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Full-Text Articles in Thermodynamics
Information In Biological Systems And The Fluctuation Theorem, Yaşar Demirel
Information In Biological Systems And The Fluctuation Theorem, Yaşar Demirel
Department of Chemical and Biomolecular Engineering: Faculty Publications
Some critical trends in information theory, its role in living systems and utilization in fluctuation theory are discussed. The mutual information of thermodynamic coupling is incorporated into the generalized fluctuation theorem by using information theory and nonequilibrium thermodynamics. Thermodynamically coupled dissipative structures in living systems are capable of degrading more energy, and processing complex information through developmental and environmental constraints. The generalized fluctuation theorem can quantify the hysteresis observed in the amount of the irreversible work in nonequilibrium regimes in the presence of information and thermodynamic coupling.
Thermodynamically Coupled Heat And Mass Flows In A Reaction-Transport System With External Resistances, Yaşar Demirel
Thermodynamically Coupled Heat And Mass Flows In A Reaction-Transport System With External Resistances, Yaşar Demirel
Yaşar Demirel Publications
Considerable work has been published on mathematically coupled nonlinear differential equations by neglecting thermodynamic coupling between heat and mass flows in reaction-transport systems. The thermodynamic coupling refers that a flow occurs without or against its primary thermodynamic driving force, which may be a gradient of temperature, or chemical potential, or reaction affinity. This study presents the modeling of thermodynamically coupled heat and mass flows of two components in a reaction-transport system with external heat and mass transfer resistances. The modeling equations are based on the linear nonequilibrium thermodynamics approach by assuming that the system is in the vicinity of global …
Modeling Of Thermodynamically Coupled Reaction-Transport Systems, Yaşar Demirel
Modeling Of Thermodynamically Coupled Reaction-Transport Systems, Yaşar Demirel
Yaşar Demirel Publications
Nonisothermal reaction-diffusion systems control the behavior of many transport and rate processes in physical, chemical and biological systems, such as pattern formation and chemical pumps. Considerable work has been published on mathematically coupled nonlinear differential equations by neglecting thermodynamic coupling between a chemical reaction and transport processes of mass and heat. This study presents the modeling of thermodynamically coupled system of a simple elementary chemical reaction with molecular heat and mass transport. The thermodynamic coupling refers that a flow occurs without or against its primary thermodynamic driving force, which may be a gradient of temperature or chemical potential or reaction …
Thermodynamically Coupled Transport In Simple Catalytic Reactions, Yaşar Demirel
Thermodynamically Coupled Transport In Simple Catalytic Reactions, Yaşar Demirel
Yaşar Demirel Publications
Considerable work published on chemical reaction-diffusion systems investigates mainly mathematically coupled nonlinear differential equations. This study presents the modeling of a simple elementary chemical reaction with thermodynamically and mathematically coupled heat and mass transport with external mass and heat transfer resistances. The thermodynamic coupling refers that a flow occurs without or against its primary thermodynamic driving force, which may be a gradient of temperature or chemical potential. The modeling is based on the linear nonequilibrium thermodynamics approach and phenomenological equations by assuming that the system is in the vicinity of global equilibrium. This approach does not need detailed coupling mechanisms. …
Non-Isothermal Reaction-Diffusion Systems With Thermodynamically Coupled Heat And Mass Transfer, Yaşar Demirel
Non-Isothermal Reaction-Diffusion Systems With Thermodynamically Coupled Heat And Mass Transfer, Yaşar Demirel
Papers in Analytical Chemistry
Non-isothermal reaction-diffusion (RD) systems control the behavior of many transport and rate processes in physical, chemical, and biological systems. A considerable work has been published on mathematically coupled nonlinear differential equations of RD systems by neglecting the possible thermodynamic couplings among heat and mass fluxes, and reaction velocities. Here, the thermodynamic coupling refers that a flux occurs without its primary thermodynamic driving force, which may be gradient of temperature, or chemical potential, or reaction affinity. This study presents the modeling equations of non-isothermal RD systems with coupled heat and mass fluxes excluding the coupling of chemical reactions using the linear …