Environmental Engineering Commons^™

Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic emissions of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of humic-like substances (HULIS). Because further processing of polyphenols in secondary organic aerosols (SOA) can continue mediated by a mechanism of ozonolysis at interfaces, a better understanding about how these reactions proceed at the air–water interface is needed. This work shows how catechol, a molecular probe of the oxygenated aromatic hydrocarbons present in SOA, can contribute interfacial reactive species that enhance the production of HULIS under atmospheric conditions. Reactive semiquinone radicals are quickly produced upon …

Reply To ‘Co2 Emissions From Crop Residue-Derived Biofuels’, Adam Liska, Haishun Yang, Matthew P. Pelton, Andrew E. Suyker

Adam Liska Papers

The soil organic carbon (SOC) model that we used was parameterized with data from arable land under normal farming conditions in North America, Europe, Africa and Asia, but the equation is insensitive to changes in tillage, soil texture and moisture. The model has reasonable accuracy, however, in predicting changes in SOC, residue remaining and CO₂ emissions from initial SOC, carbon inputs from residue, and daily temperature; the shoot-to-root ratio used in the geospatial simulation was 0.29 (that is, root carbon is 29% of total aboveground carbon), which did not underestimate carbon input to soil (Supplementary Figure 2 in Ref. …

Interactive Comment On “Iodine Oxide In The Global Marine Boundary Layer” By C. Prados-Roman Et Al., Marcelo I. Guzman

Chemistry Faculty Publications

No abstract provided.

Estimating Mineral Weathering Rates In Catskills Watersheds, Chris E. Johnson

Civil and Environmental Engineering - All Scholarship

No abstract provided.

High Voltage Rear Electric Drivetrain Design For A Parallelthrough-The-Road Plug-In Hybrid Electric Vehicle, Adam Garrett Fogarty

Open Access Theses

Purdue University was selected as one of 15 universities to participate in a three year Advanced Vehicle Technology Competition (AVTC) called EcoCar2: Plugging Into the Future. The vehicle built by the Purdue team was a Parallel-Through-The-Road Plug-in Hybrid Electric Vehicle (PTTR PHEV). The vehicle utilized a B20 diesel powertrain to power the front wheels, as well as a custom electric drivetrain to power the rear wheels. Using this vehicle during the final year of the competition, the team was successful in placing 4th overall as well as 2nd in the category of Well-To-Wheel (WTW) Greenhouse Gas Emissions. A stock 2013 …

A New Passive Surface Water Flux Meter For Simultaneous Measurement Of Contaminant And Water Fluxes In Streams And Rivers, Stephen A. Sassman

Open Access Dissertations

A passive surface water flux meter (PSFM) for measurement of contaminant concentration/flux in rivers and streams is described and tested. The novel PSFM design was developed for portability and ease of adaptability for a variety of contaminant classes. Although previous designs have been evaluated under constant flow conditions, the PSFM has never been used for measurement of pesticides or hormones and this is the first time that it has been tested under transient flow. Discharge through the PSFM is assessed by measuring miscible displacement of alcohol tracers from granular activated carbon (GAC). The tracer retardation factors (R) measured by miscible …

Irrigation With Treated Wastewater: Potential And Limitations, Anne Dare

Open Access Dissertations

As the world population increases and resources become more coveted, water emerges as a key component to global food security. The Middle East and North Africa (MENA) is among the driest regions in the world: containing just one percent of the world's freshwater resources. An increasing population creates greater quantities of wastewater and demands greater quantities of food, so an obvious connection arises. However logical wastewater reuse may be for bridging the irrigation supply-demand gap in this arid region, significant limitations prevent widespread adoption. The overall goal of this research is to take a holistic view of the limitations facing …

Water Conservation To Reduce Wet Weather Pollution Loads To The Gowanus Canal, Brooklyn, Ny, Suzanne Carol Stempel

Dissertations, Theses, and Capstone Projects

Public participation plays an important role in wet weather pollution management. However, the effects of participation programs on local water quality are often difficult to quantify. This project aims to quantify the potential effects of a community based, non-structural, BMP aimed at controlling inputs to combined sewage systems by encouraging residents to reduce their water use during rain events. A household could participate by reducing the amount of water they use for flushing toilets, washing dishes, taking showers, etc. during rain events; thereby reducing stress on the system during the time of highest demand. The Gowanus Canal sewershed in Brooklyn, …

Hydro-Climate Temporal Variations And Their Influences On Net Primary Production In A Eurasian Steppe Watershed, Xiaomin Yang

Civil & Environmental Engineering Theses & Dissertations

Climate, which is the most important factor that influences Net Primary Productivity, has been detected changing all over the world. The confounding effects of step change invalidate the stationarity assumption of commonly used trend analysis methods such as the Mann-Kendall test technique, so previous studies have failed to explain inconsistencies between detected trends and observed large anomalies. In this research, by formulating a trend analysis approach that considers nonstationary due to step changes, trends and extreme occurrences of precipitation, temperature, and runoff in annual, seasonal, and monthly scales were analyzed in a mid-latitude Eurasian steppe watershed in northeast China, and …

2014 Fall Engr333 Project Assignment, Matthew K. Heun

ENGR 333

The Fall 2014 ENGR333 project focused on net zero homes.

I asked the students “What would it take for a home in Grand Rapids to become net-zero?”

Customer

The customers for this project were several homeowners in the Grand Rapids area.

Drinking Water Treatment: Reverse Osmosis, Bruce I. Dvorak, Sharon O. Skipton

Department of Civil and Environmental Engineering: Faculty Publications

Reverse osmosis (RO) membrane filters frequently are used to reduce the levels of total dissolved solids and suspended particles within water. Some contaminants treated effectively by RO membrane filters are listed in Table I. This table is not an exhaustive list of contaminants that RO may remove, but rather lists those for which RO can be a practical treatment method for treating household drinking water.

Analysis On The Issue Of Ship Sewage In Terms Of Pollution, Discharge And Reception In The Minjiang Inland Port With Countermeasures, Binsong Zheng

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

An Examination Of Radionuclide Transport In The Vadose Zone Using Field Lysimeters, Michael Witmer

All Theses

Understanding how radionuclides interact in the subsurface is important for the remediation of contaminated sites, assessment of risk due to radioactive waste disposal, and designing new radioactive waste management strategies. The current understanding of the geochemical behavior of radionuclides in the subsurface and more specifically the vadose zone has been developed through reactive transport modeling supplemented by laboratory experiments. Interactions between radionuclides with the mineral particles and organic matter in the vadose zone can be very complex and while laboratory experiments produce valuable data, few controlled, intermediate scale transport studies have been performed. In order to accurately predict vadose zone …

Anaerobic And Aerobic Biodegradation Of The Oil Dispersant Components 1,2-Propanediol And 2-Butoxyethanol In Seawater, Benjamin Rhiner

All Theses

Oil spills are a recurring issue associated with fossil fuel consumption. The largest accidental oil spill in the history of the petroleum industry was the Deepwater Horizon explosion and seafloor well blowout, where the Deepwater Horizon oil rig exploded and sank, allowing the well to gush uncontrolled from April 20, 2010, until it was capped on July 15, 2010, releasing an estimated 210,000,000 gallons of oil. Oil dispersants were used in unprecedented quantities during the cleanup response to the spill with a total of 1,840,000 gallons of the dispersant COREXIT being applied. The goal of this research was to evaluate …

Mathematical Equations And System Identification Models For A Portable Pneumatic Bladder System Designed To Reduce Human Exposure To Whole Body Shock And Vibration, Ezzat Aziz Ayyad

UNLV Theses, Dissertations, Professional Papers, and Capstones

A mathematical representation is sought to model the behavior of a portable pneumatic foam bladder designed to mitigate the effects of human exposure to shock and whole body random vibration. Fluid Dynamics principles are used to derive the analytic differential equations used for the physical equations Model. Additionally, combination of Wiener and Hammerstein block oriented representation techniques have been selected to create system identification (SID) block oriented models. A number of algorithms have been iterated to obtain numerical solutions for the system of equations which was found to be coupled and non-linear, with no analytic closed form solution. The purpose …

Opuntia Ficus-Indica Mucilage Potential To Remove Nuclear Active Contaminants From Water Based On A Surrogate Approach, Jose Adan Leon

USF Tampa Graduate Theses and Dissertations

Potable water is a necessity and unfortunately, it can be contaminated in many different ways. This paper specifically addresses the case scenario when, water has been contaminated by radionuclides. The mucilage of Opuntia ficus-indica (OFI), has been proven to be a great flocculating agent, turbidity reducer, crude oil dispersant and an environmentally friendly substance as an absorbent of water contaminants. In this work, the OFI mucilage was investigate to evaluate its capacity to separate radioactive ions from water. The surrogate approach is modeled based on water studies performed by Willi A. Brand, who proved that radioactive isotopes behave similar to …

A Fesability Analysis Of A Novel Constructed Wetland Design Tool For Arusha, Tanzania, Michael R. Sheehan

Open Access Theses

While water is a resource necessary for all life, in Tanzania alone over 20 million people who live in rural areas have no access to improved water sources. Water stress is a major concern in rural Tanzania, where annual potential evaporation can outpace precipitation by hundreds of mm per year. There is a significant need for improved access to water sources for Tanzanians living in rural regions of Arusha. To improve access to water, both water quantity and quality need to be addressed in a treatment system. Various water collection and treatment systems were compared and contrasted through the lens …

Systematic Analysis Of Drainage Events In Free Draining And Managed Subsurface Drainage Systems, Guy Bou Lahdou

Open Access Theses

Understanding the hydrologic controls that regulate outflow from free and managed subsurface drainage systems during drainage events can offer improved insight on the overall functioning and effectiveness of the systems so that they can be better managed or retrofitted to increase their environmental benefits. This study used drainage, precipitation, water table, and soil moisture data from a monitoring site located in east central Indiana to investigate the event hydrology of 22 drainage events in free and managed subsurface drainage systems. Relationships between event drainage volume, drain flow hydrograph metrics, column soil moisture, water table depth, and precipitation characteristics were explored …

Feasibility Of Mainstream Nitrite Oxidizing Bacteria Out-Selection And Anammox Polishing For Enhanced Nitrogen Removal, Pusker Raj Regmi

Civil & Environmental Engineering Theses & Dissertations

Short-cut nitrogen removal avoids nitrite oxidation to nitrate by nitrite oxidizing bacteria (NOB) and allows a) reduction of formed nitrite to nitrogen gas via heterotrophic denitrification and/or b) oxidation of remaining ammonia with formed nitrite to nitrogen gas via anaerobic ammonia oxidation (anammox). The precondition for achieving shortcut nitrogen removal is suppression of NOB, which is favored by warm and high ammonia strength conditions found in internally generated ammonia-rich waste streams through anaerobic digestion of waste solids referred to as sidestreams or reject water. The discovery of anammox bacteria in the mid-1990s, which are capable of transforming NH₄+ …

Evaluation Of The Epa Swmm Model To Simulate Low Impact Development Features In An Urban Stormwater Environment, Holly Ann Carpenter

Civil & Environmental Engineering Theses & Dissertations

This research thesis explores the use of the Environmental Protection Agency's (EPA) Stormwater Water Management Model (SWMM) to model an urban watershed with a developed stormwater management system and test the SWMM model's ability to simulate Low Impact Development (LID) features by proposing typical LID features that can be retrofitted to the developed study area. The SWMM model is established with an existing survey of the study area's stormwater management system, and due to the lack of field data for the study area, the model developed in this research thesis is calibrated with the consideration of a published stormwater model …

The Use Of Object-Oriented Programming Concepts For Documenting A Model Ensemble, Georgii A. Alexandrov

International Congress on Environmental Modelling and Software

The spread of cloud computing services gives community modelling a reasonable opportunity to become a reality in scientific research. However, even if models will be deployed in clouds, and model codes will be open for re-use, there will be little progress in community modelling in the lack of consensus standards for model documentation. This paper is to discuss a conceptual framework for developing such standards. The proposed conceptual framework is based on the idea that a new model is often a modification of an old one, and hence, the similarities between the models of the same environmental process could be …

Diffuse Nutrient Pollution From Residential Catchments, Melissa Rachelle Butcher

USF Tampa Graduate Theses and Dissertations

Nonpoint source nutrient pollution is diffuse pollution lacking discrete origin and conveyance. This thesis synthesizes and critically reviews research on residential nitrogen and phosphorus loss to stormwater runoff and leaching. The evaluation pulls from research covering influential socio-demographic indicators, such as use of lawn maintenance services and homeowner fertilizer practices. The extent to which such social and economic factors may influence the prevalence and fate of diffuse nutrients in stormwater runoff from residential areas has not been adequately established. Understanding the source and influencing factors of diffuse nutrient pollution is important in order to effectively protect surface and groundwater resources. …

Inactivation Of Ascaris In Double-Vault Urine-Diverting Composting Latrines In Panama: Methods And Environmental Health Engineering Field Applications, Daragh A. Gibson

USF Tampa Graduate Theses and Dissertations

The United Nations Millennium Development Goals have prioritized improving access to sanitation, but unfortunately about a third of the global population is still without an improved sanitation source and one billion still practice open defecation. Lack of access to adequate and safe sanitation means the proliferation of dangerous pathogens in the environment, especially soil-transmitted helminths (STHs). In the Bocas del Toro Province of Panama (and similar locations in the world), composting latrines have been built in many of the indigenous communities in the area. They are a form of dry or ecological sanitation and are designed to produce an end …

An Integral Framework For Sustainable Building Design, Bushra Asfari

Masters Theses

Selection of materials for building design is a delicate process hinged of a number of factors which can be cost or environmental related, depending on the objectives of the design. This process becomes more difficult when designers are faced with several material options for each building component. This thesis presents the design and development of a framework that enables designers understand the trade-off between cost and environmental related factors when selecting materials for building design. The framework is based on the integration of Autodesk Revit, Microsoft access, and modeling modified Harmony search multi-objective optimization tool adapted to account for material …

College Of Engineering Senior Design Competition Spring 2014, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

Adsorption Of Synthetic Organic Chemicals: A Comparison Of Superfine Powdered Activated Carbon With Powdered Activated Carbon, Semra Bakkaloglu

All Theses

In literature, manufacturer-supplied powdered activated carbon has been ground to produce submicron particles with mean diameter lower than 1µm for use as an adsorbent during water treatment. Superfine powdered activated carbon (SPAC) can be used for removal of natural organic matter as well as synthetic organic chemicals (SOCs) from water. It has been suggested that SPAC has higher adsorption capacity than powdered activated carbon (PAC) due to larger external surface area and mesopore volume. Another advantage of SPAC over PAC is the faster uptake rate for both NOM and SOC during adsorption owing to small particle size. Therefore, understanding SPAC …

Estimating Unsaturated Flow Properties In Coarse Conglomeratic Sediment, Michael James Thoma Jr.

Boise State University Theses and Dissertations

In this dissertation, I address the lack of knowledge of unsaturated flow in coarse, conglomeratic sediment by determining if functional θ-ψ-K relationships, specifically van Genuchten-Mualem (VGM) relationships, developed to predict unsaturated flow in relatively fine-grained sediment can be directly applied to coarse, conglomeratic sediment. In the summer of 2011, a field-scale infiltration test was conducted at the Boise Hydrogeophysical Research Site to determine if functional ψ-θ-K relationships could be applied to infiltration in coarse, conglomeratic sediment, and to estimate parameter values for the VGM relationships. Vertically and laterally distributed ψ(t) and θ( …

Assessing The Impacts Of Unrestricted Pesticide Use In Small-Scale Agriculture On Water Quality And Associated Human Health And Ecological Implications In An Indigenous Village In Rural Panam[Aacute], Sarah Louise Watson

USF Tampa Graduate Theses and Dissertations

In 2014, the global pesticide industry's projected worth is $52 billion and by 2020, the developing world will make up one-third of the world's chemical production and consumption. Pesticides can have unintended negative consequences for human health and the environment, especially in the developing world where regulations are loose or nonexistent. One country with unrestricted use of pesticides is Panam[aacute], especially in Santa Rosa de Cucunatí. In this indigenous village, small-scale farmers and ranchers spray paraquat, glyphosate, picloram, and 2,4-D at higher elevations than the spring water source of a gravity-fed water system, the river, and the village. The objective …

An Assessment Of The Emas Pump And Its Potential For Use In Household Water Systems In Uganda, Jacob Daniel Carpenter

USF Tampa Graduate Theses and Dissertations

Rural improved water supply coverage in Uganda has stagnated around 64% for a number of years and at this point more than 10 million rural people do not have access to an improved drinking water source. It has been recognized that progress toward improved water supply coverage and increased service levels may be gained through Government and nongovernmental organization (NGO) support of private investment in household and shared water supplies, commonly known as Self-supply. Self-supply can be promoted by introducing and building local capacity in appropriate and affordable water supply technologies such as hand-dug wells, manually drilled boreholes, low-cost pumps, …

Algae: Opportunities For Biomass Feedstock Production, Wastewater Treatment And Educational Outreach, Trina Cassandra Halfhide

USF Tampa Graduate Theses and Dissertations

Algae are a diverse group of simple organisms that lack roots, stems or leaves and are able to use sunlight, carbon dioxide, and nutrients to produce complex compounds, such as carbohydrates, proteins and lipids. These compounds, especially lipids, are highly sought-after by agricultural, nutraceutical and energy interests. Although there is great potential for algae derived biofuels, there are technical and economic challenges associated with their cultivation. Relevant to this dissertation, the environmental impacts associated with algae cultivation can be reduced by using municipal and agricultural wastewaters as a water and nutrient source. This research was divided into three sections to …