Open Access. Powered by Scholars. Published by Universities.®

Biochemical and Biomolecular Engineering Commons™

Open Access. Powered by Scholars. Published by Universities.®

Chemical and Biochemical Engineering Faculty Research & Creative Works

Articles 511 - 540 of 548

Full-Text Articles in Biochemical and Biomolecular Engineering

Mechanical Degradation Of Dilute Solutions Of High Polymers In Capillary Tube Flow, John D. Culter, Jacques L. Zakin, Gary Kent Patterson Jan 1975

Mechanical Degradation Of Dilute Solutions Of High Polymers In Capillary Tube Flow, John D. Culter, Jacques L. Zakin, Gary Kent Patterson

Chemical and Biochemical Engineering Faculty Research & Creative Works

Experimental results on mechanical degradation in capillary tubes of polyisobutylene polymers in dilute solution are described. In laminar flow, degradation is independent of tube length, indicating that entrance effects are dominant. This shows that capillary experiments do not yield explicit information on the effect of shear stress on mechanical degradation. In turbulent flow, large entrance effects are also observed, but some degradation does take place in the fully developed flow region. Copyright © 1975 John Wiley & Sons, Inc.

Go to article

Quantitative Overdesign Of Chemical Processes, R. A. Freeman, J. L. Gaddy Jan 1975

Quantitative Overdesign Of Chemical Processes, R. A. Freeman, J. L. Gaddy

Chemical and Biochemical Engineering Faculty Research & Creative Works

Overdesign is applied to chemical processes to account for expected variations in the design data or design conditions. These variables must be treated quantitatively in order to design a process that is certain to perform adequately. Process dependability is introduced as a means of quantifying variable process behavior. Overdesign using the dependability criterion is a stochastic optimization problem. An example problem with three stochastic variables and two design variables is presented to illustrate these procedures. Copyright © 1975 American Institute of Chemical Engineers

Go to article

Drag Reduction In Solid‐Fluid Systems, I. Radin, J. L. Zakin, Gary Kent Patterson Jan 1975

Drag Reduction In Solid‐Fluid Systems, I. Radin, J. L. Zakin, Gary Kent Patterson

Chemical and Biochemical Engineering Faculty Research & Creative Works

Pressure drop measurements were made on a variety of dilute solid‐liquid suspension systems in order to study the effects of particle shape and size, concentration, fluid viscosity, and tube diameter on friction factor. The central objective was to determine under what conditions drag reduction would occur. Copyright © 1975 American Institute of Chemical Engineers

Go to article

Diffusion Coefficients Of N-Heptane And N-Decane In N-Alkanes And N-Alcohols At Several Temperatures, James W. Moore, Robert M. Wellek Apr 1974

Diffusion Coefficients Of N-Heptane And N-Decane In N-Alkanes And N-Alcohols At Several Temperatures, James W. Moore, Robert M. Wellek

Chemical and Biochemical Engineering Faculty Research & Creative Works

The diffusion coefficients of the solutes n-heptane and n-decane were measured in the series of alkane solvents n-hexane through n-decane and in the alcohol solvents n-hexanol and n-heptanol. Mutual and self-diffusivities in most cases were measured at the temperatures of 20°, 25°, 30°, and 40°C. Concentrations of the diffusion species were in the infinitely dilute region. An unsteady state porous frit technique was used with carbon-14 tagged diffusion species. The diffusion coefficients measured were compared with various liquid diffusivity prediction correlations. © 1974, American Chemical Society. All rights reserved.

Go to article

The Density Determination Of Rf Plasma Polymers, W. W. Knickmeyer, B. W. Peace, Kenneth G. Mayhan Jan 1974

The Density Determination Of Rf Plasma Polymers, W. W. Knickmeyer, B. W. Peace, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

The Anodic Dissolution Of Tin In Acidic Chloride Solutions, James W. Johnson, E. C. Liu Jan 1974

The Anodic Dissolution Of Tin In Acidic Chloride Solutions, James W. Johnson, E. C. Liu

Chemical and Biochemical Engineering Faculty Research & Creative Works

The anodic dissolution of Sn in acidic chloride solutions (pH = -2.0 to 2.9) was studied at 25 °C. The apparent valence of the dissolving ions varied from about 0.4 to 2.4, and was a function of both electrolyte and c.d. The complexing of Sn2+ by Cl- had an important influence, with SnCl-3 apparently being the dominant product. A reaction sequence is proposed involving the stepwise oxidation of Sn, accompanied by reaction with Cl-. © 1974.

Go to article

Permeability Of Selected Gases Through Radio‐Frequency Plasma‐Polymerized Films, B. Suryanarayanan, J. (Jerry) J. (James) Carr, K. (Kenneth) G. Mayhan Jan 1974

Permeability Of Selected Gases Through Radio‐Frequency Plasma‐Polymerized Films, B. Suryanarayanan, J. (Jerry) J. (James) Carr, K. (Kenneth) G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Intrinsic Viscosity Studies Of Linear Polyethylene Fractions In Good And Poor Solvents, J. S. Chiang, J. L. Zakin, Kenneth G. Mayhan Jan 1974

Intrinsic Viscosity Studies Of Linear Polyethylene Fractions In Good And Poor Solvents, J. S. Chiang, J. L. Zakin, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Modified One‐At‐A‐Time Optimization, Marshall E. Findley Jan 1974

Modified One‐At‐A‐Time Optimization, Marshall E. Findley

Chemical and Biochemical Engineering Faculty Research & Creative Works

An optimization method has been developed that searches one variable at a time under the conditions that previously searched variables are at their approximate optimum and variables to be searched later are constant. This method provides the optimum and also information on the effects of the variables. The method is based on the Partan and Powell methods and on assuming linear partial derivatives of the objective function with respect to any given variable. The procedure involves searching each variable separately with other variables either constant or varied so that they remain at their estimated optimum for the given conditions. This …

Go to article

Structure Of High-Internal-Phase-Ratio Emulsions, K. J. Lissant, B. W. Peace, S. H. Wu, K. (Kenneth) G. Mayhan Jan 1974

Structure Of High-Internal-Phase-Ratio Emulsions, K. J. Lissant, B. W. Peace, S. H. Wu, K. (Kenneth) G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Polymers From The Hydrolysis Of Tetraethoxysilane, B. W. Peace, Kenneth G. Mayhan, J. F. Montle Jan 1973

Polymers From The Hydrolysis Of Tetraethoxysilane, B. W. Peace, Kenneth G. Mayhan, J. F. Montle

Chemical and Biochemical Engineering Faculty Research & Creative Works

The hydrolysis of tetraethoxysilane was studied under various solvent and temperature conditions. A method was developed by which reaction rates can be measured even in the presence of alcohols other than ethanol. The structures of the resulting polymers were dependent upon the reaction conditions employed, those formed at high temperature being highly condensed materials. © 1973.

Go to article

Letters To The Editor, J. T. Mason, Orrin K. Crosser, Robert D. Gunn, C. Judson King Jan 1973

Letters To The Editor, J. T. Mason, Orrin K. Crosser, Robert D. Gunn, C. Judson King

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

A Study Of Medium And High Internal Phase Ratio Water/Polymer Emulsions, Kenneth J. Lissant, Kenneth G. Mayhan Jan 1973

A Study Of Medium And High Internal Phase Ratio Water/Polymer Emulsions, Kenneth J. Lissant, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Medium and high internal phase ratio water/polymer emulsions were studied utilizing scanning electron microscope techniques. Results are reported for the geometry and distribution of droplets for water/polymer ratios from 1 1 to 9 1. Electron micrographs confirm those models which predicts polyhedral droplet formation at high internal phase ratios. © 1973.

Go to article

A Study Of Homogeneous Catalysis By High-Pressure Kinetics. The Mechanism Of Catalysis Of A Diels—Alder Reaction, Bruce E. Poling, Charles A. Eckert Nov 1972

A Study Of Homogeneous Catalysis By High-Pressure Kinetics. The Mechanism Of Catalysis Of A Diels—Alder Reaction, Bruce E. Poling, Charles A. Eckert

Chemical and Biochemical Engineering Faculty Research & Creative Works

The application of high-pressure kinetics as a tool to investigate the detailed mechanism of catalysis of a reaction is demonstrated. Activation volumes have been determined for the Diels-Alder addition of 2, 3-dimethylbutadiene to n-butyl acrylate, both uncatalyzed and catalyzed with AICI3. Also, partial molal volumes of reactants and products have been measured. From these data it is shown that the volume profile along the reaction coordinate is similar for both the catalyzed and uncatalyzed reactions. Further, both reactions proceed by a concerted one-step mechanism through a compact transition state with maximum accumulation of double bonds. Thus, the role of the …

Go to article

The Plasma Polymerization Of Vinyl Monomers. I. The Design, Construction, And Operation Of An Inductively Coupled Plasma Generator And Preliminary Studies With Nine Monomers, L. F. Thompson, Kenneth G. Mayhan Jan 1972

The Plasma Polymerization Of Vinyl Monomers. I. The Design, Construction, And Operation Of An Inductively Coupled Plasma Generator And Preliminary Studies With Nine Monomers, L. F. Thompson, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

An apparatus was constructed which would allow vinyl‐type monomers (and others) to polymerize at ambient temperatures in the presence of an inductively coupled RF field. The details of the construction of the system are reported along with preliminary results obtained from nine monomers: styrene, methylvinyldichlorosilane, vinyl acetate, acrylonitrile, vinyl fluoride, 1,1‐difluoroethylene, vinyl chloride, ethylene, and 1,3‐butadiene. Copyright © 1972 John Wiley & Sons, Inc.

Go to article

Saturated Enthalpies For Mixtures Of Propane And Propene, David B. Manley, George W. Swift Jan 1972

Saturated Enthalpies For Mixtures Of Propane And Propene, David B. Manley, George W. Swift

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

The Plasma Polymerization Of Vinyl Monomers. Ii. A Detailed Study Of The Plasma Polymerization Of Styrene, L. F. Thompson, Kenneth G. Mayhan Jan 1972

The Plasma Polymerization Of Vinyl Monomers. Ii. A Detailed Study Of The Plasma Polymerization Of Styrene, L. F. Thompson, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

A study has been made on the plasma polymerization of styrene monomer in a cold, low‐power, inductively coupled RF plasma. Styrene monomer yielded an insoluble, crosslinked film which was slightly colored. A kinetic study is reported for styrene. The effects of power level, bleed rate of monomer, pressure, and reactor geometry on the rate of polymer formation are reported. A mechanism is postulated for plasma polymerization. It was found that the initiation step was the rate controlling step and that the reaction followed a cationic polymerization scheme. Both crosslinking and discoloration of the polymers occur at the time of polymerization …

Go to article

Characterization Of Poly(Methyl Methacrylate) From Radiation‐Induced Polymerization In The Presence Of A Kaolin Clay Substrate, J. J. Beeson, Kenneth G. Mayhan Jan 1972

Characterization Of Poly(Methyl Methacrylate) From Radiation‐Induced Polymerization In The Presence Of A Kaolin Clay Substrate, J. J. Beeson, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Two types of polymer are formed in the radiation‐initiated polymerization of methyl methacrylate (MMA)–kaolin clay complexes. Homopolymer can be extracted from the complex by the use of organic solvents. Inserted polymer must be removed by dissolution of the polymer–clay complex with hydrofluoric acid. The polymers formed show no differences in structure (as determined by infrared analysis), had high molecular weights (1–5 x 106), and had similar molecular weight distributions (as determined by GPC). The molecular weights of the homopolymer increased as temperature increased (25°–75°C), and dose rate decreased (24.9–7.35 rads/sec). The isotacticity of the polymers when compared to irradiated bulk …

Go to article

Discussion, A. G. Fabula, Gary Kent Patterson Jan 1972

Discussion, A. G. Fabula, Gary Kent Patterson

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Kinetic Analysis Of The Radiation Polymerization Of Methyl Methacrylate–Kaolin Clay Composites, J. J. Beeson, Kenneth G. Mayhan Jan 1972

Kinetic Analysis Of The Radiation Polymerization Of Methyl Methacrylate–Kaolin Clay Composites, J. J. Beeson, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

In the first of a two‐part series, a kinetic study has been made on the effects of gamma rays (60Co) in air and inert gas on the polymerization of a 50:50 weight‐mixture methyl methacrylate (MMA)–kaolin clay system. The effect of dose rate (7.35–24.9 rads/sec), temperature (25° to 75°C), and total dose on the percentage conversion of monomer to polymer was studied. The rate of formation of polymer at 25°C in the composite system was found to be faster when compared to a bulk MMA system at the same dose rate. This acceleration showed that the clay had a catalytic effect …

Go to article

Entrance Effects On Capillary Degradation Of Dilute Polystyrene Solutions, J. D. Culter, Kenneth G. Mayhan, Gary Kent Patterson, A. A. Sarmasti, J. (Jacques) L. Zakin Jan 1972

Entrance Effects On Capillary Degradation Of Dilute Polystyrene Solutions, J. D. Culter, Kenneth G. Mayhan, Gary Kent Patterson, A. A. Sarmasti, J. (Jacques) L. Zakin

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Effects Of Molecular Characteristics Of Polymers On Drag Reduction, Gin‐Chain ‐C Liaw, Jacques L. Zakin, Gary Kent Patterson Jan 1971

Effects Of Molecular Characteristics Of Polymers On Drag Reduction, Gin‐Chain ‐C Liaw, Jacques L. Zakin, Gary Kent Patterson

Chemical and Biochemical Engineering Faculty Research & Creative Works

Turbulent measurements in capillary tubes and in pipes were made on nonpolar solutions of seven polymer species, three at more than one molecular weight, over wide concentration ranges. A critical concentration, Cc, was taken as the minimum concentration for disappearance of the turbulence transition region. Above this concentration, friction factor‐generalized Reynolds number data show only a gradual deviation from extension of the laminar line. Cc increases with tube diameter and decreases with molecular weight. The critical dimensionless volume friction Cc [η] is less dependent on molecular weight. The levels of Cc [η] for different polymer species in a given tube …

Go to article

The Anodic Dissolution Of Tungsten, James W. Johnson, Cheng-Hsiao Wu Jan 1971

The Anodic Dissolution Of Tungsten, James W. Johnson, Cheng-Hsiao Wu

Chemical and Biochemical Engineering Faculty Research & Creative Works

The anodic dissolution of tungsten was studied in H2SO4-K2SO4 solutions (pH = -2 to 2.5) and K2SO4-K2CO3-KOH solutions (pH = 11.5 to 14.5) at 25 C. Faradaic efficiency studies in basic solutions showed the metal to be oxidized to the +6 state. In acid solutions, a thick protective film of yellow WO3 was formed. Polarization curves possessed linear Tafel regions (slope ~ 2.3 RT/F) at potentials slightly more positive than the rest potentials. An anodic dissolution mechanism is proposed which involves a surface film …

Go to article

Drag Reduction Correlations, Gary Kent Patterson, J. L. Zakin, J. M. Rodriguez Jan 1970

Drag Reduction Correlations, Gary Kent Patterson, J. L. Zakin, J. M. Rodriguez

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

A Liquid Extraction Column With Reciprocated Wire Mesh Packing, Robert M. Wellek, M. Uran Ozsoy, J. J. Carr, Dudley Thompson, Thomas V. Konkle Oct 1969

A Liquid Extraction Column With Reciprocated Wire Mesh Packing, Robert M. Wellek, M. Uran Ozsoy, J. J. Carr, Dudley Thompson, Thomas V. Konkle

Chemical and Biochemical Engineering Faculty Research & Creative Works

In a new type of pulsating, liquid extractor, pulsating energy is added to the counter currently flowing liquid streams by a stainless-steel wire mesh packing which is reciprocated vertically in a 3-inch i.d. extraction column. The mass transfer performance and flooding characteristics are studied as a function of the frequency and amplitude of reciprocation, the total solvent and feed throughputs, and choice of phase dispersion. The benzene-HAc-H2O and MIBK-HAcH2O systems were used. Extraction data for the benzene system were correlated in terms of a dimensionless pulse velocity group. Operating throughputs are significantly higher than those achieved …

Go to article

Comparison Of Lagrangian Time Correlations Obtained From Dispersion Experiments And From Space‐Time Correlation Functions, J. M. Rodriguez, Gary Kent Patterson Jan 1969

Comparison Of Lagrangian Time Correlations Obtained From Dispersion Experiments And From Space‐Time Correlation Functions, J. M. Rodriguez, Gary Kent Patterson

Chemical and Biochemical Engineering Faculty Research & Creative Works

No Abstracts. Copyright © 1969 American Institute of Chemical Engineers

Go to article

Mass And Heat Transfer Relations In Evaporation Through Porous Membranes, Marshall E. Findley, V. V. Tanna, Y. B. Rao, C. L. Yeh Jan 1969

Mass And Heat Transfer Relations In Evaporation Through Porous Membranes, Marshall E. Findley, V. V. Tanna, Y. B. Rao, C. L. Yeh

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study concerns rates of evaporation and mass transfer of water vapor from a heated salt solution through a water repellent porous membrane to a cooled water condensate. This transfer is a result of temperature differences and corresponding vapor pressure differences across the membrane. Three groups of experiments were carried out which indicate that the major factor influencing the rates of transfer is diffusion through a stagnant gas in the membrane pores. However, an equation considering film heat transfer coefficients, membrane thermal conductivity, and an empirical correction based on temperature driving force appears to be necessary for representing all the …

Go to article

Prediction Of Drag Reduction With A Viscoelastic Model, Gary Kent Patterson, J. L. Zakin Jan 1968

Prediction Of Drag Reduction With A Viscoelastic Model, Gary Kent Patterson, J. L. Zakin

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Numerical Differentiation Of Equally Spaced And Not Equally Spaced Experimental Data [3], Harry C. Hershey, Jacques L. Zakin Jan 1968

Numerical Differentiation Of Equally Spaced And Not Equally Spaced Experimental Data [3], Harry C. Hershey, Jacques L. Zakin

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Existence Of Two Types Of Drag Reduction In Pipe Flow Of Dilute Polymer Solutions, Harry C. Hershey, Jacques L. Zakin Aug 1967

Existence Of Two Types Of Drag Reduction In Pipe Flow Of Dilute Polymer Solutions, Harry C. Hershey, Jacques L. Zakin

Chemical and Biochemical Engineering Faculty Research & Creative Works

Drag reduction in the pipe flow of polymer solutions is shown to be of two types which apparently occur by two separate mechanisms. In turbulent flow, drag reduction is probably caused by viscoelastic effects. The critical solvent Reynolds number at the onset of drag reduction is proportional to about the first power of the diameter. Thus, the critical velocity is independent of tube diameter. Polymers dissolved in good solvents show more drag reduction than in poor solvents. The other type of drag reduction occurs when the laminar region is extended to high Reynolds numbers. It is followed by a transition …

Go to article

First Prev Next Last