Mechanics of Materials Commons^™

Development Of Novel Battery Materials For Lithium-Ion Batteries And Beyond, Jiyu Cai

Graduate Theses and Dissertations

As fossil fuels are depleting and causing environmental issues, it becomes imperative to widely implement renewable energies (e.g., solar and wind power). In this context, electrical energy storage (EES) systems are essential to accommodate the intermittent supply and uneven distribution of renewable energies. To this end, high-energy-density EES devices are highly demanded, such as rechargeable batteries. This dissertation presents my efforts in developing novel battery materials for lithium-ion batteries (LIBs), sodium-ion batteries (SIBs), and solidstate lithium batteries (SSLBs). These efforts include electrochemical evaluations of battery materials, surface modifications of electrodes via atomic layer deposition (ALD), and advanced characterizations of batteries …

Phase-Field Modeling Of The Polymer Membrane Formation Process For Micro- And Ultra-Filtration, Michael Rosario Cervellere

Graduate Theses and Dissertations

Porous polymer membrane filters are widely used in separation and filtration process. Micro- and ultra-filtration membranes are commonly used in biopharmaceutical applications such as filtering viruses and separating proteins from a carrier solution. The formation of these membrane filters via phase inversion is a complex and interconnected process where varying casting conditions can have a wide variety of effects on the final membrane morphol- ogy. Tailoring membrane filters for specific performance characteristics is a tedious and time consuming process. The time and length scales of membrane formation make it extremely difficult to experimentally observe membrane formation. Modeling the membrane formation …

Influence Of Extracellular Matrix Stiffness And Topography On Neuronal Cell Behavior And Neurite Outgrowth, Mohan Yasodharababu

Graduate Theses and Dissertations

The focus of regeneration therapy for traumatic brain injuries and Alzheimer's disease is on the promotion and growth of neuronal cells. In vitro research attempts to improve this by modifying the stiffness and topography of the extracellular matrix (ECM). However, the limitations of in vitro experiments make it difficult to control the individual factors influencing neuronal cell growth. A computational model can be used to decouple individual factors and study them individually to gain a better understanding of the mechanics between the neuronal cell and ECM, which will aid in the design of in vitro experimental studies.

This study develops …

Optimization Of Vaccine Supply Chains In Low- And Middle-Income Countries Utilizing Drones, Maximilian Kolter

Graduate Theses and Dissertations

Despite tremendous efforts from governments and humanitarian organizations, millions of children in low- and low-middle-income countries (LICs and LMICs) are still excluded from the benefits of immunization. The vaccine distribution in LICs and LMICs is challenging for several reasons, such as limited cold chain capacities, vaccine wastage, uncertain demand, and lack of access to immunization services. A promising avenue to address these issues is the utilization of drones for vaccine delivery. Drones can fly at high speed on direct paths and could enable on-demand deliveries to mitigate limited storage capacities. Further, their independence of road networks could allow them reaching …

Electrochemical Deposition In Energy Storage Devices, Witness Atutala Martin

Graduate Theses and Dissertations

Metals, whether in a solid or soluble ion form, are a vital part of any electrochemical storage system. More so, Li metal is widely considered as the ideal anode because of its low density and low electrochemical potential (-3.04 V vs. the standard hydrogen electrode – SHE). However, just like most metals, it does not plate or strip evenly during cycling which can lead to cycling performance issues, short cycling lifespans, and even safety concerns brought about by dendrites that can cause internal short-circuiting within cells. This research focused on investigating the electroplating of metals in both aqueous and non-aqueous …

A Computational Study Of Radiation Damage In Bilayer Silicon-Gold Structures, Cameron Hopper

Graduate Theses and Dissertations

Irradiation from sources such as nuclear reactors bombard materials with neutrons and heavy ions. The primary consequence of this irradiation is the displacement of atoms from their atomic structure. As the structure becomes damaged, the mechanical properties can change. Eventually, this can result in a failure due to embrittlement. This type of damage is hard to detect and can result in sudden, unexpected failure. Therefore, focusing on managing the consequences of irradiation has been a heavily researched topic. To manage irradiation, the focus is primarily to manage the voids and interstitials that appear during irradiation. Grain boundaries and amorphous regions …

Control Of Change Of Phase Through Physical Surface Shaping, Troy Anderson, Sidy Ndao, Craig Zuhlke, Dennis Alexander, George Gogos

Department of Mechanical and Materials Engineering: Faculty Publications

A system embodiment includes , but is not limited to , a solid structure configure to contact each of a material in a liquid phase and a material in a vapor phase , the solid structure including a plurality of microstructures protruding at angles relative to a horizontal plane ; and a layer of nanoparticles positioned on the plurality of microstructures , the layer of nanoparticles having a composition that is at least one of a same material as the plurality of microstructures and an oxide of the same material as the plurality of microstructures , the plurality of microstructures …

Atomistic Thermo-Mechanical Description Of The Deformation Behavior, Scaling Laws, And Constitutive Modeling Of Nanoporous Gold, Mohammed Hassan Yousef Saffarini

LSU Doctoral Dissertations

Metallic foams, or nanoporous (NP) metals as it is widely referred to in literature, with ligament sizes up to a few tens of nm show exceptional mechanical properties such as high strength and stiffness per weight ratio under different loading scenarios due to their high surface area to solid volume ratio. Therefore, they can be utilized in a wide range of applications making them of great interest to researchers. While their elasticity and yield strength have been the subject of several studies, very limited attention was given to the effect of size, strain rate, and temperature on the material plastic …

Preventing Transmission Of Covid 19 In Hvac Duct Systems: Implementations Of Hvac System Design Upgrade, Jacob S. Lopez, Adama Barro

Publications and Research

The recent pandemic outbreak has triggered a global alarm to increase efforts on finding the best methods to mitigate contagious viral pathogens. This project is a continuation of our mission to study engineering guidelines needed to implement upgrades to HVAC Systems in order to deter airborne pathogens such as the covid-19 virus. In our previous projects we researched how covid-19 can possibly flow through the ambient air inside of restaurants, office spaces, and locomotive train cabins. As we continued our research, we were able to find some solutions that will be best used to deactivate and prevent the virus from …

Fluid-Structure Interaction Of Nrel 5-Mw Wind Turbine, Mohamed Sayed Elkady Abd-Elhay

Theses and Dissertations

Wind energy is considered one of the major sources of renewable energy. Nowadays, wind turbine blades could exceed 100 m to maximize the generated power and minimize produced energy cost. Due to the enormous size of the wind turbines, the blades are subjected to failure by aerodynamics loads or instability issues. Also, the gravitational and centrifugal loads affect the wind turbine design because of the huge mass of the blades. Accordingly, wind turbine simulation became efficient in blade design to reduce the cost of its manufacturing. The fluid-structure interaction (FSI) is considered an effective way to study the turbine's behavior …

Minimally Invasive Delivery Of 3d Shape Recoverable Constructs With Ordered Structures For Tissue Repair, Shixuan Chen, Mark Alan Carlson, Xiaowei Li, Aleem Siddique, Wuqiang Zhu, Jingwei Xie

Department of Mechanical and Materials Engineering: Faculty Publications

Minimally invasive procedures are becoming increasingly more common in surgery. However, the biomaterials capable of delivering biomimetic, three-dimensional (3D) functional tissues in a minimally invasive manner and exhibiting ordered structures after delivery are lacking. Herein, we reported the fabrication of gelatin methacryloyl (GelMA)-coated, 3D expanded nanofiber scaffolds and their potential applications in minimally invasive delivery of 3D functional tissue constructs with ordered structures and clinically appropriate sizes (4 cm × 2 cm × 1.5 mm). GelMA-coated, expanded 3D nanofiber scaffolds produced by combining electrospinning, gas-foaming expansion, hydrogel coating, and crosslinking are extremely shape recoverable after release of compressive strain, displaying …

The Effects Of The Transient And Performance Loss Rates On Pv Output Performance, Chibuisi Chinasaokwu Okorieimoh, Brian Norton, Michael Conlon

Conference papers

Solar photovoltaic (PV) panels experience long-term performance degradation as compared to their initial performance, resulting in lower like-per-like efficiencies and performance ratios. Manufacturers of solar photovoltaic modules normally guarantee a lifespan of more than 20 years. To meet such commitments, it is important to monitor and mitigate PV module degradation during this period, as well as beyond, to recognize maintenance and repair needs. Solar PV modules degrade over time, becoming less effective, less reliable, and eventually unusable. The effects of transient and performance loss rates on the output performance of polycrystalline silicon (p-Si) solar PV modules are the focus of …

Maize Tassel Detection From Uav Imagery Using Deep Learning, Aziza Alzadjali, Mohammed H. Alali, Arun Narenthiran Weeranampalayam Sivakumar, Jitender S. Deogun, Stephen Scott, James C. Schnable, Yeyin Shi

Department of Mechanical and Materials Engineering: Faculty Publications

The timing of flowering plays a critical role in determining the productivity of agricultural crops. If the crops flower too early, the crop would mature before the end of the growing season, losing the opportunity to capture and use large amounts of light energy. If the crops flower too late, the crop may be killed by the change of seasons before it is ready to harvest. Maize flowering is one of the most important periods where even small amounts of stress can significantly alter yield. In this work, we developed and compared two methods for automatic tassel detection based on …

Uavs For Vegetation Monitoring: Overview And Recent Scientific Contributions, Ana I. De Castro, Yeyin Shi, Joe Mari Maja, Jose M. Pena

Department of Mechanical and Materials Engineering: Faculty Publications

This paper reviewed a set of twenty-one original and innovative papers included in a special issue on UAVs for vegetation monitoring, which proposed new methods and techniques applied to diverse agricultural and forestry scenarios. Three general categories were considered: (1) sensors and vegetation indices used, (2) technological goals pursued, and (3) agroforestry applications. Some investigations focused on issues related to UAV flight operations, spatial resolution requirements, and computation and data analytics, while others studied the ability of UAVs for characterizing relevant vegetation features (mainly canopy cover and crop height) or for detecting different plant/crop stressors, such as nutrient content/deficiencies, water …

Three-Dimensional Shape Analysis Of Peripapillary Retinal Pigment Epithelium-Basement Membrane Layer Based On Oct Radial Images, Junfei Tong, Pengfei Dong, Sachin Kedar, Deepta Ghate, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

The peripapillary retinal pigment epithelium-basement membrane (ppRPE/BM) layer angle was recently proposed as a potential index for estimating intracranial pressure noninvasively. However, the ppRPE/BM layer angle, measured from the optical coherence tomography (OCT) scans, varied across the radial directions of the optic disc. This made the ppRPE/BM layer angle difficult to be utilized in its full potential. In this study, we developed a mathematical model to quantify the ppRPE/BM layer angles across radial scans in relation to the ppRPE/BM 3D morphology in terms of its 3D angle and scanning tilt angles. Results showed that the variations of the ppRPE/BM layer …

On The Comparison Of Flow Physics Between Minimal And Extended Flow Units In Turbulent Channels, Ethan A. Davis, Siamak Mirfendereski, Jae Sung Park

Department of Mechanical and Materials Engineering: Faculty Publications

Direct numerical simulations were performed to study the effects of the domain size of a minimal flow unit (MFU) and its inherent periodic boundary conditions on flow physics of a turbulent channel flow in a range of 200 ≤ Re_τ ≤ 1000. This was accomplished by comparing turbulent statistics with those computed in sub-domains (SD) of extended domain simulations. The dimensions of the MFU and SD were matched, and SD dynamics were set to minimize artificial periodicities. Streamwise and spanwise dimensions of healthy MFUs were found to increase linearly with Reynolds number. It was also found that both MFU …

Converting Inorganic Rust To Organic Nanostructured Conducting Polymers: Synthesis And Applications, Yifan Diao

McKelvey School of Engineering Graduate Student Theses & Dissertations

Iron rust is a type of corrosion product, coming from the chemical reaction between iron and oxygen in the presence of water that first documented ca. 800 BCE. It is a heterogeneous inorganic solid-state material composed of multiple phases and is ubiquitous throughout the universe. Rust species such as Hematite (α-Fe2O3), Akaganeite (β-FeOOH), and ferrous hydroxide (Fe(OH)2), make up the solid-state chemical family composed of iron oxides, oxyhydroxides, and hydroxides that are typically recognized as chemical waste. Conducting polymer is a type of organic plastic composed of long chains with repeating subunits that bonding with strong interactions between neighboring molecules. …

Plasmonically-Enhanced Ultrasensitive Biodetection Technologies, Zheyu Wang

McKelvey School of Engineering Graduate Student Theses & Dissertations

Detection and quantification of biomolecules within biological fluids and tissues is of fundamental importance to biomedical research and clinical diagnostics. It is impossible to fully characterize complex, non-linear, biochemical systems without being able to accurately and quantitatively determine the component molecules. This problem is ubiquitous across all domains of biomedical research, and it is a major barrier to fully understanding health, ageing, and disease. Such bottlenecks are extremely challenging to be solved, especially for proteins and peptides, which do not have amplification schemes such as polymerase chain reaction for nucleic acids, because relevant concentrations of molecules related to diseases such …

Characterization Of Landslide Processes From Radar Remote Sensing And Hydromechanical Modeling, Yuankun Xu

Earth Sciences Theses and Dissertations

Landsides are a natural geomorphic process yet a dangerous hazard which annually causes thousands of casualties and billions of property loss in a global scale. Understanding landslide motion kinematics from early initiation to final deposition is critical for monitoring, assessing, and forecasting landslide movement in order to mitigate their hazards. Landslides occur under diverse environmental settings and appear in variable types; however, all types of landslides can be mechanically attributed to shearing failure at the basal surface due to stress regime shift contributed by internal and/or external forcing. Typical internal factors include soil/rock weathering, whereas typical external triggering forces encompass …

Aerosol Vapor Synthesis Of Organic Processable Pedot Particles And Measuring Electric Conductivity Using A 3d Printed Probe Station, Yang Lu

McKelvey School of Engineering Graduate Student Theses & Dissertations

Conducting polymers are organic semiconductors characterized by conjugated backbones (alternating single-double bonds) that enable mixed ionic-electronic conductivity. Their polymeric nature, tunable band structure and reversible redox capability have demonstrated fundamental advances in the fields ranging from electrochemical energy storage, sensing, to electro/photo catalysis and neuromorphic engineering. Conjugated backbones, the origin of all the unique physical and chemical properties associated with conducting polymers, prevent their solubility due to high lattice energy which hinders processing. Current solution utilizes a long-chain polymer (PSS) as dopants to render conducting polymer water dispersible (PEDOT:PSS). Nonetheless, PSS is highly acidic and hydrophilic limiting applicability with acid-incompatible …

Rational Design And Optimization Of Perovskite Semiconductors, Arashdeep Thind

McKelvey School of Engineering Graduate Student Theses & Dissertations

ABSTRACT OF THE DISSERTATIONRational design and optimization of perovskite semiconductors by Arashdeep Singh Thind Doctor of Philosophy in Materials Science and Engineering Washington University in St. Louis, 2021 Professor Rohan Mishra, Chair

Lead-halide perovskites have emerged as a promising class of semiconductors for next-generation solar cells and optoelectronic devices. Since the report of the photovoltaic effect in 2009 in CH3NH3PbBr3 and CH3NH3PbI3, the power conversion efficiency of these perovskites has rapidly approached 25.2% from 3.8%. These perovskite semiconductors can be synthesized using low-cost solution-based techniques, unlike traditional semiconductors that require slow and expensive growth techniques to reduce the formation of …

Modeling Hydraulic Fracturing Initiation And Propagation In Porous Rock Formationsl, Chang Huang

LSU Doctoral Dissertations

Hydraulic fracturing has long been introduced to the oil and gas industry since the early nineteenth century for both reservoir characterization and reservoir stimulation. Despite the progress made in the last two decades, many challenges still have not been tackled regarding not only the propagation problem but also the initiation problem due to its complexity. The dissertation is divided into two stages, i.e., before and after fracture initiation. The first stage of the research aimed at improving the accuracy in solving the poro-mechanical response of wellbore during fluid injection before a tensile fracture occurs, which is crucial to determine the …

Higher-Order Topolectrical Semimetal Realized Via Synthetic Gauge Fields, Xiang Ni, Andrea Alù

Advanced Science Research Center

Classical bosonic systems may be tailored to support topological order and unidirectional edge transport exploiting gauge fields. Here, we theoretically explore how synthetic gauge fields may be used to induce higher-order topological phases and zero-energy boundary states. We demonstrate these principles in two types of three-dimensional topolectrical circuits with synthetic gauge fields threading through their reduced two-dimensional lattices, leading to a half-quantized quadrupole charge within a region of the momentum space. We theoretically show the emergence of nodal line rings and Weyl points in the bulk dispersion, whose projected surfaces and hinges support surface Fermi arcs and flat hinge Fermi …

High Frequency Electron Spin Resonance Investigations On Quasi-Two-Dimensional Chromium Halide Magnets, Christian Saiz

Open Access Theses & Dissertations

Broadening the knowledge and understanding on the magnetic correlations in van der Waals layered magnets is critical in realizing their potential next-generation applications in devices such as spintronics. In this study, we employ high frequency (ν = 120 GHz, 240 GHz) electron spin resonance (ESR) spectroscopy on plate-like CrX3 (where X = Cl, Br, I) to gain insight into the magnetic interactions as a function of temperature (200 – 4.4 K) and the angle of rotation θ (degrees). We find that the temperature dependence of the ESR linewidth is well described by the Ginzburg-Landau critical model, indicative of antiferromagnetic correlations …

Synthesis And Characterization Of Functiona Materials For 3d Printed Composites, Elizabeth Irene Reza

Open Access Theses & Dissertations

The following body of work encompasses the synThesis, upscaling, additive manufacturing, and characterization of microspheres as functional fillers incorporated into polymer syntactic foams. Synthesizing microspheres permits control over morphology, dispersion of particles, and size while the use of direct write manufacturing allowed for the controllability of filler orientation. Two different syntactic foams were developed from similar methodologies: (1) a silicone syntactic foam (2) epoxy syntactic foam. The silicone epoxy foam showed an increasing in damping and elastic modulus. The epoxy syntactic foams showed an enhanced thermal and electrical properties.

Mechanical Behavior Of Cyclo-18 On Nickel And Copper Substrates, Reagan Michael Kraft

Mechanical Engineering Undergraduate Honors Theses

Carbyne, an -hybridized allotrope of carbon, has been the subject of many studies recently due to its incredible mechanical properties and small size. More recently, another -hybridized allotrope known as cyclo-18, has gained interest. In this study, computational molecular dynamics will be used to determine the mechanical properties of cyclo-18. Peeling and shearing tests of the molecule will be conducted on nickel and copper, which are respectively active and less-active transition metals. Additionally, a carbyne chain of equal length will undergo the same tests on the copper substrate to compare the mechanical properties of the two. The results conclude that …

A Study Of The Frustrated Honeycomb Battery Material Na2ni2teo6, Nathan Christopher Episcopo

Open Access Theses & Dissertations

The P2-type layered hexagonal compound Na2Ni2TeO6 with Ni2+ on a honeycomb lattice was synthesized by the standard solid-state route. Structural characterization chemical phase purity was confirmed by Rietveld refinement of laboratory and synchrotron data. The crystal structure refines well in the P63/mcm space group. Single crystal growth trials using the self-flux-melt method were conducted with limited success. The magnetic transition temperature pertaining to Ni2+ lattice was confirmed by analysis of specific heat capacity to be . The magnetic susceptibility remains largely unchanged in magnetic field of and external pressure of . There is an almost linear response in isothermal magnetization …

New Generation Of Performance-Engineered Asphalt Mixtures Based On Balanced Mix Design Concept, Victor Manuel Garcia

Open Access Theses & Dissertations

Asphalt mixtures must ideally exhibit long-lasting durability and stability to perform wellin the field. However, improving the stability and durability of asphalt mixtures has become a major concern. Given that available design approaches rely mainly on stringent volumetric criteria for asphalt mixtures, design approaches and specifications that incorporate performance tests are needed to follow a performance-engineered mix design (PEMD) process, especially with the introduction of the balanced mix design (BMD) concept

This Dissertation study presents a comprehensive investigation of a feasible designapproach that can be implemented to develop PEMD specifications and produce BMD mixtures. An experimental evaluation of different mix …

Development And Testing Of Nanostructured Materials For Extreme Environment Applications, Nanthakishore Makeswaran

Open Access Theses & Dissertations

Nanostructured materials have many potential applications in the fields of power generation and transportation technologies, particularly in the areas of gas sensing technology, industrial gas turbines and protective coatings. In the former case β-Ga2O3 represents a promising candidate due to its high degree of stability and functionality for oxygen sensing at higher temperatures (>700oC). In the latter case, the application of Y-Si-Fe compounds acting as environmental barrier coatings for gas turbine and aerospace engine applications to protect from corrosion effects has been demonstrated in recent years. In both cases, however, there is room for improvement whether it is in …

Post Processing Of Electron Beam Melted Ti-6al-4v And Binder Jetted 17-4 Stainless Steel, Ahmad Omar Abu-Issa

Open Access Theses & Dissertations

An extensive assortment of HIP parameters have been altered on EBM fabricated Ti-6Al-4V and have shown that cooling rates of 103 oC/min from temperatures above and below the beta transus produced acicular alpha-prime martensite characteristic elongations < 10 %. Optimum yield strength (0.9 GPa), UTS (1.0 GPa) and elongation (~14 %) were achieved for slow cooling (at 102 oC/min) from 850 oC HIP which produced a dense, Widmanstatten alpha structure within the retained, as-fabricated columnar grains by alpha-prime decomposition. These results suggest that manipulation of AM process parameters to produce a small-grain, equiaxed microstructure, HIPed below the beta transus and slow cooled, will have a wide range of superior, isotropic mechanical properties corresponding to a Widmanstatten alpha microstructure within the equiaxed grains. Also, Binder Jetting printing parameters for differing PSD's of low-cost water-atomized 17-4 Stainless Steel were optimized in order to produce high dense parts. Densities ranging from 94-97.5% were achieved, and issues of inhomogeneous porosity were addressed using a fumed silica flow additive.