Materials Science and Engineering Commons^™

Electrochemical Study Of Zn-Fe Alloy Coatings On Mild Steel For Automotive Applications, Ramesh Bhat, A. Chitharanjan Hegde

Journal of Metals, Materials and Minerals

This study investigates the electrochemical behavior of Zn-Fe alloy deposited on mild steel (MS) substrates for automotive applications. The electrodeposition of a Zn-Fe alloy onto MS using an acid chloride bath, with 1,2,4-Triazole as an additive to enhance the uniformity of the deposit. The hull cell method was used to optimize the bath composition and operating conditions. The coatings were produced using electrodeposition at varying current densities, with 3 A∙dm‒2 identified as the optimal current density (CD) for achieving uniform coatings. The microstructural properties, including crystallite size and micro-strain, were analyzed using X-ray diffraction (XRD) and Williamson-Hall (W-H) analysis, revealing …

Influence Of The Casting Processes And Aging Times On The Microstructure And Hardness Of Alsi12 Cu Cast Alloys, Said Beroual, Pascal Paillard, Yann Borjon-Piron

Journal of Metals, Materials and Minerals

The present study investigated the effects of the casting processes and aging times on the micro-structure and hardness of commercial AlSi12Cu alloys. The primary goal was to assess how various aging times affect the maximum hardness of the alloy and to evaluate the influence of cooling rates on hardness values obtained from sand casting (SC) and High-pressure die casting (HPDC). For both casting alloys, the solution heat treatment was performed at 540℃, followed by quenching. The alloys were then aged at 180℃ for various durations, ranging from 10 min to 50 h. The results reveal significant microstructural changes in the …

Photocatalytic Behaviour Of (Biybo3)0.5-(Batio3)0.5, Yasaswi Priyadarshini Samal, Subhalaxmi Patra, Tapan Das, Minakshi Padhy

Journal of Metals, Materials and Minerals

Different organic compounds like dyes and pharmaceutical contaminants pollute a large amount of water which can increase the chemical oxygen demand in water bodies. The photodegradation of dyes has been widely studied using TiO2-based nanomaterials, which are typical photocatalysts. TiO2 is highly effective in reducing pollutants when exposed to UV light and does not cause secondary pollution. However, TiO2 is only functional when exposed to UV light, which is not ideal for real-world use. This drawback of TiO2 pulls the research towards modified photocatalysts for better yield. In this study, the (BiYbO3)0.5 - (BaTiO3)0.5 material was formulated by solid state …

Synergistic Effects Of Co-Ni Nanoalloys On Sio2@Tio2: A Novel Approach To Photocatalytic Tetracycline Degradation, Pratyush Kumar Sahu, Alaka Rath, Aslisha Champati, Ashish Madual, Pravat Manjari Mishra, Abanti Pradhan, Brundabana Naik

Journal of Metals, Materials and Minerals

To develop a cost-effective alternative to noble metal catalysts for photocatalysis, we synthesized a series of bimetallic Co-Ni nanoalloys on core-shelled SiO2@TiO2 nanostructures via a chemical reduction approach. The research demonstrates the photocatalytic behaviour of the Co-Ni alloy-enhanced SiO2@TiO2 (ST-Co, Ni) hybrid nanocatalyst, focusing on its crystalline structures, morphological shapes, chemical conditions, and optical properties, utilizing techniques such as X-ray diffraction, field emission scanning electron microscopy, UV-visible diffuse reflectance spectroscopy, photoluminescence spectroscopy, transmission electron microscope, and electrochemical analysis. The catalyst was evaluated for its effectiveness in degrading tetracycline, an overused antibiotic that persists in aquatic environments and is known for …

Studies Of Structural, Microstructural, Dielectric, And Electrical Characterization Of Binaznmoo6 Double Perovskite, Swati Panda, Supriya Barik, Ritu Purna Sahu, Adwit Prasad Sahu, S. Mishra, S. K. Parida

Journal of Metals, Materials and Minerals

This study investigates the structural, microstructural, dielectric, and electrical properties of BiNaZnMoO₆ (BNZM) ceramic synthesized using a conventional solid-state reaction method. Preliminary structural analysis using X-ray diffraction (XRD) suggests orthorhombic crystal symmetry. Scanning electron microscopy (SEM) micrographs reveal a uniform distribution of well-grown grains with well-defined grain boundaries, which may contribute to the enhanced dielectric properties. Energy dispersive X-ray spectroscopy (EDX) analysis confirms the presence of all constituent elements Bi, Na, Zn, Mo, and O in the studied sample. Dielectric spectra analysis as a function of frequency and temperature indicates the formation of high-quality dielectric materials, evidenced by a high …

Graphitic Carbon Nitride Loaded Bi4o5i2 For Elevated Photocatalytic Tetracycline Degradation, Subhasish Mishra, Barsha Marandi, Kali Sanjay, Rashmi Acharya

Journal of Metals, Materials and Minerals

As a robust photocatalyst, Bi4O5I2 have has attracted significant scientific interest owing to its narrow bandgap energy, escalated electronic properties and high stability. Nonetheless, the unfavourable band structure and higher recombination of excitons have restricted its diversified photocatalytic applications. In this context, binary heterojunction construction using Bi4O5I2 could be considered an effective strategy for spatial charge carrier separation across the hetero-interface, leading to an enhanced activity. In this study, we have prepared Bi4O5I2/g-C3N4 Z-scheme hetero-structures via a wet impregnation strategy that preserves the spherical structure of Bi4O5I2. The phase purity, chemical bonding, morphology and microstructure of the composite were confirmed …

Photodegradation Of Malachite Green Using 2d G-C3n5 Nanosheet: A Promising Metal Free Catalyst, Sonali Biswal, Swayam Aryam Behera, Asima Subhadarshini, P. Ganga Raju Achary, Binita Nanda

Journal of Metals, Materials and Minerals

Environmental issues have become more serious these days due to the growth of modern industries. The paper and textile industries, in particular, were heavily dependent on the printing and discharge of dye, which constantly leaked into the water ecology and constituted a serious risk to public health. Organic wastewater treatment and remediation for its associated risks have received a lot of attention lately. This work explored the potential of the g-C3N5 nanostructure as a novel photocatalyst for malachite green degradation in aqueous solution while exposed to visible light. The nanocomposite was fabricated through an ultrasonicate-assisted technique. A number of analysis …

Antibacterial, Self-Adhesive Guar Gum/Polyvinyl Alcohol/Tannic Acid Conductive Hydrogels For Flexible Strain Sensors, Noppanan Putdon, Somnuk Theerakulpistut, Rawit Jittham, Pornnapa Kasemsiri

Journal of Metals, Materials and Minerals

In this research, a multifunctional strain sensor with antibacterial properties and self-adhesion capabilities was developed using guar gum (GG), polyvinyl alcohol (PVA), and tannic acid (TA). The incorporation of TA into GG-PVA hydrogel-based strain sensors was investigated to evaluate its effects on mechanical and electrical properties, self-adhesion, and antibacterial activities. The anti-bacterial activities against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) were enhanced with the increasing content of TA. The adhesive strength was observed in the range of 1.20 ± 0.10 kPa to 5.05 ± 0.23 kPa, and the values tended to increase as TA content increased. The …

Mechanochemical Synthesis Of Ni(Ii)-Tptz Complexes With Co-Ligands: Spectroscopy, Dft, And Biological Studies, Deepak Senapati, Anulipsa Priyadarshini, Debadutta Samal, P. Ramesh Babu, Satyanarayan Sahoo, Narayan Chandra Bera, Raghabendra Samantaray, Jagannath Panda, Rojalin Sahu

Journal of Metals, Materials and Minerals

New mixed-ligand Ni(II) complexes [Ni(tptz)(1,10-phen)] (1), [Ni(tptz)(2-Mimd)2] (2), and [Ni(tptz)Imd)2] (3) were synthesized via a green, solvent-free mechanochemical approach using ball milling. The primary ligand used was 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tptz), with secondary ligands being 1,10-phenanthroline, 2-methyl imidazole, and imidazole, respectively. Structural characterization by IR, UV-Visible, photoluminescence spectroscopy, and powder X-ray diffraction, supported by DFT calculations, revealed a distorted square planar geometry for complex 1 and distorted tetrahedral geometries for complex-2 and complex-3. Notably, bathochromic shifts in the UV-Vis spectra confirm metal-ligand charge transfer transitions and extended π-delocalization. Powder XRD analysis determined average crystallite sizes of 17.86 nm (1), 25 nm (2), …

Regulating Copx/Co Heterostructures For Enhanced Electrocatalytic Activity Toward Hydrazine Oxidation Reaction, Qinquan Lin, Rui Zhang, Changli Yan, Qizhao Hu, Shangbin Sang, Qiumei Wu, Kaiyu Liu, Hongtao Liu

Journal of Metals, Materials and Minerals

Hydrazine hydrate (N2H4∙H2O) is considered an ideal fuel for fuel cells. Constructing a cobalt phosphide/cobalt (CoPx/Co) heterostructure can achieve efficient electrocatalytic activity for hydrazine oxidation reaction. Traditional strategies for constructing CoPx/Co heterostructures took less consideration on the exposure of the active sites. In this study, 3D nanoflower-like nano CoPx/Co heterostructures with highly exposed active sites were obtained on a nickel foam (NF) through a dual-component phosphating strategy, i.e., regulating the relative content of Co and Co(OH)2 with cathodic current density and utilizing the differences in their phosphating behaviors. The potential at 100 mA∙cm‒2 and Tafel slope of the optimized CoPx/Co(375)@NF …

Oxidation Of Sn-1 Wt.% Bi In Air And In Oxygen Deprived Environment, Pakawat Polmanee, Benjie Fernandez, Patama Visuttipitukul, Ittipon Cheowanish, Tachai Luangvaranunt

Journal of Metals, Materials and Minerals

Oxidation of Sn-1wt% Bi in air and in oxygen deprived environment is studied in this research. Electrochemical process with SERA technique was used to determine oxide film thickness and rate of oxidation of tin alloy. The thickness of oxide film at 72 hours of the specimens that is tested in air, in vacuum, in argon environment, and wrapped with plastic film are 16, 10, 18, and 13 Å respectively. XPS was used to determine the type of oxides in the oxide layer. Result after signals deconvolution shows that SnO and SnO2 compounds were formed on the Sn-1wt% Bi surface.

Solar Radiation Assisted Photocatalytic Degradation Of Congo Red Using Ce Doped Lacoo3, Rishabh Kamal, Rasmirekha Pattanaik, Debapriya Pradhan, Suresh Kumar Dash

Journal of Metals, Materials and Minerals

A viable sol-gel synthesis technique was used to synthesize LaCoO3 and Ce doped LaCoO3 for degradation of congo red dye taking a renewable source of light i.e solar radiation. The crystalline structure, morphology, and optical properties of the synthesized catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) analysis of Ce-doped LaCoO₃ confirmed the presence of La (3d), Ce (3d), Co (2p), C (1s), and O (1s) and their valence states in the perovskite matrix, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and ultraviolet diffuse reflectance spectroscopy (UV-DRS). The XRD analysis with a prominent diffraction peak detected …

Facile Synthesis Of Bamno3-Zro2 Composite: A Step Towards The Photocatalytic Degradation Of Organic Dye, Kirttimayee Mohanta, Swayam Aryam Behera, Binita Nanda, P. Ganga Raju Achary

Journal of Metals, Materials and Minerals

Environmental contamination by synthetic dyes, particularly Methylene Blue (MB), presents a significant threat to aquatic ecosystems and human health due to their chemical stability and toxicity. This study investigates the photocatalytic degradation of MB using a BaMnO3:ZrO2 composite synthesized in a 1:2 ratio via a straightforward wet-chemical method. Structural and optical characterizations were performed using X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and Ultraviolet-visible diffuse reflectance spectroscopy (UV-DRS). The composite exhibited a reduced bandgap of 2.88 eV and uniform nanoscale morphology, both favorable for visible-light-driven photocatalysis. Under visible-light irradiation, the catalyst achieved 89% degradation efficiency within …

Optimization And Characterization Of Carrageenan/Alginate Ratio And Seaweed Waste To Develop Composite Bioplastics From Kappaphycus Alvarezii, Ali Ridlo, Retno Hartati, Agus Sabdono

Journal of Metals, Materials and Minerals

Carrageenan and alginate, derived from seaweed, offer potential as alternatives to traditional plastics. This study aims to assess the properties of biodegradable bioplastics made from a composite of carrageenan, alginate, and waste from K. alvarezii seaweed carrageenan extraction. A mixture of carrageenan and alginate was added with a ratio of 4:6 and K. alvarezii extraction waste 0, 20, 40, 60, and 80 % waste concentration,  in the carrageenan-alginate-waste mixture. The process involves blending carrageenan, alginate, waste, glycerol, and distilled water until uniform at 90o C and 1000 rpm for 45 minutes, followed by molding, immersion in a 4% CaCl2 solution, …

Liquid-Liquid Extraction Of Nd(Iii) Using [P66614][Cy272] Ionic Liquid, Prasanjit Das, Kali Sanjay, Niharbala Devi

Journal of Metals, Materials and Minerals

This study explores the extraction of Nd(III) from synthetic solutions using the ionic liquid [P66614] [Cy272]. Key extraction parameters, including the effect of phase contact time, initial pH, salting-out agents, extractant concentration, and temperature, were systematically optimized. Results revealed that a phase contact time of 15 min, an initial pH of 2.14, and 0.2 mol∙L‒1 NaCl as a salting-out agent and extractant concentration of 0.015 mol∙L‒1 [P66614][Cy272], achieved maximum extraction efficiency of 99.7%. Thermodynamic analysis confirmed the process is to be exothermic, spontaneous, and entropy-driven, highlighting the strong complexation between Nd(III) and the ionic liquid [P66614][Cy272]. Stripping tests revealed that …

Green-Synthesized Yttrium-Doped Cerium Oxide Nanoparticles: A Promising Optical Material, Sasmita Sarangi, Nibedita Nayak, Binita Nanda, Tapas Sahoo

Journal of Metals, Materials and Minerals

This work focuses on the green synthesis, characterization, and optical properties of yttrium-doped cerium dioxide (CeO2) nanoparticles. A green approach was adopted using Acacia concinna fruit extract as surfactant and stabilizing agent. Their structural, morphological, and physical-chemical properties were characterized using different analytical techniques, like XRD, FE-SEM, FTIR, PL, Raman, UV-Visible Spectroscopy. XRD study validated the structure of cubic fluorite-type structure of CeO2 nanoparticles, with the average crystallite size ranging between 7-15 nm. Raman spectroscopy validated this structure with F2g band observed at 463 cm−1. FESEM images showed irregular spherical morphologies with grain sizes in the range of 50-60 nm. …

Pyrolysis And Modification Of Coconut Shell Into Sulfonated Biochar And Its Catalytic Activity On Cellobiose Conversion, Addy Rachmat, Yessi Eka Wahyu, Poedji Loekitowati Hariani, Fahma Riyanti, Fatma Fatma

Journal of Metals, Materials and Minerals

Coconut shell was successfully valorized into sulfonated biochar through carbonization in various temperatures and duration. This work aims to provide suitable solid acid carbonaceous catalyst for cellobiose conversion into valuable product. Sulfonated biochar is characterized to evaluate its crystallinity, sulfonate, and oxygenated functional groups by XRD method and FTIR spectroscopy. The resulting solid acid carbonaceous material was tested toward cellobiose hydrolysis to assess its catalytic activity in various time, temperature, and catalyst weight. FTIR spectra reveals some of the biochar product has sulfonate group as indicated by absorbance band at 1234 cm‒1, 1070 cm‒1 and 1180 cm‒1, which belongs to …

The Effects Of Graphene Nanoplatelets And Microcrystalline Cellulose On The Mechanical Properties Of Fiberglass And Carbon Fiber Composites, Duangjai Srisamut, Nathawat Poopakdee, Warut Thammawichai

Journal of Metals, Materials and Minerals

This study investigated how graphene nanoplatelets (GNP) and microcrystalline cellulose (MCC) affect the mechanical properties of epoxy (EP), carbon fiber (CF), and fiberglass (FG) composites. The tensile and flexural properties of GNP-EP and MCC-EP of  varying reinforcement concentrations were examined. Results indicated significant improvements on tensile and flexural properties by GNP and MCC. At 0.1 wt% GNP, tensile and flexural strengths increased by 10% and 21%, while 2.0 wt% improved flexural modulus by 65%. Similarly, 2.0 wt% MCC improved tensile strength, modulus, and flexural modulus by 11%, 11%, and 46%, respectively, and a 26% increase in flexural strength at 1.0 …

Machine Learning Modeling For Hydrolysis Recycling Of Pet Waste, Jie Li, Lanjia Pan, Hossein Abedsoltan, Hailong Wang, Taiyang Liu, Xiangzhou Yuan, Yong Sik Ok, Yin Wang

Chemical and Biochemical Engineering Faculty Research & Creative Works

The hydrolysis of polyethylene terephthalate (PET) into terephthalic acid (TPA) can efficiently recycle waste PET, but achieving high conversion efficiency through smart reaction design remains challenging. To develop a robust and accurate machine learning (ML) model for the in-depth understanding and intelligent design of PET hydrolysis, we compiled a new dataset comprising 942 data points and comprehensive information of 44 variables involved in heating type, acid/base catalyst (ABC), organic solvent (OS), co-solvent (CS), phase transfer catalyst (PTC), and operational conditions. The developed Neural Network model demonstrated the best performance in predicting PET conversion, with a testing determination coefficient (R^{2 …}

Effects Of Soil Properties On Cp Performance, Cecilia Segretario

Williams Honors College, Honors Research Projects

This research aims to evaluate the affect of various soil properties on the effectiveness of cathodic protection (CP) in preventing underground pipeline corrosion. Metal coupons of common pipeline materials with applied CP will be mounted in several separate controlled soil environments to manipulate real world underground corrosion scenarios. Each soil environment will have different physical properties by mixing the soil with a prepared chemical solution. The physical properties to be evaluated include pH, resistivity, and moisture content. At the end of a corrosion duration, weight loss method will be used to evaluate the corrosion rate over that period. Additionally, the …

Design And Development Of A Rapid Tensile Quench Rig, Tyler Jewell, Justin Naylor

Williams Honors College, Honors Research Projects

This report outlines the design process and implantation of a tensile quenching rig that incorporated forced convection and a frequency generator. When any metal is quenched, a vapor barrier forms around it. When this happens, it limits the heat flux that may occur until the barrier turns into just nucleate boiling. The vapor barrier acts as an insulator and causes the heat flux to fluctuate, causing uneven hardening which would limit the use of some materials. To combat this effect, we are trying to use forced convection, and something new, which is adding high frequency waves into the quenching process. …

Reuse Of Calcium Carbonate (Caco3) Recovered From Discarded Carpets As Filler In Fiber-Reinforced Polymer (Frp) Composites, Roshan Devkota

Graduate Theses, Dissertations, and Problem Reports (ETD)

Over four billion pounds of carpet are discarded annually in the United States, making carpet waste a significant environmental concern. Calcium carbonate (CaCo₃) constitutes up to 45% of the mass of most synthetic carpets. Reusing this CaCo₃ as a filler in the rapidly growing fiber-reinforced polymer (FRP) industry, which is projected to reach USD 10.38 billion, presents a low-cost, practical approach to developing a market-based solution to post-consumer carpet waste.

This study investigates the reuse of CaCo₃ recovered from discarded carpet backing as a filler in FRP composites, focusing on its mechanical viability in comparison to virgin CaCo₃. The methodology …

Pulsed Arc Additive Manufacturing Of A Functionally Graded Er2209 Duplex Stainless Steel And Hsla-100 Structure: Morphology, Characterization, And Mechanical Performance, Stevens G. Hill Jr

College of Graduate Studies: Theses & Dissertations

Wire arc additive manufacturing is a process well suited to the efficient production of large structures. Duplex stainless steel exhibits high corrosion resistance and good strength which can be highly beneficial for industrial use. However, its use is limited due to its cost and complexity in controlling microstructure to achieve desired properties. In many cases, it can be highly beneficial to manufacture a component which uses specialty steel grades such as duplex stainless steel only where necessary, and utilizes more affordable, commonly available steels for reinforcement or bulk structural support. A functionally graded material satisfies these requirements by providing a …

Dendrite-Free Strategies For Aqueous Zinc-Ion Batteries: Structure, Electrolyte, And Separator, Gang Wu, Wu-Hai Yang, Yang Yang, Hui-Jun Yang

Journal of Electrochemistry

Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently. The development and utilization of renewable, sustainable, and clean energy sources, such as wind and solar, are crucial. However, the instability of these intermittent energy sources makes the need for energy storage systems increasingly urgent. Aqueous zinc-ion batteries (AZIBs) have received widespread attention due to their unique advantages, such as high energy density, cost-effectiveness, environmental friendliness, and safety. However, AZIBs face significant challenges, mainly the formation of zinc dendrites that seriously affect the stability and lifetime of the batteries, leading to battery …

Electrochemical-Method-Induced Strong Metal-Support Interaction In Pt-Cnt@Sno2 For Co-Tolerant Hydrogen Oxidation Reaction, Shen-Zhou Li, Zi-Jie Lin, Qi-An Chen, Zhao Cai, Qing Li

Journal of Electrochemistry

Inducing the classic strong metal-support interaction (SMSI) is an effective approach to enhance the performance of supported metal catalysts by encapsulating the metal nanoparticles (NPs) with supports. Conventional thermal reduction method for inducing SMSI processes is often accompanied by undesirable structural evolution of metal NPs. In this study, a mild electrochemical method has been developed as a new approach to induce SMSI, using the cable structured core@shell CNT@SnO₂ loaded Pt NPs as a proof of concept. The induced SnO_x encapsulation layer on the surface of Pt NPs can protect Pt NPs from the poisoned of CO impurity in …

Contributions To Journal Of Electrochemistry, The Flagship Journal Of Chinese Chemical Society Electrochemical Committee, Will Be Listed As A New Recommendation Policy For China Youth Awards Of Electrochemist, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

All-Solid-State Sodium-Ion Batteries: A Leading Contender In The Next-Generation Battery Race, Rui-Jie Zhu, Ze-Chen Li, Wei Zhang, Akira Nasu, Hiroaki Kobayashi, Masaki Matsui

Journal of Electrochemistry

All-solid-state lithium-ion batteries (LIBs) using ceramic electrolytes are considered the ideal form of rechargeable batteries due to their high energy density and safety. However, in the pursuit of all-solid-state LIBs, the issue of lithium resource availability is selectively overlooked. Considering that the amount of lithium required for all-solid-state LIBs is not sustainable with current lithium resources, another system that also offers the dual advantages of high energy density and safety— all-solid-state sodium-ion batteries (SIBs) —holds significant sustainable advantages and is likely to be the strong contender in the competition for developing next-generation high-energy-density batteries. This article briefly introduces the research …

Striking A Balance: Market Shock & Responses In Automotive Components Manufacturing, Emma Lane Mcgahey

All Theses

This thesis examines the effects of extreme market shocks on supply chain dynamics within the automotive industry. Through an analysis of demand data from an automotive manufacturer to its component suppliers (January 2018 to May 2024), the study investigates the relationship between market shocks and supply chain responses, providing insights into how auto components inventory management handles downstream responses to market shocks. With supporting public data—from FRED, BLS, and the U.S. Census Bureau resources—we explore two primary relationships: the impact of market shocks on the Average Standard Deviation of Demand (SDO) and the effect of demand variability on expedited pricing …

Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This paper presents the results of thermal conductivity characterization of six high oleic soybean oil (HOSO) and four high oleic canola oil (HOCO)-based hybrid nanofluids formulated with four types of nanoparticles (Graphene nanoplatelet (xGnP), TiO2, MoS2, and Al2O3) at nanoparticles wt.% concentration from 1 % to 7 % in 1 % increment using the two-step method for use in MQL machining of difficult-to-cut metals. Thermal conductivity of the formulated hybrid nanofluids were measured using Thermtest Transient Hot Wire Liquid Thermal Conductivity Meter at temperatures from 25 °C to 75 °C in increment of 10 °C. Obtained results showed that thermal …

Removal Capabilities Of Zeolite And Zero Valent Iron With High-Level Waste Tank Radionuclides And Metals: Cesium, Strontium And Chromium, Colette R. Towles

UNLV Theses, Dissertations, Professional Papers, and Capstones

High level nuclear waste (HLW) has been disposed for temporary storage in underground steel tanks at the Department of Energy Nuclear sites. For example, at the Hanford Site, WA, and Savannah River Site (SRS), SC, HLW account for eighty-eight million gallons (Mgal) and 450 million Curies (MCi) of radioactivity. In the early nuclear activity at Hanford, the waste was discharged to single-shell steel tanks, and the lack of secondary containment allowed leaks, contaminating soil and groundwater. Despite tremendous efforts to stabilize the liquid waste at nuclear sites, treatment is complex, costly, and time-consuming; therefore, HLW may have to be stored …