Materials Science and Engineering Commons^™

Electroreduction Of The Nittobenzene On Titanium Electrode Implanted With Palladium, Zhongda Wu, Xianjun Zhu, Hongsen Wang

Journal of Electrochemistry

The titanium substrates were bombarded with 1×10¹⁷～5×10¹⁷ ions·cm^-2 ofpalladium at the room temperature. The surface composition of implanted electrode and concentration-depth profiles of various elements were measured by AES. The electrored uction processes ofnitrobenzene (NB) in 0.1 mol/L NaOH solution at Pd/Ti electrodes have been investigated by cyclicvoltaivimetry. The results show that the palladium implanted titanium electrodes exhibit a high catalyticactivity in the electroreduction of NB. The NB radical anion, which is the product of one-electronelectroreduction of NB, was detected by ESR in-situ in conjunction with electrochemical methods. Aniline was also detected as a product of …

Electroreduction Of Holmium Ion On Iron Electrde In Molten Cholorides, Qiqin Yang, Guankun Liu, Yuzhi Su

Journal of Electrochemistry

The cyclic voltammetry, open circuit potential-time curve after poteritiostatic electrolysis, current-time curve at potential step, X-ray diffraction and electron probe microanalysiswere used to investigate the electrode process of Ho(Ⅲ) reduced on iron electrode in molten chloridesand the phases of surface alloy layer. The Ho-Fe alloys are formed at first, and then the metallic holmium is deposited when Ho(Ⅲ) is reduced on iron electrode. The charge transfer is reversible. The free energies of formation for the four inter metallic compounds of Ho-Fe system, the diffusion coefficients and diffusion activation energy of Ho in alloyed cathode are determined.

Electrocatalytic Oxidation Of Formaidehyde And Formic Acid On A Pt/SbAd Electrode, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic activity for the oxidation of formaldehyde and formic acid ona Sb-modified platinum (Pt/Sb_ad) was investigated. Results showed that the Pt/Sb_ad electrode was electrocatalytically more active than a Pt electrode in the anodic oxidation of formaldehyde and formicacid. In the case of formaldehyde, an oxidation peak appeared at a potential of ca. 0.7V. During the oxidation of formic acid, a 4-fold increase in the 1st peak current was observed. The Sb-modified platinum electrode was found to be most electrocatalytically active at a coverage of 0.75±0.05. The electrocatalytic activity of the Pt/Sb_ad electrode can be best …

Synthesis Of LiXCoo2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye

Journal of Electrochemistry

The Variations of crystal lattice parameters of Li_xCoO₂ during charge anddischarge have been st ud ied by XRD and AAR spectroscopy. It was found that the Li_xCoO₂ crystalvolume expanded during charge and contracted during discharge. The crystal lattice structure was broken because of the formation of Co₃O₄ when deeply charge.The variation of lattice parameter C₀ value in cycling process was similar to that in charge process.The variation of 006 peak was the mostsensitive in every case. In case of preheating for 20 hours at 700℃ before operating high temperature, the …

Application Of Inhibitor To Improve The Anticorrosion Performance Of Electrophoretic Coating, Changshou Cai, Fangteng Su, Bihuan Liu, Guomou Wen, Jingdong Guo, Renxin Liu, Weidong Tian

Journal of Electrochemistry

To improve the anti-corrosion performance of electrocoating, organic andinorganic inhibitors are applied in an anodic electrophoretic-coating. The results show that the deposition of polymer with zinc phospate exhibits a high inbihition efficiency. The inhibition mechanism of the inhibitor in electrocoating has been studied.

The Electrode Process Of Y(Ⅲ) On Copper Electrode And Its Surface Metallizing, Chungen Zhou, Shuzhen Duan

Journal of Electrochemistry

The reduction of yttrium ion on copper electrode in NaCl-KCl-YCl₃ molten saltshas been investigated. The results indicate that the formation of intermetallic compounds is occuredbefore the metallic yttrium to be formed. The formation of intermetallic compounds is controlled bythe process of which yttrium atoms are diffusing into copper electrode. The kinetic characters todiffusion of yttrium atoms were also discussed.

A Investigation Of Hydrogen-Storage Alloy As Catalytic Electrode For Hydrogenation Of Nitrobenzene, Shigang Lu, Hanxi Yang, Changfa Wan

Journal of Electrochemistry

Since hydrogen-storage alloy ean not only absorb hydrogen atoms to form highlyreactive metal hydride as hydrogen source by electrolysis but also possesses a certain catalytic activityfor hydrogenation,it is thus feasible to utilize the allov as a novel electrode for electrolvtichydrogenation in organic electroreduction. This work employed misch metal AB₅ type alloy as acatalytic electrode and studied the electrochemical hydrogenation of nitrobenzene.

The hydrogen-storage electrode (MH) was a plastic bonded electrode sheet made from a paste of Mm(NiCoMnAl)₅ alloy powder and teflon emulsion. The electrolysis was performed at constantcurrent and controlled potential in a three electrode cell of H-type …

Development Of Nial-Based Intermetallic Alloys: Effect Of Chromium Addition, R. Tiwari, Surendra N. Tewari, R. Asthana, A. Garg

Chemical & Biomedical Engineering Faculty Publications

The mechanical behavior of dual-phase NiAl(Cr) microstructures, consisting of elongated primary NiAl grains aligned with an intergranular NiAl-Cr eutectic phase, produced by extrusion of a cast NiAl(Cr) alloy, has been examined. Chromium addition to create a dual phase NiAl-based aligned microstructure leads to large increases in the yield strength but no significant toughness improvement. This is achieved primarily by solid solution hardening and precipitation hardening. The constitutional hardening rate resulting from deviations from stoichiometry in the nickel-rich NiAl was estimated to be about 66 MPa per atomic per cent of nickel.

Nonlinear Finite Element Micromechanic Analysis Of Thermoplastic Composite Of Recycled High Density Polyethylene Reinforced With Short Glass Fibers, Qiming Lou

Masters Theses

This thesis studied the nonlinear micromechanic behavior of thermoplastic composite of recycled high density polyethylene (HDPE) reinforced with short glass fibers using finite element method. The composite material was modeled using a micromechanic unit cell to simulate the stress distribution between the plastic matrix and the fiber in the composite. Nonlinear behavior of recycled HDPE and imperfect bonding between the fiber and matrix were investigated. Load-bearing capability of the fiber was evaluated using stress partition ratio (SPR) in the composite models. The effect of fiber aspect ratio on the stress distribution of the composite was studied to optimize the material …

Investigation Into The Behavior Of Geometrically Nonlinear Composite Arches, John C. Bailey

Theses and Dissertations

This research modifies the existing finite element formulation of a potential energy based large deformation and moderate rotation theory. Hermitian shape functions replace the existing linear bending angle interpolations. Negligible differences between the two formulations indicate the underlying kinematics limit the accuracy, not the finite element interpolations. Using the new program, numerous nonlinear arch geometries are modeled to investigate the effects of arc length and thickness variations. Local and global snapping phenomena are captured as well as through the thickness shear driven nonlinearities.

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite Subjected To Tension-Tension Cycling With Hold Time, Scott A. Grant

Theses and Dissertations

This study was carried out to investigate the elevated temperature behavior of the SiC-MAS5 cross- ply [0-90]_4S ceramic matrix composite manufactured by Corning Inc. to fatigue with loading waveforms that combine the characteristics of stress rupture and high cycle fatigue. The test results were compiled in the form of S-N (cycles to failure), S-T (exposure time versus cycles to failure), S-S (energy exposure versus cycles to failure), normalized modulus degradation, strain progression, and hysteresis loop progression. From the mechanical behavior demonstrated by these curves, relationships between the effect of the environment and loading waveform were developed. In addition, a …

Characterization Of Fatigue Behavior Of 2-D Woven Fabric Reinforced Ceramic Matrix Composite At Elevated Temperature, Daniel J. Groner

Theses and Dissertations

This study investigated the fatigue behavior and associated damage mechanisms in notched and unnotched enhanced Sic-SiC ceramic matrix composite specimens at 1100°C. Stiffness degradation, strain variation, and hysteresis were evaluated to characterize material behavior. Microscopic examination was performed to characterize damage mechanisms. During high cycle-low stress fatigue tests, far less fiber-matrix interface debond was evident than in low cycle-high stress fatigue tests. Notched specimens exhibited minimal stress concentration during monotonic tensile testing and minimal notch sensitivity during fatigue testing. Damage mechanisms were also similar to unnotched.

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite At Elevated Temperature Under Tension-Tension Loading, Craig D. Steiner

Theses and Dissertations

This study investigated the fatigue behavior and damage mechanisms of a [0-90]_4s SiC-MAS ceramic matrix composite under tension-tension loading at two elevated temperatures and two frequencies. Stress and strain hystereses, maximum and minimum strain, and modulus of elasticity were evaluated to characterize the material behavior. Microscopy and fractography were used to evaluate damage progression and mechanisms. Fatigue life was independent of frequency at both temperatures.

An Experimental And Analytical Investigation Of The Iosipescu Shear Test For Composite Materials, Barry Stuart Spigel

Mechanical & Aerospace Engineering Theses & Dissertations

Mechanical properties of composite materials under shear loading are difficult to determine. The Iosipescu Shear test, originally proposed for metals, has in recent years been applied to composites. It has the advantages of small specimen size, simple loading and a reasonably uniform shear stress in the test section.

The purpose of this work is to study the validity of the Iosipescu test method for measuring the shear modulus and shear strength of composites. Finite element analyses indicate that optimum specimen geometry and load locations depend upon the degree of orthotropy of the composite. Test results for a quasi-isotropic graphite/epoxy laminate …

Stress Fields In Composites With A Variable Interphase Under Thermo-Mechanical Loadings, Nianfeng Chen

Mechanical & Aerospace Engineering Theses & Dissertations

An interphase in a composite material has a important role for the composite performance. It influences directly or indirectly the strength, fatigue performance and effective properties of the composite. Recently, interphase has drawn increasing attention in composite mechanics. To the best of our knowledge, however, no one seems to have considered the effect of the variable material prope1ty in the interphase on the stress field in the composite material. In this research, the stress fields are determined in the continuous fiber composite and the particulate composite by using the four concentric circular cylinders model and the four phase spheres model, …

Investigation Of Compressive Behavior For Metal Matrix Composites With A Circular Hole, Janet L. Gooder

Theses and Dissertations

This study investigated the notched and unnotched macromechanical response due to micromechanical behavior of [0/±45/90]_S SCS-6/β 21 S and [0/90] _2S Sigma/β 21S subjected to static compressive loads at room temperature. The stress-strain behavior and mechanical response in the presence of a circular hole was examined. A clear description of the progressive nature of damage, which ultimately resulted in failure, was provided. The effect of elevated temperature was shown for SCS-6/β 21S. The ultimate compressive strength and elastic modulus were reported for both MMCs. Sigma/β 21S and SCS-6/β 21S were mildly notch sensitive at room temperature. Notch sensitivity of …

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite At Elevated Temperatures Under Tension-Tension Loading, Richard J. Tuznik

Theses and Dissertations

A study was conducted which investigated the behavior of a Nicalon/ Calcium-Aluminosilicate (Nicalon/CAS) cross-ply [0/90]_2S ceramic matrix composite at elevated temperatures under tension-tension fatigue loading. Tension-tension fatigue tests were performed with a load ratio of R = 0.10 and a frequency of 10 Hertz at 700°C and 850°C. These results were compared to results from a previous study conducted at room temperature. Material behavior and damage was recorded by fatigue life curves, elastic modulus' maximum and minimum strain, acetate replication techniques, and post-mortem fractography. Analysis of these results showed identical matrix dominated damage behavior at RT and 700°C. Ultimate …

Investigation Of Tension-Compression Fatigue Behavior Of A Cross-Ply Metal Matrix Composite At Room And Elevated Temperatures, Elizabeth A. Boyum

Theses and Dissertations

This research, the first load-controlled tension-compression fatigue testing to be performed on a MMC, extends the existing knowledge of MMC fatigue damage mechanisms to include the tension compression loading condition. To accomplish this, a (0/90)2, SCS-6/Ti-15-3 laminate was subjected to tension- tension fatigue at room temperature, and tension-compression fatigue at both room temperature and 427°C. Stress and strain data was taken to evaluate the macro-mechanic behavior of the material. Microscopy and fractography were performed to characterize the damage on a micro-mechanic level. On a maximum applied stress basis, the room temperature tension-tension specimens had longer fatigue lives than the room …

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite Under Strain Controlled Tension-Tension And Tension-Compression Loading, James J. Gudaitis

Theses and Dissertations

This stuidy investigates the fatigue response of a cross-ply [0/90]_2s Nicalon/Calcium Aluminosillicate (Nicalcc/CAS) ceramic matrix composite at room temperature under strain controlled tension-tension and tension-compression fatigue loading. The primary objectives were to determine strain fatigue limits for both loading cases and to complete a fatigue life diagram (Δe-N) for all tests. Failure mechanisms were also studied. The average initial modulus value for this lay-up was 120 GPa. The ultimate tensile strain was 0.00988 mn/mm (285 MPa). Eight tests were conducted with maximum strains that ranged from 0.00300 mm/mm to 0.00722 mm/mm. The tension-tension fatigue limit was found to be …

Influence Of Embedded Optical Fibers On Compressive Strength Of Advanced Composites, Stefan B. Dosedel

Theses and Dissertations

This study investigated the effects of embedding optical fibers into advanced composite materials. This combination was meant to simulate 'smart structures' that have been shown to sense several different variables in the composite including strain, temperature, and damage. A laminate orientation taken from an existing aircraft structure was used to fabricate sixteen groups of specimens which were subjected to compression testing in an IITRI fixture to determine the ultimate compressive strength and modulus of elasticity. Ten of these groups were fabricated with optical fibers while the other six were control groups and contained no optical fibers. This study showed that …

Characterization Of Fatigue Damage In A Metal Matrix Composite (Scs-6/ Ti-15-3) At Elevated Temperature, Brian P. Sanders

Theses and Dissertations

The fatigue characteristics of a unidirectional titanium based metal matrix composite (MMC) were investigated at elevated temperature (427°C). A hybrid strain controlled loading mode was used to subject the 0° and 90° laminas to fatigue. Along with the fatigue tests, microscopy and analytical modeling ware also conducted. This combination of activities led to defining the initiation and progression of damage and deformation in the MMC. Hen loading was parallel to the fiber on, the fatigue behavior was initially dominated by creep deformation of the matrix. Then, depending on the maximum strain, specimen failure was the result either fiber fractures or …

An Investigation Of Graphite Peek Composite Under Compression With A Centrally Located Circular Discontinuity, Benjamin Wham Ii

Theses and Dissertations

The purpose of this thesis was to determine (both experimentally and analytically) the initiation and progression of failure, stress-strain response, and the failure loads of Graphite/Polyetheretherketone (Gr/PEEK) laminates, incorporating a centrally located circular discontinuity, loading in axial compression at room temperature. The laminates studied were (0°)₁₆,(90°)₁₆, (0°/90°)_4S, (± 45°)_4S, and (0°/±45°/90°)_2S. The specimens were loaded within a Boeing Open Hole Compression Fixture. The micromechanical failure modes were identified using a Scanning Electron Microscope. The analytical progression of failure was predicted using a nonlinear finite element code developed by Dr. R.S. …

Investigation Of Fatigue Behavior In Notched Cross-Ply Titanium Metal Matrix Composite At Elevated Temperature, Robert P. Baker

Theses and Dissertations

The objective of this research was to investigate the initiation and progression of damage which develops in notched (0/90)_2S SCS-6/Ti-15-3 at elevated temperature. Testing consisted of a monotonic tensile test at 427°C followed by fatigue testing performed under load control with a stress ratio of 0.1 at a frequency of 10 Hz. A crack was defined to have initiated when it had attained a length greater than or equal to 0.124 mm. Crack initiation and progression was monitored by strain and modulus observations and visual inspection via telemicroscope. The cracks were recorded with edge and face replicas. Metallographic and …

Behavior Of A Titanium Matrix Composite Under Quasi-Static Tensile And Compressive Loading, Keith L. Bearden

Theses and Dissertations

Quasi-Static tensile and compressive testing was performed on a unidirectional titanium matrix composite. The specific material was SCS-9/β 21S. The initial tensile and compressive modulus for both laminates was the same. The ninety degree laminate had a tensile and compressive modulus of 115.89 GPa. The zero degree laminate had a tensile and compressive modulus of 197.51 GPa. The ninety degree laminate exhibited a three stage stress/strain response in tension. The first stage is completely linearly elastic, however, partial debonding of the fiber from the matrix was observed. This partial debased did not effect the stress/strain response. The second stage is …

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite Under Tension-Tension And Tension-Compression Loading, Frank A. Opalski

Theses and Dissertations

A study was conducted which investigated the behavior of a cross-ply [0/90]_2S Nicalon/Calcium-Aluminosilicate (Nicalon/CAS) ceramic matrix composite at room temperature under tension-compression fatigue loading. Material behavior and damage was recorded by stress-strain curves, elastic modulus, hysteretic energy density, and acetate replication techniques. Tension-tension fatigue tests at a load ratio R of 0.1 (R = σ_min/σ_max) were completed which determined that 140 MPa was the maximum stress allowable in which cycle runout (1,000,000 cycles) would occur. Above this value, transverse crack density increased with respect to cycles and failure ultimately occurred. Tension-compression tests were then performed …

Computational And Experimental Investigation Into Fracture Of Brittle Fiber - Brittle Matrix Composite Systems, James P. Solti

Theses and Dissertations

Experimental and computational analyses provided an improved understanding of quasi-static fracture in model composite systems. Constant displacement compression tests using borosilicate glass double cleavage drilled compression test templates provided qualitative assessments of localized toughening for crack growth near cylindrical inclusions. Large crack-tip stress fields induced interfacial slip and separation prior to arrival of the main crack. Debonding and the proliferation of secondary matrix cracks characterized the role of bridging fibers along weak interfaces. Strong residual normal compressive interfacial stresses diminished the influence of crack-tip stresses; however, slip was still observed. VHS tape and computer enhanced photos record a history of …

Open And Filled Hole Static Tensile Strength Characterization Of Metal Matrix Composite Scs-9/Β21s, Jacob T. Roush

Theses and Dissertations

SCS-9/β21s has a reduced gauge thickness, in comparison with other metal matrix composites, due to a smaller diameter fiber. This reduced gauge thickness makes it an attractive candidate for the skin of hypersonic vehicles. Tensile testing of (0/90)_2s and (O/±45/90)_s laminates was performed at room temperature, 482°C, and 650°C. Both notched and unnotched specimens were tested. Notched specimens, open and filled hole, had a width-to-diameter ratio of six. Materials 7075-T6 and Mar-m-246 were used as pins in the filled hole tensile testing. Analytical work was completed to predict material properties, elastic and plastic stress concentration factors, residual stresses, …

Behavior Of A Centrally Notched Cross-Ply And Unidirectional Ceramic Matrix Composite In Tension-Compression Fatigue, William A. Weidenaar

Theses and Dissertations

Centrally notched (hole), cross-ply, ((0/90)₂)_s, and unidirectional, (0)₈ laminates of Silicon Carbide fiber-reinforced Aluminosilicate glass, SiC/1723, were fatigue tested under tension-compression loading with a load ratio of -1. Damage accumulated continuously for both lay- ups, leading to eventual failure and a reduced fatigue life. Critical damage in the cross-ply consisted of longitudinal cracks in the 90° plies growing and combining with transverse cracks to effectively eliminate the 90° plies' load carrying capability and allowing the specimen to buckle. Critical damage in the unidirectional lay-up consisted of longitudinal cracks which initiated at the shear stress concentration …

Transfer Function Models And Control Of A Flexible Structure Using Piezoelectric Laminates, Joseph A. Colvin

Mechanical & Aerospace Engineering Theses & Dissertations

The development of piezoelectric polymer films has generated a great deal of excitement in the structural controls community because they are lightweight, durable, distributed in nature and have broad band frequency characteristics. The flurry of research inspired by piezoelectric films has primarily been dedicated to using them as distributed sensors, and to a lesser extent, as distributed actuators.

Active damping of structural vibrations using piezoelectric polymer films as sensors and actuators has primarily been directed toward taking advantage of their distributed nature and employing various types of distributed control theory. This approach does not easily yield insight into the dynamics …

Crack Growth Rate Modeling Of A Titanium-Aluminide Alloy Under Thermal-Mechanical Cycling, John J. Pernot

Theses and Dissertations

In this study, a model is developed to predict crack growth rates in a titanium-aluminide alloy under thermal-mechanical fatigue (TMF). This TMF crack growth rate prediction model, which requires only isothermal data to define its parameters, is distinguished from earlier models in two ways. First, it accounts for mechanical-fatigue and environmental crack growth rate contributions while it also considers a retardation mechanism thought to be caused by creep blunting of the crack tip. This is the first study to account for such a retardation mechanism during TMF. The second uniqueness of the model is that its general form can account …