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Full-Text Articles in Biochemical and Biomolecular Engineering
Determination Of Binary Co2/H2 Adsorption Isotherms And Kinetics Over Porous Organic Cage Cc3 Via Zero-Length Column Technique, Jimmy D.L. Moreno, Kyle Newport, Ali A. Rownaghi, Fateme Rezaei
Determination Of Binary Co2/H2 Adsorption Isotherms And Kinetics Over Porous Organic Cage Cc3 Via Zero-Length Column Technique, Jimmy D.L. Moreno, Kyle Newport, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Understanding the dynamics of mixed-gas adsorption is essential for industrial-scale adsorptive separations. Also, obtaining binary adsorption isotherms is essential to gain a better understanding of adsorbate-adsorbent interactions in multicomponent gas mixtures. Porous organic cages (POCs) are highly porous, crystalline materials, with a small average pore window that make them promising candidates for separation applications. In this work, we utilized zero-length column (ZLC) technique to not only determine the kinetics of CO2/H2 separation over CC3 but also obtain the binary adsorption isotherms. The ultra crystalline diffusivities of 1.49 x 10–4 and 8.31 x 10–5 cm2 …
Aryl Sulfonic Acid Catalysts: Effect Of Pendant Group Structure On Activity In Hydrolysis Of Polyethylene Terephthalate, Hossein Abedsoltan, Maria R. Coleman
Aryl Sulfonic Acid Catalysts: Effect Of Pendant Group Structure On Activity In Hydrolysis Of Polyethylene Terephthalate, Hossein Abedsoltan, Maria R. Coleman
Chemical and Biochemical Engineering Faculty Research & Creative Works
A series of aryl sulfonic acids were tested as catalysts for acid hydrolysis occurring at the surface of poly(ethylene) terephthalate (PET) particles. Specifically, p-toluene sulfonic acid monohydrate (PTSA), 2-naphthalenesulfonic acid (2-NSA), and 1,5-naphthalenedisulfonic acid tetrahydrate (1,5-NDSA) were chosen to provide sulfonic acid active groups and varying hydrophobic functionality. The effect of catalyst concentration and reaction temperature on PET hydrolysis rate was studied. The aryl sulfonic acid catalysts exhibited much higher rates of PET hydrolysis than the mineral acid, H2SO4. At 150°C and 4 M catalyst, the time required to achieve more than 90% TPA yield was …
Kinetics Study Of The Hydrodeoxygenation Of Xylitol Over A ReoX-Pd/Ceo2 Catalyst, Blake Macqueen, Michael Royko, Bradie S. Crandall, Andreas Heyden, Yomaira J. Pagán-Torres, Jochen A. Lauterbach
Kinetics Study Of The Hydrodeoxygenation Of Xylitol Over A ReoX-Pd/Ceo2 Catalyst, Blake Macqueen, Michael Royko, Bradie S. Crandall, Andreas Heyden, Yomaira J. Pagán-Torres, Jochen A. Lauterbach
Faculty Publications
In this study, we elucidate the reaction kinetics for the simultaneous hydrodeoxygenation of xylitol to 1,2-dideoxypentitol and 1,2,5-pentanetriol over a ReOx-Pd/CeO2 (2.0 weight% Re, 0.30 weight% Pd) catalyst. The reaction was determined to be a zero-order reaction with respect to xylitol. The activation energy was elucidated through an Arrhenius relationship as well as non-Arrhenius kinetics. The Arrhenius relationship was investigated at 150–170◦ C and a constant H2 pressure of 10 bar resulting in an activation energy of 48.7 ± 10.5 kJ/mol. The investigation of non-Arrhenius kinetics was conducted at 120–170◦ C and a sub-Arrhenius relation was elucidated with activation energy …
Kinetics Study Of The Hydrodeoxygenation Of Xylitol Over A ReoX-Pd/Ceo2 Catalyst, Blake Macqueen, Michael Royko, Bradie S. Crandall, Andreas Heyden, Yomaira J. Pagán-Torres, Jochen A. Lauterbach
Kinetics Study Of The Hydrodeoxygenation Of Xylitol Over A ReoX-Pd/Ceo2 Catalyst, Blake Macqueen, Michael Royko, Bradie S. Crandall, Andreas Heyden, Yomaira J. Pagán-Torres, Jochen A. Lauterbach
Faculty Publications
In this study, we elucidate the reaction kinetics for the simultaneous hydrodeoxygenation of xylitol to 1,2-dideoxypentitol and 1,2,5-pentanetriol over a ReOx-Pd/CeO2 (2.0 weight% Re, 0.30 weight% Pd) catalyst. The reaction was determined to be a zero-order reaction with respect to xylitol. The activation energy was elucidated through an Arrhenius relationship as well as non-Arrhenius kinetics. The Arrhenius relationship was investigated at 150–170◦ C and a constant H2 pressure of 10 bar resulting in an activation energy of 48.7 ± 10.5 kJ/mol. The investigation of non-Arrhenius kinetics was conducted at 120–170◦ C and a sub-Arrhenius relation was elucidated with activation energy …
Development And Validation Of A Kinetic Model For Enzymatic Hydrolysis Using Candida Rugosa Lipase, Ammar Jamie, Ali Alshami, Zuhair O. Maliabari, Muataz A. Ateih
Development And Validation Of A Kinetic Model For Enzymatic Hydrolysis Using Candida Rugosa Lipase, Ammar Jamie, Ali Alshami, Zuhair O. Maliabari, Muataz A. Ateih
Chemical Engineering Faculty Publications
Biochemical processing involving enzymatic catalysis of hydrolysis reactions of oils and fats must overcome significant technological barriers before the full benefits of the technology can be realized. Owing to their selectivity and mild reaction conditions, lipases are becoming increasingly important as biocatalysts provided that their kinetics and optimum reaction conditions are well-understood. In this study we report on the development and validation of a kinetic model for the degradation of oils using Candida rugosa lipase, from which a better understanding of the influence of different reaction conditions on hydrolysis kinetics is elucidated. Variations of reaction temperature, mixing speed, enzyme loading …
Mesophilic Digestion Kinetics Of Manure Slurry, Khursheed Karim, K. Thomas Klasson, Sadie R. Drescher, Whitney Ridenour, Abhijeet P. Borole, Muthanna H. Al-Dahhan
Mesophilic Digestion Kinetics Of Manure Slurry, Khursheed Karim, K. Thomas Klasson, Sadie R. Drescher, Whitney Ridenour, Abhijeet P. Borole, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Anaerobic Digestion Kinetics Study of Cow Manure Was Performed at 35°C in Bench-Scale Gas-Lift Digesters (3.78 L Working Volume) at Eight Different Volatile Solids (VS) Loading Rates in the Range of 1.11-5.87 G L-1 Day-1. the Digesters Produced Methane at the Rates of 0.44-1.18 L L-1 Day-1, and the Methane Content of the Biogas Was Found to Increase with Longer Hydraulic Retention Time (HRT). based on the Experimental Observations, the Ultimate Methane Yield and the Specific Methane Productivity Were Estimated to Be 0.42 L CH4 (G vs. Loaded)-1 and 0.45 L CH …
Procedure To Quantify Biofilm Activity In Carriers Used In Wastewater Treatment Systems, James Bolton, Archana Tummala, Chirag Kapadia, Manoj Dandamudi, Joanne M. Belovich
Procedure To Quantify Biofilm Activity In Carriers Used In Wastewater Treatment Systems, James Bolton, Archana Tummala, Chirag Kapadia, Manoj Dandamudi, Joanne M. Belovich
Chemical & Biomedical Engineering Faculty Publications
A procedure is presented for evaluating and comparing the biological activity of biofilms attached to various biofilm carriers by measurement of the glucose consumption rate. This technique allows for the economical design and selection of small particulate biofilm carriers that will maximize substrate removal when used in industrial-scale fluidized bioreactors. Methods for ensuring reproducible results are described. To support the glucose consumption rate findings, biofilm dry weights were obtained at the conclusion of activity rate experiments, and scanning electron micrographs were taken to evaluate the presence of biofilm and to view surface characteristics. Fourteen different biofilm carriers were evaluated ranging …