Engineering Science and Materials Commons^™

Urea Pre-Treatment Of N2-Annealed Transition Metal Oxides For Low Cost And Efficient Counter Electrodes In Dye-Sensitized Solar Cell, Hytham Elbohy

Electronic Theses and Dissertations

Photovoltaic cells have shown great promise as an alternative to fossil fuel-based energy sources. Dye-sensitized solar cells (DSSCs) have shown potential as low-cost replacement to silicon solar cells owing to their reduced material costs and simple fabrication techniques. Platinum (Pt) was used as a catalyst in the counter electrode for DSSCs. Metal oxides have been used as an alternative material to Pt. The introduction of oxygen vacancies inside metal oxides helps to facilitate electron transport to the electrolyte to enhance the reduction process of triiodide ions. Annealing n-type metal oxides under a reducing agent gas such as hydrogen (H2) at …

Development Of Enzyme-Free Hydrogen Peroxide Biosensor Using Cerium Oxide And Mechanistic Study Using In-Situ Spectro-Electrochemistry, Shashank Saraf

Electronic Theses and Dissertations

During recent development, it has been demonstrated that cerium oxide nanoparticles (CNPs) have exhibited catalytic activity which mimics naturally existing enzymes such as superoxide dismutase (SOD) and catalase. The underlying mechanism is attributed to the modulation of oxygen vacancies on CNPs lattice by dynamic switching of the oxidation states between Ce3+ and Ce4+ due to the electron transfer resulting from the redox reaction between CNPs and reactive oxygen species such as hydrogen peroxide (H2O2). Thereby the redox potential of CNPs is dependent on the surface chemistry i.e. the surface concentration of Ce3+ and Ce4+ Currently, the ratio of Ce3+/ Ce4+ …

Design Of Surface Chemical Reactivity And Optical Properties In Glasses, Antoine Lepicard

Electronic Theses and Dissertations

Thermal poling is a technique which involves the application of a strong DC electric field to a glass substrate heated below its glass transition temperature (Tg). Following the treatment, a static electric field is frozen inside the glass matrix, effectively breaking its centrosymmetry. Historically, this treatment has been used as a way to gain access to second order non-linear optical properties in glasses. However, recent efforts have shown that the treatment was responsible for structural changes as well as surface property modifications. Our study was focused on using this technique to tailor surface properties in oxide (borosilicate and niobium borophosphate) …

Improved Interpolation In Sph In Cases Of Less Smooth Flow, Oddny Brun

Electronic Theses and Dissertations

We introduced a method presented in Information Field Theory (IFT) [Abramovich et al., 2007] to improve interpolation in Smoothed Particle Hydrodynamics (SPH) in cases of less smooth flow. The method makes use of wavelet theory combined with B-splines for interpolation. The idea is to identify any jumps a function may have and then reconstruct the smoother segments between the jumps. The results of our work demonstrated superior capability when compared to a particular challenging SPH application, to better conserve jumps and more accurately interpolate the smoother segments of the function. The results of our work also demonstrated increased computational efficiency …

Spare Parts On Demand Using Additive Manufacturing : A Simulation Model For Cost Evaluation., Stefan Jedeck

Electronic Theses and Dissertations

Little is known about the impact of additive manufacturing in the spare part supply chain. A few studies are available, but they focus on specific parts and their applications only. A general model, which can be adapted to different applications, is nonexistent. This dissertation proposes a decision making framework that enables an interested practitioner/manager to decide whether using additive manufacturing to make spare parts on demand is economical when compared to conventional warehousing strategy. The framework consists of two major components: a general discrete event simulation model and a process of designing a wide range of simulation scenarios. The goal …

Freeze-Thawing Of Polyester/E-Glass As An Evaluation Of An Astm International Test Standard Proposal, Stefan Mauritz Strandlund

Electronic Theses and Dissertations

American Composites Manufacturers Association (ACMA) reported in 2009 that the four major sectors currently utilizing fiber reinforced polymers (FRP) are construction, corrosion, marine, and transportation in descending order of total FRP shipped. All of these sectors are known to be billion dollar industries and they are all involved with applications subjected to freezing and thawing. FRP encompass many characteristics that are beneficial to these sectors and also in resisting this exposure. ASTM International has yet not developed a standard to test FRP materials resistance to freeze-thaw (FT) cycling exposure. The D20.18.02 committee of the ASTM is in the process of …

Calibration Of Alumina-Epoxy Nanocomposites Using Piezospectroscopy For The Development Of Stress-Sensing Adhesives, Amanda L. Stevenson

Electronic Theses and Dissertations

A non-invasive method to quantify the stress distribution in polymer-based materials is presented through the piezospectroscopic calibration of alumina-epoxy nanocomposites. Three different alumina volume fraction nanocomposites were created and loaded under uniaxial compression in order to determine the relationship between applied stress and the frequency shift of the R-lines produced by alumina under excitation. Quantitative values for six piezospectroscopic coefficients were obtained which represent the stress-sensing property of the nanocomposites. The results were applied to an alumina-filled adhesive in a single lap shear configuration demonstrating the capability of the technique to monitor R-line peak positions with high spatial resolution and …

Effects Of Thermo-Mechanical Loading From In-Situ Studies Of Eb-Pvd Thermal Barrier Coatings, Melan N. Jansz

Electronic Theses and Dissertations

The thermo-mechanical effects on the strain evolution within an EB-PVD thermal barrier coating (TBC) is presented in this work using in-situ characterization. Synchrotron X-ray diffraction at sector 1-ID at the Argonne National Laboratory provided both qualitative and quantitative in-situ data on the strain evolution under a thermal cycle with mechanical loading. The results show that at a critical combination of temperature and load, the stress in the thermally grown oxide (TGO) layer in the TBC reaches a tensile region. These significant findings enhance existing literature showing purely compressive strains within the TGO where mechanical loads have been neglected. The results …

A Use Of Theory Of Constraints Thinking Processes For Improvements In The Merged Beams Experiment At Oak Ridge National Laboratory., Bryan Richard Gross

Electronic Theses and Dissertations

Thinking exercises used in the Theory of Constraints (TOC) were used to find and remove constraints at the Merged Beams Experiment at Oak Ridge National Laboratory. The goal of this project was to significantly reduce the amount of time used to take a certain type of measurement during an experimental cycle. After the TOC exercises were used, a basic plan for change was discovered. Preliminary data were taken to establish a baseline of performance from which changes were made. Post-Modification was analyzed showing the project was a success.

The overlying reasoning for this exercise was to prove successfully that continuous …

The Investigation Of Nano Silica In The Cement Hydration Pro, Jonathan Samuel Belkowitz

Electronic Theses and Dissertations

With the advent of nano technology, materials have been developed that can be applied to high performance concrete mix designs. Nano silica reacts with calcium hydroxide (CH) to develop more of the strength carrying structure of cement: calcium silica hydrate (CSH). In this paper, relationships have been developed to distinguish the benefits when using different sizes of nano silica in cement paste. An extensive regime of experimental analysis was carried out to determine the effect of nano silica. Through these experiments the heat of hydration of multiple cement mix designs was measured. After that, the concentration of CH was recorded …

Design Of Sea Water Heat Exchanger For Miniature Vapor Compression Cycle, James Hughes

Electronic Theses and Dissertations

Recent advances in the development of miniature vapor compression cycle components have created unique opportunities for heating and cooling applications, specifically to human physiological requirements that arise in extreme environments. Diving in very cold water between 1.7 and 5°C requires active heating because passive thermal insulation has proven inadequate for long durations. To maintain diver mobility and cognitive performance, it is desirable to provide 250 to 300 W of heat from an untethered power source. The use of a miniature vapor compression cycle reduces the amount of power (batteries or fuel cell) that the diver must carry by 2.5 times …

Droplet Flows In Microchannels Using Lattice Boltzmann Method, Amit Gupta

Electronic Theses and Dissertations

Microelectromechanical systems (MEMS) have widespread applications in medical, electronical and mechanical devices. These devices are characterized by the smallest dimension which is at least one micrometer and utmost one millimeter. Rapid progress in the manufacture and utilization of these microdevices has been achieved in the last decade. Current manufacturing techniques of such devices and channels include surface silicon micromachining; bulk silicon micromachining; lithography; electrodeposition and plastic molding; and electrodischarge machining (EDM). In recent years, electrostatic, magnetic, electromagnetic and thermal actuators, valves, gears and diaphragms of dimensions of hundred microns or less have been fabricated successfully. Sensors have been manufactured that …

Study Of The Effects Of Sodium And Absorber Microstructure For The Development Of Cuin1-Xgaxse2-Ysy Thin Film Solar Cell Using An Alternative Selenium Precursor, Vinaykumar Hadagali

Electronic Theses and Dissertations

Thin film solar cells have the potential to be an important contributor to the world energy demand in the 21st century. CuInGaSe2 thin film solar cells have achieved the highest efficiency among all the thin film technologies. A steady progress has been made in the research and development of CuInSe2 based thin film solar cells. However, there are many issues that need to be addressed for the development of CuInSe2 based thin films solar cells. High price of PV modules has been a biggest factor impeding the growth of photovoltaic modules for terrestrial application. This thesis tries to address the …

Effect Of Sodium And Absorber Thickness On Cigs2 Thin Film Solar Cells, Parag Vasekar

Electronic Theses and Dissertations

Chalcopyrites are important contenders among solar cell technologies due to direct band gap and higher absorption coefficient. CuIn1-xGaxS2 (CIGS2) thin-film solar cells are of interest for space power applications because of near optimum bandgap of 1.5 eV for AM0 solar radiation outside the earth's atmosphere. The record efficiency of 11.99% has been achieved on a 2.7 µm CIGS2 thin film prepared by sulfurization at FSEC PV Materials Laboratory. Since CIGS2 films are typically grown in copper-rich regime, excess cuprous sulfide which helps in the formation of CIGS2 is etched away. This makes CIGS2 nearly stoichiometric. However, it is difficult to …

Study Of Low Speed Transitional Regime Gas Flows In Microchannels Using Information Preservation (Ip) Method, Umit Kursun

Electronic Theses and Dissertations

Proper design of thermal management solutions for future nano-scale electronics or photonics will require knowledge of flow and transport through micron-scale ducts. As in the macro-scale conventional counterparts, such micron-scale flow systems would require robust simulation tools for early-stage design iterations. It can be envisioned that an ideal Nanoscale thermal management (NSTM) solution will involve two-phase flow, liquid flow and gas flow. This study focuses on numerical simulation gas flow in microchannels as a fundamental thermal management technique in any future NSTM solution. A wellknown particle-based method, Direct Simulation Monte Carlo (DSMC) is selected as the simulation tool. Unlike continuum …

Design And Performance Evaluation Of An Integrated Miniature Single Stage Centrifugal Compressor And Permanent Magnet Synchronous Motor, Dipjyoti Acharya

Electronic Theses and Dissertations

An attempt has been made in this present work to design, fabricate and performance evaluate an integrated single stage centrifugal compressor and permanent magnet synchronous motor which is a key component of the reverse brayton cycle cryocooler. An off the shelf compressor – the driven and electric motor – the driver was not available commercially to suffice the requirements of the reverse brayton cryocooler. The integrated compressor-motor system was designed and tested with air as the working fluid at mass flow rate of 7.3 grams per sec, with a compression ratio of 1.58 and driven by a 2 KW permanent …

Commissioning Of A Dynamic Mechanical Analyzerfor The Characterization Of Low Temperature Nitife Shape Memory Alloys, Maruthi Diwakar Nandiraju

Electronic Theses and Dissertations

NiTiFe shape memory alloys can undergo transformations between cubic, trigonal and monoclinic phases at low temperatures. The low hysteresis associated with the trigonal R-phase transformation make them candidates for actuator applications at low temperatures. However, the literature available on these alloys is limited and there is a need to establish processing structure-property correlations. This study was undertaken with the objective of determining and understanding such correlations in a Ni46.8Ti50Fe3.2 alloy. First, a dynamic mechanical analyzer (DMA) was successfully commissioned to facilitate mechanical testing between -150 and 600ºC. The experiments performed over selected ranges of stress and temperature probed a range …