Power and Energy Commons^™

Research Progress In Cycle Stability Of Silicon Based Li-Ion Battery Anodes, Ze-Liang Guo, Hui Wu

Journal of Electrochemistry

Silicon(Si), with the highest specific capacity currently known, is a promising anode material for Li-ion battery. However, in the charging and discharging process, with Li atoms inserting into and breaking out of the Si crystal lattices, the Si anode undergoes enormous volume expansion and contraction, ending in pulverization. The fact that the specific capacity of bulk Si anodes drop quickly is a challenging problem. In this review, we summarize recent progresses in Si anode. We concern about the nanostructure of silicon, cooperation of silicon with other additives and macrostructure design of anodes. We discuss strengths and shortcomings of different methods, …

Electrochemical Performance Of Crystalline Li12Si7 As Anode Material For Lithium Ion Battery, Ya-Xiong Yang, Rui-Jun Ma, Ming-Xia Gao, Hong-Ge Pan, Yong-Feng Liu

Journal of Electrochemistry

Crystalline Li₁₂Si₇ is successfully synthesized by heating the mixture of LiH and Si with a molar ratio of 12:7, which avoids the huge difference of the melting points between Li and Si. The electrochemical performance and lithium storage mechanism of the as-prepared Li12Si7 are studied in this work. It is found that only a change in cell volume takes place without a phase change during the lithiation/delithiation of Li₁₂Si₇ at a voltage range of 0.02 ~ 0.6 V, exhibiting a solid-solution lithium storage mechanism. Such a lithium storage process effectively retards the volume effect …

Continuous Synthesis And Condition Exploration Of Precursor Ni1/3Co1/3Mn1/3(Oh)2 Ternary Cathode Material, Zhi-Jun Jiang, Ya-Li Zhang, Qian Wang, Hui Zhang

Journal of Electrochemistry

Commercial LiNi_1/3Co_1/3Mn_1/3(OH)₂ ternary material is generally prepared by a combination of co-precipitation and solid state reaction method. The particle size distribution and morphology of Ni_1/3Co_1/3Mn_1/3(OH)₂ precursor have a great impact on the electrochemical performance of LiNi_1/3Co_1/3Mn_1/3O₂. In this work, the precursor Ni_1/3Co_1/3Mn_1/3(OH)₂ ternary cathode material was prepared by co-precipitation method with MnSO₄, NiSO₄, and CoSO₄ as raw materials, NaOH as a precipitating agent and NH_{3 …}

The Study Of Dynamical Electrochemical Impedance Spectroscopy For Oxygen Reduction Reaction On Pt/C Catalyst, Kun-Ming Shi, Jian-Wei Guo, Jia Wang

Journal of Electrochemistry

With joint techniques of rotating disc electrode(RDE) and electrochemical impedance spectroscopy(EIS), and further establishment on equivalent circuit model, this paper studied oxygen reduction reaction(ORR) on commercial Pt/C catalyst in acid medium. Our results found that the dynamical interface on Pt/C consists of two independent processes: 1) the PtO reduction from Pt surface, 2) the new PtO formation from ORR, thus providing key clues for catalyst stability and activity. This also implied that the dynamical interface facilitates reconstruction for porous electrode, and matches with mass transfer. One important issue is discovered that at high overpotential, the high reaction rate for ORR …

Design And Implementation Of Ccny Dc Microgrid Testbed, Mahmoud Saleh, Yusef Esa, Yassine Mhandi, Werner Brandauer, Ahmed Mohamed

Publications and Research

This paper presents the design, control, energy management, and implementation of the City College of New York (CCNY) direct current (DC) microgrid laboratory testbed. This facility was custom designed and implemented by researchers at CCNY with minimal off-the-shelf components to enable significant flexibility and reconfiguration capability. The microgrid consists of renewable energy resources, energy storage system and controllable loads, and can operate in either a grid-connected or an islanded mode. The design steps, requirements, and results of the developed testbed were discussed. Moreover, several operational scenarios were tested. The experimental results verify the applicability and flexibility of the developed microgrid …

Plasticized Polymer Coatings For Sh-Saw Sensors For High Sensitivity And Long-Term Monitoring Of Btex Analytes In Liquid Phase, Pintu Adhikari

Master's Theses (2009 -)

BTEX compounds (benzene, toluene, ethylbenzene, and xylene) are constituents of crude oil and hazardous to human health. Among them, benzene has the lowest maximum contaminant level for drinking water because of its carcinogenicity. Spills or leakage from underground storage tanks or hazardous waste sites can contaminate nearby groundwater with these volatile organic compounds. Therefore, it is very important to detect the presence of BTEX contamination as early as possible in order to start the remediation process and maintain a healthy environment. To develop an in-situ continuous monitoring sensor system, shear horizontal surface acoustic wave (SH-SAW) sensor devices are being investigated …

Configuring The Urban Smart Grid: Transitions, Experimentation, And Governance, Anthony Michael Levenda

Dissertations and Theses

In the face of challenges of energy security, decarbonization, resilience, and the replacement of aging infrastructure systems, federal, state, and local actors are facilitating the development of smart electricity networks to transition towards a more sustainable electricity system. In the United States, development of "smart grids" is being pursued as a national policy mandate and goal, promising that the deployment of smart grid technologies -- referring in general to digital information and communication technologies that sense, monitor, control and manage the electric grid -- will make electricity systems more environmentally sustainable and reliable, and at the same time, provide opportunities …

Energy Managment Of Photovoltaic Charging Station (Pv-Cs) For Green University Campus Transportation, Ayda Esfandyari, Brian Norton, Michael Conlon, Sarah Mccormack

Conference Papers

Battery Electric Vehicles (BEVs) have been recognised as the ideal solution for lowering the CO₂ emissions in the transport sector and helping to achieve a sustainable future. When BEV technology is leveraged with a solar energy source such as a Photovoltaic Charging Station (PV-CS), the CO₂ saving potential is extended to both generation and consumption points. Due to the intermittent nature of our solar resource, once the PV-CS is combined with a storage unit, energy production is achieved without risking the disruption to power supply reliability and quality. Technological University Dublin (DIT) has recognised the viability of this …

Technological Assessment Of Different Solar-Biomass Systems For Hybrid Power Generation In Europe, C. M. Iftekhar Hussain, Brian Norton, Aidan Duffy

Articles

Solar Tower thermal (ST), Parabolic Trough thermal (PT), Linear Fresnel thermal (LF) and Solar PV are discussed in the context of suitability for hybridization with biomass in Europe. Technical, economical and climate data have been compared to identify the key drivers of technology selection in setting up large scale solar-biomass hybrid power plants. The sole solar-biomass hybrid power plant is currently in operation in Spain uses PT technology due to its performance characteristics, comparatively easy installation process compared to ST and relatively higher heat and optical gain than LF. The climate condition in the EU shows that the region within …

On The Feasibility Of Carbon Nanotube Windings For Electrical Machines — Case Study For A Coreless Axial Flux Motor, Vandana Rallabandi, Narges Taran, Dan M. Ionel, John F. Eastham

Power and Energy Institute of Kentucky Faculty Publications

The latest developments in carbon nanotube (CNT) wires and yarns attract great interest for potential application to electromagnetic devices, such as electrical machines and transformers. The CNT material properties are largely different from copper and aluminum in terms of electrical conductivity, mass density, and thermal transfer, creating a new design paradigm for which the traditional rules and device topologies no longer apply. This paper proposes a brushless permanent magnet multidisc axial flux construction with coreless stator and special windings and minimal rotor back iron, as a suitable topology for CNT winding application. Specific analytical closed-form sizing equations, as a function …

Capture And Recycle Of Industrial Co2 Emissions Using Mircoalgae, Michael H. Wilson, Daniel T. Mohler, John G. Groppo, Thomas E. Grubbs, Stephanie Kesner, E. Molly Frazar, Aubrey Shea, Czarena L. Crofcheck, Mark Crocker

Center for Applied Energy Research Faculty and Staff Publications

A novel cyclic flow photobioreactor (PBR) for the capture and recycle of CO₂ using microalgae was designed and deployed at a coal-fired power plant (Duke Energy’s East Bend Station). The PBR was operated continuously during the period May–September 2015, during which algae productivity of typically 0.1–0.2 g/(L day) was obtained. Maximum CO₂ capture efficiency was achieved during peak sunlight hours, the largest recorded CO₂ emission reduction corresponding to a value of 81 % (using a sparge time of 5 s/min). On average, CO₂ capture efficiency during daylight hours was 44 %. The PBR at East Bend …

Theoretical Study Of Photoelectrochemical Reactions And Ec-Sers On Spr Metallic Electrodes Of Silver And Gold, Yuan-Fei Wu, Ran Pang, Meng Zhang, Jian-Zhang Zhou, Bin Ren, Zhong-Qun Tian, De-Yin Wu

Journal of Electrochemistry

At present photoelectrochemistry has received much concern back to nanostructures of noble metals from semiconductor electrodes. This is due to the surface plasmon resonance (SPR) effect of metallic nanostructures, which can effectively convert the far-field light to the near-field light and concentrate the photonic energy to the local surface area with high energy density. Thus, the different enhancement mechanisms, such as the local optical field enhancement, the formation of light generated hot carriers (hot electron-hole pairs), or the photothermal effect, have been proposed in literatures. On the basis of the SPR enhancement effect, the surface-enhanced Raman spectroscopy (SERS) can be …

Photoelectrochemical Water Splitting Cells: Methods For Improving Performance Of Electrodes And Recent Progress On Photocathodes, Kai-Jian Zhu, Wen-Jun Luo, Zhong-Jie Guan, Xin Wen, Zhi-Gang Zou, Wei Huang

Journal of Electrochemistry

Photoelectrochemical water splitting can convert solar energy into hydrogen which is an ideal way to utilize and store solar energy. A p-n tandem cell is considered as the most promising solar water splitting cell due to its high theory conversion efficiency, low cost and photoelectrode material flexibility. However, solar conversion efficiency of a tandem cell is still low in the experiment because of poor performance in a single photoelectrode. In this review, we have introduced some effective approaches to improve the performances of photoelectrodes by reducing recombination of photogenerated carriers in the bulk or on the surface, and suppressing back …

Preparations And Photoelectrochemical Properties Of Phosphate Modified Rgo-Biobr Nanocomposites, Shuang-Ying Chen, Zhi-Jun Li, Xu-Liang Zhang, Kang Hu, Rui Yan, Li-Qiang Jing

Journal of Electrochemistry

The RGO-BiOBr nanocomposites have been successfully synthesized by a hydrothermal process, and then modified with phosphorous acids. The photoelectrochemical properties of the fabricated RGO-BiOBr nanocomposite films were studied. The results indicate that the photocurrent densities of RGO-BiOBr were much larger compared with those of the bare BiOBr, and interestingly, the photocurrent densities were further improved after phosphate modification. Based on the analyses of the produced hydroxyl radical amounts, the enhanced photocurrent densities could be attributed to the introduction of RGO and to the formed negative fields of modified phosphate groups, which are favorable for electrons to be transferred and for …

Cathode Buffer Layer For Improving Photovoltaic Performance Of Planar P-I-N Perovskite Solar Cells, Xiao-Dong Liu, Yong-Fang Li

Journal of Electrochemistry

Organic/inorganic hybrid metal halide perovskite semiconductor materials have drawn great attention for the application in solar cells in recent years because of their combined superior photoelectrical properties of inorganic semiconductors (with high dielectric constant and high charge carriers mobility) and organic semiconductors (with good solution processability and high absorbance). The power conversion efficiency (PCE) of the organometal halide perovskite solar cells (pero-SCs) based on CH₃NH₃PbI₃ has been increased dramatically in a few years from 3.8% to a certified 22.1%, primarily owing to the development of new interfacial materials, careful optimization of morphology, and perovskite crystallization …

Special Issue: Photoelectrochemistry And New Types Of Solar Cells, Chang-Jian Lin, Yong-Fang Li

Journal of Electrochemistry

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Application Of Metal-Organic Frameworks In Dye-Sensitized Solar Cells, Ya-Feng Li, Qing-Qing Sun, Ming-Deng Wei

Journal of Electrochemistry

To assemble dye-sensitized solar cells (DSSCs) with high efficiencies, their photoanodes should have large specific surface area to establish a large adsorption amount of dyes and good light-harvesting ability. From this point of view, it will be an interesting topic to explore the application of metal-organic frameworks (MOFs) in the field of DSSCs due to their huge specific surface area. This paper introduces the application of MOFs in photovoltaic devices briefly, and then summaries our approaches in using MOFs in the study of DSSCs, including the pre-treatment and the post-treatment of photoanode, the preparation of photoanode materials and the light …

Prospects Of D-Π-A Structured Porphyrins And Their Photoelectrochemical Application, Shuang-Shuang Liu, Jian-Feng Lu, Ming-Kui Wang

Journal of Electrochemistry

Porphyrins and their metalloderivatives are a class of compounds exhibiting a wide variety of interesting and highly useful properties, such as chlorophyll. Porphyrins are particularly interesting in photoelectrochemical applications due to their structural similarity to chlorophylls in natural photosynthetic systems, as well as their strong and tunable absorption properties. Recently, various porphyrins have been extensively studied for their applications in solar cells, photocatalytic hydrogen production, optical information storage and others. This review will focus on the unique physical and chemical properties of D-π-A structured porphyrins, and their photovoltaic performances in dye-sensitized solar cells. A brief discussion in the future development …

Activation Effect Of Nano-Carbon Derived From Co2 On Lead Electrode In Sulfuric Aqueous Solution, Yu-Qiao Song, Hua Zhu, Guang-Jin Zhao, Wen-Long Wu, Shou-Bin Zhou, Di-Hua Wang

Journal of Electrochemistry

Serious sulfation of the negative plate is one of the most popular reasons of the early failure of lead-acid battery. Addition of nano-carbon was proved to be effective for recovering the sulfated electrode and the property of the carbon material always plays an important role. In this work, a new kind of nano-carbon material with high electrical conductivity and good adsorption capability for heavy metal cations, which is electrochemically prepared from CO₂ in molten carbonates, was tested as activation additive for the sulfated lead electrode by cyclic voltammetry and SEM measurements. The results showed that the as-prepared carbon can …

Hydrothermal One-Step Synthesis Of Layered Nickel/Cobalt Double Hydroxide With Using Shape-Directing Agent And Homogeneous Precipitating Agent, Li-Wei Zhu, Yun-Hai Yan, Hui Jia, Run-Fen Liang

Journal of Electrochemistry

Nickel/cobalt double hydroxide (Ni/Co-DH) has been prepared by facile hydrothermal one-step synthesis method using hexamethylene tetramine (HMT) as a homogeneous precipitating agent and cetyltrimethylammonium bromide (CTAB) as a shape-directing agent. With the hydrolysis of HMT and the use of CTAB, the Ni/Co-DH could be synthesized without additional alkali source, and in the meantime, the Ni/Co-DH exhibited a controlled mesopore size of 13.4 nm and a large BET surface area of 93.6 m² •g^-1 . The X-ray diffraction (XRD) pattern displays that the Ni/Co-DH existed as a mixture of α-Ni(OH)₂-β-Co(OH)₂. The scanning electron microscope (SEM) …

Large Scale Monolithic Solar Panel Simulation - A Study On Partial Shading Degradation, Suhas V. Baddela, Xingshu Sun, Muhammad A. Alam

The Summer Undergraduate Research Fellowship (SURF) Symposium

Shadow-induced degradation is a major concern for both power output and long-term reliability in solar cells. Apart from the obvious fact that shading reduces the amount of solar irradiance available to solar panels, it may lead to formation of hot spots, where solar cells are forced to reverse breakdown with localized heating, and potentially, permanent damage. To get a better understanding of shadow-induced degradation, we develop an electro-thermal coupled simulator that can self-consistently solve the electrical and thermal distributions of solar panel under arbitrary shading conditions. The simulation framework consists of two part: a) compact models that can describe the …

Advanced Microwave Remote Sensing, David Long

BYU Research Development Office Research Networking Conference

New Techniques for reconstruction SIR/AVE optimized for ASCAR. Bayes estimator selection to optimally select between wind-only, and rain-only correction

The Influence Of The Electric Supply Industry On Economic Growth In Less Developed Countries, Edward Richard Bee

Dissertations

This study measures the impact that electrical outages have on manufacturing production in 135 less developed countries using stochastic frontier analysis and data from World Bank’s Investment Climate surveys. Outages of electricity, for firms with and without backup power sources, are the most frequently cited constraint on manufacturing growth in these surveys.

Outages are shown to reduce output below the production frontier by almost five percent in Africa and by a lower percentage in South Asia, Southeast Asia and the Middle East and North Africa. Production response to outages is quadratic in form. Outages also increase labor cost, reduce exports …

Determining The Power And Energy Capacity Of A Battery Energy Storage System Utilizing A Smoothing Feeder Profile To Accommodate High Photovoltaic Penetration On A Distribution Feeder, Osama Mohammed Abbas Aly Mansour

Dissertations and Theses

Electricity is a perishable commodity; once it is generated it needs to be consumed or stored. Electric energy storage provides both power and energy capacity. Power capacity applications reduce the need for generation, while energy capacity allows for energy consumption to be decoupled from generation. Previous research was done to develop an algorithm for determining the power (MW) and energy (MWh) capacities of a battery energy storage system (BESS) to mitigate the adverse impacts of high levels of photovoltaic (PV) generation. The algorithm used a flat feeder profile, and its performance was demonstrated on the equinoxes and solstices.

Managing feeder …

Loss Model For Gallium Nitride Dc-Dc Buck Converter, Rushi Patel, Daniel Costinett

BCoE Publications

In recent years, more research has been done on Enhancement Mode Gallium Nitride (eGaN) converters as the world is moving towards more power efficient converters. The process to make converters more efficient was complicated and slow in the twentieth century. With help of simulation tools such as MATLAB and LTspice, this process has become much faster and reliable in the modern era. In order to make this process even faster, one of the important aspects in power electronics is to evaluate different losses in the converter. A model for estimating power losses for eGaN DC-DC buck converter (12V/1.2V) is illustrated …

Large-Scale Optimization Of Synchronous Reluctance Machines Using Ce-Fea And Differential Evolution, Yi Wang, Dan M. Ionel, Vandana Rallabandi, Minjie Jiang, Steven Stretz

Power and Energy Institute of Kentucky Faculty Publications

A novel automated design optimization procedure based on the application of an ultrafast computationally efficient finite-element analysis (CE-FEA) for current-regulated synchronous reluctance machines supplied from power electronic converters is proposed. The CE-FEA uses only a minimum number of magnetostatic solutions in order to comprehensively evaluate performance, including ripple torque and core losses. The optimization algorithm is based on differential evolution, and uses as independent variables the torque angle and ratios for a generic rotor topology with four flux barriers. Two problems, one with two and the other with three objectives, are studied and results are compared. Global performance indices and …

Wake Character In The Wind Turbine Array: (Dis-)Organization, Spatial And Dynamic Evolution And Low-Dimensional Modeling, Nicholas Michael Hamilton

Dissertations and Theses

To maximize the effectiveness of the rapidly increasing capacity of installed wind energy resources, new models must be developed that are capable of more nuanced control of each wind turbine so that each device is more responsive to inflow events. Models used to plan wind turbine arrays and control behavior of devices within the farm currently make questionable estimates of the incoming atmospheric flow and update turbine configurations infrequently. As a result, wind turbines often operate at diminished capacities, especially in arrays where wind turbine wakes interact and inflow conditions are far from ideal. New turbine control and wake prediction …

Go With The Flow –Thermoelectric Energy, Shawn Bell

Middle School Lesson Plans

In this unit, students will learn how thermal energy be transferred and transformed. They will carry out investigations to gather evidence to support an explanation about direct conversion of heat into electrical energy. They will develop a model that shows the components of the system and changes in the system being investigated, and they will use evidence from the investigation to construct an explanation for how the energy flows.

Configuration And Optimization Of A Novel Compressed-Air-Assisted Wind Energy Conversion System, Jie Cheng

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

The increasing concerns over the environmental impact of carbon emissions and the unsustainability of conventional fossil fuel power plants are stimulating interest in the implementation of renewable energy in current power systems. Among all of the renewable energies, wind energy holds a prominent place because of its high output and the maturity of the technology. However, like all of the other renewable energies, integration of wind energy into the power grid causes some quality and control issues, such as overvoltage or undervoltage and frequency excursion.

To mitigate these issues and build a robust wind power system, a novel structure referred …

Simulation, Measurement, And Emulation Of Photovoltaic Modules Using High Frequency And High Power Density Power Electronic Circuits, Yunas Erkaya

Electrical & Computer Engineering Theses & Dissertations

The number of solar photovoltaic (PV) installations is growing exponentially, and to improve the energy yield and the efficiency of PV systems, it is necessary to have correct methods for simulation, measurement, and emulation. PV systems can be simulated using PV models for different configurations and technologies of PV modules. Additionally, different environmental conditions of solar irradiance, temperature, and partial shading can be incorporated in the model to accurately simulate PV systems for any given condition.

The electrical measurement of PV systems both prior to and after making electrical connections is important for attaining high efficiency and reliability. Measuring PV …