Civil Engineering Commons^™

Potential Use Of Waste-Derived Products In Producing Geopolymer Sorbents, Mariam Mohammed Al Nuaimi

Thesis/ Dissertation Defenses

Environmental sustainability and the circular economy are central to addressing global challenges in waste management and water pollution. This study investigates the synthesis and performance of geopolymers derived from industrial wastes, including fly ash, waste glass, silt deposits, and carbide lime, as adsorbents for methylene blue (MB) dye removal from water. Geopolymers were engineered under varying particle sizes, NaOH addition methods, and curing temperatures. Their physicochemical and microstructural properties were thoroughly characterized via scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier Transform Infrared Spectroscopy (FTIR), andparticle size analysis (PSA). Among the tested formulations, the sodium silicate–sodium hydroxide …

Integrating Off-Spec Scms Into Plc Blends, George A. Qubty

Civil Engineering Theses - Archive

Off-spec supplementary cementitious materials (SCMs) remain underutilized due to variability in reactivity and non-conformance with existing standards. This study evaluates the hydration behavior and fresh-state and mechanical performance of these materials in Portland limestone cement (PLC) systems. One Class F fly ash (FA), one bottom ash (BA), and two calcined clays (HACC and LACC) were evaluated as 20 % replacements to PLC. Hydration behavior was characterized using isothermal calorimetry and thermogravimetric analysis (TGA), while fresh-state and mechanical performance were assessed through flow table, Vicat setting time, load–crack mouth opening displacement (CMOD) flexural testing, and compressive strength testing. HACC increased compressive …

An Investigation Into The Effect Of Performance Engineered Mixture (Pem) Design On The Workability And Strength Of Concrete Pavement Mixtures, Alexander Cook

Graduate Theses and Dissertations

The Arkansas Department of Transportation (ARDOT) currently requires a minimum cement content of 564 pounds of cement per cubic yard of concrete. This minimum cement requirement can be reduced through the utilization of optimized gradation of aggregates within concrete mixtures as well as the addition of supplementary cementitious materials (SCMs) such as fly ash. The study presented in this paper aims to demonstrate how the use of the Tarantula Curve can be used to design concrete mixtures with reduced cement contents while maintaining sufficient workability for concrete mixtures to be used for slipform paving. Fresh workability was measured using the …

Performance Of Geopolymer Concrete Incorporating Recycled Aggregates And Glass Fibers, Mohammed Abughali

Thesis/ Dissertation Defenses

This study aims to investigate the potential use of geopolymer concrete (GC) incorporating recycled concrete aggregates (RCA) and glass fibers (GF) as a sustainable alternative to traditional cement-based concrete. It comprehensively evaluated the impact of RCA and GF on the fresh, physical, mechanical, and durability properties. A blended precursor binder consisting of ground granulated blast furnace slag and fly ash was utilized. To mitigate the challenges associated with the brittle behavior and low crack resistance of GC, mainly when incorporating RCA, two types of GF were used. Type A had a length of 24 mm, while Type B exhibited a …

Improvement Of Subgrade California Bearing Ratio (Cbr) Using Recycled Concrete Aggregate And Fly Ash, Safkat Tajwar Ahmed, Mozaher Ul Kabir, Chowdhury Zubayer Bin Zahid, Tahsin Tareque, Seyedali Mirmotalebi

Civil Engineering Faculty Publications

The study aims to understand the effect of different admixtures on improving the quality of flexible pavement subgrades. In this paper, recycled concrete aggregates (RCA) and Fly Ash were used as the admixtures in improving the maximum dry density (MDD), swelling potential, and California bearing ratio (CBR) of subgrade soil. The percentages of RCA and fly Ash used were 5%, 10%, and 15%. With the upscaling in fly ash dosage, the optimum moisture content and the California bearing ratio increased. However, the MDD of soil decreased for higher fly ash contents. On the contrary, the optimum moisture content (OMC) of …

Effect Of Lime Content, Curing Temperature, And Aging Condition On Low-Alkaline Concrete, Mahdi Parsa Pour, Reza Shaban Sharghi, Faezeh Nejati, Elmira Khaksar Najafi

Makara Journal of Technology

This study determines how curing temperatures, aging condition, and hydrated lime contents affect the unconfined compressive strength (UCS), modulus of elasticity, and workability of low-alkaline concrete. Samples were prepared in two different groups to determine the optimum hydrated lime content and aging conditions to assess the mutual effect of NaOH molarity and curing temperature, that is, 70 °C for 48 h or room temperature, on samples with and without lime. The results showed that the increase in hydrated lime content affected alkali concentration. The samples with lime exhibited a clear peak in UCS (6 M NaOH) compared with the continuous …

Mechanical And Durability Properties Of Fly Ash Geopolymer Concrete – A Review, Ali Shebli, Jamal Khatib, Adel Elkordi

BAU Journal - Science and Technology

Geopolymers have emerged as a promising alternative for Ordinary portland cement (OPC) in construction industry, due to their potential to minimize the emissions of carbon dioxide (CO₂) and improve the efficiency of waste recycling. This paper aims to study the fresh and hardened properties of fly ash geopolymer concrete (GPC), as well as to review the raw materials used in the production of geopolymers. Several factors impact the mechanical and durability properties of fly ash GPC, including the specific type of fly ash utilized, the curing temperature, the alkaline activator (AA) concentration, and the type of AA used. …

Investigation Of Natural Pozzolans: Analyzing The Practicality Of Natural Pozzolans As A Partial Substitute For Cement In Grout Production, Jadyn I. Breien, Andrew J. Baro, Logan T. Marino

Architectural Engineering

This senior project aims to investigate whether natural pozzolans are more sustainable than fly ash and a sufficient substitute for cement in the production of grout. By following the intent of the ASTM (American Society of Testing and Materials) standards, a conclusion will be made to determine if natural pozzolans can contribute comparable strength in compression. The objective is to prove that natural pozzolans should be utilized in the production of grout rather than alternatives such as fly ash because it can provide similar strength while being more economical and more sustainable.

Review Of Fly-Ash As A Supplementary Cementitious Material, Nikki Shaji, Niall Holmes Dr., Mark Tyrer

Conference papers

This paper presents a review of fly-ash as a Supplementary Cementitious Material (SCM) in concrete in terms of its effects on hydration and durability. The climate change agenda has focused the cement and concrete industry on using low embodied CO2 materials and much effort has been made on incorporating industrial by-products into cement as SCMs. With worldwide cement production (circa 4 billion tonnes) currently accounting for approximately 8% of global CO2 emissions and 7% of industry energy use, the use of suitable SCMs to partially replace cement in concrete is extremely important. However, while coal-fired power stations are in the …

The Effects Of Curing Temperature On The Hydration Kinetics Of Plain And Fly Ash Pastes And Compressive Strength Of Corresponding Mortars With And Without Nano-Tio2 Addition., Dan Huang, Mirian Velay-Lizancos, Jan Olek

International Conference on Durability of Concrete Structures

Incorporation of fly ash in cementitious systems containing ordinary portland cement (OPC) increases their long-term strength and durability. However, replacement of cement by fly ash also reduces the heat of hydration of such systems and reduces early-age strength development. The reduced rate of strength development can increase the risk of durability problems, e.g. scaling, in cases when young concrete is exposed to low temperatures and deicing chemicals. This study investigated the potential of nano-titanium dioxide (nano-TiO₂) particles to modify the hydration kinetics of fly ash pastes and compressive strength development of corresponding mortars cured under low (4°C) and …

Mechanical Behavior Of Clay Soil Stabilized With Fly Ash And Bottom Ash, Soewignjo Agus Nugroho, Azra Zulnasari, Ferry Fatnanta, Andius Dasa Putra

Makara Journal of Technology

Soil is one of the most important aspects of an infrastructure given its functions of receiving and holding structural loads. However, not all soils have good physical and mechanical properties. To overcome those conditions, stabilization of the soil is practiced to meet the technical requirements. This study aims to determine the behavior of high plasticity clay stabilized with lime, fly ash, and bottom ash. These additives can be used as a stabilizing agent to increase soil strength. The percentage of additives varied from 5%–25% then mixed with clay and were tested through the (Unconfined Compression Strength (UCS) test. The UCS …

Estimation And Mitigation Of Stresses In Mass Concrete Structures Containing Ground Granulated Blast Furnaceslag And Fly Ash, Guadalupe Leon

Graduate Theses, Dissertations, and Problem Reports (ETD)

In large concrete structures, due to concrete’s low thermal conductivity, the interior temperature rise can approach the concrete’s adiabatic temperature rise. As the concrete’s surface losses heat to the environment and cools rapidly, the interior of the concrete attempts to expand while the exterior provides an internal restraint. The phenomenon causes thermal stresses at the concrete’s surface. If the thermal stresses exceed the concrete’s tensile strength, there is a high probability of cracking. The cracks usually appear during the first few days after construction while the concrete’s tensile strength is low. These early-age cracks can reduce the service life of …

A Critical State Approach To The Mechanical Behavior Of Early-Age Cemented Paste Backfill, Amin B. Ghorbanpour

Civil Engineering Dissertations - Archive

Low plasticity to non-plastic mine tailings are typically transported to a storage area through pipelines in form of slurry or thickened tailings. The main concern with such tailings deposits is the possibility of liquefaction and the consequent failure of the tailings retaining dams. Tailings can also be used as Cemented Paste Backfill (CPB) material to fill previously mined underground voids. The state of practice to improve the mechanical properties of tailings is to add a small quantity of cementitious materials or binder agents. Portland cement (PC) is the most common binder agent that is used to improve the mechanical properties …

Effect Of Mix Parameters On Strength Of Geopolymer Mortars - Experimental Study, Abdolhossein Naghizadeh, Stephen O. Ekolu

International Conference on Durability of Concrete Structures

In this article, an investigation is reported on development of strength in South African fly ash (FA) – based geopolymer mixtures. Locally available Class F, FA from one of the coal power stations was used in the investigation. The alkali-activator used consisted of sodium silicate (SS) and sodium hydroxide (SH) mixed in varied ratios of 1.0, 1.5, 2.0, 2.5 and 3.0 SS to SH. The SS of silicate modulus = 2.5 was used but the SH concentration in the activator was varied to 10, 12, 14M NaOH. Mortars of 2.25 aggregate/binder ratio were used to prepare 50 mm cubes. In …

The Influence Of Waste Glass Powder On The Chloride Binding Capacity Of Fly Ash/Cement Hardened Paste, Jh Yan, Tingyu Hao

International Conference on Durability of Concrete Structures

The potential of using waste glass powder to increase the chloride binding capacity of fly ash/cement hardened paste was investigated. When only fly ash replacing cement, the chloride binding capacity was raised within 28d when the fly ash replacement level was in the range from 30-50% by mass. But at a longer age of 60 to 90d, the binding performance was increased at the replacement level of 10-30wt%. The chloride binding capacity of glass powder-fly ash-cement system was increased by adding glass powder of 2% and 4% by mass at 7d while those at larger addition and longer age reduced. …

Effect Of Nanosilica On The Sulfate Attack Resistivity Of Cement Mortar, Pengkun Hou, Zh Guo, Q Yu, N Xie, X Cheng, Sp Shah

International Conference on Durability of Concrete Structures

The effect of nanosilica on the sulfate attack resistivity of cement mortar was investigated through study on the mechanical property evolution and the length change of the cement mortar under 5 wt.% sodium sulfate for 6 months. Meanwhile, the effects were compared with those of fly ash-replacement mortar. Results showed that by taking the advantages of nanosilica and fly ash in improving the property of cement mortar at early and later ages, the sulfate attack resistance of cement mortar can be enhanced in mechanical property increase and expansion reduction. Further, it implies that a combination of both pozzolans could enhance …

Compressive Strength, Free Expansion And Shrinkage Of Expansive Concrete Containing Fly Ash, Warangkana Saengsoy, Rachot Chatchawan, Somnuk Tangtermsirikul

International Conference on Durability of Concrete Structures

This study is aimed to investigate effect of fly ash on compressive strength, free expansion and shrinkage of expansive concrete. High CaO and low CaO fly ashes are used in this study. The replacement percentages of total binders by fly ash are 0 and 30% by weight. The replacements of expansive additive are 0, 20 and 30 kg/m³ of concrete. The test results revealed that the use of fly ash especially the high CaO fly ash can enhance expansion of expansive concrete at early age. The use of fly ash also reduces shrinkage at long term of the expansive …

Feasibility Study For Sustainable Controlled Low-Strength Material (Clsm) Incorporating Off-Specification Fly Ash And Bottom Ash, Alexis K. Vandomelen

Masters Theses

“Controlled low-strength material (CLSM) is a self-consolidating cementitious material used in applications requiring high flowability and low strength. The primary components of this material, being cement and sand, however, negatively impact the environment. Cement is a large contributor to CO2 emissions, and the vast depletion of sand causes physical and political issues. Furthermore, over 100 million short tons of coal combustion products (CCP), including fly ash and bottom ash, are created annually in the United States, while nearly half of all CCP remain unused. No off-specification fly ash has been implemented in CLSM. This study uses coal ashes sourced from …

Thermal Curing Efficiency Of Geopolymer Mortars, Simon Peter Sargon

Masters Theses

”Missouri is the fourth largest coal consumer in the U.S. with coal-fired power plants generate 81.3% of the electricity in the state which generate about 2.7 million tons of coal combustion residuals (CCRs) annually. The CCR, including fly ash, disposal issue is not limited to Missouri, rather it is a national issue with CCRs being the second largest waste stream in the U.S. Ninety million tons of fly ash are stored in landfills and ash ponds annually. Hence, using this waste product effectively is necessary. One of the emerging applications of fly ash is to use it as binder in …

A Comparative Study On The Durability Of Geopolymer Mortars Produced With Ground Glass Fiber, Fly Ash, And Glass-Powder In Sodium Sulfate Solution, Hassan Rashidian-Dezfouli, Prasada Rao Rangaraju

Publications

An experimental investigation was conducted to investigate the performance of geopolymers made with three different precursors consisting of fly ash, Ground Glass Fiber (GGF), and Glass-Powder (GLP) exposed to sodium sulfate solution. Precursors were activated using either sodium hydroxide solution or combinations of sodium hydroxide and sodium silicate solution with varying levels of sodium and silica content. Among the mixtures with each of the three precursors, mortar mixtures with the highest compressive strength were selected to test their resistance against exposure to a 5% sodium sulfate solution. Changes in the weight and compressive strength of the specimens were monitored up …

Performance Of Lime- And Cement- Based Treatments Of Sulfate-Rich Soil Via Rc Testing, Azadeh Asghariastaneh

Civil Engineering Theses - Archive

Chemical treatment of expansive sulfate-rich soils, particularly lime- and cement-based methods, had been rather popular due to their relatively low cost and ready availability. However, over the last few decades, extensively documented pavement failures, mainly caused by excessive heaving and/or shrinkage of lime- and cement-treated subgrades with moderate-to-high sulfate content, have led to thorough investigations to assess the actual feasibility and effectiveness of calcium based stabilizers in sulfate-rich soils. Studies have concluded, with solid experimental evidence, that the calcium present in the chemical stabilizers react with the sulfate and alumina of the treated soil to form Ettringite, an expansive mineral …

Sustainable Reuse Of Fly Ash To Mitigate Landfill Methane, Sharon Priyadarshini

Civil Engineering Theses - Archive

According to US, EIA 2014 coal alone produces nearly 40% of electricity more than another source in US. Out of the 110 million tons of Coal combustion by-products (CCBs) generated per year as a result of coal combustion, 47% is reused whereas 53% is stored on-site or sent to landfills. There are a number of adverse economic and environmental impacts associated with storage and disposal of coal. Methane (CH4) is a powerful greenhouse gas (GHG), contributing 32% of current climate forcing (US EPA, 2015). Landfill gas comprises of 50-55% CH4 and 40-45% CO2. Global warming potential of CH4 is 28 …

Shear Behavior Of Reinforced Fly Ash-Based Geopolymer Concrete, Noor S. Yacob

Masters Theses

"The geopolymerisation of aluminosilicate materials such as fly ash has been a radical change in construction material's chemistry and composition, compared to the portland cement-based concrete calcium silicate-hydrate chemistry. The adoption of fly ash in concrete industry is a good use of by-product ashes to reduce emissions of the greenhouse gas implicitly. However, in this research, the replacement of portland cement by fly ash is 100%, which makes it a zero-cement concrete with no proprietary chemical additives.

Geopolymer concrete (GC) is a revolutionary synthetic material that combines sustainability and high engineering properties, and it is relatively cost-effective compared to portland …

Effect Of Fly Ash Fortification In The Manufacture Process Of Making Concrete Towards Characteristics Of Concrete In Sulfuric Acid Solution, Asep Handaya Saputra, Muhammad Shohibi, Masatoshi Kubouchi

Makara Journal of Technology

Fly ash is a silica or alumino silica material that can be used as a constituent of cement in the concrete manufacturing process. Utilization of fly ash aims to improve durability and minimize the reduction of concrete’s compressive strength exposed to an acidic environment, which can be achieved through the pozzolanic reaction of fly ash with Ca(OH)2 within concrete. The reduced content of Ca(OH)2 through pozzolanic reaction will minimize the tendency of ettringite formation (compounds that cause deterioration and decrease the compressive strength of concrete). In order to determine the relation between fly ash replenishment into concrete with concrete’s characteristics …

Alkali Silica Reaction Mitigation Using High Volume Class C Fly Ash, William Joseph Phillips

Graduate Theses and Dissertations

Alkali-Silica Reaction (ASR) is a neutralization reaction that occurs between an acid (silicic acid) and a basic pH pore solution (Calcium Oxide, Potassium Oxide, and Sodium Oxide). ASR causes deleterious expansion within concrete, which can cause durability issues decreasing the life span of concrete. ASR in concrete has been found in increasing quantities since its discovery in 1940 by Stanton. Several cases of ASR have occurred in Arkansas near Fayetteville, Pine Bluff, and Little Rock. The purpose of this research was to develop preventative measures using Class C fly ash in concrete, which contains the moderately reactive aggregates found in …

Mechanical Characteristics Of Organically Modified Fly Ash-Kaolinite Mixtures, Xin Kang

Doctoral Dissertations

"Fly ash is a hazardous waste material to the environment. Beneficial reuse of fly ash, however, brings economic and environmental benefits, i.e., decreases the cost of disposal, reduces greenhouse gas emission, and improves mechanical properties of construction materials. Due to the lack of pozzolanic properties, the reuse rate of Class F fly ash in geotechnical engineering is relatively low (ACAA 2013). In order to promote the effectiveness and sustainability of high volume reuse of class F fly ash in geotechnical engineering, biopolymers (Chitosan, and Xanthan gum) and synthetic polymers (Polyethylene Oxide, PEO) were used instead of the traditional stabilizers to …

High Strength Steel Fiber Reinforced Flow-Able Or Scc Concrete With Variable Fiber By Volume Fractions For Thin Plate And Shell Structures, Abebe Berhe

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this study is to incorporate discrete, short, mechanically deformed, small diameter steel fibers into high strength concrete with f'c > 70 MPa (10 ksi) in an attempt to reduce and partially eliminate the need for steel rebar in concrete construction. By introducing steel fibers to high strength concrete mixture, the overall tensile, compressive and shear strength of the mixture can be improved immensely thus, replacing portions or major parts of the longitudinal, temperature and shrinkage reinforcements. The reduction or elimination of longitudinal and transverse reinforcements in the construction of structural or non-structural members can result in savings in …

Influence Of Fly Ash On Surface Chloride Concentration Under Shallow Immersion Condition, Jun Liu, Xiaodong Wang, Feng Xing, Ningxu Han

International Conference on Durability of Concrete Structures

In this paper, the influence of fly ash content on concrete surface chloride concentration was investigated through periodical tests of surface chloride concentration of concrete by immersing three kinds of concrete specimens in 5.0 wt.% sodium chloride solution. One kind of specimen is common concrete without fly ash, whereas the other two kinds of specimens are mixed with fly ash. The results show that the surface chloride ion concentration ranges from 0.295 to 0.777 wt.% for the immersed concrete samples in this study; in the initial stage of immersion, the concrete surface chloride ion concentration is affected by added fly …

Surface Treatment Of Fly Ash For Improving The Tensile Strength Of Fly Ash/Unsaturated Polyester Composites, Sugiman Sugiman, Paryanto Dwi Setyawan

Makara Journal of Technology

The paper presents the surface treatment of fly ashes using acid and alkali solution on the tensile strength of the fly ash/unsaturated polyester (UP) composites. Sulfuric acid (H2SO4), hydrofluoric acid (HF) and sodium hydroxide (NaOH) solution with concentration of 0%, 5%, 10%, 15%, and 20% (by weight) were used for surface treatment of fly ashes. Generally, the tensile strength of the treated fly-ash/UP composites shows a significant increase compared to the untreated fly ash. Of all surface treatments studied, the optimum tensile strength was obtained at a concentration of 10%. At this concentration, at a fly ash content of 30% …

Pozzolanic Properties Of Biomass Fly Ash, Robert Lowe

All Theses

As biomass power production becomes more main stream, problems with waste disposal arise. Coal fly ash, a by-product of coal power production, has beneficial strength and durability properties when used as a cement replacement material. This study examined strength and durability characteristics of mortar and concrete samples containing biomass fly ash obtained from Craven County Wood Energy in North Carolina and examined methods of processing the material to enhance its pozzolanic characteristics.
The chemical and mineralogical compositions of the ash were determined using X-ray fluorescence (XRF), X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDS). The compositions met the requirements …