Mechanics of Materials Commons^™

Mechanically Activated Magnesiothermic Combustion Synthesis Of Zirconium And Hafnium Diborides, Sergio Cordova

Open Access Theses & Dissertations

Magnetohydrodynamic (MHD) generation of electric power has the potential to increase the thermal efficiency of fossil-fuel burning power plants. Electrode materials in MHD generators must possess a high melting point, high electrical and thermal conductivities, chemical stability, and resistance to thermal shock, oxidation, and plasma sparks/arcs. Ultra-high temperature ceramics based on diborides of zirconium and hafnium (ZrB2 and HfB2) are promising materials for this application. Self-propagating high-temperature synThesis (SHS) is an attractive method for their large-scale fabrication, but SHS of ZrB2 and HfB2 from elemental Zr, Hf, and B is not economically viable because of the high cost of the …

Methods For Producing Graphene From Petroleum By-Products, Eva M. Deemer

Open Access Theses & Dissertations

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On Demand 3d Printed Hybrid Scaffolds For Tissue Engineering Applications, Ivan D. Hernandez

Open Access Theses & Dissertations

A composite 3D printed polymer scaffold with inbuilt porosity and filled with a hydrogel can provide an ideal support system for cell growth, proliferation, and vascularization. Therefore, a hybrid system of 3D printed polycaprolactone (PCL) scaffold and a hydroxyapatite-based hydrogel was developed for application in the reconstruction of bone defects, which are inherently difficult to repair without any guided therapies. In the present study, a 3D printed gyroid structure of PCL allowed the loading of a higher amount of hydrogel as compared to conventionally used 3D printed mesh structure of the same volume and strut thickness. The hydrogel was composed …

Ac Susceptibility And Epr Investigations Of Superspin Dynamics In Manganese Oxide Nanoparticles, Mahesh Koirala

Open Access Theses & Dissertations

We have investigated the superspin dynamics of 5 nm and 10 nm mixed state Mn3O4 nanoparticles utilizing ac-susceptibility and electron paramagnetic resonance measurements. The out of phase component of the ac-susceptibility measurements show a magnetic anomaly below (T

Protonic Conductors For Intermediate Temperature Fuel Cell Electrolytes: Superprotonic Csh2po4 Stabilization And In-Doped Snp2o7 Structure Study, Heber Jair Martinez Salinas

Open Access Theses & Dissertations

Proton conductor solid electrolytes CsH2PO4 and In-doped tin pyrophosphate have been investigated as candidates to fill a gap of suitable electrolytes for fuel cells at the intermediate temperature range due their unusually high conductivities between 200 and 300 °C. Unfortunately, in the case of CsH2PO4, complicated experimental conditions, like a humidified environment, or high pressure, are needed to preserve the sought high conducting phase.

In the first stage of this work, X-ray diffraction on CsH2PO 4 samples performed in air, and under normal conditions of humidity and pressure, evidence of the cubic phase of CsH2PO4 was observed during short intervals …

Structural And Mechanical Characterization Of Nanocrystalline Tungsten And Tungsten-Based Alloy Thin Films For Extreme Environment Applications, Gustavo Martinez

Open Access Theses & Dissertations

Extreme environments associated with nuclear applications often results in degradation of the physical, mechanical and thermo-mechanical properties of the materials. Tungsten (W) exhibits unique physical and mechanical properties, which makes tungsten a good candidate for nuclear applications; however, intrinsic W exhibits low fracture toughness at all temperatures in addition to a high ductile to brittle transition. In the present work, nanocrystalline W, W-Y and W-Mo alloys were nanoengineered for nuclear applications. Nanocrystalline tungsten coatings with a thickness of ~1 µm were deposited onto Silicon (100) and Sapphire (C-plane) using RF and DC sputtering techniques under various growth conditions. Yttrium content …

Raman Microscopic Analysis Of Internal Stress In Boron-Doped Diamond Thin Films, Emma M.A. Sundin

Open Access Theses & Dissertations

The correlations between induced stress on undoped and boron-doped diamond (BDD) thin films, sample chemical composition, and fabrication substrate are investigated in this study via confocal Raman microspectroscopic analysis. Stability of BDD films is relevant to fast-scan cyclic voltammetry, as film delamination and dislocation of BDD-coated electrodes that can occur during neurosurgical electrode implantation can negatively impact the biosensing reliability of this technique. Electrodes were fabricated by coating cylindrical tungsten rods using a custom-built chemical vapor deposition reactor. The results of the analysis reveal a direct correlation between regions of pure diamond and enhanced material stress, as well as preferential …

Structural And Electrical Characterization Of Tin Oxide Resistive Switching, Arka Talukdar

Open Access Theses & Dissertations

Resistive switching in metal oxide is a phenomenon in which the metal oxide changes its resistance upon application of electric field and thus giving two states; high resistance state (HRS) and low resistance state (LRS). Many metal oxides have been investigated however very little is known about unipolar resistive switching in SnO2 though it has shown excellent resistive switching characteristics. Defects in the material play a vital role in resistive switching of the metal oxides. In this work, the role of defects in resistive switching of SnO2 are investigated in Ti/SnO2/Au structures. Two methods were used to control the concentration …

Comprehensive Finite Element Modeling Of Ti-6al-4v Cellular Solids Fabricated By Electron Beam Melting, Edel Arrieta

Open Access Theses & Dissertations

Additive manufacturing permits the fabrication of cellular metals which are materials that can be highly customizable and possess multiple and extraordinary properties such as damage tolerance, metamorphic and auxetic behaviors, and high specific stiffness. This makes them the subject of interest for innovative applications. With interest in these materials for energy absorption applications, this work presents the development of nonlinear finite element models in commercial software platforms (MSC Patran/Nastran) that permit the analysis of the deformation mechanisms of these materials under compressive loads. In the development of these models, a detailed multiscale study on the different factors affecting the response …

Characterization & Extraction Of Extracellular Matrix From Porcine Adipose Tissue, Rahulkumar Kantibhia Bhoi

Open Access Theses & Dissertations

Tissue in particular extracellular matrix(ECM) plays a vital role in the growth and the function of each cell types and promote tissue regeneration and repair an impair organs. Many techniques have been developed so far to decellularized porcine tissue for the purpose to use as regenerative medicine and in tissue engineering. We aimed to optimized a method to decellularized porcine tissue while effectively eliminating xenogeneic epitopes, lipids and to retain necessary component of it intact without disrupting ECM. We have developed 2-week protocol to optimize well preserved ECM component that may keep xenogeneic biomaterial for tissue engineering and regenerative medicine. …

Low-Drag Events In Transitional Wall-Bounded Turbulence, Richard D. Whalley, Jae Sung Park, Anubhav Kushwaha, David J.C. Dennis, Michael D. Graham, Robert J. Poole

Department of Mechanical and Materials Engineering: Faculty Publications

Intermittency of low-drag pointwise wall shear stress measurements within Newtonian turbulent channel flow at transitional Reynolds numbers (friction Reynolds numbers 70 – 130) is characterized using experiments and simulations. Conditional mean velocity profiles during low-drag events closely approach that of a recently discovered nonlinear traveling wave solution; both profiles are near the so-called maximum drag reduction profile, a general feature of turbulent flow of liquids containing polymer additives (despite the fact that all results presented are for Newtonian fluids only). Similarities between temporal intermittency in small domains and spatiotemporal intermittency in large domains is thereby found.

Flowtaxis Of Osteoblast Migration Under Fluid Shear And The Effect Of Rhoa Kinase Silencing, Brandon D. Riehl, Jeong Soon Lee, Ligyeom Ha, Il Keun Kwon, Jung Yul Lim

Department of Mechanical and Materials Engineering: Faculty Publications

Despite the important role of mechanical signals in bone remodeling, relatively little is known about how fluid shear affects osteoblastic cell migration behavior. Here we demonstrated that MC3T3-E1 osteoblast migration could be activated by physiologically-relevant levels of fluid shear in a shear stress-dependent manner. Interestingly, shear-sensitive osteoblast migration behavior was prominent only during the initial period after the onset of the steady flow (for about 30 min), exhibiting shear stress-dependent migration speed, displacement, arrest coefficient, and motility coefficient. For example, cell speed at 1 min was 0.28, 0.47, 0.51, and 0.84 μm min^-1 for static, 2, 15, and 25 …

Fluid-Structure Interaction In Abdominal Aortic Aneurysm: Effect Of Modeling Techniques, Shengmao Lin, Xinwei Han, Yonghua Bi, Siyeong Ju, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, the impact of modeling techniques on predicting the mechanical behaviors of abdominal aortic aneurysm (AAA) is systematically investigated. The fluid-structure interaction (FSI) model for simultaneously capturing the transient interaction between blood flow dynamics and wall mechanics was compared with its simplified techniques, that is, computational fluid dynamics (CFD) or computational solid stress (CSS) model. Results demonstrated that CFD exhibited relatively smaller vortexes and tends to overestimate the fluid wall shear stress, compared to FSI. On the contrary, the minimal differences in wall stresses and deformation were observed between FSI and CSS models. Furthermore, it was found that …

High Temperature Near-Field Nanothermomechanical Rectification, Mahmoud Elzouka, Sidy Ndao

Department of Mechanical and Materials Engineering: Faculty Publications

Limited performance and reliability of electronic devices at extreme temperatures, intensive electromagnetic fields, and radiation found in space exploration missions (i.e., Venus & Jupiter planetary exploration, and heliophysics missions) and earth-based applications requires the development of alternative computing technologies. In the pursuit of alternative technologies, research efforts have looked into developing thermal memory and logic devices that use heat instead of electricity to perform computations. However, most of the proposed technologies operate at room or cryogenic temperatures, due to their dependence on material’s temperature-dependent properties. Here in this research, we show experimentally—for the first time—the use of near-field thermal radiation …

Surface Charge Switchable And Ph-Responsive Chitosan/Polymer Core-Shell Composite Nanoparticles For Drug Delivery Application, W. F. Huang, C. P. Tsui, M. Yang, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

The mutually conflicting surface charge requirements for nanoparticles to have long circulation and good cell affinity have made the development of polymer nanoparticles for controlled drug delivery fall into a dilemma. In order to solve this problem, the first attempt has been made in this work to develop vancomycin loaded composite nanoparticles with a novel chitosan core and poly (lactide-co-glycolide) (PLGA) shell structure and with both pH-responsive and surface charge switchable properties. Spherical composite nanoparticles have been successfully fabricated through a modified emulsion-gelation method with a controllable size (316–573 nm), surface charge (–27.6–31.75 mV) and encapsulation efficiency up to 70.8%. …

Molecular Dynamics Simulations Of Heterogeneous Cell Membranes In Response To Uniaxial Membrane Stretches At High Loading Rates, Lili Zhang, Zesheng Zhang, John Jasa, Dongli Li, Robin O. Cleveland, Mehrdad Negahban, Antoine Jérusalem

Department of Mechanical and Materials Engineering: Faculty Publications

The chemobiomechanical signatures of diseased cells are often distinctively different from that of healthy cells. This mainly arises from cellular structural/compositional alterations induced by disease development or therapeutic molecules. Therapeutic shock waves have the potential to mechanically destroy diseased cells and/or increase cell membrane permeability for drug delivery. However, the biomolecular mechanisms by which shock waves interact with diseased and healthy cellular components remain largely unknown. By integrating atomistic simulations with a novel multiscale numerical framework, this work provides new biomolecular mechanistic perspectives through which many mechanosensitive cellular processes could be quantitatively characterised. Here we examine the biomechanical responses of …

High-Velocity Projectile Impact Induced 9r Phase In Ultrafine-Grained Aluminium, Sichuang Xue, Zhe Fan, Olawale B. Lawal, Ramathasan Thevamaran, Qiang Li, Yue Liu, K. Y. Yu, Jian Wang, Edwin L. Thomas, Haiyan Wang, Xinghang Zhang

Department of Mechanical and Materials Engineering: Faculty Publications

Aluminium typically deforms via full dislocations due to its high stacking fault energy. Twinning in aluminium, although difficult, may occur at low temperature and high strain rate. However, the 9R phase rarely occurs in aluminium simply because of its giant stacking fault energy. Here, by using a laser-induced projectile impact testing technique, we discover a deformation-induced 9R phase with tens of nm in width in ultrafine-grained aluminium with an average grain size of 140 nm, as confirmed by extensive post-impact microscopy analyses. The stability of the 9R phase is related to the existence of sessile Frank loops. Molecular dynamics simulations …

Controllable Energy Absorption Of Double Sided Corrugated Tubes Under Axial Crushing, Hozhabr Mozafari, Shengmao Lin, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

To maximize the controllable energy absorption of corrugation troughs as observed in the single sided corrugated (SSC) tube, we proposed and tested a new structure design, i.e., double-sided corrugated (DSC) tube made of Al 6060-T6 aluminum alloy or CF1263 carbon/epoxy composite. Finite element models were developed to test the mechanical advantage of the DSC tube in comparison with both SSC and classical straight (S) tubes under axial crushing. Results have shown that the total absorbed energy of the DSC aluminum tube with 14 corrugations was 330% and 32% higher than that of the SSC tube with 14 corrugations and the …

Novel Polyethylene Fibers Of Very High Thermal Conductivity Enabled By Amorphous Restructuring, Bowen Zhu, Jing Liu, Tianyu Wang, Shah R. Valloppilly, Shen Xu, Xinwei Wang

Department of Mechanical and Materials Engineering: Faculty Publications

High-thermal-conductivity polymers are very sought after for applications in various thermal management systems. Although improving crystallinity is a common way for increasing the thermal conductivity (k) of polymers, it has very limited capacity when the crystallinity is already high. In this work, by heat-stretching a highly crystalline microfiber, a significant k enhancement is observed. More interestingly, it coincides with a reduction in crystallinity. The sample is a Spectra S-900 ultrahigh-molecular-weight polyethylene (UHMW-PE) microfiber of 92% crystallinity and high degree of orientation. The optimum stretching condition is 131.5 °C, with a strain rate of 0.0129 s−1 to a low strain ratio …

Dislocations Interaction Induced Structural Instability In Intermetallic Al2Cu, Qing Zhou, Jian Wang, Amit Misra, Ping Huang, Fei Wang, Kewei Xu

Department of Mechanical and Materials Engineering: Faculty Publications

Intermetallic precipitates are widely used to tailor mechanical properties of structural alloys but are often destabilized during plastic deformation. Using atomistic simulations, we elucidate structural instability mechanisms of intermetallic precipitates associated with dislocation motion in a model system of Al₂Cu. Interaction of non-coplanar <001> dislocation dipoles during plastic deformation results in anomalous reactions—the creation of vacancies accompanied with climb and collective glide of <001> dislocation associated with the dislocation core change and atomic shuffle—accounting for structural instability in intermetallic Al₂Cu. This process is profound with decreasing separation of non-coplanar dislocations and increasing temperature and is likely to be …

A Rapid And Non-Invasive Method For Measuring The Peak Positive Pressure Of Hifu Fields By A Laser Beam, Hua Wang, Deping Zeng, Ziguang Chen, Zengtao Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Based on the acousto-optic interaction, we propose a laser deflection method for rapidly, non-invasively and quantitatively measuring the peak positive pressure of HIFU fields. In the characterization of HIFU fields, the effect of nonlinear propagation is considered. The relation between the laser deflection length and the peak positive pressure is derived. Then the laser deflection method is assessed by comparing it with the hydrophone method. The experimental results show that the peak positive pressure measured by laser deflection method is little higher than that obtained by the hydrophone, confirming that they are in reasonable agreement. Considering that the peak pressure …

Benchmark Burnishing With Almen Strip For Surface Integrity, Z. Y. Liu, C. H. Fu, M. P. Sealy, Y. Zhao, Y. B. Guo

Department of Mechanical and Materials Engineering: Faculty Publications

Burnishing is a surface treatment process widely used in aerospace, navy and other industries to improve fatigue and corrosion resistance by introducing a compressive residual stress layer. The measurement of residual stress by XRD is expensive, time consuming, and tedious. This work presented a quick method to determine the residual stress by using Almen strips. Inspired by the application of Almen strips in shot peening, deflections of burnished Almen strips under different burnishing conditions were measured. It was found that the deflection of Almen strip reflects the magnitude and penetration depth into subsurface of induced stress. Higher burnishing force, smaller …

Effects Of Aspect Ratio On The Mode Couplings Of Thin-Film Bulk Acoustic Wave Resonators, Nian Li, Zhenghua Qian, Jiashi Yang

Department of Mechanical and Materials Engineering: Faculty Publications

We studied mode couplings in thin film bulk acoustic wave resonators of a piezoelectric film on a dielectric layer operating with the fundamental thickness-extensional mode. A system of plate equations derived in our previous paper was used which includes the couplings to the unwanted in-plane extension, flexure, fundamental and second-order thickness shear modes. It was shown that the couplings depend strongly on the plate length/thickness ratio. For a relatively clean operating mode with weak couplings to unwanted modes, a series of discrete values of the plate length/thickness ratio should be avoided and these values were determined in the present paper. …

Clustering On Magnesium Surfaces – Formation And Diffusion Energies, Haijian Chu, Hanchen Huang, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

The formation and diffusion energies of atomic clusters on Mg surfaces determine the surface roughness and formation of faulted structure, which in turn affect the mechanical deformation of Mg. This paper reports first principles density function theory (DFT) based quantum mechanics calculation results of atomic clustering on the low energy surfaces {0001} and {1011}. In parallel, molecular statics calculations serve to test the validity of two interatomic potentials and to extend the scope of the DFT studies. On a {0001} surface, a compact cluster consisting of few than three atoms energetically prefers a facecentered- cubic stacking, to serve as a …

Review Of Sustainability Issues In Non-Traditional Machining Processes, Kamlakar Rajurkar, H. Hadidi, J. Pariti, G. C. Reddy

Department of Mechanical and Materials Engineering: Faculty Publications

Non-traditional machining processes (such as EDM and ECM) provide alternatives or sometimes the only alternative in generating highly complex 3-D features in very difficult-to -machine materials. This paper reviews recently published work on sustainability issues related to these processes. For example in Electrochemical machining (ECM) the effect of sludge generation and selection of dielectric in Electrodischarge machining (EDM) need to be investigated from the sustainability point of view. All processes need to be studied not only for resulting productivity and accuracy but also their environmental impact during product generation and usage. This paper addresses process mechanisms, surface integrity, sensing and …

Accommodation Of The Human Lens Capsule Using A Finite Element Model Based On Nonlinear Regionally Anisotropic Biomembranes, G. David, Ryan M. Pedrigi, J. D. Humphrey

Department of Mechanical and Materials Engineering: Faculty Publications

Accommodation of the eyes, the mechanism that allows humans to focus their vision on near objects, naturally diminishes with age via presbyopia. People who have undergone cataract surgery, using current surgical methods and artificial lens implants, are also left without the ability to accommodate. The process of accommodation is generally well known; however the specific mechanical details have not been adequately explained due to difficulties and consequences of performing in vivo studies. Most studies have modeled the mechanics of accommodation under assumptions of a linearly elastic, isotropic, homogenous lens and lens capsule. Recent experimental and numerical studies showed that the …

Growth Mechanisms Of Multiscale, Mound-Like Surface Structures On Titanium By Femtosecond Laser Processing, Edwin Peng, Ryan Bell, Craig A. Zuhlke, Meiyu Wang, Dennis R. Alexander, George Gogos, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Faculty Publications

Femtosecond laser surface processing (FLSP) can be used to functionalize many surfaces, imparting specialized properties such as increased broadband optical absorption or superhydrophobicity/-hydrophilicity. In this study, the subsurface microstructure of a series of mound-like FLSP structures formed on commercially pure titanium using five combinations of laser fluence and cumulative pulse counts was studied. Using a dual beam Scanning Electron Microscope with a Focused Ion Beam, the subsurface microstructure for each FLSP structure type was revealed by cross-sectioning. The microstructure of the mounds formed using the lowest fluence value consists of the original Ti grains. This is evidence that preferential laser …

Design And Field Testing Of A Combined Flaming And Cultivation Implement For Effective Weed Control, Brian D. Neilson, Chris A. Bruening, Strahinja Stepanovic, Avishek Datta, Stevan Z. Knezevic, George Gogos

Department of Mechanical and Materials Engineering: Faculty Publications

Flaming is a thermal weed control method that uses heat to control weeds within or between crop rows. Mechanical cultivation is another weed control method which undercuts weeds between crop rows, while leaving a strip of weeds within the crop row. A combination flamer/cultivator implement was designed to take advantage of the good qualities of both flaming and cultivation methods to provide a more consistent weed control than using either flaming or mechanical cultivation alone. Flaming hoods were designed in the spring of 2010 and retrofitted on an existing row crop cultivator. The flaming hoods were redesigned in the spring …

Robotic Surgical Devices, Systems, And Related Methods, Shane M. Farritor, Erik Mumm, Philip Chu, Nishant Kumar, Jason Dumpert, Yutaka Tsutano

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incorporated into robotic and/or in vivo medical devices. Certain embodiments include various modular medical devices for in vivo medical procedures.

Methods , Systems , And Devices Relating To Surgical End Effectors, Shane M. Farritor, Tom Fredrick, Joe Bartels

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incorporated into robotic and/or in vivo medical devices, and more specifically including end effectors that can be incorporated into such devices. Certain end effector embodiments include various vessel cautery devices that have rotational movement as well as cautery and cutting functions while maintaining a relatively compact structure. Other end effector embodiments include various end effector devices that have more than one end effector.