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USF Tampa Graduate Theses and Dissertations

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Articles 331 - 360 of 387

Full-Text Articles in Civil and Environmental Engineering

Estimation Of The Impact Of Single Airport And Multi-Airport System Delay On The National Airspace System Using Multivariate Simultaneous Models, Nagesh Nayak Jan 2012

Estimation Of The Impact Of Single Airport And Multi-Airport System Delay On The National Airspace System Using Multivariate Simultaneous Models, Nagesh Nayak

USF Tampa Graduate Theses and Dissertations

Airline delays lead to a tremendous loss of time and resources and cost billions of dollars every year in the United States (U.S.). At certain times, individual airports become bottlenecks within the National Airspace System (NAS). To explore solutions for reducing the delay, it is essential to understand factors causing flight delay and its impact on airports in the NAS. Major causal factors of flight delay at airports include over-scheduling, en-route convective weather, reduced ceiling and visibility around airports, and upstream delay propagation. Delay at one airport can be passed on to other airports in the NAS, in another word, …


Analysis And Remediation Of Chlorinated Hydrocarbons In Environmental Media, Jonathan Ticknor Jan 2012

Analysis And Remediation Of Chlorinated Hydrocarbons In Environmental Media, Jonathan Ticknor

USF Tampa Graduate Theses and Dissertations

The two objectives of this work were to develop a simplified method for the analysis of chlorinated organics in water samples and to improve an existing soil remediation technology. The contaminants considered for these studies were chlorinated hydrocarbons because of their relative frequency of appearance at contaminated sites. The first half of this study involved the analysis of chlorinated ethenes by gas chromatography with flame ionization detection (GC-FID). I tested the hypothesis that the FID response factor is the same for all chlorinated ethene compounds. The rationale for this investigation is that if the hypothesis is correct, a single calibration …


On The Development Of The Extradosed Bridge Concept, Steven Lynn Stroh Jan 2012

On The Development Of The Extradosed Bridge Concept, Steven Lynn Stroh

USF Tampa Graduate Theses and Dissertations

The Extradosed Prestressed Bridge represents a relatively new bridge type. The first of this type bridge was constructed in Japan in 1994, and Japan has since built at least 29 examples of this bridge type. Throughout the rest of the world, another 34 of this bridge type have been built, with most countries having only one, or at most a few, examples. A broader application of this bridge type has been hampered by lack of design information and in particular lack design criteria for the stay cables. The purpose of this dissertation is to progress the understanding and application of …


Corrosion Evaluation And Durability Estimation Of Aluminized Steel Drainage Pipes, Mersedeh Akhoondan Jan 2012

Corrosion Evaluation And Durability Estimation Of Aluminized Steel Drainage Pipes, Mersedeh Akhoondan

USF Tampa Graduate Theses and Dissertations

Aluminized steel pipes are expected to have a long service life, e.g. 75 years. Spiral ribbed aluminized pipes (SRAP) have been widely specified and used by the Florida Department of Transportation (FDOT) for drainage of runoff water. Confidence in the long term durability of SRAP has been challenged by recent unexpected early corrosion failures in various Florida locations. SRAP premature corrosion incidents have occurred in two modalities. Mode A has taken place in near-neutral soil environments and has often been associated with either gross manufacturing defects (i.e. helical cuts) or corrosion concentration at or near the ribs. Mode B took …


Optimization Of An Advanced Water Treatment Plant: Bromate Control And Biofiltration Improvement, Dustin William Bales Jan 2012

Optimization Of An Advanced Water Treatment Plant: Bromate Control And Biofiltration Improvement, Dustin William Bales

USF Tampa Graduate Theses and Dissertations

The David L. Tippin Water Treatment Facility (DLTWTF) serving the city of Tampa, Florida is an advanced drinking water treatment facility consisting of coagulation/flocculation, ozonation, granular activated carbon biofiltration, and disinfection by chloramine. New regulations and the recent economic crisis pushed the facility to investigate methods to decrease costs and meet regulatory requirements easier.

The two major issues identified as priorities for investigation were the optimization of the biofiltration system and the use of a novel process to reduce the formation of bromate during ozonation.

Optimization of the biofiltration system is needed to remove more of the assorted particles that …


Aggregation Of Sediment And Bacteria With Mucilage From The Opuntia Ficus-Indica Cactus, Audrey Lynn Buttice Jan 2012

Aggregation Of Sediment And Bacteria With Mucilage From The Opuntia Ficus-Indica Cactus, Audrey Lynn Buttice

USF Tampa Graduate Theses and Dissertations

Flocculants are commonly used in industrial settings where solid-liquid separations are desired including industrial and municipal wastewater management and potable water production facilities. Conventional flocculants include inorganic metal salts and synthetic organic polymers. The cost, availability, and harmful effects of the non-biodegradable nature of these flocculants have led to the widespread study of natural flocculants. Current natural flocculants being studied include polysaccharides cultivated from microbial extracellular matrix products and plant based materials. In this study, the mucilage of Opuntia ficus-indica cactus was evaluated as a natural flocculant for sediments and bacteria. The O. ficus-indica cactus is also known as the …


Precipitation Of Phosphate Minerals From Effluent Of Anaerobically Digested Swine Manure, Alex Y. Lin Jan 2012

Precipitation Of Phosphate Minerals From Effluent Of Anaerobically Digested Swine Manure, Alex Y. Lin

USF Tampa Graduate Theses and Dissertations

Swine production represents approximately 40% of the world's meat production, and its wastes contain high concentrations of organic carbon, nitrogen (N), and phosphorus (P). Anaerobic digestion is an increasingly popular technology for treating animal wastes while simultaneously generating energy. Its propagation and ability to solubilize organic N and P make adding a struvite recovery process attractive. Recovering struvite (MgNH4PO4) from anaerobically digested swine waste can address global P shortages, meet P discharge guidelines, and produce slow-release fertilizer, which can be sold for revenue.

Anaerobic digesters were operated with at organic loading rates of 3.4-3.9 g volatile solids per liter per …


Numerical Simulation Of Sliding Friction And Wet Traction Force On A Smooth Tire Sliding On A Random Rough Pavement, Janaka Vishwanath Kosgolla Jan 2012

Numerical Simulation Of Sliding Friction And Wet Traction Force On A Smooth Tire Sliding On A Random Rough Pavement, Janaka Vishwanath Kosgolla

USF Tampa Graduate Theses and Dissertations

Availability of analytical and numerical tools that can provide reliable and accurate estimates of wet frictional resistance in different pavements would preclude the need for time consuming field tests. Therefore, many research efforts have been made to develop such tire-pavement friction predictive tools that are invaluable for friction management programs. However, due to the complexity of the problem, most existing tools have been developed based on several simplifying assumptions and without field verification of their predictions. The current study is focused on the evaluation of two specific prediction methods that can be used to predict friction on a smooth tire …


Development And Application Of Its Operations Evaluation Models (Itsoems), Gummadavelly Narasimha Murthy Jan 2012

Development And Application Of Its Operations Evaluation Models (Itsoems), Gummadavelly Narasimha Murthy

USF Tampa Graduate Theses and Dissertations

Intelligent Transportation Systems (ITS) play an important role in supporting motorists and first responders to handle major incidents, hazmat spills, security measures and other emergency operations. Increasingly, technology advancements and applications are providing invaluable integration opportunities to interconnect safety, maintenance, ITS, traffic operations, facilities, and transportation equipment programs to maximize available resources and achieve efficiency in transportation operations.

This research focuses on one of the prominent ITS devices: Dynamic Message Signs (DMS) operations. Using real time incident management operations data and ITS operations data, an attempt is made to develop ITS Operations Evaluations Models (ITSOEMs) that are capable of quantifying …


Water's Dependence On Energy: Analysis Of Embodied Energy In Water And Wastewater Systems, Weiwei Mo Jan 2012

Water's Dependence On Energy: Analysis Of Embodied Energy In Water And Wastewater Systems, Weiwei Mo

USF Tampa Graduate Theses and Dissertations

Water and wastewater treatment is a critical service provided for protecting human health and the environment. Over the past decade, increasing attention has been placed on energy consumption in water and wastewater systems for the following reasons: (1) Water and energy are two interrelated resources. The nexus between water and energy can intensify the crises of fresh water and fossil fuel shortages; (2) The demand of water/wastewater treatment services is expected to continue to increase with increasing population, economic development and land use change in the foreseeable future; and (3) There is a great potential to mitigate energy use in …


Assessing The Reuse Potential Of Wastewater For Irrigation: The Removal Of Helminth Eggs From A Uasb Reactor And Stabilization Ponds In Bolivia, Matthew Eric Verbyla Jan 2012

Assessing The Reuse Potential Of Wastewater For Irrigation: The Removal Of Helminth Eggs From A Uasb Reactor And Stabilization Ponds In Bolivia, Matthew Eric Verbyla

USF Tampa Graduate Theses and Dissertations

Extreme hunger, malnutrition, and the lack of access to sanitation are among the most pressing development challenges, but the world is not on track to meet the targets that have been established by the Millennium Development Goals. The integration of wastewater treatment and food production systems allows for the recovery of resources from wastewater, and can provide an important solution to meet the sanitation needs of growing urban populations and provide periurban farmers with a consistent supply of water and nutrients. Stabilization ponds have been long considered to be an appropriate technology for wastewater reuse systems in developing countries, but …


Comparative Life Cycle Assessments Of Lignocellulosic And Algae Biomass Conversion To Various Energy Products Through Different Pathways, Maria Juliana Pinilla Nov 2011

Comparative Life Cycle Assessments Of Lignocellulosic And Algae Biomass Conversion To Various Energy Products Through Different Pathways, Maria Juliana Pinilla

USF Tampa Graduate Theses and Dissertations

Bioenergy has the potential to reduce the world's dependence on fossil fuels, and to decrease the CO2 emissions due to fossil combustion. Lignocellulosic and algae biomass have been presented as promising feedstocks for bioenergy production.

In this study, a comparative Life Cycle Assessment (LCA) has been developed to evaluate the environmental impacts associated with different energy products via different routes across the whole life of algal and lignocellulosic bioenergy. Results were compared per energy basis, the production of 1 million BTU of energy products.

For the development of the comparative algae biomass conversion LCA, algal biomass was converted to liquid …


Effects Of Solids Loadings And Particle Size Distribution On Siphon Ceramic Candle Filters, Danielle Renzi Jan 2011

Effects Of Solids Loadings And Particle Size Distribution On Siphon Ceramic Candle Filters, Danielle Renzi

USF Tampa Graduate Theses and Dissertations

In the rural areas of Madagascar only 29% of the population has access to clean water and 10% has access to improved sanitation. It has been estimated that environmental risk factors, such as inadequate access to clean drinking water and proper sanitation, are responsible for 94% of the diarrheal disease burden. This study was focused on testing a point-of-use technology called the Tulip filter, which is a siphon ceramic candle filter impregnated with silver. The purpose is to assess its feasibility for implementation in rural regions of Madagascar through a laboratory study performed at the University of South Florida.

The …


Pilot Assessment Of Novel Membrane Bioreactor Processes - Improvements In Biological Nutrient Removal And Membrane Operation, Shaleena Smith Jan 2011

Pilot Assessment Of Novel Membrane Bioreactor Processes - Improvements In Biological Nutrient Removal And Membrane Operation, Shaleena Smith

USF Tampa Graduate Theses and Dissertations

With increasing water reuse applications and upcoming stringent regulations for treated wastewater effluent discharge, wastewater plants need to consider alternative technologies beyond conventional treatment processes. The new regulations, Numeric Nutrient Criteria (NNC), may regulate discharge nitrogen and phosphorus concentrations to as low as 0.5 mg/L as N and 10 μg/L as P respectively. To meet these target requirements, system retrofitting to incorporate chemical or advanced nutrient removal systems possibly with membrane technology will most likely be required. Although microfiltration/ultrafiltration membranes coupled with biological processes, otherwise known as membrane bioreactors (MBR), remove contaminants and suspended solids, nutrient removal is minimal to …


A Discrete-Continuous Modeling Framework For Long-Distance, Leisure Travel Demand Analysis, Caleb Van Nostrand Jan 2011

A Discrete-Continuous Modeling Framework For Long-Distance, Leisure Travel Demand Analysis, Caleb Van Nostrand

USF Tampa Graduate Theses and Dissertations

This study contributes to the literature on national long-distance travel demand modeling by providing an analysis of households' annual destination choices and time allocation patterns for long-distance leisure travel purposes. An annual vacation destination choice and time allocation model is formulated to simultaneously predict the different destinations that a household visits and the time it spends on each of these visited destinations, in a year. The model takes the form of a Multiple Discrete-Continuous Extreme Value (MDCEV) structure (Bhat, 2005; Bhat, 2008). The model assumes that households allocate their annual vacation time to visit one or more destinations in a …


The Evaluation Of Hybrid Slurry Resulting From The Introduction Of Additives To Mineral Slurries, Kyle Douglas Yeasting Jan 2011

The Evaluation Of Hybrid Slurry Resulting From The Introduction Of Additives To Mineral Slurries, Kyle Douglas Yeasting

USF Tampa Graduate Theses and Dissertations

Drilled shaft construction often requires the use of drill slurry to maintain borehole stability during excavation and concreting. While drill slurry may be composed of fluids ranging from air to petroleum, drilled shaft construction typically makes use of water based drilling fluids. Although clean water may be utilized as a drilling fluid, a premixed slurry consisting of water, minerals, and/or polymers is more commonly used. Florida Department of Transportation (FDOT) specifications require the use of mineral slurry for all primary structures. The slurry resists the intrusion of groundwater, slows the outward migration of drilling fluid from the excavation, and aids …


Design Of Small Scale Anaerobic Digesters For Application In Rural Developing Countries, Laurel Erika Rowse Jan 2011

Design Of Small Scale Anaerobic Digesters For Application In Rural Developing Countries, Laurel Erika Rowse

USF Tampa Graduate Theses and Dissertations

The high incidence of upper respiratory diseases, contamination of waterways due to pathogens and nutrients from human and animal wastes, unsustainable deforestation, gender disparities in burden of disease due to unequal exposure to indoor air pollutants, and carbon black emissions from the burning of solid fuels are interrelated problems in many developing countries. Small scale anaerobic digestion provides a means of alleviating these problems by treating livestock waste onsite to produce biogas (methane and carbon dioxide) in rural areas in developing countries. Fuel can then be used for cooking, lighting, and heating. Methane fuel is an alternative to traditional three-stone …


In Situ Biofiltration Of Dissolved Organic Carbon In Reverse Osmosis Membrane Filtration, Russell Rosario Ferlita Jan 2011

In Situ Biofiltration Of Dissolved Organic Carbon In Reverse Osmosis Membrane Filtration, Russell Rosario Ferlita

USF Tampa Graduate Theses and Dissertations

Biofouling, or the formation of biofilm on membrane surfaces, can decrease the performance (decreased flux and/or increased operating pressure) of a reverse osmosis (RO) membrane system in a water treatment plant. However, biofilms have been used in water treatment systems to remove organic carbon from water via biofilters and successfully reduce biofilm growth downstream. This research investigates the possibility that the heterotrophic biofilm present on membrane surfaces removes nutrients from the treatment water, thereby making it nutrient deprived as it travels along the treatment train. This may potentially be exploited as an in situ biofilter to actively remove dissolved organic …


Cactus Mucilage-Assisted Heavy Metal Separation: Design And Implementation, Dawn Iona Fox Jan 2011

Cactus Mucilage-Assisted Heavy Metal Separation: Design And Implementation, Dawn Iona Fox

USF Tampa Graduate Theses and Dissertations

Natural contamination of groundwater by arsenic (As) has become a critical public health threat in many parts of the world. The well-known regions associated with As contamination of groundwater are Bangladesh and West Bengal, India where approximately 100 million people are exposed to high levels of arsenic by drinking arsenic-contaminated groundwater and about 35 million are already affected. Long-term drinking of arsenic-contaminated water leads to arsenicosis, which is characterized by cancers of the skin, organ disease and certain other types of cancer. Affected developing communities are at higher risk because they may not have access to conventional water treatment facilities. …


Feasibility Of Wastewater Reuse For Fish Production In Small Communities In A Developing World Setting, Joshua James Girard Jan 2011

Feasibility Of Wastewater Reuse For Fish Production In Small Communities In A Developing World Setting, Joshua James Girard

USF Tampa Graduate Theses and Dissertations

Eradicating poverty, malnutrition, and the burden of disease have been included as three of the major issues facing the world. The United Nation member countries, having set forth the Millennium Development Goals, have committed themselves to solving these problems. Two major factors which affect solutions to these problems are increasing water stress and implementing improved sanitation. Integration of tilapia aquaculture and reuse of wastewater has been suggested as a solution which addresses both of these factors. The objective of this study is to examine the feasibility, and explore the benefits and drawbacks, to implementing small community wastewater fed (WWF) aquaculture …


Safety Evaluation Of Roadway Lighting Illuminance Levels And Its Relationship With Nighttime Crash Injury Severity For West Central Florida Region, Enrique Gonzalez-Velez Jan 2011

Safety Evaluation Of Roadway Lighting Illuminance Levels And Its Relationship With Nighttime Crash Injury Severity For West Central Florida Region, Enrique Gonzalez-Velez

USF Tampa Graduate Theses and Dissertations

The main role of roadway lighting is to produce quick, accurate and comfortable visibility during nighttime conditions. It is commonly known that good lighting levels enable motorists, pedestrians and bicyclists to obtain necessary visual information in an effective and efficient manner. Many previous studies also proved that roadway lighting minimizes the likelihood of crashes by providing better visibility for roadway users.

Appropriate and adequate roadway lighting illuminance levels for each roadway classification and pedestrian areas are essential to provide safe and comfortable usage. These levels are usually provided by national, or local standards and guidelines. The Florida Department of Transportation …


Embodied Energy Assessment Of Rainwater Harvesting Systems In Primary School Settings On La Peninsula Valiente, Comarca Ngobe Bugle, Republic Of Panama, Kaitlin Elinor Green Jan 2011

Embodied Energy Assessment Of Rainwater Harvesting Systems In Primary School Settings On La Peninsula Valiente, Comarca Ngobe Bugle, Republic Of Panama, Kaitlin Elinor Green

USF Tampa Graduate Theses and Dissertations

The United Nations Millennium Development goals aim to make improvements in access to potable water. In the Bocas del Toro region of Panama, rainwater harvesting systems are making that goal more attainable. Rainwater harvesting, especially in rural, difficult access areas, may be a viable water source improvement that will allow a greater population to access improved water. This study uses the Carnegie Mellon University Economic Input-output Life Cycle Assessment tool to assess the embodied energy of plastic and ferrocement rainwater harvesting systems in rural Panama. Rainwater harvesting systems are assessed as source improvement technologies that increase access to potable water. …


Oxygen Diffusion Characterization Of Frp Composites Used In Concrete Repair And Rehabilitation, Chandra K. Khoe Jan 2011

Oxygen Diffusion Characterization Of Frp Composites Used In Concrete Repair And Rehabilitation, Chandra K. Khoe

USF Tampa Graduate Theses and Dissertations

Many independent studies have conclusively demonstrated that fiber reinforced polymers (FRP) slow down chloride-induced corrosion of steel in concrete. The mechanism for this slow down is not well understood but it has been hypothesized that FRP serves as a barrier to the ingress of chloride, moisture, and oxygen that sustain electrochemical corrosion of steel.

This dissertation presents results from an experimental study that determined the oxygen permeation rates of materials used in infrastructure repair. In the study, the oxygen permeation constants for epoxy, carbon and glass fiber laminates, concrete, epoxy-concrete and FRP-concrete systems were determined and a method developed to …


Biodegradation Of Bisphenol-A And 17b-Estradiol In Soil Mesocosms Under Alternating Aerobic/Anoxic/Anaerobic Conditions, Won-Seok Kim Jan 2011

Biodegradation Of Bisphenol-A And 17b-Estradiol In Soil Mesocosms Under Alternating Aerobic/Anoxic/Anaerobic Conditions, Won-Seok Kim

USF Tampa Graduate Theses and Dissertations

Soil-aquifer treatment (SAT) has been proposed as a method for reusing treated municipal wastewater. SAT is characterized by alternating cycles of aerobic and anaerobic conditions in the subsurface, in response to alternating cycles of flooding and drainage of a surface impoundment. It is not yet known how these alternating redox conditions affect the removal of potentially harmful endocrine-disrupting compounds (EDCs) from treated effluent.

The overall objective of my doctoral research is to determine the fate of EDCs in alternating aerobic/anoxic/anaerobic conditions under simulated SAT conditions. To assess the fate of EDCs in simulated SAT conditions, I first had to develop …


Minimal And Symmetric Global Partition Polynomials For Reproducing Kernel Elements, Mario Jesus Juha Jan 2011

Minimal And Symmetric Global Partition Polynomials For Reproducing Kernel Elements, Mario Jesus Juha

USF Tampa Graduate Theses and Dissertations

The Reproducing Kernel Element Method is a numerical technique that combines finite element and meshless methods to construct shape functions of arbitrary order and continuity, yet retains the Kronecker-δ property. Central to constructing these shape functions is the construction of global partition polynomials on an element. This dissertation shows that asymmetric interpolations may arise due to such things as changes in the local to global node numbering and that may adversely affect the interpolation capability of the method. This issue arises due to the use in previous formulations of incomplete polynomials that are subsequently non-affine invariant. This dissertation lays out …


Operational Performance Evaluation Of Four Types Of Exit Ramps On Florida's Freeways, Linjun Lu Jan 2011

Operational Performance Evaluation Of Four Types Of Exit Ramps On Florida's Freeways, Linjun Lu

USF Tampa Graduate Theses and Dissertations

This research focuses primarily on the analysis of exit ramp performance related to safety and operations. The safety analysis focuses on the impacts of different exit ramp types for freeway diverge areas and different factors contributing to the crashes that occur on the exit ramp sections. The operational analysis is based mainly on simulations by TSIS-CORSIM. Different ramp effects and guidance for selecting optimal exit ramp type are concluded. Issues related to ramp sections and crossroad sections are also demonstrated. Minimum ramp length and minimum distance between ramp terminal and downstream or upstream intersections are calculated. The operational analysis was …


A Swmm-5 Model Of A Denitrifying Bioretention System To Estimate Nitrogen Removal From Stormwater Runoff, Michelle D. Masi Jan 2011

A Swmm-5 Model Of A Denitrifying Bioretention System To Estimate Nitrogen Removal From Stormwater Runoff, Michelle D. Masi

USF Tampa Graduate Theses and Dissertations

This research estimates nitrogen removal from stormwater runoff using a denitrifying bioretention system using the USEPA Storm Water Management Model Version 5 (SWMM-5). SWMM-5 has been used to help planners make better decisions since its development in 1971. A conventional bioretention system is a type of Low Impact Development (LID) technology, which designed without a media layer specifically for achieving nitrogen removal. More recently studies have showed that high TN removal efficiencies are possible when incorporating a denitrification media layer. These systems are known as denitrifying bioretention systems, or alternative bioretention systems. LID projects are currently being designed and developed …


Investigation Of The Optimal Dissolved Co2 Concentration And Ph Combination For The Growth Of Nitrifying Bacteria, Raymond Anthony Morris Jan 2011

Investigation Of The Optimal Dissolved Co2 Concentration And Ph Combination For The Growth Of Nitrifying Bacteria, Raymond Anthony Morris

USF Tampa Graduate Theses and Dissertations

Ammonium (NH4+) is a biological nutrient that is transformed in a wastewater treatment plant (WWTP) in a process called activated sludge. This is accomplished in an aerobic environment using microorganisms and inorganic carbon that convert the ammonium to nitrate (NO3-). This process is termed nitrification. Removal of ammonium is necessary due to its oxygen demand and toxicity to the environment.

Nitrification is considered a slow process due to the slow growth rate of the nitrifying bacteria. Ammonia oxidizing bacteria (AOB) first covert the ammonium (NH4+) to nitrite (NO2-) …


Effectiveness Of In-Line Chlorination Of Gravity Flow Water Supply In Two Rural Communities In Panama, Kevin Orner Jan 2011

Effectiveness Of In-Line Chlorination Of Gravity Flow Water Supply In Two Rural Communities In Panama, Kevin Orner

USF Tampa Graduate Theses and Dissertations

It is well established that water quality is directly linked to health. In-line chlorination is one technology that can be used in the developing world to potentially inactivate pathogens and improve water quality. The purpose of this study was to determine the effectiveness of the Panamanian Ministry of Health's in-line PVC chlorinator under three different operating conditions in a rural water supply system. Free and total chlorine were measured entering the storage tank, leaving the storage tank, and at three households along the transmission line of the water system in the two rural indigenous communities of Calabazal and Quebrada Mina …


Catalytic Hydrodehalogenation And Hydrogenation Of Halogenated Aromatic Organic Contaminants For Application To Soil Remediation, Claire J. Osborn Jan 2011

Catalytic Hydrodehalogenation And Hydrogenation Of Halogenated Aromatic Organic Contaminants For Application To Soil Remediation, Claire J. Osborn

USF Tampa Graduate Theses and Dissertations

The objective of this research was to aid in the development of a new method for removing and destroying soil contaminants. In particular, 1,2,4,5-tetrachlorobenzene (TeCB) was selected for this research. Hydrodehalogenation (HDH) was paired with hydrogenation for remedially destroying TeCB without generating a secondary waste stream in a single batch reactor. Palladium- and rhodium-catalyzed HDH and hydrogenation were applied in a batch reactor at room temperature and moderate hydrogen pressure. Cyclohexane was formed as an end product with benzene as an intermediate reactant.

An analytical method was developed to measure TeCB, benzene, and cyclohexane in a solution of water and …