Catalysis and Reaction Engineering Commons^™

What Difference Does A Catalyst Make?, Tammy Guthrie, Mike Jackson, Holly Haney

High School Lesson Plans

Students will use different catalysts for the decomposition of Hydrogen Peroxide, to determine if different catalysts affect the energy that is generated during the reaction.

The Potentials Of Faecal Sludge Treatment Using Local Conditioners In Tanzania: A Review, Doglas Benjamin1

Tanzania Journal of Engineering and Technology (TJET)

Worldwide, every day human beings generate millions of tons of Faecal Sludge (FS), which is rich in water, nutrients, energy, and organic compounds. Yet FS is not being managed in a way that permits us to derive value from its reuse, while at the same time, millions of farmers struggle with depleted soils and lack of water. In most of the developing countries, energy for cooking is mainly derived from cutting of trees, either as wood or charcoal. Resource recovery and reuse from FS can create livelihoods, enhance food security, support green economies, reduce waste and contribute to cost recovery …

Reduction Of Nox Emissions In A Single Cylinder Diesel Engine Using Sncr With In-Cylinder Injection Of Aqueous Urea, Anthony Timpanaro

UNF Graduate Theses and Dissertations

The subject of this study is the effect of in-cylinder selective non-catalytic reduction (SNCR) of NO_x emissions in diesel exhaust gas by means of direct injection of aqueous urea ((NH₂)₂CO) into the combustion chamber. A single cylinder diesel test engine was modified to accept an electronically controlled secondary common rail injection system to deliver the aqueous urea directly into the cylinder during engine operation.

Direct in-cylinder injection was chosen in order to ensure precise delivery of the reducing agent without the risk of any premature reactions taking place. Unlike direct in-cylinder injection of neat water, …

Improving The Delivered Specific Impulse Of Composite Rocket Propellant Through Alteration Of Chemical Composition: Methodology And Parameters For Characterization Of Propellant And Validation Of Simulation Software Common To The Amateur Rocketry Community, Isaac O'Brien, Austin Ryan

Williams Honors College, Honors Research Projects

In this study, two solid composite rocket propellants were designed utilizing ProPEP, a rocket propellant formulation software common in the amateur and hobby rocketry communities. The two propellants were designed to optimize specific impulse relative to a literature propellant designed by 1020 Research Labs. The literature propellant was also tested in order to validate the design of experiment as well as the mixing and testing procedures. All three propellants, which includes the literature propellant RCS-P, and the two novel propellants AKR-P1 and AKR-P2 were characterized with static tests. The results of the static tests provide data on propellant performance and …

Towards Sustainable Production Of Chemicals And Fuels From The Fast Pyrolysis Of Waste Polyolefin Plastics, Ulises Gracida Alvarez

Dissertations, Master's Theses and Master's Reports

The increasing amount of plastic waste (PW) generation has become an important concern due to the leveled-off recycling rates. Therefore, governmental agencies around the world, including state governments in the United States, have proposed initiatives to minimize the amount of PW that is landfilled and encourage recycling or energy recovery. Circular economy is a strategy that attempts on reusing PW to produce new polymers while avoiding its disposal and the use of virgin material. Chemical recycling raises an interesting technology prospect due to the potential reduction of pollutant emissions and the establishment of a circular economy through the production of …

Performance Of C2H4 Reductant In Activated-Carbon-Supported Mnox-Based Scr Catalyst At Low Temperatures, Guangli Liu, Dongtai Han, Jie Cheng, Yongshi Feng, Wenbin Quan, Li Yang, Kozo Saito

Mechanical Engineering Faculty Publications

Hydrocarbons as reductants show promising results for replacing NH₃ in SCR technology. Therefore, considerable interest exists for developing low-temperature (< 200 °C) and environmentally friendly HC-SCR catalysts. Hence, C₂H₄ was examined as a reductant using activated-carbon-supported MnOx-based catalyst in low-temperature SCR operation. Its sensitivity to Mn concentration and operating temperature was parametrically studied, the results of which showed that the catalyst activity followed the order of 130 °C > 150 °C > 180 °C with an optimized Mn concentration near 3.0 wt.%. However, rapid deactivation of catalytic activity also occurred when using C₂H₄ as the reductant. The mechanism of deactivation was explored and is …

Increased Energy Yield Through Fast Pyrolysis: Empowering Malawian Villages, Diehl Mutamba

Undergraduate Honors Theses

Biomass contributes to several renewable energy technologies. This project will explore the use of fast pyrolysis to produce fuels by designing an apparatus for fast pyrolysis. Malawian people harvest firewood from the forests, which is a major contributor to deforestation. Furthermore, they convert some of it to charcoal with about 10-15% efficiency to sell to city dwellers. The project will enable herbaceous fuels to replace wood, increase charcoal yields and create new products. Firewood and charcoal produce smoke and carbon monoxide (CO) that compromises the villagers’ health.

This project will address deforestation problems, improve sustainability, decrease health hazards and improve …

NoX Formation In Light-Hydrocarbon, Premixed Flames, Robert T. Hughes

Theses and Dissertations--Mechanical and Aerospace Engineering

This study explores the reactions and related species of NO_x pollutants in methane flames in order to understand their production and consumption during the combustion process. To do this, several analytical simulations were run to explore the behavior of nitrogen species in the pre-flame, post- flame, and reaction layer regions. The results were then analyzed in order to identify all "steady-state" species in the flame as well as the determine all the unnecessary reactions and species that are not required to meet a defined accuracy. The reductions were then applied and proven to be viable.

Energy From Chemical Reactions: Understanding The Combustion Engine, Tammy Guthrie, Kathy Prophet, Greg Herzig, Cassie Kautzer

Middle School Lesson Plans

Automobiles produce a large amount of heat generated by the burning of gasoline. Burning gasoline is a chemical reaction that causes a phase change. This is called combustible energy. During combustion fuel combines with oxygen to release energy (such as heat, light, sound) along with another product that is often considered waste. Most of the energy produced is not used to power the automobile, but is released as heat. 19.3 pounds of the greenhouse gas, carbon dioxide, is produced from the combustion of 1 gallon of U.S. gasoline according to the U.S. Energy Information Administration.

Numerical Simulation On The Combustion Characteristic Of Iron Ore Sintering With Flue Gas Recirculation, Gan Wang, Zhi Wen, Guofeng Lou, Ruifeng Dou, Xunliang Liu, Fuyong Su, Sizong Zhang

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

Micro Debris Generator, Gordan Bradaric, Ross Byers, Stephen Quanci

Mechanical Engineering

This senior project team at Cal Poly consisting of Stephen Quanci, Gordan Bradaric, and Ross Byers has been commissioned by Erik Brown of Lawrence Livermore National Labs to create a way to reliably and consistently entrain microscopic particles into the hot HTTU flow. These particles will be used to compare the loading rates of new HEPA filters by measuring the pressure drop across the filter. The generated particles would simulate typical conditions in which these HEPA filters are expected to operate, namely fine ash. The particles used for loading the filter are intended to simulate the particulate reaching the LLNL …

Size-Controlled Large-Diameter And Few-Walled Carbon Nanotube Catalysts For Oxygen Reduction, Xianliang Wang, Qing Li, Hengyu Pan, Ye Lin, Yujie Ke, Haiyang Sheng, Mark T. Swihart, Gang Wu

Faculty Publications

We demonstrate a new strategy for tuning the size of large-diameter and few-walled nitrogen-doped carbon nanotubes (N-CNTs) from 50 to 150 nm by varying the transition metal (TM = Fe, Co, Ni or Mn) used to catalyze graphitization of dicyandiamide. Fe yielded the largest tubes, followed by Co and Ni, while Mn produced a clot-like carbon morphology. We show that morphology is correlated with electrocatalytic activity for the oxygen reduction reaction (ORR). A clear trend of Fe > Co > Ni > Mn for the ORR catalytic activity was observed, in both alkaline media and more demanding acidic media. The Fe-derived N-CNTs exhibited …

The Role Of Surface Area In Catalytic Gasification Of Biomass, Elizabeth A. Wachs, Nitish Kumar, Indraneel Sircar, Prithviraja Basak, Jay P. Gore Phd

The Summer Undergraduate Research Fellowship (SURF) Symposium

Gasification of biomass has the potential to provide a carbon-negative source of liquid fuels. The current limited use of gasification is due in part to the high temperatures necessary to achieve high conversion levels. These temperatures can be lowered by the use of catalysts, but the mechanisms by which catalysts affect the reaction rate are not fully understood. Here, the structural component of potassium carbonate’s role in the gasification process was examined. Samples of pinewood sawdust were impregnated with potassium carbonate, then pyrolyzed with N2 in a fixed bed reactor at 750°C (heater thermocouple reading). Half of the char was …

Experimental Study Of Co2 Recycling Using Metal-Oxide Enhanced Coconut Char Gasification: Catalytic Effect Of Potassium Carbonate On Gasification, Mengqi Gao, Indraneel Sircar, Jay P. Gore

The Summer Undergraduate Research Fellowship (SURF) Symposium

Biomass gasification is an important process in the production of bio-derived fuels and renewable energy. Biomass gasification with CO₂ is an endothermic process requiring high temperatures, resulting in low process-efficiency. Metals found in the ash in biomass feedstock have shown rate-promoting effects on the C-CO₂ reaction and have motivated the study of low-temperature catalytic gasification. The present study investigates the catalytic effects of potassium (K) on the biomass gasification reactivity of a coconut-derived char (>99.9% carbon) within the temperature range of 600 – 1000 ^oC. A wet-impregnation technique is used to prepare K-treated chars. Gasification of …

Investigation Of Carbon Corrosion Resistance Of Cnt Containing Electrode, Diana Larrabee, William A. Rigdon, Eli Mcpherson, Joshua Sightler, Xinyu Huang

Faculty Publications

Carbon support corrosion is one of the major degradation mechanisms of polymer electrolyte membrane (PEM) fuel cell. Carbon oxidation occurs in PEM electrode and is accelerated at high potential created by adverse operating conditions and improper distribution of reactants and products [1, 2, 3]. Carbon corrosion can lead to the thinning of the electrode layer and severe performance degradation. The detailed mechanisms of carbon support corrosion induced performance loss are still not fully understood; it is believed that the following events contribute to the decay: (1) structural collapse of the porous electrode due to the loss of carbon; (2) carbon …

Evaluation Of Cathode Materials For Low Temperature (500-700c) Solid Oxide Fuel Cells, Alexander M. Lassman

Master's Theses

Solid oxide fuel cells (SOFC) have gained a great deal of interest, due to their potential for high efficiency power generation and ability to utilize hydrogen fuel, as well as various hydrocarbon-based fuels. A recent trend in SOFC development has been towards lower operating temperatures (500-700°C), which can substantially reduce the cost and complexity of the system. This thesis presents an investigation into state of the art Ba- and La- based cathode materials for use in low temperature (500-700°C) solid oxide fuel cells.

Synthesis of A-site deficient [A=0.97] Ba_0.5Sr_0.5Co_0.8Fe_0.2O₃ (BSCF) was …

Applied Control Strategies At A Cogeneration Plant, Joseph William Burns

Master's Theses

The purpose of this paper is to demonstrate the effectiveness of “classical strategies for dynamic control” on authentic cogeneration processes. These strategies are applied to several processes at the University of Connecticut’s cogeneration plant. Case studies of their applications are presented in this paper. Strategies that are applied include the following:

1) The classical SISO feedback structure

2) The First Order Plus Dead Time (FOPDT) process model

3) The Internal Model Control (IMC) correlations for PI controller tuning

4) Static feed forward with feedback trim

5) Cascade Control

Thermodynamically Coupled Transport In Simple Catalytic Reactions, Yaşar Demirel

Yaşar Demirel Publications

Considerable work published on chemical reaction-diffusion systems investigates mainly mathematically coupled nonlinear differential equations. This study presents the modeling of a simple elementary chemical reaction with thermodynamically and mathematically coupled heat and mass transport with external mass and heat transfer resistances. The thermodynamic coupling refers that a flow occurs without or against its primary thermodynamic driving force, which may be a gradient of temperature or chemical potential. The modeling is based on the linear nonequilibrium thermodynamics approach and phenomenological equations by assuming that the system is in the vicinity of global equilibrium. This approach does not need detailed coupling mechanisms. …

Socio-Economic Impacts Of Computer Viruses In Tanzania, M Victor

Tanzania Journal of Engineering and Technology (TJET)

This paper reports on a research project conducted with an objective of identifying and assessing various approaches used by different computer users (Management, System Administrators and end users) in Tanzania to combat computer viruses (CVs), and to assess users' awareness level on CVs. Specifically, the study aimed at assessing the awareness level on CVs to the Tanzanian business community; analyze the socio -economic impact caused by CVs in Tanzania and; assess existing methods, capacity and limitations on controlling CVs in Tanzania. Data was collected using both questionnaires and interview from financial institutions such as NBC and BOT, and telecommunications sector …

Review Of The Product Development Process And Information Flow In The Manufacturing Industry: Problems And A Possible Wav Forward, E Opiyo

Tanzania Journal of Engineering and Technology (TJET)

No abstract provided.

Modeling And Simulation Of The Chemical Etching Process In Niobium Cavities, Qin Xue

UNLV Theses, Dissertations, Professional Papers, and Capstones

Niobium Cavities are important parts of the integrated NC/SC high-power linear accelerator (linac) that can accelerate over 100 mA of protons to several GeV. Surface finish of the niobium cavity plays an important role of achieving the best performance of niobium cavity. The chemical etching techniques have been widely used.

Chemical etching of the inner surface of the cavity is achieved by circulating acid through it. The acid interacts with the surface and eliminates imperfections. During the etching process, a pipe with baffles is inserted within the cavity to direct the flow along the surfaces.

A 2-D, axisymmetric, steady state, …

Application Of Vibrational Techniques In Determination Of Dynamic Properties Of Agricultural Products-State Of The Arton Of Vibrational Techniques In Determination Of Dynamic Properties Of Agricultural Products-State Of The Art, Silas Kajuna

Tanzania Journal of Engineering and Technology (TJET)

Vibration is one of the techniques employed in the determination of dynamic properties of fruits and vegetables. It entails generation of a mechanical or acoustic vibrational signal which is propagated through the flesh of the agricultural material. A transducer is either attached or held close to the specimen to monitor the propagation of the signal through the specimen. The manner in which the signal is transmitted through the material is analyzed, and the dynamic properties of the specimen which relate to its firmness or its internal being are derived. The technique has been around for the past 30 years or …