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Articles 121 - 150 of 222

Full-Text Articles in Environmental Engineering

Characterization Of Microbial Processes That Degrade Chlorinated Solvents In A Constructed Wetland Using Organic Acid And Inorganic Anion Concentration Profiles, Chad B. Bondurant Mar 2004

Characterization Of Microbial Processes That Degrade Chlorinated Solvents In A Constructed Wetland Using Organic Acid And Inorganic Anion Concentration Profiles, Chad B. Bondurant

Theses and Dissertations

Chlorinated solvents have been used in industrial cleaning and degreasing processes in the United States since the early 1900s, and their induction into the environment increased significantly with the growth of industrial processes over the past century. PCE, TCE and their daughter products have been associated with a number of human health concerns and are currently the most common contaminants found in groundwater in the United States. Wetlands possess characteristics necessary for the complete degradation of chlorinated ethenes by microorganisms via anaerobic and aerobic regions that foster the necessary oxidation-reduction conditions. Organic acid and inorganic anion concentrations were evaluated in …

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Application Of Horizontal Flow Treatment Wells For In Situ Treatment Of Mtbe-Contaminated Groundwater, Preston F. Rufe Mar 2004

Application Of Horizontal Flow Treatment Wells For In Situ Treatment Of Mtbe-Contaminated Groundwater, Preston F. Rufe

Theses and Dissertations

This study utilized a three-dimensional numerical model to evaluate the potential application of HFTWs to manage MTBE-contaminated groundwater. HFTWs consist of two dual-screened treatment wells. One well operates in an upflow mode, with MTBE-contaminated water extracted from an aquifer through a screen in the deep portion of an aquifer and injected into the aquifer through a shallow well screen, while the adjacent well operates in a downflow mode, extracting water from the shallow zone of the aquifer and injecting it into the deep zone. As the MTBE-contaminated water flows through the wells, an electron acceptor and/or another electron donor is …

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Making The Business Case For Sustainable Design In The Department Of Defense, David M. Warnke Mar 2004

Making The Business Case For Sustainable Design In The Department Of Defense, David M. Warnke

Theses and Dissertations

Buildings are one of the largest consumers of natural resources, a major source of ecological pollution, and occasionally toxic to human health. Sustainable design is the common term associated with buildings which, during their construction, use, and eventual disposal, seek to minimize their negative impact on the environment and human health. The U.S. Green Building Council's Leadership in Energy and Environmental Design (LEED) rating system helps to assess a building's sustainability level. In the Federal Government's push to set the example for the rest of the nation, nearly every Federal Agency has chosen to adopt the LEED assessment tool. Each …

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Modeling A Field Application Of In Situ Bioremediation Of Perchlorate-Contaminated Groundwater Using Horizontal Flow Treatment Wells (Hftws), Peter G. Chosa Mar 2004

Modeling A Field Application Of In Situ Bioremediation Of Perchlorate-Contaminated Groundwater Using Horizontal Flow Treatment Wells (Hftws), Peter G. Chosa

Theses and Dissertations

Perchlorate contaminated groundwater is rapidly becoming a significant environmental remediation issue for the Department of Defense. In this study, an existing numerical model that simulates the operation of a Horizontal Flow Treatment Well (HFTW) system to effect the in situ biodegradation of perchlorate through the addition of an electron donor is modified to include a submodel that describes bioclogging. Bioclogging restricts flow out of the HFTW due to the accumulation of biomass directly adjacent to the well. The modified model is then applied to an existing perchlorate contaminated site that will be used for an evaluation of the HFTW technology. …

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Characterization Of Chlorinated Solvent Degradation In A Constructed Wetland, Nathan D. Clemmer Mar 2003

Characterization Of Chlorinated Solvent Degradation In A Constructed Wetland, Nathan D. Clemmer

Theses and Dissertations

Widespread chlorinated ethene contamination of aquifers coupled with high costs of current treatment technologies demand innovative remediation solutions. Wetlands, maintaining anaerobic and aerobic zones promoting the complete degradation of chlorinated ethenes such as Tetrachloroethylene (PCE), could be the answer. This thesis characterized the chlorinated solvent contamination levels in three strata of an upward flow constructed wetland. Analysis of samples was accomplished by purge-and-trap gas chromatography. Water quality parameters, Dissolved Oxygen (DO), Oxidation Reduction Potential (ORP), pH, Conductivity, and Temperature, were also measured in monitoring wells with a water monitoring sonde. After removing data outliers caused by short-circuiting flow, PCE concentrations …

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Optimizing An In Situ Bioremediation Technology To Manage Perchlorate-Contaminated Groundwater, Mark R. Knarr Mar 2003

Optimizing An In Situ Bioremediation Technology To Manage Perchlorate-Contaminated Groundwater, Mark R. Knarr

Theses and Dissertations

Combining horizontal flow treatment wells (HFTWs) with in situ biodegradation is an innovative approach with the potential to remediate perchlorate-contaminated groundwater. A technology model was recently developed that combines the groundwater flow induced by HFTWs with in situ biodegration processes that result from using the HFTWs to mix electron donor into perchlorate-contaminated groundwater. A field demonstration of this approach is planned to begin this year. In order to apply the technology in the field, project managers need to understand how contaminated site conditions and technology design parameters impact technology performance. One way to gain this understanding is to use the …

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Modeling Catalytic Destruction Of Subsurface Contaminants In Recirculating Wells, Kerry J. Cadena Mar 2003

Modeling Catalytic Destruction Of Subsurface Contaminants In Recirculating Wells, Kerry J. Cadena

Theses and Dissertations

Groundwater and soil contamination is a significant problem throughout the nation, with approximately 300,000 to 400,000 sites affected (National Research Council, 1994). Examples of groundwater contaminants of special interest to DoD and AF installations include fuel hydrocarbons, chlorinated hydrocarbons, and nitroaromatic compounds. Traditional remediation technologies, which include pump-and-treat, permeable reactive barriers, and natural attenuation, have numerous drawbacks associated with them. These drawbacks have prompted researchers to look for innovative contamination clean-up methods. The technology investigated in this thesis, reticulating horizontal flow treatment wells (HFTWs) with in-well palladium (Pd) catalyst reactors, offers the potential for destruction of groundwater contaminants commonly found …

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Palladium-Catalyzed Destruction Of Nitro Aromatic-Contaminated Groundwater, Dennis Landon Phillips Mar 2003

Palladium-Catalyzed Destruction Of Nitro Aromatic-Contaminated Groundwater, Dennis Landon Phillips

Theses and Dissertations

Of the over 17,000 DoD sites that potentially require remediation, sites containing soil and groundwater contaminated by energetic compounds are prevalent (Larson et al., 2001). Production of energetics such as 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5 - trinitro- 1,3,5 -triazine (RDX), and octahydro-1,3,5,7-tetranitro- 1,3,5,7-tetrasocine (HMX) for use in munitions has created a DoD-wide problem due to improper disposal techniques (Price et al., 2001), Nitro aromatic compounds (NACs) similar to those used in explosives can also be found in insecticides, herbicides, pharmaceuticals, dyes, plastics, and many other commonly used products. The natural breakdown of these contaminants creates byproducts such as amines, which are known …

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Groundwater Flow Through A Constructed Treatment Wetland, Andrew C. Entingh Mar 2002

Groundwater Flow Through A Constructed Treatment Wetland, Andrew C. Entingh

Theses and Dissertations

This study examines the flow of groundwater through one of the treatment cells. A major goal of the study is to determine whether the system design facilitates uniform vertical flows through the subsurface soil sediments or if preferential flows occur. Conceptually, uniform flows will achieve the most efficient degree of contaminant removal possible by evenly dispersing the groundwater contaminants throughout the full volume of the subsurface media. A three-dimensional grid of piezometers is used to generate potentiometric contour maps, and in-situ tests of hydraulic conductivity facilitate construction of a numerical computer model. The contours of hydraulic head, measured conductivities, and …

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Determination Of Chlorinated Solvent Contamination In An Upward Flow Constructed Wetland, Bryan C. Opperman Mar 2002

Determination Of Chlorinated Solvent Contamination In An Upward Flow Constructed Wetland, Bryan C. Opperman

Theses and Dissertations

The purpose of this study is to determine chlorinated solvent contamination levels in an upward flow constructed wetland at Wright-Patterson Air Force Base (WPAFB), Ohio. A stratified grid sampling methodology will be used in sampling the contaminated groundwater. Analysis will be accomplished by means of purge-and-trap gas chromatography. The contaminant concentration levels will be used to enhance the design and construction of man-made wetlands used to remove chlorinated solvents from aquifers. PCE levels declined from an average of 33.97 ppb in the inflow stream to an average of 3.65 ppb in the upper layer, a 91% reduction. High concentrations occurred …

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Hexavalent Chromium Dissociation From Overspray Particles Into Fluid For Three Aircraft Primers, Richard A. Schilke Mar 2002

Hexavalent Chromium Dissociation From Overspray Particles Into Fluid For Three Aircraft Primers, Richard A. Schilke

Theses and Dissertations

DOD and industry use chromate-containing primers extensively to inhibit corrosion on metal assets. Chromate contains Cr6+, a human carcinogen, but there is little epidemiological evidence of increased lung cancer among spray painters. Using bio-aerosol impingers, overspray particles from three primers (solvent-borne epoxy, water-borne epoxy, and solvent-borne polyurethane) were collected into water to test the hypothesis that the paint matrix inhibits Cr6+ release into water, under the premise that this simulates Cr6+ release from particles into lung fluid. Particles were allowed to reside in water for 1 or 24 hours, then separated from the water by centrifugation, …

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An Analysis Of Horizontal Flow Treatment Well Applicability For The Treatment Of Chlorinated Solvent Contaminated Groundwater At United States Forces Korea Installations, Michael R. Staples Mar 2002

An Analysis Of Horizontal Flow Treatment Well Applicability For The Treatment Of Chlorinated Solvent Contaminated Groundwater At United States Forces Korea Installations, Michael R. Staples

Theses and Dissertations

Past research has shown that there is a rising public concern with environmental issues in the Republic of Korea (ROK). As Korean government and public interest in the environment grow, there is likely to be increased pressure to remediate environmental contamination at United States Department of Defense (DoD) installations in Korea. Impacting DoD's ability to remediate contaminated sites overseas is the fact that limited environmental funds must compete with high priority mission requirements. Thus, particularly at overseas bases, there is an urgent need for inexpensive and effective groundwater remediation technologies. Horizontal Flow Treatment Well (HFTW) systems have been demonstrated in …

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Modeling Biodegradation Of Chlorinated Groundwater Contaminants Under Iron-Reducing Conditions Of A Constructed Wetland: A System Dynamics Approach, Max E. Johnson Mar 2001

Modeling Biodegradation Of Chlorinated Groundwater Contaminants Under Iron-Reducing Conditions Of A Constructed Wetland: A System Dynamics Approach, Max E. Johnson

Theses and Dissertations

The purpose of this study is to determine and explore the fundamental processes associated with biodegradation of chlorinated ethenes in iron-reducing conditions of a constructed wetland and to evaluate the impacts of changing conditions (both natural and engineer-controlled) on the system. The modeler uses a system dynamics approach to construct a model that represents behavior in the iron-reducing environment. The model incorporates hematite, a form of oxidized iron (Fe3+), as the electron acceptor in microbial biodegradation in the system. Vinyl chloride, cis-dichloroethene, and trans-dichloroethene are known to anaerobically degrade to carbon dioxide in the presence of oxidized iron. …

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A System Dynamics Approach To Modeling Temperature Effects In Solid Waste, David A. Jokinen Mar 2001

A System Dynamics Approach To Modeling Temperature Effects In Solid Waste, David A. Jokinen

Theses and Dissertations

The amount of municipal solid waste discarded to landfills is continually increasing even with extensive recycling efforts. The need to understand the behavior of waste in landfills is increased due to the decreasing number of active landfills, communities' concern to the potential hazards associated with landfills, and companies or installations with landfills on-site need to understand landfill behavior comply with new legislation concerning design and detecting hazardous material movement of-site. This research is focused on increasing the understanding of landfill behavior by examining the effects of temperature in a landfill system. A system dynamics approach was used in this research …

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Chromate Content Bias As A Function Of Particle Size In Aircraft Primer Paint Overspray, David B. Novy Mar 2001

Chromate Content Bias As A Function Of Particle Size In Aircraft Primer Paint Overspray, David B. Novy

Theses and Dissertations

Spray painting operations using chromate-containing primer paints produce particles which may expose workers to strontium chromate. Chromate contains hexavalent chromium (Cr(VI)) which is a confirmed human carcinogen. It is suspected that the smaller particles contain disproportionately less Cr(VI) than larger particles. In order to determine if a bias in chromate content exists, paint particles were collected and separated based on particle size and the Cr(VI) concentration was determined. Aviation primer paint from the DeSoto and Deft companies was sprayed in a booth and seven-stage cascade impactors were used to separate particles.

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Modeling Chlorinated Ethene Removal In The Methanogenic Zone Of Constructed Wetlands: A System Dynamics Approach, Randall L. Roberts Mar 2001

Modeling Chlorinated Ethene Removal In The Methanogenic Zone Of Constructed Wetlands: A System Dynamics Approach, Randall L. Roberts

Theses and Dissertations

The purpose of this study is to gain understanding of the dynamics of the processes that degrade Perchloroethene (PCE) to ethene, within the confines of the methanogenic zone of a constructed wetland. A system dynamics modeling approach is used. This model is focused on determining conditions that will enhance contaminant degradation. The chemical and biological processes within the methanogenic zone of a wetland system are extremely complex and dynamic processes. The model is broken up into three simultaneous processes: dechlorination, methanogenesis, and fermentation. The system behavior of the methanogenic zone can be adequately described by the classical formulations of representative …

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A Model For Palladium Catalyzed Destruction Of Chlorinated Ethenes In Contaminated Groundwater, Christopher M. Stoppel Mar 2001

A Model For Palladium Catalyzed Destruction Of Chlorinated Ethenes In Contaminated Groundwater, Christopher M. Stoppel

Theses and Dissertations

Groundwater contamination by chlorinated ethenes is a widespread environmental problem. Conventional remediation technologies have shortcomings that have prompted further research into the development of novel treatment technologies. A palladium/ alumina catalyst in the presence of dissolved molecular hydrogen (referred to hereafter as a PD/H2 system) has been demonstrated to rapidly destroy chlorinated ethene contaminated groundwater. First-order kinetics have been used to model chlorinated ethene destruction in a PD/H2 reactor. However, catalyst deactivation and regeneration are important processes that also need to be modeled in order to better understand their effect on treatment efficiency. This study presents a model …

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Decision Analysis Methodology To Evaluate Integrated Solid Waste Management Alternatives For A Remote Alaskan Air Station, Mark J. Shoviak Mar 2001

Decision Analysis Methodology To Evaluate Integrated Solid Waste Management Alternatives For A Remote Alaskan Air Station, Mark J. Shoviak

Theses and Dissertations

Eareckson Air Station (AS), a remote U.S. Air Force installation, faces the complex decision of selecting a new municipal solid waste (MSW) management strategy to replace its current non-compliant system. This research effort applies value-focused thinking and multiattribute preference theory to decision analysis techniques to produce a multiple-objective decision analysis model that captures all of the site's MSW goals, objectives, and concerns in order to facilitate the evaluation of MSW management strategies available. The model ranks 40 specific MSW management alternatives, which were developed in accordance with the decision-maker's assumptions and constraints, based on how well they meet Eareckson's overall …

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Determining The Value Of Groundwater Contamination Source Removal: A Methodology, Benjamin C. Recker Mar 2001

Determining The Value Of Groundwater Contamination Source Removal: A Methodology, Benjamin C. Recker

Theses and Dissertations

Subsurface contamination by industrial chemicals is one of the most prevalent and costly environmental problems facing the United States government. This contamination problem must be managed to protect human health and the environment. Two basic strategies are used to deal with subsurface contamination: source removal and contaminant containment. While much cost and performance data are available for individual technologies associated with each of these strategies, there have been very few studies that have examined the benefits of implementing source removal technologies in order to reduce contaminant containment (and hopefully total) costs. This study examines the tradeoff between extent of source …

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Quantitative Validation Of A Model Of Chlorinated Ethene Natural Attenuation, Harold C. Young Mar 2001

Quantitative Validation Of A Model Of Chlorinated Ethene Natural Attenuation, Harold C. Young

Theses and Dissertations

Chlorinated ethenes are among the most prevalent groundwater contaminants at hazardous waste sites nationwide. In an attempt to manage the risks posed by these contaminants, while controlling costs, monitored natural attenuation (MNA) is being considered as a remediation strategy at many sites. MNA relies on naturally occurring physical, chemical, and biological processes in the subsurface to reduce the risk posed by the contamination. The implementation of MNA, however, requires a detailed understanding of these processes, and how they impact contamination at a particular site. One way to gain this understanding is through contaminant fate and transport modeling. In this study, …

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Effects Of Moisture Content In Solid Waste Landfills, Craig P. Eck Mar 2000

Effects Of Moisture Content In Solid Waste Landfills, Craig P. Eck

Theses and Dissertations

Solid waste landfills are an extremely complex and heterogeneous environment. Modeling the biodegradation processes within a landfill must involve an understanding of how environmental factors affect these processes. Arguably, the most important environmental factor influencing biodegradation processes is solid waste moisture content. This research effort, which is an extension of a system dynamics model previously presented by Colborn (1997) and amended by Benter (1999), attempts to understand and model the effects of moisture content on waste degradation and landfill gas generation. The new moisture structure that was added to the previous models provides a better representation of the impact of …

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In Situ Treatment Of Chlorinated Ethene-Contaminated Groundwater Using Horizontal Flow Treatment Wells, Derek R. Ferland Mar 2000

In Situ Treatment Of Chlorinated Ethene-Contaminated Groundwater Using Horizontal Flow Treatment Wells, Derek R. Ferland

Theses and Dissertations

The limitations of conventional containment technologies for groundwater contaminated with chlorinated solvents have motivated development of innovative technologies to achieve national groundwater remediation objectives. One inn9vative technology that is currently under development involves metal reductants or catalysts to chemically destroy the dissolved chlorinated solvent. Models are important tools that can be used to help transition this technology to the field. Model studies can be used to gain understanding about the technology, help determine when the prospective technology might work for a given site, and design full-scale field applications.

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Modeling The Effect Of Nonlinear And Rate-Limited Sorption On The Natural Attenuation Of Chlorinated Ethenes, Peter P. Feng Mar 2000

Modeling The Effect Of Nonlinear And Rate-Limited Sorption On The Natural Attenuation Of Chlorinated Ethenes, Peter P. Feng

Theses and Dissertations

Chlorinated solvents like tetrachloroethene (PCE) and trichloroethene (TCE) are the most common detected groundwater contaminants at Department of Defense installations in the United States. Unfortunately, technologies conventionally used to remediate chlorinated solvent-contaminated groundwater often fall short of achieving regulatory goals. Natural attenuation of chlorinated solvents offers an alternative remediation strategy that may achieve goals. However, the processes involved with natural attenuation are not fully understood, and this lack of understanding has hindered acceptance of natural attenuation by regulatory agencies. This study involved use of a numerical model that incorporated the physical, chemical, and biological processes thought to be relevant to …

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Use Of Genetic Algorithms To Characterize Groundwater Contamination Source Areas, Chaz M. Williamson Mar 2000

Use Of Genetic Algorithms To Characterize Groundwater Contamination Source Areas, Chaz M. Williamson

Theses and Dissertations

In this work, genetic algorithms (GAs) were used to help interpret tracer breakthrough curves from partitioning interwell tracer tests (PITTs) conducted at Hill AFB, Utah by researchers from the University of Florida. Two transport models were developed to simulate tracer transport in the test cells. One model assumed the cell consisted of multiple layers, and that transport in each layer could he described by the one-dimensional advective/dispersive equation. The second model also assumed multiple layers, and modeled transport in the individual layers as advective transport through 100 tubes. Transport times were represented by a stochastic (lognormal) distribution. The model solutions …

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Concept Design And Optimization Of Msw Management System, James R. Palmer Mar 1999

Concept Design And Optimization Of Msw Management System, James R. Palmer

Theses and Dissertations

The maximum recovery of recyclables from municipal solid waste (MSW) using material recovery facility (MRF) technologies is determined. Two waste streams at Spangdahlem AB, Germany are analyzed; stationary container wastes and commingled recyclables. Three schemes are considered, one for each waste stream, and one for both. Multi-criteria decision making is the methodology. The criteria are recovery and annual benefit minus cost (B-C). Recovery is determined using the recovery factor transfer function of Diaz et al. (1982). Each technology, or unit operation, in a sequence is independent because particle size distribution of each waste component is considered. B-C is based on …

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Expeditious Methods For Site Characterization And Risk Assessment At Department Of Defense Hazardous Waste Sites In The Republic Of Korea, Dean H. Hartman Mar 1999

Expeditious Methods For Site Characterization And Risk Assessment At Department Of Defense Hazardous Waste Sites In The Republic Of Korea, Dean H. Hartman

Theses and Dissertations

The overall goal of this research was to provide Department of Defense (DoD) decision-makers in the Republic of Korea (ROK) with preferred innovative site characterization technologies and risk assessment methods to meet their needs in obtaining hazardous waste site data and then prioritizing those sites for remediation based upon risk. The study examined the following: primary sources and types of existing contamination at DoD installations in the ROK; available site characterization data; criteria to be used in selecting innovative site characterization technologies; costs and capabilities of the innovative site characterization technologies; risk assessment or risk-based corrective action (RBCA) methods available …

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Substrate Availability In Solid Waste Landfills, Brian D. Benter Mar 1999

Substrate Availability In Solid Waste Landfills, Brian D. Benter

Theses and Dissertations

Numerous models exist to both predict and represent the many biological activities that occur in the modern landfill. These different models use varying methods of characterizing what is happening, what is thought to happen, or what should be happening based on both empirical data and theoretical reasoning. The model presented here is an extension of the system dynamics model originally presented by Colborn in 1997. The revamped model presents a different perspective on what happens as solid organic waste is transformed to simpler substances. This new view involves a bacterial population performing hydrolysis whose growth is limited by the amount …

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Development Of Site Characterization Simulator, Neil W. Kassel Mar 1999

Development Of Site Characterization Simulator, Neil W. Kassel

Theses and Dissertations

The purpose of this study was to develop a tool for Remedial Project Managers (RPMs) to learn and practice the site characterization process. One of the key difficulties encountered by RPMs during site characterization is the need to develop a model of the site based on limited data. These limited data are used to determine parameters that describe hydrogeologic and contaminant properties (aquifer hydraulic conductivity, contaminant concentration, etc.) and are obtained using sampling techniques that interrogate a very small volume, usually much smaller than node spacing of the computer model used to simulate site conditions. The value of the parameter …

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Optimal Pulsed Pumping Schedule Using Calculus Of Variation Methodology, Tay W. Johannes Mar 1999

Optimal Pulsed Pumping Schedule Using Calculus Of Variation Methodology, Tay W. Johannes

Theses and Dissertations

Application of a variational optimization technique has demonstrated the potential strength of pulsed pumping operations for use at existing pump-and-treat aquifer remediation sites. The optimized pulsed pumping technique has exhibited notable improvements in operational effectiveness over continuous pumping. The optimized pulsed pumping technique has also exhibited an advantage over uniform time intervals for pumping and resting cycles. The most important finding supports the potential for managing and improving pumping operations in the absence of complete knowledge of plume characteristics. An objective functional was selected to minimize mass of water removed and minimize the non-essential mass of contaminant removed. General forms …

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Natural Attenuation Of Chlorinated Ethenes By Anaerobic Reductive Dechlorination Coupled With Aerobic Cometabolism, Derek D. Veerkamp Mar 1999

Natural Attenuation Of Chlorinated Ethenes By Anaerobic Reductive Dechlorination Coupled With Aerobic Cometabolism, Derek D. Veerkamp

Theses and Dissertations

Chlorinated solvents and their daughter products are the most common contaminants of groundwater at industrial and military facilities in the United States. Limitations of conventional technologies have intensified efforts to find alternative methods to remediate contaminated sites to regulatory goals set by CERCLA. Natural attenuation of chlorinated solvents is a promising alternative to traditional pump and treat methods but has not been well understood or widely accepted. This modeling study investigated the ability of TCE to completely degrade under various aquifer conditions and rate order constants. It also examined a case study of a former landfill site at Moody AFB. …

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