Environmental Engineering Commons^™

Anthropogenic Organic Chemical Removal From A Surficial Groundwater And Mass Transfer Modeling In A Nanofiltration Membrane Process, Samantha Black

Electronic Theses and Dissertations

This dissertation reports on research related to trace organic compounds (TrOCs) in surficial groundwater supplies and their subsequent removal from nanofiltration (NF) membranes. The research was conducted along coastal South Florida in cooperation with the Town of Jupiter Water Utilities, Jupiter, FL (Town). The focus of the research was to determine the extent of reclaimed water impacts on surficial groundwater supplies and subsequent effects on the Town's NF water treatment plant. Routine monitoring of fourteen TrOCs in reclaimed water and at the water treatment facility revealed varying degrees of TrOC detection in the environment. Certain TrOCs, including caffeine and DEET, …

Protein-Targeted Corona Phase Molecular Recognition, Gili Bisker, Juyao Dong, Hoyoung D. Park, Nicole M. Iverson, Jiyoung Ahn, Justin T. Nelson, Markita P. Landry, Sebastian Kruss, Michael S. Strano

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Corona phase molecular recognition (CoPhMoRe) uses a heteropolymer adsorbed onto and templated by a nanoparticle surface to recognize a specific target analyte. This method has not yet been extended to macromolecular analytes, including proteins. Herein we develop a variant of a CoPhMoRe screening procedure of single-walled carbon nanotubes (SWCNT) and use it against a panel of human blood proteins, revealing a specific corona phase that recognizes fibrinogen with high selectivity. In response to fibrinogen binding, SWCNT fluorescence decreases by >80% at saturation. Sequential binding of the three fibrinogen nodules is suggested by selective fluorescence quenching by isolated sub-domains and validated …

Calibration Procedure For Fuel Flow Meters At The Nebraska Tractor Test Lab, Michael F. Kocher, Matthew T. Wold, Roger M. Hoy, Austin Lammers, Erin E. Blankenship

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Reports in the literature indicated several factors that can influence the accuracy of Coriolis Effect mass flow meters. A Coriolis Effect mass flow meter is used to verify tractor manufacturer’s fuel consumption claims at the Nebraska Tractor Test Laboratory (NTTL). The accuracy requirement placed on the flow meter by the Organization for Economic Co-operation and Development (OECD) in the Code 2 tractor performance test procedure is not clear, but in the most conservative interpretation is ±0.5% of each flow rate measured. Results showed a dynamic weighing calibration method was not accurate enough to obtain a calibration of the flow meter …

Corrigendum To “Energy Savings Across Eu Domestic Building Stock By Optimizing Hydraulic Distribution In Domestic Space Heating Systems”, Ciara Ahern, Brian Norton

Articles

No abstract.

Characteristics And Composition Of Magnetic Concentrates Of Bottom Ash Samples From Two Types Of Thermal Power Plants In Odisha, India, Subir Kumar Das

Coal Combustion and Gasification Products Journal Archive

Aluminosilicate bottom ash samples were examined from a thermal power plant in Talcher (sample NT-BA) and in Sambalpur (sample HR-BA), Odisha, India, to determine magnetic particle morphology, internal structure, mineralogy, mineral chemistry, ash fusion temperature, chemical composition, and leaching characteristics. The Talcher plant has adopted pulverized coal combustion, whereas the Sambalpur plant uses circulating fluidized bed combustion boiler technology. For NT-BA, most magnetic particles were ideal solid spheres (ferrospheres) with diverse morphological features (smooth, granular, dendritic and skeletal, porous, spotted, polygonal, and hollow [magnetite cenospheres]). For HR-BA, magnetic particles were subspherical, oval, and angular and showed widely varying surface morphologies, …

Distribution Of Uranium And Other Radionuclides In Coal And Coal Combustion Products, With Discussion Of Occurrences Of Combustion Products In Kentucky Power Plants, James C. Hower, Shifeng Dai, Greta Eskenazy

Coal Combustion and Gasification Products Journal Archive

Uranium and thorium are part of the mineral assemblages within coals. Uranium can also occur in organic associations, particularly in low-rank coals. While the average U concentration in coals is 2.9 ppm for low-rank coals and 1.9 ppm for bituminous and higher rank coals, high concentrations are known from certain low-rank and thin coals and from coals in areas associated with U mineralization. No high-U coals are mined for power production in the United States. Uranium and Th in coal combustion products are found in amounts more or less in proportion to their concentrations in the feed coal. Not being …

Preliminary Investigation Into The Rate Of Carbonation Of Concrete Blocks Under Normal Production Yard Conditions, Aimee Byrne, Eanna Nolan

Conference papers

The release of CO2 from calcination during the manufacture of cement can be partially or fully offset by the CO2 it naturally absorbs during its lifetime. This paper reports results from a preliminary investigation into the rate of carbonation in concrete blocks stacked in a production yard over a period of 6 months. The blocks were stacked in a normal manner under natural exposure conditions. Carbonation progress was determined by splitting the blocks and spraying the freshly exposed surface with a phenolphthalein solution at intervals over the test period. It was found that the rate of the carbonation front progression …

Long-Term Patterns Of Air Temperatures, Daily Temperature Range, Precipitation, Grass-Reference Evapotranspiration And Aridity Index In The Usa Great Plains: Part I. Spatial Trends, Meetpal S. Kukal, Suat Irmak

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Due to their substantial spatio-temporal behavior, long-term quantification and analyses of important hydrological variables are essential for practical applications in water resources planning, evaluating the water use of agricultural crop production and quantifying crop evapotranspiration patterns and irrigation management vs. hydrologic balance relationships. Observed data at over 800 sites across the Great Plains of USA, comprising of 9 states and 2,307,410 km² of surface area, which is about 30% of the terrestrial area of the USA, were used to quantify and map large-scale and long-term (1968-2013) spatial trends of air temperatures, daily temperature range (DTR), precipitation, grass-reference evapotranspiration (ET …

A Generalized Spatial Measure For Resilience Of Microbial Systems, Ryan S. Renslow, Stephen R. Lindemann, Hyun-Seob Song

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The emergent property of resilience is the ability of a system to return to an original state after a disturbance. Resilience may be used as an early warning system for significant or irreversible community transition; that is, a community with diminishing or low resilience may be close to catastrophic shift in function or an irreversible collapse. Typically, resilience is quantified using recovery time, which may be difficult or impossible to directly measure in microbial systems. A recent study in the literature showed that under certain conditions, a set of spatial-based metrics termed recovery length, can be correlated to recovery time, …

Carbon Dioxide Adsorption Studies On Fly Ash Zeolites, Denitza Zgureva

Coal Combustion and Gasification Products Journal Archive

In this study, the potential of fly ash zeolites (FAZ) Linde (LTA) and faujasite (FAU) to adsorb carbon dioxide (CO2) was investigated in view of the results of implementation in postcombustion carbon-capture technologies. Adsorption isotherms of selected samples were measured at 273.15 K by a Micromeritics Tristar II 3020 surface analyzer. The highest adsorption capacity was obtained for FAZ with a FAU structure synthesized by a two-stage fusion hydrothermal process from fly ash (FA) that was composed of 65 wt% amorphous components. The adsorption capacity for this sample reached a value of 136.40 mg CO2/g FAZ at atmospheric pressure, a …

Analysis Of Scientific Investigations Related To Reclamation Of Surface Mining Control And Reclamation Act Permitted Coal Mines With Coal Combustion By-Products, Kimery C. Vories

Coal Combustion and Gasification Products Journal Archive

In the United states, the placement of coal combustion by-products (CCBs) (i.e., fly ash, bottom ash, boiler slag, flue gas desulfurization material, and fluidized bed combustion material) in coal mines has been an area of controversy. Federal and state governments, universities, the National Energy Technology Laboratory, and industrial research organizations have taken an active role in encouraging and promoting technological advances, research, and technology transfer related to the use of CCBs at coal mines. CCBs have been placed at Surface Mining Control and Reclamation Act of 1977 (SMCRA) permitted mines since 1977 to serve the following purposes: (1) a seal …

Coal Ash By-Product From Shanxi Province, China, For The Production Of Portland–Calcium Sulfoaluminate, Tristana Y. Duvallet, Thomas L. Robl, Kevin R. Henke, Yongmin Zhou, David Harris

Coal Combustion and Gasification Products Journal Archive

Twenty bulk samples were collected from ponded coal combustion ash in Shanxi Province, China, as part of an investigation of their beneficiation potential. The samples were shipped to the University of Kentucky, where they were chemically analyzed. The samples were highly consistent in chemistry, falling within the ASTM C-618 class F compositional range. The particle size of the ponded ash was relatively coarse, with only ,7% by weight on average, falling below 200 mesh (75 mm) particle size. The bulk of the material (.80%) was within 50 by 200 mesh (equivalent to 300 by 75 mm). X-ray diffraction investigation combined …

Effect Of Coal Fly Ash Leachate On The Bioluminescence Intensity Of Vibrio Fischeri, Shiro Ikeda, Irena Kostova, Hideaki Sekine, Yoshika Sekine

Coal Combustion and Gasification Products Journal Archive

Coal fly ash is a residue of coal-fired thermoelectric power plants (TPPs) and is mostly dumped in ash ponds or landfill sites, even though it potentially contains significant amounts of water-soluble hazardous contaminants. Bioassay using the bioluminescent bacterium *Vibrio fischeri* is known to be applicable for assessing the short-term and sublethal toxicity of complex mixtures without the need for precise chemical characterization. However, this type of bioassay is potentially adversely influenced by the pH-induced protein denaturation of cells. Because coal fly ash leachates often have alkaline or acidic properties, when applying the *V. fischeri*-based bioassay to the samples, we need …

Influence Of Coal-Fired Power Plant Emissions Regulations And Consequent Engineering Controls And Coal-Supply Modifications On Fly Ash Chemistry And Petrology: Examples From Kentucky Power Plants, Madison M. Hood, John G. Groppo, Michelle N. Johnston, James C. Hower, Herek L. Clack, Diego S. De Medeiros, Silvio R. Taffarel, Cesar M.N.L. Cutruneo, Luis F.O. Silva

Coal Combustion and Gasification Products Journal Archive

The chemistry and petrology of fly ash are controlled by a number of factors: (1) chemistry of the feed coal (and added fuels, such as petroleum coke, tires, biomass, etc.), (2) particle size of the fuel feed (controlled by pulverized fuel vs. cyclone combustion, maintenance of pulverizers, etc.), (3) design of the boiler and pollution-control system, and (4) temperature of the flue gas at the collection point. In general, for any electrostatic precipitator or baghouse system, the concentrations of volatile trace elements in fly ash will increase with a drop in the flue gas temperature and a decrease in the …

Application Of Landfill Treatment Approaches For The Stabilization Of Municipal Solid Waste, Stephanie Bolyard

Electronic Theses and Dissertations

This research focused on the fundamental requirements of stabilizing a mature landfill using three treatment approaches as well as the implications of discharging leachate organic matter (LOM) to wastewater treatment plants (WWTPs). Three treatment approaches aimed at removing releasable carbon and nitrogen from mature landfills including flushing with clean water, leachate recirculation with ex-situ chemical oxidation, and leachate recirculation with ex-situ chemical oxidation and in-situ aeration were evaluated. After extensive treatment of the waste in the flushing bioreactor (FB) scenarios, the overall biodegradable fraction was reduced relative to mature waste. Leachate quality improved for all FBs but through different mechanisms. …

Reuse Of Aqueous Waste Streams For Transportation-Related Applications, Gregory L. Hansen

Electronic Theses and Dissertations

Aqueous waste streams produced from commercial, industrial, and municipal processes may be potentially reused for transportation applications. The objectives of this project were to identify potential transportation-related applications for aqueous waste streams available in South Dakota, develop guidance for the beneficial reuse of aqueous waste streams, and evaluate the reuse of MIEX® brine generated by the Watertown Municipal Water Treatment Plant (WMWTP). This study identified many aqueous wastes from municipal water and wastewater treatment facilities, industrial and agricultural processes in South Dakota that can be potentially used for ice and dust control. Beneficial reuse of these waste streams requires a …

Resolving The Policy Paradox: The Case Of Biofuel Production In Ireland, Alan Gilmer, Mark J. Mcgarrity, Vivienne Byers

Articles

Purpose – The purpose of this paper is to determine the status of policy design and policy implementation in the biofuel sector in Ireland. The focus of the work addresses the overarching operational context of the biofuel sector in Ireland and the role of different actors in shaping and resolving inconsistencies in policy outlook and practice. Design/methodology/approach – This study used a qualitative research approach involving a series of semi-structured interviews with members of the relevant sub-groups concerned. This study sought to address two questions – whether current or proposed policy is likely to affect consumption of indigenous biofuel feedstocks …

Reactivity Of Hydroxyl Radical: Mechanistic Insight Into The Reactivity With Dissolved Organic Matter, Mallika Khare

Dissertations, Master's Theses and Master's Reports

Advanced Oxidation Processes (AOPs) that produce highly reactive hydroxyl radicals (HO•) are attractive and promising water and wastewater treatment technologies because HO• can destroy a variety of organic compounds. However, background dissolved organic matter (DOM) significantly reduces the performance of AOPs by scavenging HO•. The conventional experimental approach to identifying ‘average’ reactivity limits our mechanistic understanding of the reaction of HO• with complex mixture of surrogate DOM. This is the first study to use quantum mechanical methods to understand the elementary reactions of HO• with a model monomer of DOM. “Temple Northeastern Birmingham model” (TNB). The theoretically calculated aqueous-phase free …

Evaluating The Anaerobic Codigestion Potential Of Stillage And Dairy Manure In A Tubular Digester, Brad J. Weiss

Dissertations, Master's Theses and Master's Reports

Evaluations of the anaerobic treatment of sugarcane stillage and dairy manure in a low cost tubular digester were performed in small scale batch experiments and using mathematical simulations. A local sensitivity analysis of the model was performed, and key input parameters were adjusted until the predicted COD removal was consistent with data obtained using two full-scale digesters. Simulations were performed to evaluate COD removal and biogas production for nine different mixtures of stillage and manure at four different temperatures ranging from 15˚C to 30˚C. Digestion of stillage alone was not effective, but when codigested with 20% or more manure, COD …

Use Of Lidar In The Design Of Grassed Waterways: Case Study In Agricultural Management In Oklahoma, Annette Sparks

Dissertations, Master's Theses and Master's Reports

Before the advent of Light Detection and Ranging (LiDAR) technology, farm-level infrastructure for sustainable agriculture was designed using topographic maps. LiDAR is a remote sensing method whereby reflected laser pulses are measured to generate high-resolution 3D images of the terrain. This report compares these two methods in the design of grassed waterways for flood drainage and evaluates how the quantitative difference between the two methods can affect the overall hydrologic design. The benefits of LiDAR are expected to be higher accuracy and precision in design, as well as greater reproducibility or consistency, regardless of the designer. To carry out this …

2016 Nebraska Groundwater Quality Monitoring Report

Nebraska Department of Environmental Quality: Reports

The 2001 Nebraska Legislature passed LB329 (Neb. Rev. Stat. §46-1304) which, in part, directed the Nebraska Department of Environmental Quality (NDEQ) to report on groundwater quality monitoring in Nebraska. Reports have been issued annually since December 2001. The text of the statute applicable to this report follows: “The Department of Environmental Quality shall prepare a report outlining the extent of ground water quality monitoring conducted by natural resources districts during the preceding calendar year. The department shall analyze the data collected for the purpose of determining whether or not ground water quality is degrading or improving and shall present the …

Enhanced Pump Schedule Optimization For Large Water Distribution Networks To Maximize Environmental And Economic Benefits, Seyed Mohsen Sadatiyan Abkenar

Wayne State University Dissertations

For more than four decades researchers tried to develop optimization method and tools to reduce electricity consumption of pump stations of water distribution systems. Based on this ongoing research trend, about a decade ago, some commercial pump operation optimization software introduced to the market. Using metaheuristic and evolutionary techniques (e.g. Genetic Algorithm) make some commercial and research tools able to optimize the electricity cost of small water distribution systems (WDS). Still reducing the environmental footprint of these systems and dealing with large and complicated water distribution system is a challenge.

In this study, we aimed to develop a multiobjective optimization …

Control Architecture For Multi-Robot System, John H. Posselius, Christopher A. Foster, Santosh K. Pitla, Scott A. Shearer, Joe D. Luck, Michael P. Sama, Rodrigo S. Zandonadi

Department of Agricultural and Biological Systems Engineering: Faculty Publications

A multiple robot control architecture including a plurality of robotic agricultural machines including a first and second robotic agricultural machine. Each robotic agricultural machine including at least one controller configured to implement a plurality of finite state machines within an individual robot control architecture (IRCA) and a global information module (GIM) communicatively coupled to the IRCA. The GIMs of the first and second robotic agricultural machines being configured to cooperate to cause said first robotic agricultural machine and said second agricultural machine to perform at least one agricultural task.

Objective Climatological Analysis Of Extreme Weather Events In Arizona During The North American Monsoon, Jeremy J. Mazon, Christopher L. Castro, David K. Adams, Hsin-I Chang, Carlos M. Carrillo, John J. Brost

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Almost one-half of the annual precipitation in the southwestern United States occurs during the North American monsoon (NAM). Given favorable synoptic-scale conditions, organized monsoon thunderstorms may affect relatively large geographic areas. Through an objective analysis of atmospheric reanalysis and observational data, the dominant synoptic patterns associated with NAM extreme events are determined for the period from 1993 to 2010. Thermodynamically favorable extreme-weather-event days are selected on the basis of atmospheric instability and precipitable water vapor from Tucson, Arizona, rawinsonde data. The atmospheric circulation patterns at 500 hPa associated with the extreme events are objectively characterized using principal component analysis. The …

A Novel Approach For Evaluating The Impact Of Fixed Variables On Photovoltaic (Pv) Solar Installations Using Enhanced Meta Data Analysis Among Higher Education Institutions In The United States, Diane N. De Hoyos

Open Access Theses & Dissertations

The global demand for electric energy has continuously increased over the last few decades. Some mature, alternative generation methods are wind, power, photovoltaic panels, biogas and fuel cells. In order to find alternative sources of energy to aid in the reduction of our nation's dependency on non-renewable fuels, energy sources include the use of solar energy panels. The intent of these initiatives is to provide substantial energy savings and reduce dependence on the electrical grid and net metering savings during the peak energy-use hours.

The focus of this study explores and provides a clearer picture of the adoption of solar …

Effects Of Citric Acid Coated And Uncoated Cerium Oxide Nanoparticles In Tomato (Solanum Lycopersicum) Plants, Ana Cecilia Barrios

Open Access Theses & Dissertations

This research was performed to examine the physiological and biochemical effects of bare (nCeO2) and citric acid coated (nCeO2+CA) cerium oxide nanoparticles in tomato (Solanum lycopersicum). Plants were germinated and grown to full maturity in soil amended with 0-500 mg/kg and periodically analyzed using ICP-OES/MS and other spectroscopic and biochemical techniques. Although Ce in tissues increased as the external nCeO2 increased, there were no visible signs of toxicity. In mature plants, nCeO2 induced developmental changes and altered nutritional quality (essential elements) in fruits. On the other hand, nCeO2+CA affected fruit carbohydrate composition (sugars and starch). This study gives insights on …

Minimizing Environmental Impacts For Hub And Spoke Distribution Network Problems Through The Use Of Multi-Objective Evolutionary Algorithms, Ileana Delgado

Open Access Theses & Dissertations

While transportation is crucial to our economy and our personal lives, as a sector it is also a significant source of greenhouse gas (GHG) emissions. The AASHTO report states, "America's transportation system has served us well, but now faces the challenges of congestion, energy supply, environmental impacts, climate change, and threatens the economic, social, and environmental future of the nation". With respect to the environment, transportation is the most visible aspect of supply chains. Transportation emissions can be reduced by implementing approaches that contribute to GHG emissions reduction, for example, the use of low-carbon fuels, new and improved vehicle technologies, …

A Study On The Current State Of Contaminants Of Concern Research, With A Focus On Biosolids And Regulations, Maren Mariah Fulton

Civil and Environmental Engineering Master's Project Reports

Wastewater treatment plants are a major source of contaminants of emerging concern, as these facilities are the main receptors of these products via household, commercial, and industrial drains, and transport via stormwater runoff. Biosolids are composed of numerous constituents, with a number of environmentally persistent and potentially toxic contaminants of emerging concern identified as present in large concentrations. Research is needed to understand the transport and fate mechanisms of these compounds in biosolids. Additionally, this research is needed to determine a new priority framework to regulate CECs, both on the national level and regional levels. Wastewater treatment plant influent and …

Long-Term Effects Of Forestry Best Management Practices On Hydrology And Water Chemistry In Three Appalchian Headwater Catchments, Kameryn I. Wright

Theses and Dissertations--Biosystems and Agricultural Engineering

In 1982, a study was initiated in the Field Branch watershed, in the University of Kentucky’s Robinson Forest, to evaluate forestry best management practice (BMP) effectiveness after intensive harvesting. The study utilized a paired watershed approach on three adjacent Field Branch subcatchments. One subcatchment was left as the control, one had BMPs implemented (including a 50-ft undisturbed buffer along the stream), and one was clear-cut to the stream’s banks without the use of BMPs (i.e. logger’s choice). Prior research has shown that logging can negatively impact watershed functions by altering stream hydrology, geomorphology, water quality, and instream habitat. Thus, the …

Development Of Regional And Hydraulic Geometry Curves For The Eastern Kentucky Coalfields, Ashlan Berry

Theses and Dissertations--Biosystems and Agricultural Engineering

Regional curves and hydraulic geometry curves relate bankfull channel dimensions to drainage area and bankfull discharge, respectively. These curves are used in the natural channel design process to help identify bankfull and to estimate bankfull dimensions of the design channel. Nineteen streams were surveyed to determine their bankfull parameters (cross-sectional area, width, mean depth, discharge, slope, and Manning’s n), along with 27 streams previously surveyed in other studies. The data were used to create regional and hydraulic geometry curves for three hydrologic landscape regions (HLR 9, HLR 11, and HLR 16, individually) in the Eastern Kentucky Coalfields (EKC) as well …