Membrane Science Commons^™

Experimental Evaluation Of Membranes In The Recovery Of Hydrogen From Serpentinization, Rafael Dos Santos

LSU Master's Theses

Natural hydrogen generated through serpentinization reactions has emerged as a promising low-carbon energy resource. However, serpentinization-derived gas streams commonly contain methane (CH₄) and carbon dioxide (CO₂), requiring purification before hydrogen can be utilized in industrial applications. Membrane-based gas separation technologies offer a potentially cost-effective solution for hydrogen recovery; however, to the best of the author's knowledge, no previous studies have specifically investigated their application to serpentinization-derived gas streams.

This work evaluates the performance of two commercial polymeric membrane modules (Evonik and Generon) and one palladium-copper (Pd-Cu) membrane module (Okaya) for hydrogen recovery from gas compositions representative of serpentinization environments. An …

Turning Down The Heat: Fine-Tuning Tempo-Modified Nanocellulose And Emim-Ac Ionic Liquid Membranes For Kidney Dialysis, Olivia Reid

Chemical Engineering Undergraduate Honors Theses

TEMPO modified nanocellulose membranes are utilized across various laboratory and industrial applications from protein purification to advancements in kidney dialysis. This study investigates the effect of varying coagulation temperatures on the morphology and transport properties of these membranes to enhance their performance for targeted filtration. It was hypothesized that higher temperatures would accelerate the solvent-nonsolvent exchange during phase inversion, resulting in larger pore structures. Conversely, lower temperatures were expected to slow solvent diffusion, yielding smaller, more uniform pores. The membranes[JH1]  were synthesized using 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) to improve selectivity and antifouling characteristics. Scanning electron microscopy (SEM) served as the primary …

Strengthening Kidney Dialysis One Membrane At A Time: Enhancing Tempo-Oxidized Nanocellulose And Ionic Liquid Membrane Strength Through The Variation Of Cosolvents, Bailey M. Butler

Chemical Engineering Undergraduate Honors Theses

Chronic kidney disease occurs when the kidneys lose the ability to effectively filter the blood, which causes waste build up. End-stage kidney disease (ESKD) is the most severe case of kidney disease and requires either dialysis or a kidney transplant. Hemodialysis, the most common form of dialysis, is an extremely time-intensive and physically burdensome process that is currently limited by membrane performance. The polysulfone (PSf) membranes that are widely used for dialysis today have many limitations, including fouling, toxin rejection, and essential protein loss. Recently, new membranes made from TEMPO-Oxidized nanocellulose dissolved in 1-ethyl-3-methylimidazolium acetate (EMIM-Ac) have shown promising characteristics, …

Polymer Charge Effects On Scaling In Membrane Distillation, Lucia Milans Del Bosch

Chemical Engineering Undergraduate Honors Theses

This research evaluates the effectiveness of polymeric inhibitors at suppressing scaling during direct contact membrane distillation (DCMD). Anionic polyacrylic acid (PAA), neutral polyethylene glycol (PEG), and cationic polyethyleneimine (PEI), were investigated. Experiments were conducted using both hypersaline single-salt and multi-component mixed-salt feeds to determine how the presence of different ions influences performance. Results from single-salt experiments showed that PAA and PEG effectively maintained permeate flux through chelation and steric hindrance, respectively, while PEI caused rapid membrane failure due to interfacial aggregation and pore wetting. In complex mixed-salt solutions, PEG was the additive, maintaining a steady flux with only a 7.33% …

Continuous Sorption Of Ionic Dyes Onto Nanoporous Faujasite Zeolite And The Regeneration Of The Adsorbent, Frederick O. Oshomogho, Miracle Aisosa Omorogieva

BAU Journal - Science and Technology

This study evaluates the efficiency of synthesized faujasite zeolite in the continuous removal of methylene blue from water and tests the reusability of the regenerated adsorbent. Faujasite Zeolite was synthesized from locally available aluminosilicate clay in Edo State using standard methods documented in the literature. XRF analysis affirmed the elemental composition, showing high levels of silica and alumina, which increased its adsorption capacity. SEM images depicted a crystal-clear structure with an octahedral shape and visible micro-pores on the surface. TGA showed effective thermal stability below 300 ºC, with a 10% weight loss between 28.59 ºC and 300 ºC. BET analysis …

Nanostructured Cathode Catalysts For Aem Electrolysis: From Catalyst Design To Degradation And Hydrogen Dynamics, Yamini Kumaran

Electronic Theses & Dissertations (2024 - present)

Anion exchange membrane water electrolysis (AEMWE) presents a promising pathway toward cost-effective and sustainable hydrogen production by integrating the chemical robustness of alkaline systems with the compact, zero-gap design of proton exchange membrane electrolyzers. However, the widespread implementation of AEMWE is limited by the availability of highly active and durable platinum-group-metal (PGM)-free catalysts and by an incomplete understanding of their degradation behavior under realistic operating conditions.

This dissertation focuses on the development, characterization, and mechanistic investigation of nanostructured MoNi₄–MoO₂-based electrodes for efficient and stable hydrogen generation under alkaline and membrane-integrated environments. MoNi₄–MoO₂ nanorods …