Electrical and Computer Engineering Commons^™

The Electrochemical Reduction Of 2-Ethylanthraquinone (2eaq), Yaobin Zhu

Journal of Electrochemistry

The process of electrochemical reduction of 2EAQ in DMSO is studied using CVand ESR methods in this work, Pt, Pd and some implanted materials are used as electrodes. The quasi-rever-sible property of two electron transfer steps and their following homogeneous chemical reactions are illustrated. The mechanism of the electrochemical red uction of 2EAQ and the kinetic parameters of the related steps are obtained. Having measured the influence of water content in the system, the effect of the proton donor is discussed. After comparising the experimental results with each other these experiments gives us the idea that the replacement of metal …

Horseradish Peroxidase/Poly-O-Phen Ylenediamine Mem Brane Electrode: Preparation And Properties, Dong Wei, Huihuang Wu

Journal of Electrochemistry

A horseradish peroxidase (HRP)/poly-o-phenylenediamine (PPD) membrane electrode was prepared by electropolymerization of o-phenylenediamine on glassy carbon in pH 7.0 phosphate buffer, the process of the enzyme immobilization was studied. The enzyme electrode obtained exhibits the activity to catalyze the electroreduction of hydrogen peroxide in the absence of any electron transfer mediator. The red uction reaction occurs in the potential range of PPD redoxprocess, it was believed that the polymer participates in electron transfer of the enzyme. The enzyme reaction kinetics at rotating HRP/PPD electrode was analysed, and the factors influencing kinetic parameters were discussed.

Laser Scanning In-Situ Photoelectrochemical Microscopictechnique And Its Applications, Zugeng Lin, Jinkua You, Xiangdong Zhuo, Chun Zhang, Yong Yang

Journal of Electrochemistry

The main factors of the laser scanning in-situ photoelectrochemical microscopic measurement system which is set up in our lab have been discusaed in this paper. Some applications of this technique for in-situ study of modification and processing of semiconductor electrodes, monitoring of electro deposition process of semiconducting material and redox reaction occurring at metal oxide electrodes have also been presented. The results have shown that the technique is very powerful that for studing local photoelectrochemical properties of semiconductors and metal oxide electrodes. These provide important information on the micro structural and electronic properties in the solid/electrolyte interface.

Studies On Low Temperature Performance Of Rechargeable Mh-Ni Batteries, Wenkuan Zhang, Jingxian Shi, Yuwan Lou, Qiusheng Duan

Journal of Electrochemistry

The Dependence of low temperature performance on the alloy composition and electrolyte component for rechargeable MH-Ni batteries is studied, the suitable composition of alloy and electrofyte are founds.

An Indirect Electrochemical Oxidation Of Toluene──Anodic Oxidation Of Mn(Ⅱ) On The Lead Electrode, Zhonghua Wang, Qingmin Hua, Guacai Chen, Zhongquan Wang, Yunan Qiu, Xingguo Yan

Journal of Electrochemistry

The electrochemical oxidation of Mn(Ⅱ) to Mn(Ⅱ) in concentrated H₂SO₄ (2 ~ 8 mol⋅L^-1) at lead electrode has been studied. It is found that the electrode surface is oxidized to PbO₂ in a direct electrochemical reaction, then PbO₂ formed reacts with Mn(Ⅱ) in a chemical reaction. Some effects involves current density, concentration of H₂SO₄, temperature and conversionwere evaluated. The rule of electrogenerated Mn(Ⅲ) in flow electrolysis cell were determined at several conditions. The current efficiency at greater than 90% is obtained in general.

Electrochemically Modified Glassy Carbon Electrode And Determination Of Copper By Anodic Stripping Voltammetry, Jinrui Xu, Yie Liu, Xiurun Zhuang, Tomoo Miwa, Toyohide Takeuchi

Journal of Electrochemistry

This paper reported the glassy carbon electrode modified by cyclic voltammetrybetween -0.1 and +1.5 V (vs. SCE) in an aqueous solution containing catechol, for maldehyde and talium hydroxide. The modified electrode can be applied to the determination of copper(Ⅱ) in water, and its sensitivity is about 35 times higher than that of unmedified glassy carbon electrode, The quantitative limit with this modified electrode is 0.1 ng/ml.

The Reduction Of Oxygen To Hydrogen Peroxide At The Poly(O-Phenylenediamine)-Filmed Electrode, Zhaoe Lu, Tiangeng Zhong, Guanyong Zhang

Journal of Electrochemistry

The poly(o-phenylenediamine) (PPD) filmed graphite electrode was formed by electro-polymerization of o-phenylenediamine in acidified (pH=1) 0.2 mol·L^-1 Na₂SO₄ solution using the cyclic voltammetric methed. The catalytic effect of the electrcareduction of oxygen in acid olution was demonstrated by the voltammogram of the electrode in the oxygen saturated acid solutionof Na₂SO₄. The current efficiency of the reduction of oxygen to hydrogen peroxide was determined by the electrolysis in a divided cell under the condition of constant current. The various effectsinfluencing the accmulation of H₂O₂ in the catholyte were discussed.

Studies On Coordination Behavior Of Dimethyl Sulfoxide In Complex Of Rare Earth With Cryptand, Shichang Liu, Tianpei Zhu

Journal of Electrochemistry

Electrochemical reduction reaction in the course of the titration of Eu(2.2.2) and Eu(2.2) using strong bonding solvent, DMSO, in C₂H₄Cl₂ has been investigated by cyclic voltammetry. The greater the concentration of strong bonding solvent, the more negative the half-wave potentials for the reduction reaction are. The coordination number of Eu(2.2.2) and Eu(2.2) which are 2 and 3 respectively, with DMSO can be calculated, according to the relations between half-wave potentials and the variety of concentration of DMSO.

Differential Current Switch Logic: A Low Power Dcvs Logic Family, Dinesh Somasekhar, Kaushik Roy

Department of Electrical and Computer Engineering Technical Reports

We present a new logic family, Differential Current Switch Logic (DCSL) for implementing clocked CMOS circuits. The circuit is in principle a differential cascode voltage switch logic circuit (DCVS). In cornparimsonto other forms of' clocked DCVS, DCSL achieves better performance both in terms of power and speed by restricting internal voltage swings in the N tree. Automatic lock-out of inputs on completion of evaluation is a novel feature of the circuit and allows new implementation of logic functions and the possibility of operating with reduced voltage swings. SPICE simulattions carried out with. the MOSIS 1 . 2 process indicate that …

The Study Of The Growth Processes Of The Oxides On Lead Electrodes In Sulfuric Acid Solution, Hesheng Zhai, Xuguang Chen, Jinkua You, Yong Yang, Zugeng Lin

Journal of Electrochemistry

The growth processes of PbO and PbO₂ on lead electrodes have been investigatedby using in-situ methods that are combined with temporary AC resistance measurment technique and in-situ laser scanning photoelectrochemical microscopy. It is found that a linear relationship existsbetween the electrode resistance(R) and^1/2 after the electrode is oxidized at +0.6 V(vs.Hg/H₂SO₄/35% H₂SO₄) for more than 5 min. This result suggests that the growth of PbO is well distributed during the early stage of oxidation. The study by using laser scanning photoelectrochemical microscopy has further proved this point. The results also …

The Catalytic Behavior For Ni-W Electrode Modified By Carbon Ion Beam Implantion, Jishuang Zhang, Yaojiao Lv, Qinglian Li, Baoen Shen

Journal of Electrochemistry

The hydrogen evolution activity in acidic and basic mediums for Ni-W electrodemodified by carbon ion bean implantation was investigated. The experimental results show thiselectrode has superior catalytic activity for the hydrogen evolution reaction than that of the unmodified Ni-electrode. Long period testing of electrolysis under high current density show that this electrode hasalonger useful life hence it is a practical electrode material. The temperature effect of electrocatalytic property was also inverstigated. The experimental regularities are explained on the basis of the formation of surface multialloys of Ni-W-WC.

A Photoelectrochemical Investigation Of Zirconium Oxide Film, Maizhi Yang, Ping Wei, Di Quarto F., Piazza S., Sunseri C.

Journal of Electrochemistry

A photoelectrochemical investigation has been carried out on zirconium initialoxide film and its oxide film grownanodically at constant rate up to different thickness. Both anodicand cathedic photocurrents on the photocurrent spectrum depended on the potential, but had littlerelation with the forming anedic films or measuring solutions. Photocurrent spectrum and photocurrenttransients suggested that the oxide films on zirconium were duplex layers structure. The internal layerwas ZrO₂ and the external layer ZrO₂·(H₂O)_n. The photocurrent included photogenerated carrier ininternal and external oxide films, as well as internal photoinjection process for electrons from thesubstrate metal into the …

Electroreduction Of The Nittobenzene On Titanium Electrode Implanted With Palladium, Zhongda Wu, Xianjun Zhu, Hongsen Wang

Journal of Electrochemistry

The titanium substrates were bombarded with 1×10¹⁷～5×10¹⁷ ions·cm^-2 ofpalladium at the room temperature. The surface composition of implanted electrode and concentration-depth profiles of various elements were measured by AES. The electrored uction processes ofnitrobenzene (NB) in 0.1 mol/L NaOH solution at Pd/Ti electrodes have been investigated by cyclicvoltaivimetry. The results show that the palladium implanted titanium electrodes exhibit a high catalyticactivity in the electroreduction of NB. The NB radical anion, which is the product of one-electronelectroreduction of NB, was detected by ESR in-situ in conjunction with electrochemical methods. Aniline was also detected as a product of …

Electroreduction Of Holmium Ion On Iron Electrde In Molten Cholorides, Qiqin Yang, Guankun Liu, Yuzhi Su

Journal of Electrochemistry

The cyclic voltammetry, open circuit potential-time curve after poteritiostatic electrolysis, current-time curve at potential step, X-ray diffraction and electron probe microanalysiswere used to investigate the electrode process of Ho(Ⅲ) reduced on iron electrode in molten chloridesand the phases of surface alloy layer. The Ho-Fe alloys are formed at first, and then the metallic holmium is deposited when Ho(Ⅲ) is reduced on iron electrode. The charge transfer is reversible. The free energies of formation for the four inter metallic compounds of Ho-Fe system, the diffusion coefficients and diffusion activation energy of Ho in alloyed cathode are determined.

Electrocatalytic Oxidation Of Formaidehyde And Formic Acid On A Pt/SbAd Electrode, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic activity for the oxidation of formaldehyde and formic acid ona Sb-modified platinum (Pt/Sb_ad) was investigated. Results showed that the Pt/Sb_ad electrode was electrocatalytically more active than a Pt electrode in the anodic oxidation of formaldehyde and formicacid. In the case of formaldehyde, an oxidation peak appeared at a potential of ca. 0.7V. During the oxidation of formic acid, a 4-fold increase in the 1st peak current was observed. The Sb-modified platinum electrode was found to be most electrocatalytically active at a coverage of 0.75±0.05. The electrocatalytic activity of the Pt/Sb_ad electrode can be best …

Synthesis Of LiXCoo2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye

Journal of Electrochemistry

The Variations of crystal lattice parameters of Li_xCoO₂ during charge anddischarge have been st ud ied by XRD and AAR spectroscopy. It was found that the Li_xCoO₂ crystalvolume expanded during charge and contracted during discharge. The crystal lattice structure was broken because of the formation of Co₃O₄ when deeply charge.The variation of lattice parameter C₀ value in cycling process was similar to that in charge process.The variation of 006 peak was the mostsensitive in every case. In case of preheating for 20 hours at 700℃ before operating high temperature, the …

An Overview Of Flexible Ac Transmission Systems, P. Asare, T. Diez, A. Galli, E. O'Neill-Carillo, J. Robertson, R. Zhao

Department of Electrical and Computer Engineering Technical Reports

FACTS or "flexible AC transmission systems" is a term that has been suggested for the use of solid state devices to control bulk power flow in transmission systems. The Electric Power Research Institute supported this idea, and many researchers have invested efforts on the value and potential of FACTS. At this time, it appears that the main value of FACTS lies in improving transmission capability; increasing the flexibility of power flow control (e.g., for wheeling or for economic dispatch); for controlling voltage (and var flow); and possibly additional advantages in lower voltage systems (e.g., distribution systems). This report is an …

The Impact Of Electronic Ballast Compact Fluorescent Lighting On Power Distribution Systems, Reid Iwao Sasaki

Department of Electrical and Computer Engineering Technical Reports

Due to the high costs of expanding generation and transmission capacities, utilities have been initiating programs to reduce peak power demand by the customer. A number of these programs, which are commonly referred to as demand side management programs, have turned to the promotion of electronic ballast compact fluorescent lamps (CFLs) as an alternative to traditional incandescent lamps. These lamps provide a higher luminance and increased life as compared to their incandescent counterparts. Unfortunately, electronic ballast CFLs consume large amounts of harmonic current which may prove detrimental to the power distribution system. This thesis presents an introduction to the electronic …

An Appraisal Of Electricity Supply In Nigeria And The Privatisation Option, E. I. K. Sule, C. M. Anyanwu

CBN Occasional Papers

Incessant electric power cuts in most parts of the country has become a normal feature of electricity supply throughout Nigeria. The power outages cause much inconvenience and economic losses to all and sundry. This study has shown that the most critical factor behind the incessant power failure is the problem of inadequate funding of the industry at a time it was forced to accommodate rapid expansion. Other factors include lack of autonomy, inefficiency, poor organization as well as lack of skilled manpower. The paper has examined these problems on the basis of which suggestions are made on how the worrisome …

The Effects Of Channel Curvature And Protusion Height On Nucleate Boiling And The Critical Heat Flux Of A Simulated Electronic Chip, John E. Leland

Office for Research Publications and Presentations

The quest for higher power yet smaller electronics has given rise to the need for very effective cooling of these electronics. Because one of the foremost problems in electronics cooling is achieving high heat flux cooling within small packages while expending minimal pumping power, one focus of this study was to investigate the effects of channel curvature on the CHF. Experimental data were obtained for flow rates of 1-7 m/s, subcoolings of 5-35"C, and radii of curvature of 25.4 and 50.8 mm. A correlation was obtained for these data which provided an excellent fit.

One condition that has been ignored …

Plains Electric Members Service Area_04-29-1994, University Of New Mexico Bureau Of Business And Economic Research

BBER Publications

This report presents historical and projected socioeconomic data for 19 New Mexico and two Arizona counties which comprise the service areas of the distribution cooperatives in the Plains Electric Generation and Transmission Cooperative, Inc., system.

Basic Resonant Topologies For Switching Power Supplies, Zacharias K. Vachaparambil

Department of Electrical and Computer Engineering Technical Reports

The objective of this thesis is to study the basic resonant converter topologies for switching power supplies and to compare their performance under different operating conditions. The series and parallel resonant converters are analyzed in detail. The analysis uses the state plane method, which gives a good insight of the operation of the converter. It is found that these converters have more desirable characteristics when operated at a frequency above the resonant frequency rather than below it. Analytical results are verified by sinlulation and experiment.

Coping With The Risk Of Cancer In Children Living Near Power Lines, Eileen N. Abt

RISK: Health, Safety & Environment (1990-2002)

Ms. Abt briefly summarizes evidence linking power lines with a possible increase in risk of childhood cancer. She also recounts how, although many experts remain skeptical of causality, public fears, whether or not warranted, have themselves created serious problems. Finally, she proposes ways to address those problems.

A Study Of Dc Permanent Magnet Motor Noise Related To Line Current, Candace Rogers Suriano

Department of Electrical and Computer Engineering Technical Reports

Lightweight, compact and inexpensive DC permanent magnet motors are well suited for low cost high production use in industry. Unfortunately, the audible noise emanating from these motors can cause a false negative perception of the motor's quality. In cars, for example, fan motor noise can be a nuisance. The objective of this thesis is to examine the connection between motor noise and the line current wave form for a specific four pole DC permanent magnet motor. It is further concerned with identifying the underlying factors which influence the line current ripple. An audible noise to motor current transfer function is …

An Analysis Of The Payback Potential Of New Lighting Technology, James L. Cox

Masters Theses

Recent, energy saving improvements in lighting technology have been made involving the use of more efficient lamps, silver coated light reflectors, and electronic light ballasts. Research indicates that it is economically feasible to retrofit existing light fixtures to utilize the advantages of these developments. This process consists of the removal of all standard lamps and ballasts in each light fixture, the installation of a highly refined light reflector and the replacement of the existing lamps with brighter, more efficient ones. Standard magnetic ballasts are exchanged for more efficient electronic ballasts. Resulting is a light fixture that produces a comparable amount …

Low‐Cost Technique For Preparing N‐Sb2S3/P‐Si Heterojunction Solar Cells, O. Savadogo, K. C. Mandal

Faculty Publications

No abstract provided.

Losses In Electric Power Systems, E. Benedict, T. Collins, D. Gotham, S. Hoffman, D. Karipides, S. Pekarek, R. Ramabhadran

Department of Electrical and Computer Engineering Technical Reports

This report concerns losses in power systems. The report was assembled by seven authors in EE 532 class at Purdue University in December, 1992. The work was part of a class project on losses . All aspects of losses are discussed from the transmission system through utilization stages. High efficiency motors and lighting are also considered . The students participating in this project also videotaped presentations on power system losses .

Transient Stability Test Systems For Direct Stability Methods, V. Vittal, D Martin, R Chu, J Fish, J C. Giri, C K. Tang, F. Eugenio Villaseca, R G. Farmer

Electrical and Computer Engineering Faculty Publications

A standard set of power system data with benchmark results are presented against which direct stability techniques to assess transient stability can be compared and tested. The test systems have been selected to display a wide range of dynamic characteristics to provide a robust test of the efficacy and accuracy of the various analytical techniques to analyze transient stability. Transient stability test system data and benchmark results obtained from two commercially available time-domain stability analysis packages are presented

Studies Of High Field Conduction In Diamond For Electron Beam Controlled Switching, R. P. Joshi, M. K. Kennedy, K. H. Schoenbach, W. W. Hofer

Bioelectrics Publications

Experimental studies on a vertical metal‐diamond‐silicon switch structure have been conducted for potential pulsed power applications. Both the dc current‐voltage characteristics and the transient switching response have been measured for a range of voltages. With a 1 μm diamond film, the switch has been seen to withstand electric fields up to 1.8 MV/cm. Our results show a polarity dependence which can be associated with current injection at the asymmetric contacts. Polarity effects were also observed in the presence of e‐beam excitation, and arise due to nonuniform carrier generation near the diamond‐silicon interface. Our switching transients were seen to follow …

A New Method For Calculating The Economic Benefits Of Varying Degrees Of Power Factor Correction For Industrial Plant Loads, Mohammed Ishaque

Dissertations and Theses

A comparative study of the economic benefits that can be obtained from different degrees of power factor correction for medium and small scale industrial installations is shown. A new approach for precise calculation of kws and kvars required at different power factors is presented. These calculated values are used to find the return on investments for the capacitors needed for power factor correction. The developed method is easy to use, cost effective, accurate and will help electrical engineers with minimum knowledge of power systems to precisely determine the savings available by improving the power factor of an industrial load.