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2019

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Articles 61 - 68 of 68

Full-Text Articles in Other Engineering Science and Materials

Correlation Microanalysis Of Localized Molecular Structure And Nano-Mechanical Property Of Pvdf Based Copolymer, Wen Qian, Shuo Sun, Charles Nguyen, Stephen Ducharme, Joesph A. Turner Jan 2019

Correlation Microanalysis Of Localized Molecular Structure And Nano-Mechanical Property Of Pvdf Based Copolymer, Wen Qian, Shuo Sun, Charles Nguyen, Stephen Ducharme, Joesph A. Turner

Department of Mechanical and Materials Engineering: Faculty Publications

Poly (vinylidenefluoride) (PVDF) and its copolymers, are well-recognized electroactive polymers. The PVDF polymer can crystallize in a quasi-hexagonal close-packed “β-phase” structure with the dipoles of all chains aligned with maximum spontaneous polarization [1-3]. Due to the limited availability of quantitative methods for nanoscale molecular structure and mechanical analysis, the polymer organization has not been fully optimized. For such ferroelectric polymers, the influence of nanoscale molecular structure on mechanical response is not well understood. In this paper, we demonstrate nanoscale characterization and measurement techniques, by comprehensive integrating atomic force microscopy (AFM), X-ray diffraction (XRD), nano-infrared (nanoIR) spectroscopy, nanoindentation, chemical nanoIR mapping, …


Mechanical Characterizations Of 3d-Printed Plla/Steel Particle Composites, Hozhabr Mozafari, Pengfei Dong, Haitham Hadidi, Michael P. Sealy, Linxia Gu Jan 2019

Mechanical Characterizations Of 3d-Printed Plla/Steel Particle Composites, Hozhabr Mozafari, Pengfei Dong, Haitham Hadidi, Michael P. Sealy, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

The objective of this study is to characterize the micromechanical properties of poly-L-lactic acid (PLLA) composites reinforced by grade 420 stainless steel (SS) particles with a specific focus on the interphase properties. The specimens were manufactured using 3D printing techniques due to its many benefits, including high accuracy, cost effectiveness and customized geometry. The adopted fused filament fabrication resulted in a thin interphase layer with an average thickness of 3 μm. The mechanical properties of each phase, as well as the interphase, were characterized by nanoindentation tests. The effect of matrix degradation, i.e., imperfect bonding, on the elastic modulus of …


Hemodynamic Interference Of Serial Stenoses And Its Impact On Ffr And Ifr Measurements, Siyeong Ju, Linxia Gu Jan 2019

Hemodynamic Interference Of Serial Stenoses And Its Impact On Ffr And Ifr Measurements, Siyeong Ju, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

The hemodynamic interference of serial stenoses poses challenges for identifying the functional severity using the fractional flow reserve (FFR) method. The instantaneous wave-free ratio (iFR), i.e., the distal-to-proximal pressure ratio at 75% of diastole, was recently proposed to overcome the disadvantages of the FFR. However, the underlying mechanism remained ambiguous due to the lack of quantitative definition of hemodynamic interference. The objective of this study is to quantitatively define the hemodynamic interference and then examine its role on the FFR and iFR measurements. Pressure distributions, velocity fields, and Q-criterion which identifies vortices, were obtained through the computational fluid dynamics (CFD) …


Hemodynamics And Wall Mechanics After Surgical Repair Of Aortic Arch: Implication For Better Clinical Decisions, Siyeong Ju, Ibrahim Abdullah, Shengmao Lin, Linxia Gu Jan 2019

Hemodynamics And Wall Mechanics After Surgical Repair Of Aortic Arch: Implication For Better Clinical Decisions, Siyeong Ju, Ibrahim Abdullah, Shengmao Lin, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

Graft repair of aortic coarctation is commonly used to mimic the physiological aortic arch shape and function. Various graft materials and shapes have been adopted for the surgery. The goal of this work is to quantitatively assess the impact of graft materials and shapes in the hemodynamics and wall mechanics of the restored aortic arch and its correlation with clinical outcomes. A three-dimensional aortic arch model was reconstructed from magnetic resonance images. The fluid–structure interaction (FSI) analysis was performed to characterize the hemodynamics and solid wall mechanics of the repaired aortic arch. Two graft shapes (i.e., a half-moon shape and …


Interface Facilitated Reorientation Of Mg Nanolayers In Mg-Nb Nanolaminates, Y. Chen, Mingyu Gong, N. A. Mara, Jian Wang Jan 2019

Interface Facilitated Reorientation Of Mg Nanolayers In Mg-Nb Nanolaminates, Y. Chen, Mingyu Gong, N. A. Mara, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Mg/Nb nanolaminates synthesized through vapor deposition techniques exhibit high flow strength without conventional twinning in Mg. In this work, we investigated the influence of laminated microstructures on deformation mechanisms of Mg nanolayers. Using molecular dynamics simulations, we explored that (0001)-oriented Mg layers transform or re-orient to {10¯10}-oriented Mg layers through nucleation and growth of {10¯12} twins by atomic shuffling, instead of conventional {10¯12} twinning shear. Such a reorientation accommodates in-plane compressive strain and out-of-plane tensile strain when Mg/Nb laminates are subjected to compression parallel to the Mg/Nb interfaces. The nucleation of {10¯12} twins is promoted at the Mg/Nb interface due …


Predictive Peridynamic 3d Models Of Pitting Corrosion In Stainless Steel With Formation Of Lacy Covers, Siavash Jafarzadeh, Florin Bobaru, Ziguang Chen Jan 2019

Predictive Peridynamic 3d Models Of Pitting Corrosion In Stainless Steel With Formation Of Lacy Covers, Siavash Jafarzadeh, Florin Bobaru, Ziguang Chen

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, the peridynamic corrosion model is used for 3D simulation of pitting corrosion in stainless steel. Models for passivation and salt layer formation are employed to predict detailed characteristics of pit growth kinetic in stainless steels, such as lacy cover formation on top of the pit, and the diffusion-controlled regime at the pit bottom. The model is validated against an experimentally grown pit on 316L stainless steel in NaCl solution. Lacy covers in this model are formed autonomously during the simulation process. They are remarkably similar to the covers observed on top of the real pits.


Predictive Peridynamic 3d Models Of Pitting Corrosion In Stainless Steel With Formation Of Lacy Covers, Siavash Jafarzadeh, Florin Bobaru, Ziguang Chen Jan 2019

Predictive Peridynamic 3d Models Of Pitting Corrosion In Stainless Steel With Formation Of Lacy Covers, Siavash Jafarzadeh, Florin Bobaru, Ziguang Chen

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, the peridynamic corrosion model is used for 3D simulation of pitting corrosion in stainless steel. Models for passivation and salt layer formation are employed to predict detailed characteristics of pit growth kinetic in stainless steels, such as lacy cover formation on top of the pit, and the diffusion-controlled regime at the pit bottom. The model is validated against an experimentally grown pit on 316L stainless steel in NaCl solution. Lacy covers in this model are formed autonomously during the simulation process. They are remarkably similar to the covers observed on top of the real pits.


Engineering Of Earth-Abundant Electrochemical Catalysts, Dylan D. Rodene Jan 2019

Engineering Of Earth-Abundant Electrochemical Catalysts, Dylan D. Rodene

Theses and Dissertations

Alternative energy research into hydrogen production via water electrolysis addresses environmental and sustainability concerns associated with fossil fuel use. Renewable-powered electrolyzers are foreseen to produce hydrogen if energy and cost requirements are achieved. Electrocatalysts reduce the energy requirements of operating electrolyzers by lowering the reaction kinetics at the electrodes. Platinum group metals (PGMs) tend to be utilized as electrocatalysts but are not readily available and are expensive. Ni1-xMox alloys, as low-cost and earth-abundant transition metal nanoparticles (NPs), are emerging as promising electrocatalyst candidates to replace expensive PGM catalysts in alkaline media. Pure-phase cubic and hexagonal Ni1-x …