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2021

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Articles 31 - 60 of 249

Full-Text Articles in Power and Energy

Prospect Of Harnessing Solar Energy, Offshore Wind Energy And Installing Liquid Air Energy Storage System To Power Chittagong Port And Design Of A Hybrid Power System, Muhammad Abul Basar Oct 2021

Prospect Of Harnessing Solar Energy, Offshore Wind Energy And Installing Liquid Air Energy Storage System To Power Chittagong Port And Design Of A Hybrid Power System, Muhammad Abul Basar

World Maritime University Dissertations

No abstract provided.


The Viability Of Solar Power Supply : A Feasibility Study Of Monkey Bay Maritime Base Port In Malawi, Josephine Ellah Kambale Oct 2021

The Viability Of Solar Power Supply : A Feasibility Study Of Monkey Bay Maritime Base Port In Malawi, Josephine Ellah Kambale

World Maritime University Dissertations

No abstract provided.


A Feasibility Study Of Sustanaible Offshore Wind Energy Development In Kenya, Kelvin Kinyosi Nyambegera Oct 2021

A Feasibility Study Of Sustanaible Offshore Wind Energy Development In Kenya, Kelvin Kinyosi Nyambegera

World Maritime University Dissertations

No abstract provided.


Renewable Energy Alternatives For Cargo Ships : Case Study Of Application Of Flettner Rotors Combined With Pv Panels On Bulk Carriers, Leopaul Singor Tamdjokouen Oct 2021

Renewable Energy Alternatives For Cargo Ships : Case Study Of Application Of Flettner Rotors Combined With Pv Panels On Bulk Carriers, Leopaul Singor Tamdjokouen

World Maritime University Dissertations

No abstract provided.


Performance And Mechanism Of PtXCuY/C Electrocatalyst For Methanol Oxidation, Jia Tang, Xiao-Ming Zhang, Shan-Sheng Yu, Su-Li Wang, Gong-Quan Sun Oct 2021

Performance And Mechanism Of PtXCuY/C Electrocatalyst For Methanol Oxidation, Jia Tang, Xiao-Ming Zhang, Shan-Sheng Yu, Su-Li Wang, Gong-Quan Sun

Journal of Electrochemistry

Direct methanol fuel cell (DMFC), which directly converts the chemical energy of methanol fuel into electrical energy, has the advantages of high energy conversion efficiency, environmental friendliness, and abundance of fuel sources. DMFC is considered as the promising substitutes in the field of portable devices, military applications, and stationary power stations, while the broad application is severely hindered by the sluggish kinetic of methanol oxidation reaction (MOR) in the anode and the high cost of platinum (Pt)-based anodic electrocatalysts. Herein, a series of carbon supported PtxCuy (PtxCuy/C) binary metal electrocatalysts, featured with high …


Electrochemical Synthesis Of P-(Β-Hydroxyethyl Sulfone) Aniline, Hao Guo, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang Oct 2021

Electrochemical Synthesis Of P-(Β-Hydroxyethyl Sulfone) Aniline, Hao Guo, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang

Journal of Electrochemistry

Para-ester is the most important intermediate for the preparation of ethylene sulfone type reactive dyes, which is usually used in the dyeing of cellulose fibers and synthetic fibers. P-(β-hydroxyethyl sulfone) aniline is an important intermediate for the synthesis of para-ester. In this paper, p-(β-hydroxyethyl sulfone) aniline was prepared by electrochemical method, having the advantages of simple process, mild reaction condition, less environmental pollution, easy reaction control and so on. It has strong development potential and industrial application prospect. The electrochemical reduction of p-nitrophenyl-β-hydroxyethyl sulfone on a lead plate electrode to prepare p-(β-hydroxyethyl …


Mathematical Expression And Quantitative Analysis Of Impedance Spectrum On The Interface Of Glassy Carbon Electrode, Lei Cheng, Pu-Xuan Yan, You-Jun Fan, Hua-Hong Zou, Hong Liang Oct 2021

Mathematical Expression And Quantitative Analysis Of Impedance Spectrum On The Interface Of Glassy Carbon Electrode, Lei Cheng, Pu-Xuan Yan, You-Jun Fan, Hua-Hong Zou, Hong Liang

Journal of Electrochemistry

Glassy carbon electrode (GCE) is a common basic electrode for various electrochemical sensors, and the detection properties are determined by its interfacial characteristics. In this paper, we established an equivalent circuit including electrolyte resistance (Rel), charge transport resistance (Rct), diffusion impedance (Rdi, Cdi), electrochemical (oxidation/reduction) reaction impedance (RR, CR), surface adsorption impedance (Rads , Cads), double-layer capacitance (CDL), and derived the mathematical expression for the equivalent circuit. The Rel and CDL are contributed by inactive …


Effect Of Alkyl Chain Length Of Symmetrical Quaternary Ammonium Hydroxide On Oxalic Acid Electroreduction Reaction, Bo Huang, Xin-Sheng Zhang, Dong-Fang Niu, Shuo-Zhen Hu Oct 2021

Effect Of Alkyl Chain Length Of Symmetrical Quaternary Ammonium Hydroxide On Oxalic Acid Electroreduction Reaction, Bo Huang, Xin-Sheng Zhang, Dong-Fang Niu, Shuo-Zhen Hu

Journal of Electrochemistry

Glyoxylic acid with the dual characteristics of acid and aldehyde is an important chemical raw material and organic synthesis intermediate, which is extensively used in the perfumery, pharmaceutical and fine chemical industries. A family of symmetric quaternary ammonium hydroxides (QAHs) with different alkyl chain lengths was used as the additives in generating glyoxylic acid from oxalic acid electroreduction reaction (OAER). The effects of alkyl chain length on OAER and the corresponding side reaction, i.e., hydrogen evolution reaction (HER), were investigated. Linear sweep voltammetric (LSV) results showed that the adsorption of the additives suppressed more on the HER than that on …


Synthesis Of Nickel Phosphide/Nitrogen Phosphorus Co-Doped Carbon And Its Application In Lithium Ion Batteries, Jian Hu, Yan-Shuang Meng, Qian-Ru Hu Oct 2021

Synthesis Of Nickel Phosphide/Nitrogen Phosphorus Co-Doped Carbon And Its Application In Lithium Ion Batteries, Jian Hu, Yan-Shuang Meng, Qian-Ru Hu

Journal of Electrochemistry

In recent years, the nickel-based phosphide has drawn great attention because of its low intercalation/deintercalation platform and lower polarization compared to sulfides and oxides as anodes for next-generation high-energy lithium-ion batteries. The Ni2P anode can deliver high theoretical specific capacity of 542 mAh·g-1, but it subject to a conversion reaction mechanism, which make them unsuitable for commercial applications. The agglomeration of Ni2P nanoparticles during material fabrication and the structural deterioration of electrode associated with large volume change during charge-discharge process lead to poor cycle stability and low utilization of active materials. Meanwhile, the low …


Virtual Power Plant Control For Large Residential Communities Using Hvac Systems For Energy Storage, Huangjie Gong, Evan S. Jones, Rosemary E. Alden, Andrew G. Frye, Donald G. Colliver, Dan M. Ionel Oct 2021

Virtual Power Plant Control For Large Residential Communities Using Hvac Systems For Energy Storage, Huangjie Gong, Evan S. Jones, Rosemary E. Alden, Andrew G. Frye, Donald G. Colliver, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Heating, ventilation, and air-conditioning (HVAC) systems use the most electricity of any household appliance in residential communities. HVAC system modeling facilitates the study of demand response (DR) at both the residential and power system levels. In this article, the equivalent thermal model of a reference house is proposed. Parameters for the reference house were determined based on the systematic study of experimental data obtained from fully instrumented field demonstrators. Energy storage capacity of HVAC systems is calculated and an equivalent state-of-charge is defined. The uniformity between HVAC systems and battery energy storage system is demonstrated by DR control. The aggregated …


Equivalent Electric And Heat-Pump Water Heater Models For Aggregated Community-Level Demand Response Virtual Power Plant Controls, Huangjie Gong, Tim Rooney, Oluwaseun M. Akeyo, Brian T. Branecky, Dan M. Ionel Oct 2021

Equivalent Electric And Heat-Pump Water Heater Models For Aggregated Community-Level Demand Response Virtual Power Plant Controls, Huangjie Gong, Tim Rooney, Oluwaseun M. Akeyo, Brian T. Branecky, Dan M. Ionel

Electrical and Computer Engineering Faculty Publications

Advanced control techniques may be used to establish a virtual power plant to regulate the operation of electric water heaters, which may be regarded as a “uni-directional battery” and a major component of a hybrid residential energy storage system. In order to estimate the potential of regulating water heaters at the aggregated level, factors including user behavior, number of water heaters, and types of water heaters must be considered. This study develops generic water heater load curves based on the data retrieved from large experimental projects for resistive electric water heaters (EWHs) and heat pump water heaters (HPWHs). A community-level …


Design Optimization And Experimental Study Of Coreless Axial-Flux Pm Machines With Wave Winding Pcb Stators, Peng Han, Damien Lawhorn, Yaser Chulaee, Donovin Lewis, Greg Heins, Dan M. Ionel Oct 2021

Design Optimization And Experimental Study Of Coreless Axial-Flux Pm Machines With Wave Winding Pcb Stators, Peng Han, Damien Lawhorn, Yaser Chulaee, Donovin Lewis, Greg Heins, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper presents a systematic design optimization and experimental study of coreless axial-flux permanent magnet (AFPM) machines with wave winding printed circuit board (PCB) stators. Existing PCB winding configurations are briefly reviewed and compared to serve as a performance reference. A new concept –the “macro coil”– is proposed to model PCB stator windings in 3D finite element analysis (FEA) to facilitate large-scale multi-objective optimization with the winding eddy current losses evaluated in each design candidate. The detailed trace-by-trace model for a selected optimal design is then built to check the voltage difference between parallel paths and the resulting circulating currents. …


Political Processes Of Displacement In Infrastructure Development: The Case Of Aldeia Da Luz And The Alqueva Dam, Cordelia Walz Oct 2021

Political Processes Of Displacement In Infrastructure Development: The Case Of Aldeia Da Luz And The Alqueva Dam, Cordelia Walz

Independent Study Project (ISP) Collection

In 2002, the residents of Aldeia da Luz left their village for the final time, displaced to make room for the Alqueva Dam, a massive regional hydropower and irrigation project almost half a century in the making. The Alqueva Multipurpose Project was marketed by the Portuguese government as a way to develop the impoverished region of the Alentejo and bring innovation to the agricultural sector. The village of Luz was the only physical obstacle to this goal and, therefore, its residents were dispossessed, sacrificed for the development of the greater Alentejo region. However, unlike many other large-scale infrastructure projects that …


Design Optimization Of A Very High Power Density Motor With A Reluctance Rotor And A Modular Stator Having Pms And Toroidal Windings, Peng Han, Murat G. Kesgin, Dan M. Ionel, Rohan Gosalia, Nakul Shah, Charles J. Flynn, Chandra Sekhar Goli, Somasundaram Essakiappan, Madhav Manjrekar Oct 2021

Design Optimization Of A Very High Power Density Motor With A Reluctance Rotor And A Modular Stator Having Pms And Toroidal Windings, Peng Han, Murat G. Kesgin, Dan M. Ionel, Rohan Gosalia, Nakul Shah, Charles J. Flynn, Chandra Sekhar Goli, Somasundaram Essakiappan, Madhav Manjrekar

Power and Energy Institute of Kentucky Faculty Publications

This paper proposes a new high power density permanent magnet (PM) motor design for traction applications to achieve the 50kW/L target set by the US Department of Energy by increasing the torque capability and operating speed compared to conventional PM machine topologies. A large-scale multi-objective design optimization based on 2D finite element analysis (FEA) and differential evolution algorithm was conducted to achieve the best trade-off among high efficiency, high power density and high power factor. The torque-speed envelopes are also checked for the Pareto front designs to make sure they have a constant power speed ratio of at least 3:1. …


Generalized Energy Storage Model-In-The-Loop Suitable For Energy Star And Cta-2045 Control Types, Huangjie Gong, Evan S. Jones, A. H. M. Jakaria, Aminul Huque, Ajit Renjit, Dan M. Ionel Oct 2021

Generalized Energy Storage Model-In-The-Loop Suitable For Energy Star And Cta-2045 Control Types, Huangjie Gong, Evan S. Jones, A. H. M. Jakaria, Aminul Huque, Ajit Renjit, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

The paper proposes a generalized energy storage (GES) model for battery energy storage systems (BESS), electric water heaters (EWH) and heating, ventilation, and air-conditioning (HVAC) systems. The analogies, including state of charge versus water temperature differential, are identified and explained, and models-in-the-loop (MIL) are introduced, which are compatible with the Energy Star and CTA-2045 general specifications and command types. Emphasis is placed on the proposed EWH model as it needfully fulfills a gap in present literature. The corresponding MIL has been implemented in the DER integration testbed, which was originally developed by EPRI, and satisfactorily validated against experimental results. A …


On The Modeling Of Bearing Voltage And Current In Pwm Converter-Fed Electric Machines Using Electromagnetic Finite Element Analysis, Peng Han, Yibin Zhang, Murat G. Kesgin, Greg Heins, Dean Patterson, Mark Thiele, Dan M. Ionel Oct 2021

On The Modeling Of Bearing Voltage And Current In Pwm Converter-Fed Electric Machines Using Electromagnetic Finite Element Analysis, Peng Han, Yibin Zhang, Murat G. Kesgin, Greg Heins, Dean Patterson, Mark Thiele, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Bearing voltages and resulting currents in electric machines driven by PWM converters with fast switching and high dv/dt can cause premature bearing failures. With the transition from conventional Si devices to wide bandgap (WBG) devices and increase in switching frequency, bearing voltages and currents become more significant and need to be addressed from the early design stage. This paper proposes to use coupled field-circuit electromagnetic finite element analysis (FEA) to model bearing voltage and current in electric machines, which takes into account the influence of distributed winding conductors and frequency-dependent winding RL parameters. The three known bearing current types are …


Improving The Power Outage Resilience Of Buildings With Solar Pv Through The Use Of Battery Systems And Ev Energy Storage, Huangjie Gong, Dan M. Ionel Sep 2021

Improving The Power Outage Resilience Of Buildings With Solar Pv Through The Use Of Battery Systems And Ev Energy Storage, Huangjie Gong, Dan M. Ionel

Electrical and Computer Engineering Faculty Publications

Buildings with solar photovoltaic (PV) generation and a stationary battery energy storage system (BESS) may self-sustain an uninterrupted full-level electricity supply during power outages. The duration of off-grid operation is dependent on the time of the power fault and the capabilities of the home energy management system (HEMS). In this paper, building resilience is quantified by analyzing the self-sustainment duration for all possible power outages throughout an entire year. An evaluation method is proposed and exercised on a reference house in California climate zone 9 for which the detailed electricity usage is simulated using the EnergyPlus software. The influence of …


Power Factor And Reactive Power In Us Residences – Survey And Energyplus Modeling, Hope C. Anderson, Abdullah Al Hadi, Evan S. Jones, Dan M. Ionel Sep 2021

Power Factor And Reactive Power In Us Residences – Survey And Energyplus Modeling, Hope C. Anderson, Abdullah Al Hadi, Evan S. Jones, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Electric power systems are experiencing a growing number of electronic loads in the residential sector as modern appliance technology progresses, and it has become increasingly more important to consider the total power factor (PF) of residential communities. This paper provides a survey based on literature and publicly available information of typical appliance PF values and effects at the residential level as well as a discussion on appliance energy use and corresponding operation schedules. A procedure for the calculation of equivalent PF is proposed and exemplified with minutely experimental data at 15-minute and hourly time intervals, which correspond to smart metering …


Application Of Artificial Neural Networks To Power System State Estimation, James P. Carmichael, Yuan Liao Aug 2021

Application Of Artificial Neural Networks To Power System State Estimation, James P. Carmichael, Yuan Liao

Electrical and Computer Engineering Presentations

State estimation function is essential for effective and timely execution of power system automation and control systems, especially in modern active distribution systems where more intermittent renewable energy systems are integrated into the grid. Distribution system state estimation faces a lot of challenges including lack of monitoring devices and possible incorrect topology information. Developing efficient state estimation for distribution systems is thus of great interest. This paper presents results on utilizing artificial neural networks for this purpose.

Artificial neural networks have been used in power distribution system state estimation. However, there is a lack of systematic analysis and study of …


Zip Load Modeling For Single And Aggregate Loads And Cvr Factor Estimation, Yiqi Zhang, Yuan Liao, Evan S. Jones, Nicholas Jewell, Dan M. Ionel Aug 2021

Zip Load Modeling For Single And Aggregate Loads And Cvr Factor Estimation, Yiqi Zhang, Yuan Liao, Evan S. Jones, Nicholas Jewell, Dan M. Ionel

Electrical and Computer Engineering Presentations

ZIP load modeling has been used in various power system applications. The aggregate load modeling is common practice in utility companies. However, little research has been done on the theoretical formulation of the aggregate load. This paper formulates the aggregate ZIP load model using the single ZIP load model. The factors that may affect aggregate ZIP load estimation are studied. Common ZIP parameter estimation methods including least squares method, optimization method and neural network method have been used in this paper to estimate ZIP parameters. The case studies are based on the IEEE 13-bus and 34-bus system built in OpenDSS. …


Dft Study Of NiM@Pt1AuN-M-1 (N=19, 38, 55, 79; M = 1, 6, 13, 19) Core-Shell Orr Catalyst, Wen-Jie Li, Dong-Xu Tian, Hong Du, Xi-Qiang Yan Aug 2021

Dft Study Of NiM@Pt1AuN-M-1 (N=19, 38, 55, 79; M = 1, 6, 13, 19) Core-Shell Orr Catalyst, Wen-Jie Li, Dong-Xu Tian, Hong Du, Xi-Qiang Yan

Journal of Electrochemistry

The slow kinetics of oxygen reduction reaction (ORR) limits the performance of low temperature fuel cells. Thus, it needs to design effective catalysts with low cost. Core-shell clusters (CSNCs) show promising activity because of their size-dependent geometric and electronic effects. The ORR activity trend of Nim@Pt1Aun-m-1(n = 19, 38, 55, 79; m = 1, 6, 13, 19) was studied using the GGA-PBE-PAW methods. The adsorption configurations of *O, *OH and *OOH were optimized and the reaction free energies of four proton electron (H+ + e-) transfer steps …


One-Pot Synthesis Of Fe2O3@Fe-N-C Oxygen Reduction Electrocatalyst And Its Performance For Zinc-Air Battery, Hua Lin, Yi-Jin Wu, Jun-Tao Li, Yao Zhou Aug 2021

One-Pot Synthesis Of Fe2O3@Fe-N-C Oxygen Reduction Electrocatalyst And Its Performance For Zinc-Air Battery, Hua Lin, Yi-Jin Wu, Jun-Tao Li, Yao Zhou

Journal of Electrochemistry

Oxygen reduction reaction (ORR) plays a profound role in determining cathode performance in metal-air batteries and fuel cells. Owing to its inherently sluggish kinetics, high-performance ORR catalysts which favors the scissoring of O-O bond and formation of O-H bond are a requisite. In this regard, Pt has been explored as the most efficient ORR electrocatalysts. Nevertheless, due to its expensiveness, the usage of Pt catalysts represents one of the major sources of cost in those energy conversion devices. Thus, the development of alternative ORR electrocatalysts with minimized Pt utilization has been widely pursued over the past few decades. Metal-nitrogen-carbon catalysts …


Study On Mxene-Carbon Black/Sulfur Composite In Integrated Electrode Of Lithium-Sulfur Batteries, Ye-Peng Fan, Ye-Qiang Luo, Pei-Kang Shen Aug 2021

Study On Mxene-Carbon Black/Sulfur Composite In Integrated Electrode Of Lithium-Sulfur Batteries, Ye-Peng Fan, Ye-Qiang Luo, Pei-Kang Shen

Journal of Electrochemistry

Lithium-sulfur (Li-S) batteries are considered as a promising energy storage device due to their ultrahigh theoretical energy density of 2500 Wh·kg-1 and low cost. However, the practical application of Li-S batteries is seriously limited by their low actual energy density, the shuttle effect of polysulfides (LiPSs), and the insulating nature of sulfur and lithium sulfides. Carbon materials have been developed in the design of sulfur hosts due to their adjustable pore structure and high electrical conductivity, but their non-polar surfaces have weak interactions with LiPSs. Herein, MXene-carbon black/sulfur (Ti3C2Tx-CB/S) composites were prepared and …


Preparation And Electrochemical Evaluation Of Mos2/Graphene Quantum Dots As A Catalyst For Hydrogen Evolution In Microbial Electrolysis Cell, Hong-Yan Dai, Hui-Min Yang, Xian Liu, Xiu-Li Song, Zhen-Hai Liang Aug 2021

Preparation And Electrochemical Evaluation Of Mos2/Graphene Quantum Dots As A Catalyst For Hydrogen Evolution In Microbial Electrolysis Cell, Hong-Yan Dai, Hui-Min Yang, Xian Liu, Xiu-Li Song, Zhen-Hai Liang

Journal of Electrochemistry

Microbial electrolysis cell (MEC) is a relatively new bioelectrochemical technology that produces H2 and meanwhile treats organic wastewater. Cathode hydrogen evolution catalyst plays a key role in MEC. The doping of Graphene Quantum Dots (GQDs) into MoS2 nanosheets can improve the catalytic activity of MoS2 by creating abundant defect sites both in the edge plane and the basal plane, as well as enhancing the electrical conductivity. In this paper, using Na2MoO4 , cysteine and GQDs as raw materials, a series of MoS2/GQDs composites were firstly synthesized via hydrothermal method, and then loaded …


Preparation Of Coo/Rgo@Ni Foam Electrode And Its Electrocatalytic Reduction Of Co2, Qian Guo, Jia-Long Fu, Cheng-Yan Zhang, Chao-Yue Cai, Cheng Wang, Li-Hua Zhou, Rui-Bo Xu, Ming-Yan Wang Aug 2021

Preparation Of Coo/Rgo@Ni Foam Electrode And Its Electrocatalytic Reduction Of Co2, Qian Guo, Jia-Long Fu, Cheng-Yan Zhang, Chao-Yue Cai, Cheng Wang, Li-Hua Zhou, Rui-Bo Xu, Ming-Yan Wang

Journal of Electrochemistry

The worldwide extensive release of carbon dioxide (CO2) has caused serious environmental pollution and unprecedented climate change problems. Thus, for the sustainable development of human society, it is very necessary to convert CO2 to renewable fuels through clean and economical processes. The electrochemical CO2 reduction reaction (CO2RR) is regarded as a promising approach for the recycling of carbon resource and the generation of sustainable fuels. However, the slow kinetics and formation of multiple products in CO2RR hinder its large-scale application. Hence, great research efforts are made to develop electrocatalysts with high product …


Preparation Of 3d Semi-Interpenetrated Polymer Networks Polymer Electrolyte For Lithium Metal Battery, Yun-Feng Zhang, Jia-Ying Wang, Xiao-Jie Li, Shi-Yu Zhao, Yang He, Shi-Kang Huo, Ya-Ying Wang, Chang Tan Aug 2021

Preparation Of 3d Semi-Interpenetrated Polymer Networks Polymer Electrolyte For Lithium Metal Battery, Yun-Feng Zhang, Jia-Ying Wang, Xiao-Jie Li, Shi-Yu Zhao, Yang He, Shi-Kang Huo, Ya-Ying Wang, Chang Tan

Journal of Electrochemistry

As the next generation high-energy batteries, lithium metal battery has attracted more and more attention due to its highest specific capacity (3860 mA·h·g-1) and the lowest anode potential (-3.04 V versus the standard hydrogen electrode, SHE). However, the safety problem caused by lithium dendrite growth is one of the biggest challenges for the commercialization of lithium metal batteries. Single ion conducting polymer electrolytes, which deliver high lithium ion transference number, represent one of the important strategies to inhibit lithium dendrite growth. However, the poor compatibility with electrodes and low ionic conductivity largely limit their practical application. In the …


Study On Inhibition Of Lithium Dendrite Growth By Mg(No3)2 Additive In Carbonate Electrolyte, Biao Zhang, Yi Shuai, Yu Wang, Na-Chuan Yang, Kang-Hua Chen Aug 2021

Study On Inhibition Of Lithium Dendrite Growth By Mg(No3)2 Additive In Carbonate Electrolyte, Biao Zhang, Yi Shuai, Yu Wang, Na-Chuan Yang, Kang-Hua Chen

Journal of Electrochemistry

In the lithium-sulfurized polyacrylonitrile battery system, the formation and growth of lithium dendrites in the negative electrode seriously deteriorate the charge and discharge performance of the battery. If the growth of lithium dendrites pierces the separator and causes thermal runaway, it will also bring serious damage to the battery, causing potential safety risks. In the carbonate electrolyte that is more conducive to stabilizing the positive electrode sulfurized polyacrylonitrile material, the growth of lithium dendrites is particularly serious. In this paper, magnesium nitrate was added to the carbonate electrolyte to investigate the combined effect of nitrate and magnesium ions on the …


A Comparison In Structural Transformation Of Li[NiXCoYMnZ]O2 (X = 0.6, 0.85) Cathode Materials In Lithium-Ion Batteries, Li-Juan Li, Zhen-Dong Zhu, Juan Dai, Rong-Rong Wang, Wen Peng Aug 2021

A Comparison In Structural Transformation Of Li[NiXCoYMnZ]O2 (X = 0.6, 0.85) Cathode Materials In Lithium-Ion Batteries, Li-Juan Li, Zhen-Dong Zhu, Juan Dai, Rong-Rong Wang, Wen Peng

Journal of Electrochemistry

In this paper, the phase transformation voltage ranges of two layered oxide ternary cathode materials, namely, Li(Ni0.85Co0.10Mn0.05)O2 (referred to Ni85, presenting high Ni content) and Li(Ni0.6Co0.2Mn0.2)O2 (referred to Ni60, presenting common low Ni content), were classified and determined. The structural differences between high Ni and common low Ni ternary materials were studied in order to understand the structure instability of high nickel material during the charging process. At the same time, the differential capacity (dQ·dV-1) curves of Ni85 and Ni60 positive …


Effect Of Conductive Additives On Electrochemical Performance Of All-Solid-State Li-S Batteries, Dong-Hao Wang, He-Feng Yan, Zheng-Liang Gong Aug 2021

Effect Of Conductive Additives On Electrochemical Performance Of All-Solid-State Li-S Batteries, Dong-Hao Wang, He-Feng Yan, Zheng-Liang Gong

Journal of Electrochemistry

All-solid-state lithium sulfur batteries (ASSLSBs) with inorganic solid electrolytes offer an opportunity to realize both high energy density (lithium metal ~ 3860 mAh·g-1, sulfur ~ 1675 mAh·g-1), safety and reliability, via eliminating the polysulfides shuttle effect and flammable liquid electrolyte. However, it still remains a huge challenge for ASSLSBs to achieve high areal active mass loading, high utilization efficiency of the active materials and good cycle stability simultaneously due to the insulating nature of sulfur and Li2S (conductivities of sulfur and Li2S are 5×10-30 S·cm-1 and 3.6×10-7 S·cm-1 …


Storage Performance And Mechanism Of Mose2 Nanospheres In Lithium And Magnesium Ion Batteries, Yi Peng, Wei Zhang, Fang-Zhen Zuo, Hao-Ying Lv, Kai-Jun Hong Aug 2021

Storage Performance And Mechanism Of Mose2 Nanospheres In Lithium And Magnesium Ion Batteries, Yi Peng, Wei Zhang, Fang-Zhen Zuo, Hao-Ying Lv, Kai-Jun Hong

Journal of Electrochemistry

Molybdenum diselenide (MoSe2) is a two-dimensional (2D) transition metal dichalcogenide (TMD) material, attracting wide attention in lithium ion battery (LIB) and exhibiting great potential in next-generation magnesium ion battery (MIB) due to its unique layered structure with fast ion mobility and weak van der Waals interlayer interaction. However, the reported literatures related to MoSe2 mainly focus on the enhancement of performance in LIB without deep storage mechanisms investigations. Meanwhile,the magnesium storage capacity and mechanisms have not been explored. In this work, MoSe2 nanospheres were synthesized via wet chemical route and followed by annealing treatment. When used …