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Articles 91 - 120 of 222
Full-Text Articles in Environmental Engineering
Influence Of Media Size And Flow Rate On The Transport Of Silver Nanoparticles In Saturated Porous Media: Laboratory Experiments And Modeling, Travis J. Meidinger
Influence Of Media Size And Flow Rate On The Transport Of Silver Nanoparticles In Saturated Porous Media: Laboratory Experiments And Modeling, Travis J. Meidinger
Theses and Dissertations
Silver nanoparticles (AgNPs) are widely produced and used. Because of their potential toxicity and the possibility of their release into the environment, it is important to understand the factors involved in their transport; particularly how they may move in groundwater, which is a potential pathway to human and environmental receptors. By passing a solution of 15 mg/L AgNPs with an average size of 17 nm through sand-filled glass columns, this study looks at the physical effects of flow rate and media size on transport. Three different sand sizes ( 0.074, 0.21-0.297, and 0.4-2.0mm) were used, as well as two different …
Biodegradation Of An Organophosphate Chemical Warfare Agent Simulant By Activated Sludge With Varying Solid Retention Times, Allen K. Janeczko
Biodegradation Of An Organophosphate Chemical Warfare Agent Simulant By Activated Sludge With Varying Solid Retention Times, Allen K. Janeczko
Theses and Dissertations
This study examined the fate of malathion, a surrogate compound for VX studies, in bench-scale sequencing batch bioreactors being operated under varied solid retention times (SRTs) to simulate the activated sludge process in wastewater treatment facilities. Results show that a constant influent of the malathion will largely be removed. However, the heterotrophic bacteria undergo a stress response which temporarily inhibits malathion removal, the extent of which increases with increasing SRTs. After this stress response takes place, the activated sludge is able to resume a high degree of malathion removal, even with increased influent concentration; however, this is done so at …
Fate Of Malathion In An Activated Sludge Municipal Wastewater Treatment System, Edward B. Walters
Fate Of Malathion In An Activated Sludge Municipal Wastewater Treatment System, Edward B. Walters
Theses and Dissertations
Organophosphate compounds are used as pesticides and in chemical warfare agents such as nerve agents. VX (O-ethyl S-[2-(diisopropylamino)ethyl] methylphosphonothioate) is one of the most toxic and environmentally persistent of these nerve agents. This research examined the fate of malathion, a pesticide and surrogate of VX (O-ethyl S-[2-(diisopropylamino)ethyl] methylphosphonothioate), in bench-scale activated sludge (AS) sequencing batch reactors. Sorption kinetics and sorption equilibrium isotherm experiments indicate that sorption to AS biomass was not a statistically important removal mechanism. However, approximately 90% of the initial 4.25 mg L-1 malathion concentration degraded primarily via heterotrophic activity.
Evaluation Of Municipal Wastewater Treatment Plant Activated Sludge For Biodegradation Of Propylene Glycol As An Aircraft Deicer, Justin D. Delorit
Evaluation Of Municipal Wastewater Treatment Plant Activated Sludge For Biodegradation Of Propylene Glycol As An Aircraft Deicer, Justin D. Delorit
Theses and Dissertations
Aircraft deicing fluid used at airport facilities is often collected for treatment or disposal in order to prevent serious ecological threats to nearby surface waters. This study investigated lab scale degradation of propylene glycol (PG), the active ingredient in a common aircraft deicing fluid, by way of a laboratory-scale sequencing batch reactor containing municipal waste water treatment facility activated sludge (AS) performing simultaneous organic carbon oxidation and nitrification. The ability of AS to remove PG was evaluated by studying the biodegradation and sorption characteristics of PG in an AS medium. The results indicate sorption may play a role in the …
Optimization Of Nanoscale Zero-Valent Iron For The Remediation Of Groundwater Contaminants, Andrew W. E. Mcpherson
Optimization Of Nanoscale Zero-Valent Iron For The Remediation Of Groundwater Contaminants, Andrew W. E. Mcpherson
Theses and Dissertations
Nanoscale zero-valent iron (nZVI) is an emerging tool for the remediation of groundwater contaminants. The nanoparticles are capable of reductively destroying or immobilizing a wide range of contaminants. Their small size results in a high surface area to mass ratio, making them much more reactive compared to their more-coarse predecessors. Small particle size also allows nZVI particles to be injected directly into contaminated areas via a well, limiting the above-ground footprint and allowing access to contaminated areas that are beyond the reach of some conventional methods. nZVI technology has the potential to facilitate remediation in difficult situations, improve remediation outcomes, …
Biodegradation Of Organophosphate Chemical Warfare Agents By Activated Sludge, Steven J. Schuldt
Biodegradation Of Organophosphate Chemical Warfare Agents By Activated Sludge, Steven J. Schuldt
Theses and Dissertations
Organophosphates (OPs) have been widely used as Chemical Warfare Agents (CWAs) as well as pesticides since World War II and still remain a threat to national security. While efforts have been taken at military installations and civilian communities to secure these chemicals and prevent their misuse, a determined adversary could still obtain and deploy them to injure, kill, or instill terror. The lethal properties of this group of compounds are primarily owed to their irreversible inhibition of the enzyme acetyl cholinesterase (AChE) and thus may alter the human nervous system or affect the hormonal balance of children in particular. In …
Characterization And In Vitro Toxicity Of Copper Nanoparticles (Cu-Nps) In Murine Neuroblastoma (N2a) Cells, Sitao Veronica Brownheim
Characterization And In Vitro Toxicity Of Copper Nanoparticles (Cu-Nps) In Murine Neuroblastoma (N2a) Cells, Sitao Veronica Brownheim
Theses and Dissertations
Nanomaterials, classified as materials within the 1 - 100 nanometer range, have seemingly endless applications. It is very important to the Air Force to increase the understanding of Cu-NPs and the possible health impacts from nanomaterial exposure prior to wide-spread industry and military use. Therefore, the purpose of this research is to thoroughly characterize the properties of three different copper samples upon suspension into aqueous solutions over time: Cu-NPs (Cu 25 nm), CuO-NPs (CuO 40 nm), and Cu-MSP (Cu 500nm). Additionally, this research seeks to observe in vitro effects upon murine neuroblastoma cells (N2A) by these three types of particles …
Retrospective Geospatial Modeling Of Pm10 Exposures From Open Burning At Joint Base Balad, Iraq, John P. Rinker
Retrospective Geospatial Modeling Of Pm10 Exposures From Open Burning At Joint Base Balad, Iraq, John P. Rinker
Theses and Dissertations
Predicting, determining, and linking theater-related source-specific exposures to health effects has proven difficult. The purpose of this research is to delineate retrospective exposure zones using spatially interpolated particulate air sampling point data from Joint Base Balad, create burn pit exposure isopleths from dispersion model outputs, and merge into a combined exposure model in GIS. Interpolated monitoring results and dispersion modeled results were combined to compare modeled exposures across base. Burn pit contribution to total PM10 was also modeled. The combined dispersion and interpolation map showed elevated concentrations within a 1 kilometer buffer of the burn pit. Buildings within this area …
Ground Source Heat Pumps Vs. Conventional Hvac: A Comparison Of Economic And Environmental Costs, Paul W. Fredin
Ground Source Heat Pumps Vs. Conventional Hvac: A Comparison Of Economic And Environmental Costs, Paul W. Fredin
Theses and Dissertations
The world is undergoing a dramatic transformation with regard to how it produces and consumes energy due to increasing demand from developing nations and diminishing new resource discoveries. In addition, there has been increased concern over the effect of carbon dioxide emissions on the environment. All of these issues have created a combined pressure to force the world to begin to redefine how energy is utilized. Geothermal or ground source heat pumps (GSHPs) may provide one potential solution to these problems. This research investigated vertical borehole closed-loop GSHP systems in direct comparison to natural gas furnaces combined with traditional air-conditioning …
Development Of A Screening Tool To Facilitate Technology Of An Innovative Technology To Treat Perchlorate-Contaminated Water, Daniel A. Craig
Development Of A Screening Tool To Facilitate Technology Of An Innovative Technology To Treat Perchlorate-Contaminated Water, Daniel A. Craig
Theses and Dissertations
Perchlorate contamination of drinking water is a significant problem nationwide. The purpose of this study was to develop a tool to predict the cost and performance of tailored granular activated carbon (T-GAC), an innovative technology that is being evaluated as a cost-effective treatment for perchlorate-contaminated water. The ability to accurately predict performance and cost can facilitate the transfer and commercialization of innovative technologies. In the study, a model was developed to predict T-GAC performance and life-cycle costs for removing perchlorate under varying influent water quality and technology operating conditions. The model's design parameters were obtained from laboratory rapid small-scale column …
Linking Embeddedness And Macroinvertebrate In Two Southwest Ohio Streams, Jonathan P. Kochersberger
Linking Embeddedness And Macroinvertebrate In Two Southwest Ohio Streams, Jonathan P. Kochersberger
Theses and Dissertations
Environmental managers utilize a variety of tools when assessing lotic systems for stressors attributed to anthropogenic sources. Stream deposited sediment has been recognized as one of the major stressors affecting streams in the U.S. The detrimental effect on aquatic biota of sediment depositing within the interstitial spaces of stream substrate (embeddedness) has been established, yet lacking is an effective in situ method of quantifying embeddedness over short time periods. The goal of this research was to develop a short-term embeddedness (EMB) quantification method that can be linked to benthic macroinvertebrate health. Such a method would be a valuable tool when …
Molecular Characterization Of Wetland Soil Bacterial Communities In Constructed Mesocosms, Elisabeth M. Leon
Molecular Characterization Of Wetland Soil Bacterial Communities In Constructed Mesocosms, Elisabeth M. Leon
Theses and Dissertations
16S rRNA gene analysis was performed on soil samples from a subsurface flow mesocosm experiment, mimicking a constructed wetland. Three typical wetland species of plant were used in nine of the columns and three columns were unplanted controls. Analyses showed that plant presence, plant species, and depth did not have a significant effect on microbial community composition. However, richness analyses illustrated that plant presence had a positive effect on richness, plant species analyses indicated that there was evidence that plant species affected richness in a significant manner, and lastly richness was negatively affected in the bottom depth for the control …
Modeling In Situ Bioremediation Of Perchlorate-Contaminated Groundwater, Roland E. Secody
Modeling In Situ Bioremediation Of Perchlorate-Contaminated Groundwater, Roland E. Secody
Theses and Dissertations
Perchlorate-contaminated groundwater is a significant problem for the Department of Defense and the United States Air Force. An innovative technology was recently developed which uses dual-screened treatment wells to mix an electron donor into perchlorate-contaminated groundwater in order to effect in situ bioremediation of the perchlorate by indigenous perchlorate reducing bacteria without the need to extract the contaminated water from the subsurface. In this study, a model that simulates operation of the technology is calibrated and validated using 761 days of observational data obtained from a field-scale technology evaluation project. A genetic algorithm was used with the first 113 days …
Biofiltration As A Viable Alternative For Air Pollution Control At Department Of Defense Surface Coating Facilities, David M. Hudock
Biofiltration As A Viable Alternative For Air Pollution Control At Department Of Defense Surface Coating Facilities, David M. Hudock
Theses and Dissertations
Surface coating operations at aircraft depot facilities are common throughout the Department of Defense (DoD). During paint application processes at Navy and Marine Corps Fleet Readiness Centers (FRCs), spray paints emit volatile organic compounds (VOCs) known to have harmful effects on human health and the environment. FRC East at Marine Corps Air Station Cherry Point, does not control the emissions of VOCs from any of its paint booths. The purpose of this research is to determine if FRC East and its surrounding area can benefit both economically and environmentally from a biofiltration system for air pollution control (APC) rather than …
Development Of A Screening Model For Design And Costing Of An Innovative Tailored Granular Activated Carbon Technology To Treat Perchlorate-Contaminated Water, William C. Powell
Development Of A Screening Model For Design And Costing Of An Innovative Tailored Granular Activated Carbon Technology To Treat Perchlorate-Contaminated Water, William C. Powell
Theses and Dissertations
Perchlorate contamination of drinking water is a problem that has recently gained national attention. The purpose of this research was to develop a tool to predict the cost and performance of tailored granular activated carbon (T-GAC), an innovative technology to treat perchlorate-contaminated water. The ability to predict cost and performance is essential to promote transfer and commercialization of innovative technologies. This study investigated how data obtained from small-scale laboratory tests could be applied to predict cost and performance of a full-scale T-GAC system to treat perchlorate-contaminated water. A technology model was developed using GAC design principles and using a multi-component …
The Effects Of Orthophosphate As A Copper Corrosion Control Inhibitor In High Alkalinity Drinking Water Systems, Stephen Grace
The Effects Of Orthophosphate As A Copper Corrosion Control Inhibitor In High Alkalinity Drinking Water Systems, Stephen Grace
Theses and Dissertations
The purpose of this research was to investigate orthophosphate as a corrosion inhibitor for copper pipe in a high-alkalinity drinking water system. Specifically, this thesis sought to answer three research questions regarding the impact of orthophosphate treatment, the nature of the mechanism by which orthophosphate controls copper corrosion, and the value of equilibrium modeling in predicting orthophosphate’s effects. The research questions were answered through a comprehensive literature review and experimental methodology integrating laboratory jar tests, water sampling and analysis from a field investigation, qualitative solids analysis, and equilibrium model application. This study analyzed field data obtained over the course of …
Using Value-Focused Thinking To Evaluate The Use Of Innovative Stormwater Management Technologies On Air Force Installations, Jeffrey T. Falcone
Using Value-Focused Thinking To Evaluate The Use Of Innovative Stormwater Management Technologies On Air Force Installations, Jeffrey T. Falcone
Theses and Dissertations
Stormwater runoff occurs naturally after every storm event; however, traditional development practices have created many impervious surfaces, such as buildings, parking lots, and streets that increase runoff volume and flow rate. Conventional stormwater management practices focus on collecting runoff into centralized channels and conveying it as quickly as possible to local bodies of water. This type of conveyance system decreases the opportunity for stormwater to naturally infiltrate back into the ground. It also prevents contaminants from being naturally filtered out of stormwater flows. As a result, centralized conveyance systems can cause flooding, erosion, and terrestrial and aquatic habitat degradation. Innovative …
Characterization Of Chlorinated Ethene Degradation In A Vertical Flow Constructed Wetland, James M. Waldron
Characterization Of Chlorinated Ethene Degradation In A Vertical Flow Constructed Wetland, James M. Waldron
Theses and Dissertations
Chlorinated solvents, including perchloroethene (PCE) and trichlorethene (TCE), are among the most common groundwater contaminants found in the United States. Once released into the environment, chlorinated solvents are extremely persistent and often require costly and lengthy remedial actions. The use of constructed wetlands has shown promise as an effective and less costly alternative for the treatment of chlorinated solvent contaminated groundwater. This study characterized and evaluated the concentration of chlorinated ethenes within a vertical flow constructed wetland, fed with PCE contaminated groundwater, at Wright-Patterson Air Force Base (WPAFB), Ohio. Chlorinated ethene concentrations were characterized within three distinct layers of the …
Evaluation Of Microbial Diversity In Wetland Through Polymerase Chain Reaction (Pcr) And Restriction Fragment Length Polymorphism (Rflp), Gregory K. Joseph
Evaluation Of Microbial Diversity In Wetland Through Polymerase Chain Reaction (Pcr) And Restriction Fragment Length Polymorphism (Rflp), Gregory K. Joseph
Theses and Dissertations
The diversity of microbial communities in wetlands has not been fully measured. These communities may offer tools to naturally remediate sites polluted with chlorinated compounds. Polmerase Chain Reaction (PCR) and Restriction Fragment Length Polymorphism (RFLP) are genomic techniques that are capable of rapidly characterizing bacteria communities and can provide valuable information about the diversity of microbial communities.
Molecular Characterization Of Wetland Soil Bacterial Community In Constructed Mesocosms, Ethan C. Bishop
Molecular Characterization Of Wetland Soil Bacterial Community In Constructed Mesocosms, Ethan C. Bishop
Theses and Dissertations
The use of wetlands to effectively remediate aquifers contaminated with chlorinated solvents is an emerging technique, which shows high promise. In order to better understand this process and test its legitimacy, a treatment wetland was constructed at Wright-Patterson AFB, Dayton, Ohio and, in a joint effort with Wright State University (WSU), has previously shown the effective removal of PCE. The purpose of this research was to characterize the soil bacterial community, pre-PCE injection, among three wetland plant species from the sedge family (Cyperaceae) within constructed wetland mesocosms and to identify any bacterial dominance. Carex comosa, Scirpus atrovirens, and Eleocharis erythropoda …
Investigation Of Copper Contamination And Corrosion Scale Mineralogy In Aging Drink Water Distributions Systems, Nadja F. Turek
Investigation Of Copper Contamination And Corrosion Scale Mineralogy In Aging Drink Water Distributions Systems, Nadja F. Turek
Theses and Dissertations
Research has shown higher levels of copper appear in drinking water conveyed through relatively new copper piping systems; older piping systems typically deliver lower copper levels in their drinking water. This research contributes field data from a real drinking water distribution system, providing a better understanding of this phenomenon, as it relates to treatment considerations and compliance with the Lead and Copper Rule. Copper pipes and copper levels were sampled from drinking water taps of 16 buildings with pipes ranging in age from less than 1 to 48 years. Water samples from each building were collected before and following a …
Modeling Study To Quantify The Benefits Of Groundwater Contaminant Source Remediation, David E. Wagner
Modeling Study To Quantify The Benefits Of Groundwater Contaminant Source Remediation, David E. Wagner
Theses and Dissertations
The purpose of this research was to quantify the benefits of groundwater contaminant source remediation by using a model to simulate how reduction of source mass was related to reduction of contaminant concentration at a receptor. This thesis sought to answer three research questions: (1) how are contaminant source mass reduction and reduction of mass flux leaving the source-zone related; (2) how can we quantify the effect of the important natural attenuation processes that act upon the dissolved contaminant as it travels from the source zone to downgradient receptors, and (3) under specified site conditions, what is the maximum contaminant …
Analysis Of Bacterial Population And Distribution In The Developing Strata Of A Constructed Wetland Used For Chlorinated Ethene Bioremediation, Milton J. Clausen Jr.
Analysis Of Bacterial Population And Distribution In The Developing Strata Of A Constructed Wetland Used For Chlorinated Ethene Bioremediation, Milton J. Clausen Jr.
Theses and Dissertations
Chlorinated hydrocarbons and their degradation products are among of the most common organic groundwater contaminates in the United States. These compounds attack the central nervous system in animals and can affect the photosynthesis of plants. These compounds are also resistant to degradation in the environment and, because of this, pose a risk to any ecosystem in which they are present. This study identified the dominant microbial species in a constructed treatment wetland at Wright-Patterson AFB, Dayton, Ohio using 16S rRNA gene sequence analysis. Samples were taken from three different depths and during each of the four seasons. These samples were …
Removal Of Cyclohexane From A Contaminated Air Stream Using A Dense Phase Membrane Bioreactor, Michael G. Roberts
Removal Of Cyclohexane From A Contaminated Air Stream Using A Dense Phase Membrane Bioreactor, Michael G. Roberts
Theses and Dissertations
The purpose of this research was to determine the ability of a dense phase membrane bioreactor to remove cyclohexane, a volatile organic compound in JP-8 jet fuel, from a contaminated air stream using a biologically active film for degradation. The research answered questions regarding applications of membrane bioreactors, the ability of cyclohexane to diffuse through a dense phase membrane, growth of a viable microbial culture, and determination of the performance capabilities of the reactor. To answer these questions, a literature review was conducted and laboratory experiments were performed. Through the design, construction, and testing of the dense phase membrane bioreactor …
Validation Of An Innovative Groundwater Contaminant Flux Measurement Method, Seh J. Kim
Validation Of An Innovative Groundwater Contaminant Flux Measurement Method, Seh J. Kim
Theses and Dissertations
The ability to measure groundwater contaminant flux is increasingly being recognized as crucial in order to prioritize contaminated site cleanups, estimate the efficiency of remediation technologies, measure rates of natural attenuation, and apply proper source terms to model groundwater contaminant transport. An innovative mass flux measurement method using horizontal flow treatment wells (HFTWs) was developed recently to compensate for the disadvantages of other flux measurement methods that are being used. Flux measurement methods can be categorized as either point methods or integral methods. As the name suggests, point methods measure flux at a specific point or points in the subsurface. …
An Investigation Into Palladium-Catalyzed Reduction Of Perchlorate In Water, Eric G. Barney
An Investigation Into Palladium-Catalyzed Reduction Of Perchlorate In Water, Eric G. Barney
Theses and Dissertations
In this study, application of a catalytic reactor to facilitate chemical reduction of perchlorate was investigated. Palladium-coated pellets were used as the catalyst, and formic acid was used as the reductant. Reactor performance was evaluated under a variety of operating conditions (influent pH, reductant concentration, residence time). Very little perchlorate reduction was observed under any operating condition. At best, approximately 8% perchlorate reduction was observed. This small reduction efficiency is clearly not sufficient for environmental treatment applications. Perchlorate strongly adsorbed to the catalyst at low pH (3 - 3.3). At higher pH (4 - 10), little adsorption was observed. This …
An Analysis Of The Relationship Between Environmental Management And Environmental Compliance At Marine Corps Installations, Bevin J. Keen
An Analysis Of The Relationship Between Environmental Management And Environmental Compliance At Marine Corps Installations, Bevin J. Keen
Theses and Dissertations
Environmental compliance on military is challenging for a number of reasons, including the complexity of regulations, and the variety of operations which impact the environment. At times, public concerns and penalties stemming from environmental issues has infringed upon the United States Marine Corps' (USMC) ability to use all installation resources without restriction. This thesis examines which facets of environmental management are closely associated with high levels of compliance. Five variables of interest: Total Compliance, Total Management, Audit Management, Policy Management, and Training Management were isolated from 1998-2004 USMC environmental audit data, and subjected to statistical analysis. Through the examination of …
Modeling Groundwater Flow And Contaminant Transporting Fractured Aquifers, Jason M. Bordas
Modeling Groundwater Flow And Contaminant Transporting Fractured Aquifers, Jason M. Bordas
Theses and Dissertations
The hybrid discrete fracture network/equivalent porous medium (DFN/EPM) model was selected for analysis and application to simulate a contaminated site in this study. The DFN/EPM was selected because it appeared to have the potential to aid decision making by remedial project managers at contaminated DoD fractured aquifer sites. This model can use data that are typically available at a site while incorporating the important processes relevant to describing contaminant transport in a fractured medium. The model was applied to simulate the operation of a pump-and-treat remedial action at a trichloroethene-contaminated fractured aquifer at Pease AFB. The model was able to …
An Evaluation Of Wind Turbine Technology At Peterson Afb, Randy C. Combs
An Evaluation Of Wind Turbine Technology At Peterson Afb, Randy C. Combs
Theses and Dissertations
Wind energy technology is a viable source for attaining the emission reduction and renewable energy use goals set forth by the executive office. In accordance with Executive Orders, the Air Force must reduce greenhouse emissions and energy consumption, and expand the use of renewable energy sources within its facilities nation-wide by year 2010. This mandate requires that the Air Force look at alternative electrical production and rely more on such renewable energy resources as wind power. The specific problem addressed by this research is whether on-site wind energy generation can be more economically feasible than the conventional energy consumption at …
Modeling Application Of Hydrogen Release Compound To Effect In Situ Bioremediation Of Chlorinated Solvent-Contaminated Groundwater, Ryan C. Wood
Theses and Dissertations
This study investigates how application of Hydrogen Release Compound (HRC) might be implemented to remediate a site contaminated with tetrachloroethene (PCE) or its daughter products, under varying site conditions. The 3-D reactive transport model RT3D was coupled with a dual-Monod biodegradation submodel to simulate the effect of the hydrogen generated by HRC on accelerating the biodegradation of dissolved chlorinated solvents. Varying site conditions and injection well configurations were investigated to determine the effect of these environmental and design conditions on overall treatment efficiency. The model was applied to data obtained at a chlorinated solvent contaminated site at Vandenberg AFB, where …