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- Cluster-channel model; fluoropolymers; hydrophilic polymers; mechanical properties; micromechanical modeling; PFSA membranes; structure– property relations; swelling; temperature; Young’s modulus (1)
- Conductive membrane (1)
- Electrodeposition (1)
- Interdigitated surface electrode (1)
- Magnetic alignment (1)
Articles 1 - 3 of 3
Full-Text Articles in Membrane Science
Electrodeposition Of Nickel Nanowires And Nanotubes Using Various Templates, Asli Ertan, Surendra N. Tewari, Orhan Talu
Electrodeposition Of Nickel Nanowires And Nanotubes Using Various Templates, Asli Ertan, Surendra N. Tewari, Orhan Talu
Chemical & Biomedical Engineering Faculty Publications
Nickel nanotubes and nanowires are grown by galvanostatic electrodeposition in the pores of 1000, 100, and 15 nm polycarbonate as well as in anodised alumina membranes at a current density of 10 mA cm-2. The effects of pore size, porosity, electrodeposition time, effective current density, and pore aspect ratio are investigated. Nickel nanotube structures are obtained with 1000 nm pore size polycarbonate membrane without any prior treatment method. At the early stages of electrodeposition hollow nickel nanotubes are produced and nanotubes turn into nanowires at longer depositon times. As effective current density accounting for the membrane porosity decreases, the axial …
Micromechanics Model Based On The Nanostructure Of Pfsa Membranes, Ahmet Kusoglu, Michael H. Santare, Anette M. Karlsson, William B. Johnson, Simon Cleghorn
Micromechanics Model Based On The Nanostructure Of Pfsa Membranes, Ahmet Kusoglu, Michael H. Santare, Anette M. Karlsson, William B. Johnson, Simon Cleghorn
Mechanical Engineering Faculty Publications
A micromechanics model is developed to predict Young’s modulus of perfluorosulfonic acid (PFSA) membranes at various temperatures and water contents. The morphology of PFSA membranes is characterized by a two-phase structure, where hydrophilic clusters expand to hold water molecules during swelling, whereas the hydrophobic polymer network maintains the structural stability. A representative volume element (RVE) is proposed based on the descriptions for the nanostructure of PFSA membranes available in the literature. On the basis of mechanics model, we estimate Young’s modulus in tension of PFSA membranes as a function of water volume fraction for various temperatures. The results show that …
Optimizing Performance Of Conductive Nanoparticle-Filled Membranes, Alison Chen
Optimizing Performance Of Conductive Nanoparticle-Filled Membranes, Alison Chen
Honors Scholar Theses
Conductive membranes were prepared by magnetic alignment of graphite-coated iron nanoparticles (GCINs) in a polyisobutylene (PIB) matrix, which was cast onto an interdigitated surface electrode. Toluene and tetrahydrofuran (THF) were used as solvents for the casting solution. Different molecular weights of PIB and solutions with concentrations ranging from 0.05- to 50-wt% were explored to optimize the mechanical and physical properties of the membrane. The amount of GCINs used in the membranes ranged from 0.1- to 2.5-wt%, and a sonicator was used to disperse the particles in the membrane. Sedimentation and surfactant studies were conducted to investigate the dispersion of GCINs …