Civil and Environmental Engineering Commons^™

Investigation Of Acetaminophen And Caffeine Removal Using Manganese Oxides And Granular Activated Carbon In Column Experiments, Rachael E. Miera

Civil Engineering ETDs

This study was conducted to investigate the application of manganese dioxide (MnO_x(s)) and granular activated carbon (GAC) media for the removal of the acetaminophen and caffeine. Treatment of emerging micropollutants has become a concern due to their effects on environmental health. Manganese oxides can be a viable alternative for water treatment due to their abundance in the environment. Laboratory scale flow through column experiments were performed using different combinations of commercial MnO_x(s) and GAC to assess the removal of caffeine and acetaminophen, and the release of Mn due to the reductive dissolution of MnO_x(s). Results …

Modeling And Simulation Of Damage In The Brazilian Indirect Tension Test Using The Finite-Discrete Element Method, Jeremiah C. Leyba

Civil Engineering ETDs

The Brazilian indirect tension test is used to investigate possible correlations between progressive damage and associated permeability changes. The test offers ease of replicability with a damage behavior known to lead to fracture openings as a tool for interpreting the indirect tensile strength of concrete and rocks. This behavior can lend insight into the nature of tensile damage and fracture progression in association with changes in permeability. The nature of these brittle materials is known to exhibit rapid failures in the Brazilian indirect tension test and require a method to retard the progression of damage for the possibility of acquiring …

Understanding Asphalt Concrete Aging Using Nanoindentation, Hasan M. Faisal

Civil Engineering ETDs

Asphalt concrete (AC) is created by mixing liquid asphalt binder with solid aggregates. When asphalt binder is mixed with aggregates, it creates a thin film (about 7-16 microns thick) around the aggregate surface. Fine aggregate (smaller than 0.075 mm size) get entrapped within the binder film or mixed with the binder, and create a phase called mastic. Both asphalt film and mastic play significant roles in aging of asphalt pavement. To this day, tests were performed mainly on the bulk liquid asphalt, but not on the film or mastic. In this study, for the first time, nanoindentation tests were done …

Decision-Making Framework For The Selection Of Sustainable Alternatives For Energy-Retrofits, Amirhosein Jafari

Civil Engineering ETDs

Buildings are major consumers of energy worldwide. On the other hand, over 60% of the US housing inventory is over 30 years old and a large number of these homes are energy inefficient. Therefore, it is essential to target the existing building stock for energy efficient interventions as a key to substantially reduce the adverse impacts of buildings on the environment and economy.

Building energy retrofitting has emerged as a primary strategy for reducing energy use and carbon emissions in existing buildings. An energy retrofit can be defined as a physical or operational change in a building, its energy-consuming equipment, …

An Investigation Into Remote Sensing Techniques For Describing Hydraulic Roughness, Smriti Chaulagain

Civil Engineering ETDs

Riparian vegetation, an indicator of healthy river system, increases the hydraulic roughness and reduces the conveyance capacity of a channel. Vegetation provides dominant drag force influencing the velocity distribution, turbulence intensity and water depth. Thus, the study of hydraulic roughness due to vegetation is essential to determine the characteristics of flow. Traditionally, a constant Manning’s roughness value is assigned based on land cover maps and that does not adequately account for vegetation. The roughness due to vegetation are determined on the basis of its parameters like height, density, LAI and flexibility. Remote sensing data (LiDAR, aerial photos or satellite images) …

Characterizing Patterns In E. Coli Levels In Rio Grande River Water And Riverbed Sediments Near Albuquerque, Nm, James Fluke

Civil Engineering ETDs

In this work I examined how Fecal indicator Bacteria (FIB) behave in a large environmental system (Rio Grande near Albuquerque, ~60 km distance). I addressed the questions: How do FIB levels in river water and riverbed sediments of this reach change with distance along the river and throughout one year?

I conducted year-round river water and sediment sampling for concentration of E. coli bacteria, a persistent contaminant in the area. I found that over the year, E. coli loading in river water increased along the 60 km reach and E. coli in the sediments mainly increased near the Albuquerque urban …

Metal Reactivity In Laboratory Burned Wood From A Watershed Affected By Wildfires, Asifur Rahman

Civil Engineering ETDs

Massive amounts of wood ash are deposited into nearby streams as a result of runoff from storm events after increasing frequency of wildfire events that negatively affect water quality. Ash and debris from burned vegetation can alter the pH, turbidity and dissolved oxygen (DO) in water and can release heavy metals, organic matter, and nutrients. We investigated interfacial processes affecting metal mobility in wood ash burned under laboratory-controlled conditions using aqueous chemistry, microscopy and spectroscopy analyses. Wood was collected from the Valles Caldera National Preserve in New Mexico which has experienced two wildfires since 2011 that have caused devastating effects. …

The Investigation Of Silica Removal In Reverse Osmosis Concentrate By Changing Design Parameters, John M. Stomp Iv

Civil Engineering ETDs

Silica at high concentrations can precipitate and polymerize, forming scales on heat exchangers, boilers and turbines in industrial equipment, and on the feed side of the semi-permeable membranes in Reverse Osmosis (RO). Silica scale can cause decreased efficiency, increased treatment costs and, in some cases, irreversible damage. The removal of silica scale is challenging because it requires the handling of dangerous and hazardous chemicals. Therefore, much research has gone into the removal of soluble silica. The purpose of this research was to compare the overall effectiveness of silica removal in RO concentrate water with freshly precipitated Mg(OH)₂ and Fe(OH) …

Study Of Building Vibrations Caused By Machinery, Bipesh Shrestha

Civil Engineering ETDs

ABSTRACT

This thesis studies the vibration of structures caused by machinery. Machines exhibit unique vibrational characteristics. This thesis focuses on detection of these unique vibrational characteristics through the study of structural vibration caused by machines. The study extends from simple laboratory structures to a real existing building called the Ford Utility Building. The vibrational readings on the roof of the Ford Utility Building are studied to capture signals that can be attributed to machines running inside the building. This thesis supports the research in remote detection and identification of concealed machinery through SAR vibrometry.

A study of human perception of …

Achieving Public Health And Climate Change Goals: What Do We Need To Know About The Transportation System?, Mohammad Tayarani

Civil Engineering ETDs

The overall aim of this dissertation is evaluating what new knowledge can be gained about the environmental and public health outcomes of regional transportation planning strategies by implementing a suite of more spatially and temporally detailed transportation and air quality models. This new knowledge can be used to better understand the potential health effects of emissions exposure while also guiding the development of new transportation and land-use plans, and related policies that have the potential to achieve large reductions in pollution exposure and green house gas emissions at local and regional level.

Growth Of An Algae Polyculture And Dunaliella Tertiolecta In Oilfield Produced Water At A Range Of Salinities And Nutrient Concentrations For Biofuels Production., Thomas C. Hopkins

Civil Engineering ETDs

Growth of algae in saline produced waters (wastewater) from oil and gas production is of interest for potential production of algal biofuels, wastewater treatment and potential reuse or disposal. The objectives of this study were to determine the effects of salt concentrations and nitrogen source (ammonia or nitrate) and concentration on algal growth, lipid production, and nutrient removal to help determine suitability for growth on saline produced waters. Dunaliella tertiolecta (a marine algae) and a polyculture (previously discovered growing in PW) were grown on produced water with a range of salinities and varying nitrogen source and concentration, in a series …

Industry Requirement Gap Analysis For Sustainable Construction Technology, Parya Nickbeen

Civil Engineering ETDs

As sustainable construction becomes a standard necessity in the construction industry, construction engineering and management programs seek to integrate sustainable construction concepts and skills into their degree programs. The aim of this research is to identify industry-required competencies and recognize the possible gaps between industry skills demands and the education provided by academia for sustainable construction technologist jobs. In this study, industry requirements for sustainable construction technologist (mid-level) positions were identified through the analysis of job advertisements, literature review, job analysis (i.e., Developing a Curriculum-DACUM- process), and surveys. Results from the DACUM process provided a categorization of 4 main duties …

Modeling The Interdependencies Of Energy And Water In New Mexico: Historic Drivers, Hydrologic Impacts, And Energy Requirements, Catherine M. Zemlick 5774203

Civil Engineering ETDs

There is increasing need to understand the interdependencies between energy resource development and water resources, particularly in arid regions with vast energy reserves like New Mexico. The state has a long history of energy resource development, including both uranium and fossil fuels. These activities have and continue to impact scarce water resources. There exist gaps in knowledge regarding the drivers of historic uranium mining and the uncertainties inherent in past estimates of groundwater impacts because of mining activity and in current understanding of the energy required to manage water in the oil and gas industry. Although uranium has not been …

Assessing The Power Of Remotely-Sensed Snow Cover Extent To Improve Understanding Of Snowpack-Streamflow Dynamics: An Application Of Modis Snow Cover In Western U.S. Mountain Watersheds, Jennifer N. Van Osdel

Civil Engineering ETDs

Mountain snowpacks provide essential water for socio-economic systems around the world, with nearly two billion people living in snow sensitive regions. Therefore, methods for characterizing the snowpack-streamflow dynamics at the watershed level are essential for understanding how changes in temperature and precipitation due to climate change will affect the water supply in these regions. However, in-situ snowpack measurements, such as snow water equivalent (SWE), are often unavailable or insufficient due to the financial and logistical constraints of installing snowpack monitoring systems. Remotely-sensed snow cover extent (SCE), or the proportion of a watershed that is covered in snow, has been previously …

Investigation Of Anion And Cation Exchange Membranes For Enhancing Desalination And Power Generation In A Microbial Desalination Cell, Francisco Lopez Moruno

Civil Engineering ETDs

Microbial desalination cell (MDC) is a bioelectrochemical system capable of oxidizing organics, generating electricity and reducing the salinity content into the desalination chamber. In the first part of this study, quaternary ammonium poly(2,6-dimethyl 1,4-phenylene oxide) (QAPPO) anion exchange membranes (AEMs) with topographically patterned surfaces were assessed in a microbial desalination cell (MDC) system. The MDC results with these QAPPO AEMs were benchmarked against a commercially available AEM. The MDC with the non-patterned QAPPO AEM (Q1) displayed the best desalination rate (a reduction of salinity by 53±3 %) and power generation (189±5 mW m^-2) when compared against the commercially …

Physical And Chemical Interactions Affecting U And V Transport From Mine Wastes, Sumant Avasarala

Civil Engineering ETDs

This research investigates the physical and chemical interactions that affect the transport of uranium (U) and vanadium (V) from uranium mine waste sites by integrating laboratory experiments and reactive transport modelling with various spectroscopy, microscopy, and diffraction techniques. The document consists of results from three related studies. In the first study (Chapter 3), the reactive transport of U and V was investigated by sequentially reacting mine wastes collected from Blue Gap/Tachee Claim-28 mine site, AZ with 10mM NaHCO₃ (7.9) and 10mM CH₃COOH (3.4) during continuous flow through column experiments. Under both of these conditions (pH 3.4 and …

Characterization Of Wellbore Microannuli, Serafin Garcia Fernandez

Civil Engineering ETDs

Wellbore integrity is a principal concern for the safe and efficient underground storage of hydrocarbons, disposal of various wastes and in oil and gas production. Poor wellbore integrity can lead to leakage and loss of extracted or stored material, and the potential for contamination of groundwater. The microannuli, which is the space between the steel casing and the cement sheath has been identified as a common and critical leakage pathway. There are no data of the actual size or character of microannuli; however, it is possible to estimate the hydraulic aperture of the microannulus from flow measurements at the wellhead. …

Moving Bed Biofilm Reactors: Evaluation Of Geometry, Attachment Surface Material And Biofilm Populations On The Uptake Of Ammonia And Synthetic Organic Contaminants In Wastewater., Patrick D. Mclee

Civil Engineering ETDs

Plastic biofilm carriers are used in biological wastewater treatment to encourage the attachment and retention of microorganisms that metabolize pollutants. The following research was conducted to better understand how different characteristics of the biofilm carrier affect the treatment performance of the attached biofilms in moving bed bioreactors. Lab scale reactors were used in this study to grow nitrifying biofilms in reactors with contrasting and controlled conditions. The effect of surface geometry on nitrification performance was evaluated by testing commercially available moving bed bioreactor media that contrast in physical design, and by varying operational parameters. Additionally, mature biofilm from a similar …

Quantifying The Effect Of Construction Site Factors On Concrete Quality, Costs And Production Rates, Jorge L. Santamaria

Civil Engineering ETDs

Factors affecting concrete can be categorized as structured factors or unstructured factors. The first group of factors consists of those related to the production process of concrete including water-cement ratio, properties of raw materials and mix proportions. Unstructured factors or construction site factors are related to labor skills and local conditions during the construction process of a project. Concrete compressive strength as a quality metric, costs and production rates may be affected significantly by such factors while performing concrete operations at the jobsite. Several prior studies have investigated the effect of structured factors on concrete. However literature is limited regarding …

Development Of Design Equations For Drilled Shafts In Granular Dense Soils Using Dem Simulations, Sadia Faiza

Civil Engineering ETDs

Drilled shafts have proven to be cost-effective, excellent performing, deep foundation systems where large loads and lateral resistance are major factors. The available design methods that are recommended by FHWA (2010) for drilled shafts are mostly empirical and are developed based on generalized data which sometimes can be conservative for a particular soil. The main objective of this study is to develop a design methodology for estimating the side resistance of an axially loaded drilled shaft based on the current and the unique properties of the soil. The objective was met through using the discrete element method (DEM) to investigate …

Characterization And Modeling Of Asphalt Concrete For Dynamic Properties And Performances, A S M A. Rahman

Civil Engineering ETDs

The recently developed mechanistic-empirical pavement design guide (MEPDG, also known as Pavement M-E design method) uses the nationally calibrated, binder viscosity-based dynamic modulus predictive model for the design and analysis of asphalt pavements. In this study, this model is assessed for its appropriateness for asphalt-aggregate mixtures typically used in New Mexico. In essence, this study investigates the predictability issue of complex modulus of New Mexico mixes. A total of 54 Superpave mixes with different aggregate gradations, air voids, and binder grades were collected from the mixing plants and from the pavement construction sites. The loose asphalt mixtures were then compacted, …

Viscoelastic Behavior Of Carbon Fiber Reinforced Polymer Composites Incorporating Nanomaterials, Amy R. Garner

Civil Engineering ETDs

Carbon fiber reinforced polymer (CFRP) composites are increasingly being used in a variety of industries such as aerospace and infrastructure. This investigation experimentally examines the effect of incorporating alumina nanoparticles (ANPs), non-functionalized multi-walled carbon nanotubes (NF-MWCNTs), and functionalized multi-walled carbon nanotubes (F-MWCNTs) on the off-axis stiffness and stress-relaxation of carbon fiber reinforced polymer (CFRP) composites. Epoxy- nanocomposites incorporating 0.0, 1.0, 2.0, and 3.0 wt.% ANPs; 0.0 0.5, 1.0, and 1.5 wt. % NF-MWCNTs; 0.0 0.5, 1.0, and 1.5 wt. % F-MWCNTs of the total weight of epoxy are examined. Off-axis tension stiffness and stress-relaxation tests were performed on CFRP coupons …

Applying Modern Technology In The Preservation Of Historic Concrete Picnic Tables, Michele M. Anderson

Civil Engineering ETDs

Preserving historical concrete structures recognizes the work and skills of past generations and allows the communities surrounding these pieces of history the opportunity to enjoy the character and purpose of their construction. Restoration of concrete picnic tables, constructed in the 1930s by the Civilian Conservation Corps, required researching materials and methods of construction during the original construction period. Eight decades of environmental and weather cycles did not decay the historic structures. Acts of vandalism destroyed the purpose of the tables and benches. Restoration of the historic picnic tables required extensive literature review for the materials and methods used during the …

Hydrogeochemical Investigation Of Recharge Pathways To Intermediate And Regional Groundwater In Cañon De Valle And Technical Area 16, Los Alamos National Laboratory, Brendan W. Brady

Civil Engineering ETDs

In aquifers consisting of fractured or porous igneous rocks, as well as conglomerate and sandstone products of volcanic formations, silicate minerals actively dissolve and precipitate (Eby, 2004; Eriksson, 1985; Drever, 1982). Dissolution of hydrated volcanic glass is also known to influence the character of groundwater to which it is exposed (White et al., 1980). Hydrochemical evolution, within saturated zones of volcanic formations, is modeled here as a means to resolve the sources feeding a perched groundwater zone. By observation of solute mass balances in groundwater, together with rock chemistry, this study characterizes the chemical weathering processes active along recharge pathways …

State-Based Peridynamic Particle Method, Siavash Nikravesh Kazeroni

Civil Engineering ETDs

In this study, a novel discrete Peridynamics framework called the “State-Based Peridynamic Particle Model (SPPM)” is introduced. In this approach, a solid body is simulated by neither solving differential equations nor integral equations; instead, the simulation is accomplished by directly solving discrete systems of equations using finite summations. SPPM is formulated for a random distribution of particles, hence, it can be considered as a meshfree method. The assumptions of continuity and homogeneity are not necessary for this approach. The SPPM is a generalization of the “State-Based Peridynamic Lattice Model (SPLM)”. In the SPLM formulation, for sake of simplicity and computational …

Comprehensive Evaluation Of Rutting Performance Of Asphalt Concrete Mixtures, Ivan Syed

Civil Engineering ETDs

Rutting is the permanent deformation along the wheel paths of an asphalt pavement caused by repeated traffic loading. It is considered as one of the primary distresses of asphalt pavements. Recently, Hamburg Wheel Tracking Device (HWTD) has shown to measure the rutting performance of an asphalt mixture in the laboratory. In this study, this device has been used to measure rutting of asphalt concrete (AC) and relate them with the mixture’s dynamic modulus. To this end, the rut deformation of AC mixtures were modeled in this study using a semi-empirical |E*|-based rut predictive model based on the HWTD …

Characterization Of Asphalt Healing And Incorporation In A Fatigue Damage Model, Umme A. Mannan

Civil Engineering ETDs

Healing is defined as the restoration of the material property during the rest period after damage. The healing property of the asphalt binder is opposite to fatigue damage, which occurs due to repeated traffic loading. On the other hand, healing occurs in the rest period between loading. Most of the existing methods for characterizing the fatigue damage and healing of asphalt are empirical in nature and do not consider the mechanism of healing. Although the asphalt concrete is a mixture of asphalt binder, fines and aggregates, most of the healing occurs in the asphalt binder. Therefore, it is important to …

A Numerical Investigation Of The Implications Of Altered Channel-Floodplain Connectivity On Hydrodynamic Flood Wave Processes, Colin F. Byrne

Civil Engineering ETDs

With severely altered rivers throughout the developed world, hydrodynamic processes and floodplain connectivity have changed drastically. The research presented here focuses on quantification of two hydrodynamic processes: flood wave attenuation and channel-floodplain fluxes. Objectives of the three research chapters were to (1) evaluate how the ecosystem service of flood wave attenuation has changed with the implementation of river engineering practices as well as contemporary river restoration efforts, (2) describe the sensitivities of flood wave attenuation to contemporary and altered conditions, and (3) characterize channel-floodplain connectivity through lateral flux metrics. All chapter objectives were met using high-resolution, two-dimensional hydrodynamic modeling techniques …

Rejection Of Low Molecular Weight Neutral Organics By Reverse Osmosis Membranes For Potable Reuse, Lauren N. Breitner

Civil Engineering ETDs

Factors such as increasing population, urbanization, and climate change have made the management of water resources a challenge for many municipalities. Water reuse, especially direct potable reuse (DPR) of treated wastewater, is increasingly seen as a potential source of water for communities facing water shortages. Due to improvements in analytical capabilities as well as concerns regarding toxicology of contaminants of emerging concern (CECs), the need for investigating the removal of CECs has become crucial for further DPR considerations. Reverse osmosis (RO) has been demonstrated to remove many CECs. Many studies, however, have investigated the removal of well-known CECs, often with …

Characterization Of Unknown Bridge Foundations, Saman Rashidyan

Civil Engineering ETDs

The National Bridge Inventory (NBI) recognized 86,133 bridges in the United States have no foundation data on record in 2003. It is evident that an unknown percentage of the 86,133 bridges identified by NBI with missing foundation data could also be highly vulnerable to scouring induced by water flow coupled with erodible soils. Conventional excavation, coring and boring excavations to identify unknown bridge foundation depths and types are deemed to be expensive, destructive, and limited in their application to the unknown foundation problem. Many surface and borehole nondestructive testing (NDT) technologies have been developed for this purpose. Three economical proven …