Environmental Engineering Commons^™

Adsorption Capacity Assessment Of Advance Green Environmental Media To Remove Nutrients From Stormwater-Runoff, Hanan Elhakiem

Electronic Theses and Dissertations

Best Management Practices (BMPs) in stormwater treatment are a suite of treatment alternatives to deal with pollutant removal problems from stormwater runoff. Biosorption-activated media (BAM) are green sorption media consists of recycled materials have shown excellent nutrient removal as an effective BMP by enhancing physicochemical and microbiological processes. In this study, Iron-Filling Green Environmental Media (denoted as IFGEM-3) and Advanced Green Environmental Media 1 and 2 (denoted as AGEM-1 and AGEM-2) were produced and tested for their adsorption capacities as well as removal and recovery potential for phosphate, nitrate, and ammonia against natural soil (baseline) collected from a stormwater retention …

Optimal Recipe Screening And Applications Of Iron-Filings Based Green Environmental Media (Ifgem) For Stormwater Treatment, Andrea Valencia

Electronic Theses and Dissertations

The applications of green sorption media for stormwater treatment and nutrient removal benefit surface and ground water bodies by reducing non-point source pollution from stormwater runoff. To enhance nitrogen and phosphorus removal, a sequential study was performed to develop an improved green sorption media in this study by including the iron filings into the previous biosorption activated media (BAM). The iron-filings-based green environmental media (IFGEM) are thus composed of sand, tire crumb, clay and ground iron filings in which clay and iron particles are supposed to have salient interactions that cannot be present in BAM. However, the optimal ratio between …

Comparative Nutrient Removal With Innovative Green Soprtion Media For Groundwater And Stormwater Co-Treatment, Dan Wen

Electronic Theses and Dissertations

As indicated by the National Academy of Engineering, the understanding of nitrogen cycle has been deemed as one of 14 grand challenges in engineering of the 21st century. Due to rapid population growth and urbanization, the stormwater runoff increased in quantity as well as its nutrient concentrations, which may trigger serious environmental issues such as eutrophication in aquatic systems and ecosystem degradation. This study focuses on stormwater and groundwater quality control via Biosorption Activated Media (BAM) which can be applied to enhance the nutrient removal potential as an emerging Best Management Practices (BMPs). BAM was tested in this study with …

Variability Of E. Coli In Streambed Sediments And Its Implication For Water Quality, Sadia Salam

Electronic Theses and Dissertations

Fecal indicator bacteria (FIB), including E. coli, are the number one cause of water quality impairments in the United States according to the USEPA. FIB are used as a predictor to identify the possible presence of pathogens in waterbodies. E. coli is a useful indicator of gastrointestinal (GI) related illnesses from contact with fresh water. While surface water is routinely monitored for water quality, streambed sediments are rarely considered as a source of FIB to the overlying water column. This study focuses on understanding the variation of E. coli concentrations in streambed sediments and the potential impact of sediment sources …

Electrochemical Microsensors For In Situ Monitoring Of Chemical Compounds In Engineered And Natural Aquatic Systems, Jared Church

Electronic Theses and Dissertations

The adaption of needle-type electrochemical microsensor (or microelectrode) techniques to environmental science and engineering systems has transformed how we understand mass transport in biotic and abiotic processes. Their small tip diameter (5-20μm) makes them a unique experimental tool for direct measurements of analytes with high spatial and temporal resolutions, providing a quantitative analysis of flux, diffusion, and reaction rate at a microscale that cannot be obtained using conventional analytical tools. However, their applications have been primarily limited to understanding mass transport dynamics and kinetics in biofilms. With the advancement of sensor fabrication and utilization techniques, their potential applications can surpass …

Comparison Of A Modified And Traditional Rapid Infiltration Basin For Treatment And Control Of Nutrients In Wastewater Effluent, Jessica Cormier

Electronic Theses and Dissertations

Rapid infiltration basins (RIB) have been historically used in Florida for groundwater recharge, effluent disposal, or a combination of both. However, this technique has proven ineffective in providing nitrogen control unless the RIB is modified in some manner. In this study, a traditional RIB was compared to a modified RIB constructed with manufactured biosorption activated media (BAM) to evaluate nitrate removal from reclaimed water. The RIBs are used for reclaimed and excess storm water disposal. Few, if any, studies have been published where BAM-modified RIBs have been used for this purpose. In this work, a mixture of clay, tire crumb, …

Nanofiltration Of Perfluorinated Compounds As A Function Of Water Matrix Properties, Hadi Toure

Electronic Theses and Dissertations

Perfluorinated compounds (PFCs) have been manufactured and used in various industries including food packaging, paintings, and coating industries. Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) are the most commonly investigated PFCs that have bioaccumulative properties and a strong persistence in environment. Despite the growing interest in using membrane technology to remove PFOA and PFOS from water, little information is available on the impact of natural water matrices on the removal of PFOA and PFOS when using nanofiltration (NF). The presence of natural organic matter (NOM) and cations (Ca2+ and Mg2+) in water matrices and their interactions with the PFCs …

Assessment And Optimization Of Environmental Systems Using Data Analysis And Simulation., Milad Ebrahimi

Electronic Theses and Dissertations

For most environmental systems, specifically wastewater treatment plants and aquifers, a significant number of performance data variables are attained on a time series basis. Due to the interconnectedness of the variables, it is often difficult to assess over-arching trends and quantify temporal operational performance. The objective of this research study was to provide an effective means for comprehensive temporal evaluation of environmental systems. The proposed methodology used several multivariate data analyses and statistical techniques to present an assessment framework for the water quality monitoring programs as well as optimization of treatment plants and aquifer systems. The developed procedure considered the …

Cost And Environmental Impacts Of Leachate Nitrogen/Phosphorus Management Approaches, Alaa Alanezi

Electronic Theses and Dissertations

Landfill leachate is a challenging wastewater to discharge into municipal wastewater treatment plants (WWTPs), the most common approach for leachate management, due to the presence of contaminants that may affect the performance of the treatment plant. Treatment, disposal, and transportation of leachate are expensive and therefore a concern. Currently, sidestream treatment is becoming increasingly common in WWTPs prior to returning the liquid to the plant influent. For this research, a new treatment scheme is introduced combining centrate and leachate to reduce contaminants, recover phosphorous and nitrogen through struvite precipitation, and reduce energy requirements through anaerobic ammonium oxidation (Anammox). By combining …

Disinfection By-Product Reduction Study Of A Small Central Florida Public Water System, Paul Staubus

Electronic Theses and Dissertations

The disinfection of water for potabilization has proven to be one of the most significant public achievements of the 20th century. Although chemical disinfectants are successfully utilized to inactivate acute pathogenic organisms, they may react with natural organic matter (NOM) to produce potentially-harmful disinfection by-products (DBPs). As a result, the United States Environmental Protection Agency regulates DBPs such as total trihalomethanes (TTHMs) and haloacetic acids (HAAs). The research herein is focused on the formation, removal, and control of TTHMs and HAAs in a small public water system (PWS) in Polk County, Florida (County). Pilot-scale tests were implemented to determine the …

A Framework For Assessing Water Quality, Prioritizing Recovery Potential, And Analyzing Placement Of Best Management Practices, Tadesse Animaw Sinshaw

Electronic Theses and Dissertations

Motivated by the U.S. EPA goals, this research developed a framework to support identification and restoration of nutrient-impaired water bodies. The study objectives were developing total nitrogen (TN) and total phosphorus (TP) prediction models, evaluating the impact of social indicators on assessing recovery potential, and developing a spatial decision support system for choice and placement of best management practices (BMPS). An artificial neural network was used to develop TN and TP predictive regional models for U.S. lakes using easily measurable and cost-effective variables. The performance of models was superior for regions trained with larger datasets and/or regions with lower temperature …

Assessing The Impact Of Radionuclides Released Into The Floridan Aquifer By A Massive Sinkhole On Local Municipal Water Supplies, Maria Arenas Daza

Electronic Theses and Dissertations

In late August 2016, a sinkhole spanning 45 feet (13.7 meters) in diameter opened at a phosphate fertilizer facility (Mosaic Company) near Mulberry, Florida, leaking an estimated 215 million gallons (813,000 cubic meters) of radionuclide-contaminated water 300 feet into the Floridan aquifer. An investigation to determine possible impacts to the environment and local community drinking water supplies was implemented that focused on two 1.5 million gallon per day (MGD) Tampa Bay Water (TBW) production wells and two Polk County Utilities (PCU) water treatment facilities. Water samples collected between June 2017 and January 2018 at the TBW and PCU sites were …

Evaluating Hydrologic Fluxes Through Stormwater Treatment Systems: Implication To Freshwater Springs In A Karst Environment, Nyle Rice

Electronic Theses and Dissertations

In recent years, concentrations of nutrients such as nitrogen and phosphorus have increased in surface and groundwater resources, due in part to non-point source pollution associated with stormwater runoff. The elevated nutrient concentrations found in stormwater runoff have prompted the design of best management practices (BMP's) to mitigate the problem. The overall objective within this thesis is to analyze the performance of innovative surface BMPs and investigate connections between the BMPs and groundwater flows to freshwater springs within a karst environment. The performance of two stormwater BMPs, blanket filters and vertical reactors containing Bio-sorption Activated Media (BAM), are assessed in …

Use Of Accelerated Calcite Precipitation Method To Investigate Calcium Carbonate Precipitation From Recycled Concrete For Drainage System Applications, Toni Curate

Electronic Theses and Dissertations

Recycled concrete aggregate (RCA) is a sustainable construction material that is a viable option for use in drainage systems by replacing virgin aggregate. Replacing virgin aggregate with RCA is beneficial from both economic and environmental perspectives. However, the use of RCA as pipe backfill materials may cause a long-term performance issue such as potential clogging due to fines accumulation and calcite precipitation on filter fabric. Previous studies investigated the long-term performance of RCA regarding flow rate. Therefore, this study investigated calcite precipitation potential of RCA. The Accelerated Calcite Precipitation (ACP) procedure was devised and used to estimate "life-time" calcite precipitation …

Evaluating The Integration Of Chlorine Dioxide Into A Coagulation, Sedimentation, And Filtration Process Treating Surface Water, Martin Coleman

Electronic Theses and Dissertations

Methods of optimizing the coagulation, flocculation, sedimentation, and filtration (CSF) process at a conventional surface water treatment plant (WTP) were conducted to investigate opportunities for the reduction of disinfection by-product (DBP) precursor material. The research had two primary components: (1) optimize coagulant dosage and associated operating pH and (2) investigate pretreatment oxidation with chlorine dioxide (ClO2) and potassium permanganate (KMnO4). To accomplish the first component, jar tests were conducted at various pH and aluminum sulfate (alum) dosages to model current and potential treatment conditions during the CSF process at a WTP. Isopleths were developed to examine the removal efficiencies of …

Harmful Algal Bloom Mitigating Using Recycled Concrete Aggregate Coated With Fixed-Quat., Ikenna Ezeodurukwe

Electronic Theses and Dissertations

Human activities generate surplus nutrients which may lead to algal bloom events in water resources along with serious ecological problems and thus substantial economic losses. Particularly, harmful algal blooms (HABs) represent toxic cyanobacterial blooms which produce cyanotoxins. The primary concerns of HABs are the exposures to a wide variety of cyanotoxins via ingestion of contaminated drinking water, inhalation during recreational activities, and consumption of contaminated fish and shellfish. However, conventional physical and chemical methods are not always possible to efficiently handle these HABs events. It is urgent to develop viable and rapid solutions to control HABs in field and mitigate …

Treatment Of Leachate Organic Matter Through Sunlight Driven Processes, Duncan Lozinski

Electronic Theses and Dissertations

The ability to manage leachate during post-closure care (PCC) of a landfill may be increasingly difficult as leachate organic matter (LOM) becomes recalcitrant when a landfill ages, requiring advanced and costly treatment technologies. This research investigated the ability to treat LOM through sunlight driven processes, with a focus on photolysis, to provide insight to landfill owners and operators on the potential of wetlands treatment as a means for reducing long-term risks and costs associated with leachate treatment during PCC. The study was completed in eight batch tests, where leachate was exposed to natural sunlight in central Florida for a period …

Evaluating E. Coli Particle Attachment And The Impact On Transport During High Flows, Louis Amegbletor

Electronic Theses and Dissertations

Fecal indicator bacteria, including E. coli, are the leading cause of water quality impairments within assessed waters in the United States. The source of E. coli includes WWTP, leaking sewers, animal manure, wildlife, livestock, and stream bed sediment. Storm events contribute to bacteria loading within waters through wash-in of land sources of bacteria and resuspension of bacteria within sediments. Bacteria introduced into the water column are either attached to particles or are unattached (or free-living). The goal of this study was to examine the attachment of E. coli to different particle sizes, including their impact on contributing to water …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Engineering Applications Of Organic Surfactant Modified Bentonite In Sorptive Soil Barriers., Sadra Javadi

Electronic Theses and Dissertations

Earthen barriers such as CCLs and GCLs have been employed in geotechnical practices to provide a low permeability hydraulic barrier since long time ago. These types of barriers exhibited satisfactory performance for many applications such as landfills. The performance of low permeability barriers is based on the swelling potential of their component, which is mostly Na-bentonite, in contact with polar fluids such as water. However, the acceptable range of conductivity cannot be achieved by traditional earthen barriers when they are permeated by non-polar fluids such as gasoline. This phenomenon occurs due to the incompatibility of earthen barrier constituent with non-polar …

Cationic Surfactant Modification And Its Impact On The Engineering Behaviors Of Montmorillonite., Mohammad Ghavami

Electronic Theses and Dissertations

This study focuses on the microstructure of organoclays after organic surfactant modifications and the potential use in geoenvironmental engineering applications including waste containment in earthen barrier, rheological control agents for drilling fluid and soil stabilization. Organoclays, or clays modified by organic matters, are often synthesized by exchanging the naturally occurring interlayer inorganic cations (e.g., Na+, Ca²⁺) of the clay with organic cationic surfactants. In this research, montmorillonites intercalated with two quaternary ammonium surfactants, hexadecyltrimethylammonium (HDTMA+) and bis (hydrogenated tallow alkyl) dimethyl ammonium were used as the representative organo-rich, partitioning clays. The laboratory characterization techniques including XRD, TEM and …

Effect Of High Cationic Flocculant On Anaerobic Digestion Of Municipal Wastewater., Prathap D. John

Electronic Theses and Dissertations

Anaerobic digestion (AD) of municipal sludge is a widely used stabilization process at municipal wastewater treatment plants. It is highly effective in reducing sludge volume and produces methane gas which is used as fuel in the wastewater plant. Following digestion sludge is sent to a centrifuge to separate the solids from the liquids. Louisville MSD adds flocculent to material in the centrifuge to better coagulate the solids, thereby aiding in separation of the solids from the liquids. The potential for further AD, COD reduction, and methane generation of the liquid effluent from the centrifuge was unknown, particularly in regards to …

Assessing Interactions Between Estuary Water Quality And Terrestrial Land Cover In Hurricane Events With Multi-Sensor Remote Sensing, Chandan Mostafiz

Electronic Theses and Dissertations

Estuaries are environmentally, ecologically and environmentally important places as they act as a meeting place for land, freshwater and marine ecosystems. They are also called nurseries of the sea as they often provide nesting and feeding habitats for many aquatic plants and animals. These estuaries also withstand the worst of some natural disasters, especially hurricanes. The estuaries as well as the harbored ecosystems undergo significant changes in terms of water quality, vegetation cover etc. and these components are interrelated. When hurricane makes landfall it is necessary to assess the damages as quickly as possible as restoration and recovery processes are …

Development And Application Of Microelectrodes To Study In Situ Disinfectant Loss And Corrosion On Metal Surface, Xiangmeng Ma

Electronic Theses and Dissertations

The primary objective of this research was to develop, fabricate, evaluate and utilize microelectrodes to metal coupons in artificial water system. In the brass experiment, it presented profiles of direct measurements of free chlorine/monochloramine, oxygen and pH to brass and cement based coupons. In monochloraminated water, brass showed a much faster corrosion process under observation. Profiles showed a less monochloramine consumption with as high as 7% greater oxygen utilization comparing to the brass in free chlorine solution, reflecting oxygen could be a major part of the corrosion initiation process. While cement showed less reactive characteristics to disinfectants and oxygen compared …

Investigating Novel Water Treatment Methods And Monitoring Techniques For Sulfide-Laden Groundwater Supplies, Benjamin Yoakum

Electronic Theses and Dissertations

This dissertation reports on research related to novel water treatment and monitoring techniques for sulfide-laden groundwater supplies. The dissertation is divided into several chapters with four core chapters focused on investigations studying a novel water treatment method or monitoring technique. The first investigation assessed the efficacy of multi-pass spray aeration treatment to remove trihalomethanes (THMs) and to reduce the total THM formation potential (TTHMFP) of an aerated water column post-aeration. A recirculating spray aeration pilot unit was constructed to make this assessment. To assess the effect of multi-pass spray aeration on the TTHMFP, water was recirculated through a fabricated spray …

Evaluation Of Woodchip Bioreactor Denitrification Kinetics, Abdoul Aziz Kouanda

Electronic Theses and Dissertations

Agricultural subsurface drainage is a water management practice used to remove excess water in poorly drained soil. The use of fertilizers combined with subsurface drainage practice affects negatively surface water quality due to nutrient loss. Woodchip bioreactors have previously been used as a technology for removing nitrate from agricultural subsurface drainage. Understanding the mechanism that governs nitrate removal in woodchip bioreactors is crucial for field bioreactor design and application. The objective of this project is to determine woodchip bioreactor denitrification kinetics parameters under different operating conditions including hydraulic retention time, temperature and influent nitrate concentrations. Laboratory column experiments were conducted …

Linking Climate Change And Socio-Economic Impact For Long-Term Urban Growth In Three Mega-Cities, Qi Lu

Electronic Theses and Dissertations

Urbanization has become a global trend under the impact of population growth, socio-economic development, and globalization. However, the interactions between climate change and urban growth in the context of economic geography are unclear due to missing links in between the recent planning megacities. This study aims to conduct a multi-temporal change analysis of land use and land cover in New York City, City of London, and Beijing using a cellular automata-based Markov chain model collaborating with fuzzy set theory and multi-criteria evaluation to predict the city's future land use changes for 2030 and 2050 under the background of climate change. …

Biological Nutrient Removal (Bnr) Process Optimization And Recovery Of Embedded Energy Using Biodiesel By-Product, Sultan Salamah

Electronic Theses and Dissertations

Enhanced biological phosphorus removal (EBPR) as well as biological nitrogen removal require a carbon source to be carried out. Volatile fatty acid (VFAs) (mainly acetic and propionic acids) are the major driving force for EBPR. Many domestic wastewaters have an insufficient amount of VFAs. However, carbon sources such as acetic and propionic acids can be produced using primary solids fermentation process. Due to the cost of VFA production, an external carbon source can be added to the biological nutrient removal (BNR) system that can be fermented to provide the desired VFAs. Glycerol (biodiesel by-product) offers a solution to reduce carbon …

Reducing Sulfuric Acid Pretreatment In A Nanofiltration Process Treating Surficial Groundwater, Carlyn Higgins

Electronic Theses and Dissertations

Nanofiltration (NF) is a pressure driven membrane process employed in drinking water treatment that requires pretreatment for reliable operation. The objective of this research was to determine if NF membranes can proficiently operate with a decreased or eliminated dose of sulfuric acid pretreatment. When used as pretreatment, sulfuric acid prevents calcium carbonate scaling on NF membranes, yet is costly, hazardous, and imparts high sulfate concentrations to NF feed and concentrate streams. To conduct this research, a 0.324 million gallon per day (MGD) NF pilot plant was operated for 3,855 run-hours at a flux rate of 15 gallons per square foot-day. …

Extreme Weather Disaster Resilient Port And Waterway Infrastructure For Sustainable Global Supply Chain, Quang Van Nguyen

Electronic Theses and Dissertations

Global supply chain is largely dependent on seaports and marine terminals. Ports serve international cargo traffic for imports and exports. About 90% of the world’s goods are transported by sea and over 70% as containerized cargo ships. Coastal hurricanes/cyclones and rainfall flood disasters cause major disruptions for sea shipping traffic, disruptions of port infrastructure, and adverse impacts on coastal communities each year. Additionally, these weather related disasters threaten millions of people, damage infrastructure, and cost billions of dollars in global supply chain disruptions. Sustainable global supply chains, port infrastructure, and coastal community impact by these extreme weather disasters are the …