled by the extrinsic electrons formed by the Nb donors through the electronic compensation process. The experimental results also indicate that this material conducts electricity via a small polaron mechanism with an electron mobility around 0.004-0.01 cm2/V sec between 1100 and 1300°C. © 1989.

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Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3 Nonstoichiometry And Defect Structure, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin Jan 1989

Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3 Nonstoichiometry And Defect Structure, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Undoped and Sr-doped LaMnO3 showed reversible oxidation-reduction behavior. These perovskites can be excess, stoichiometric or deficient in oxygen content depending on the specific conditions. Under very reducing conditions decomposition into new phases occurs. Phase stabilities for these oxides were determined. The results showed that Sr doping caused the LaMnO3 to dissociate at higher oxygen activities than those necessary for undoped LaMnO3. Defect models are proposed to interpret the thermogravimetric results in which metal vacancies are assumed for the oxygen excess condition and oxygen vacancies are assumed for the oxygen deficient condition. Thermodynamic properties were calculated which …

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Gaas Photoconductive Closing Switches With High Dark Resistance And Microsecond Conductivity Decay, M. S. Mazzola, K. H. Schoenbach, V. K. Lakdawala, R. Germer, G. M. Loubriel, F. J. Zutavern Jan 1989

Gaas Photoconductive Closing Switches With High Dark Resistance And Microsecond Conductivity Decay, M. S. Mazzola, K. H. Schoenbach, V. K. Lakdawala, R. Germer, G. M. Loubriel, F. J. Zutavern

Electrical & Computer Engineering Faculty Publications

Silicon-doped n-type gallium arsenide crystals, compensated with diffused copper, were studied with respect to their application as photoconductive, high-power closing switches. The attractive features of GaAs:Cu switches are their high dark resistivity, their efficient activation with Nd:YAG laser radiation, and their microsecond conductivity decay time constant. In the authors' experiment, electric fields are high as 19 kV/cm were switched, and current densities of up to 10 kA/cm2 were conducted through a closely compensated crystal. At field strengths greater than approximately 10 kV/cm, a voltage `lock-on' effect was observed.

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Nanosecond Optical Quenching Of Photoconductivity In A Bulk Gaas Switch, M. S. Mazzola, K. H. Schoenbach, V. K. Lakdawala, S. T. Ko Jan 1989

Nanosecond Optical Quenching Of Photoconductivity In A Bulk Gaas Switch, M. S. Mazzola, K. H. Schoenbach, V. K. Lakdawala, S. T. Ko

Electrical & Computer Engineering Faculty Publications

Persistent photoconductivity in copper-compensated, silicon-doped semi-insulating gallium arsenide with a time constant as large as 30 µs has been excited by sub-band-gap laser radiation of photon energy greater than 1 eV. This photoconductivity has been quenched on a nanosecond time scale by laser radiation of photon energy less than 1 eV. The proven ability to turn the switch conductance on and off on command, and to scale the switch to high power could make this semiconductor material the basis of an optically controlled pulsed-power closing and opening switch.

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30th Rocky Mountain Conference Jul 1988

30th Rocky Mountain Conference

Rocky Mountain Conference on Magnetic Resonance

Program and abstracts from the 30th annual meeting of the Rocky Mountain Conference, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, July 31 - August 5, 1988.

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Reactions Of Diketones With Phosphorous Ylides, Amal Mohamed Lakany Jul 1988

Reactions Of Diketones With Phosphorous Ylides, Amal Mohamed Lakany

Archived Theses and Dissertations

No abstract provided.

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The Relationship Of Pore Volume And Pore Size Distribution To The Development Of Gloss And Scattering Coefficient, John A. Cook Jun 1988

The Relationship Of Pore Volume And Pore Size Distribution To The Development Of Gloss And Scattering Coefficient, John A. Cook

Masters Theses

This study describes in a quantitative manner the relationships between coating structure and optical properties. Gloss, scattering coefficient and void volume were measured after applying different blends of polystyrene spheres to mylar film. Each coating was modeled using large spherical particles of the same size ratios to measure pore size distribution. The coating structure followed well with theoretical packing characteristics of spheres. Optical properties were related to changes in coating structure. Scattering coefficient and gloss correlated better with pore size distribution than particle size. Gloss increased when total void volume was reduced, while the scattering coefficient decreased.

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