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Microwave-Assisted Ammonia Synthesis Over Cs-Ru/Ceo2 Catalyst, Alazar Kesete Araia Jan 2023

Microwave-Assisted Ammonia Synthesis Over Cs-Ru/Ceo2 Catalyst, Alazar Kesete Araia

Graduate Theses, Dissertations, and Problem Reports

Ammonia synthesis is one of the greatest innovations of the 20th century with extensive applications from fertilizers to intermediates for nitrogen-containing chemicals and pharmaceuticals. Annually, more than 242 million tons of ammonia is produced globally, supporting approximately 27% of the world’s population. One of the fast-growing applications for ammonia is as H2 energy carrier due to its high energy storage capacity, considered to be a decarbonized energy source. The low volumetric energy density and incompressibility makes Hydrogen a non-preferable energy carrier; an alternative carrier becomes a requirement. Ammonia possesses unique property as an energy-dense carrier to store and …


Microwave-Assisted Natural Gas Conversion To Value-Added Chemicals, Xinwei Bai Jan 2021

Microwave-Assisted Natural Gas Conversion To Value-Added Chemicals, Xinwei Bai

Graduate Theses, Dissertations, and Problem Reports

Stranded gas is a raw gas mixture of volatile hydrocarbons where the main composition is methane. The producers flare the stranded gas at the site because the cost of collecting and transporting the gas is higher than the value of the gas itself. To reduce the waste of this natural resource, it is worthwhile to utilize the on-site stranded natural gas as feedstock to produce value-added chemicals without emitting greenhouse gas. Direct natural gas conversion process is more desirable because of lower capital investment. Methane and ethane, the two major components of natural gas, are very stable molecules that usually …


Process Modeling And Techno-Economic Analysis Of Thermo-Catalytic Dimethyl Ether Synthesis And Microwave-Based Aromatics Production Technologies From Shale Gas, Chirag Mevawala Jan 2020

Process Modeling And Techno-Economic Analysis Of Thermo-Catalytic Dimethyl Ether Synthesis And Microwave-Based Aromatics Production Technologies From Shale Gas, Chirag Mevawala

Graduate Theses, Dissertations, and Problem Reports

Production of dimethyl ether (DME) and direct non-oxidative methane dehydroaromatization (DHA) to aromatics via conventional and microwave (MW)-assisted processes are investigated in this research. Plant-wide models of the shale gas to DME process with integrated CO2 capture via direct and indirect synthesis routes have been developed. Optimal parameter estimation, and model validation are undertaken for various sections of the process including the pre-reforming reactor, auto-thermal reforming reactor, DME synthesis reactors, CO2 capture units and separation sections. A novel DME separation process has been developed for efficient separation of DME, syngas, and CO2. Plant-wide techno-economic optimization is …


Review Of Established And Emergent Methods For The Production Of C4 Olefins, James Matthew Koval Jan 2020

Review Of Established And Emergent Methods For The Production Of C4 Olefins, James Matthew Koval

Graduate Theses, Dissertations, and Problem Reports

Current production of C4 olefins is dominated by naphtha cracking and butane dehydrogenation, but significant research interest is developing in alternate feedstocks due to an abundance of inexpensive natural gas and bioethanol. The current C4 olefin production methods are costly, make use of already-depleted petroleum resources, and are often hazardous to workers, which forms the impetus for investigation into alternative methods and assessment of their viability as a future means of olefin production. Methods of natural gas conversion to higher order hydrocarbons are discussed, including Fischer-Tropsch synthesis and oxidative methane coupling, each of which could form the first …