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Full-Text Articles in Thermodynamics
Nonequilibrium Thermodynamics Modeling Of Coupled Biochemical Cycles In Living Cells, Yaşar Demirel
Nonequilibrium Thermodynamics Modeling Of Coupled Biochemical Cycles In Living Cells, Yaşar Demirel
Yaşar Demirel Publications
Living cells represent open, nonequilibrium, self organizing, and dissipative systems maintained with the continuous supply of outside and inside material, energy, and information flows. The energy in the form of adenosine triphosphate is utilized in biochemical cycles, transport processes, protein synthesis, reproduction, and performing other biological work. The processes in molecular and cellular biological systems are stochastic in nature with varying spatial and time scales, and bounded with conservation laws, kinetic laws, and thermodynamic constraints, which should be taken into account by any approach for modeling biological systems. In component biology, this review focuses on the modeling of enzyme kinetics …
Thermodynamically Coupled Heat And Mass Flows In A Reaction-Transport System With External Resistances, Yaşar Demirel
Thermodynamically Coupled Heat And Mass Flows In A Reaction-Transport System With External Resistances, Yaşar Demirel
Yaşar Demirel Publications
Considerable work has been published on mathematically coupled nonlinear differential equations by neglecting thermodynamic coupling between heat and mass flows in reaction-transport systems. The thermodynamic coupling refers that a flow occurs without or against its primary thermodynamic driving force, which may be a gradient of temperature, or chemical potential, or reaction affinity. This study presents the modeling of thermodynamically coupled heat and mass flows of two components in a reaction-transport system with external heat and mass transfer resistances. The modeling equations are based on the linear nonequilibrium thermodynamics approach by assuming that the system is in the vicinity of global …
Modeling Of Thermodynamically Coupled Reaction-Transport Systems, Yaşar Demirel
Modeling Of Thermodynamically Coupled Reaction-Transport Systems, Yaşar Demirel
Yaşar Demirel Publications
Nonisothermal reaction-diffusion systems control the behavior of many transport and rate processes in physical, chemical and biological systems, such as pattern formation and chemical pumps. Considerable work has been published on mathematically coupled nonlinear differential equations by neglecting thermodynamic coupling between a chemical reaction and transport processes of mass and heat. This study presents the modeling of thermodynamically coupled system of a simple elementary chemical reaction with molecular heat and mass transport. The thermodynamic coupling refers that a flow occurs without or against its primary thermodynamic driving force, which may be a gradient of temperature or chemical potential or reaction …
Exergy Use In Bioenergetics, Yaşar Demirel
Exergy Use In Bioenergetics, Yaşar Demirel
Papers in Analytical Chemistry
Every developed and adapted biological system extracts useful energy from outside, converts, stores it, and uses for muscular contraction, substrate transport, protein synthesis, and other energy utilizing processes. This energy management in a living cell is called the bioenergetics, and the useful energy is the exergy, which is destroyed in every irreversible process because of the entropy production. The converted exergy is the adenosine triphosphate (ATP) produced through the oxidative phosphorylation coupled to respiration in which the exergy originates from oxidation of reducing equivalents of nutrients. A living cell uses the ATP for all the energy demanding activities; it has …