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Articles 1 - 30 of 548
Full-Text Articles in Biochemical and Biomolecular Engineering
Age-Related Hearing Loss Involves Mitochondrial Dna Instability And Copy Number Depletion In The Cochlea: Insights From In Vivo And In Vitro Models, Akil Turner, Bo Ding, Xiaoxia Zhu, Tam Nguyen, Parveen Bazard, Robert D. Frisina
Age-Related Hearing Loss Involves Mitochondrial Dna Instability And Copy Number Depletion In The Cochlea: Insights From In Vivo And In Vitro Models, Akil Turner, Bo Ding, Xiaoxia Zhu, Tam Nguyen, Parveen Bazard, Robert D. Frisina
Chemical and Biochemical Engineering Faculty Research & Creative Works
Age-related hearing loss (ARHL) is a highly prevalent sensory neurodegenerative disorder that involves various molecular mechanisms. The present study investigated if age-related oxidative stress (OS) induces alterations in mitochondrial DNA (mtDNA) copy number and heteroplasmy, using complementary in vivo and in vitro models. Aged (30-month) CBA/CaJ mice have elevated auditory brainstem response (ABR) thresholds amplitudes vs. young (3-month) CBA/CaJ mice, a key physiological characteristic of ARHL The in vitro experiments employed the strial SV-K1 cochlear cell line treated with hydrogen peroxide (H2O2). Both the aged cochleae and H2O2-treated cells exhibited a significant …
Bone Void Filler Materials For Augmentation In Comminuted Fractures: A Comprehensive Review, S. Sina Mohammadi, Sunjeev S. Phull, B. Sonny Bal, Mark R. Towler
Bone Void Filler Materials For Augmentation In Comminuted Fractures: A Comprehensive Review, S. Sina Mohammadi, Sunjeev S. Phull, B. Sonny Bal, Mark R. Towler
Chemical and Biochemical Engineering Faculty Research & Creative Works
Comminuted fractures, characterized by multiple bone fragments, present significant challenges in orthopedic surgery. Effective treatment often requires augmentation techniques to enhance fixation stability and promote bone regeneration. This review explores the application of bone void filler materials, including autografts, allografts, polymethyl methacrylate (PMMA), and synthetic bone substitutes such as calcium phosphate ceramics and bioactive glass, in managing comminuted fractures. Autografts are the gold standard due to their superior osteogenic potential but are limited by donor site morbidity and availability. Allografts mitigate these issues but face concerns regarding immunogenicity and reduced biological activity. PMMA, widely used for structural augmentation, provides immediate …
Fluorosilane-Induced Softening And Collapse Of Micropillar Arrays, Gabriela Moreira Lana, Maja Fehlberg, Petra Herbeck-Engel, Gisela Heppe, Raimund Schlüßler, Torsten Jähnke, Eduard Arzt, Roland Bennewitz
Fluorosilane-Induced Softening And Collapse Of Micropillar Arrays, Gabriela Moreira Lana, Maja Fehlberg, Petra Herbeck-Engel, Gisela Heppe, Raimund Schlüßler, Torsten Jähnke, Eduard Arzt, Roland Bennewitz
Chemical and Biochemical Engineering Faculty Research & Creative Works
Replica molding is a widely used technique for the fabrication of polymer microstructures. As structural dimensions decrease, anti-stick surface treatment of the mold becomes increasingly critical to ensure clean demolding and preserve structural integrity. We fabricated arrays of micropillars with 20 µm diameter and 60 µm height using medical-grade polydimethylsiloxane (PDMS), MDX4-4210, and observed a high fraction of collapsed pillars for the first molding after fluorosilanization of the mold to reduce sticking. To address this issue, we systematically investigated the surface treatment protocol for the molds, made from the PDMS Sylgard 184. We provide results from complementary measurement methods, to …
Gallium-Containing Bioactive Glasses: Their Influence On Ion Release And The Bioactivity Of Resulting Glass Polyalkenoate Cements, Lana Margaret Placek, Danielle Lee Perry, Mark Robert Towler, Anthony William Wren
Gallium-Containing Bioactive Glasses: Their Influence On Ion Release And The Bioactivity Of Resulting Glass Polyalkenoate Cements, Lana Margaret Placek, Danielle Lee Perry, Mark Robert Towler, Anthony William Wren
Chemical and Biochemical Engineering Faculty Research & Creative Works
A series of glasses (0.48SiO2 − [0.40-x]ZnO − 0.12CaO-xGa2O3, x = 0, 0.8, 0.16) was developed to formulate a series of Ga-containing glass polyalkenoate cements (GPCs). The solubility of GPCs was tested using DI water, and it was found that the sample containing the highest mol% of Ga, LGa-2, had the most Ga ion release. The GPCs were incubated in SBF, and SEM/EDS analysis revealed that the at% of P increased, while the at% of Si decreased, highlighting the CaP precipitation on the GPC surface. The at% of Ga also decreased, reinforcing the Ga release from the GPC. Cellular testing …
Cooperative And Bifunctional Ga-Ca-Cr2o3@Cao Structured Monoliths As Versatile Platform For Reactive Capture Of Co2 And Its Subsequent Conversion To Ethylene, Khaled Baamran, Ali A. Rownaghi
Cooperative And Bifunctional Ga-Ca-Cr2o3@Cao Structured Monoliths As Versatile Platform For Reactive Capture Of Co2 And Its Subsequent Conversion To Ethylene, Khaled Baamran, Ali A. Rownaghi
Chemical and Biochemical Engineering Faculty Research & Creative Works
Cooperative and bifunctional materials (BFMs) that integrate adsorbents and catalysts offer a promising strategy for the reactive capture of CO2 to produce valuable fuels and chemicals. In this study, we developed structured BFMs via 3D printing that combine CaO as an adsorbent with Ga–Ca–Cr2O3 metal oxides as the catalyst for the reactive capture of CO2 and its subsequent conversion to C2H4 via the oxidative dehydrogenation of C2H6 (CO2-ODHE). Three different Ga–Ca compositions were used to modify the catalyst surface characteristics and enhance C2H4 selectivity. …
Graphite Particles Modified By Zno Atomic Layer Deposition For Li-Ion Battery Anodes, Ahmad Helaley, Han Yu, Xinhua Liang
Graphite Particles Modified By Zno Atomic Layer Deposition For Li-Ion Battery Anodes, Ahmad Helaley, Han Yu, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Graphite, with a modest specific capacity of 372 mA h g−1, is a stable material for lithium-ion battery anodes. However, its capacity is inadequate to meet the growing power demands because the formation of an irregular solid electrolyte interphase (SEI) can result in unstable performance. In this research, we used a few cycles of atomic layer deposition (ALD) to deposit ZnO on graphite particles as an anode with improved electrochemical stability. Transmission electron microscopy revealed that ZnO was in the form of nanoparticles due to the inert surface properties of graphite and only a few cycles of ALD. Electrochemical characterization …
Process Development And Techno-Economic Analysis For Combined And Separated Co2 Capture-Electrochemical Utilization, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Process Development And Techno-Economic Analysis For Combined And Separated Co2 Capture-Electrochemical Utilization, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Combining CO2 capture and utilization into a single unit operation offers a feasible solution for converting a sustainable feedstock into marketable commodity chemicals, while reducing energy requirements from separated processes. In this research, we developed a process model and performed a techno-economic analysis (TEA) for point-source CO2 capture and electrochemical-based utilization in light olefins production under both separated and integrated scenarios. CO2 containing flue gas from a 500 MW power plant was utilized as a feed while CO2 utilization involved electrochemical reduction reactions to produce light olefins directly from CO2. A meticulous analysis was …
Atomic Layer Deposition Of Ru Nanoclusters On Ba-Laceox: A Highly Efficient Catalyst For Ammonia Synthesis Under Mild Conditions, Kaiying Wang, Baitang Jin, Xiaoqing He, Xinhua Liang
Atomic Layer Deposition Of Ru Nanoclusters On Ba-Laceox: A Highly Efficient Catalyst For Ammonia Synthesis Under Mild Conditions, Kaiying Wang, Baitang Jin, Xiaoqing He, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Ammonia synthesis has significant implications for global energy and environmental issues, driving the need for highly active catalysts that operate under mild conditions. This study reports the successful deposition of uniform ∼1.0 nm metallic ruthenium (Ru) nanoclusters onto Ba-LaCeOx particles via atomic layer deposition (ALD). The catalytic performance of the ALD-prepared Ru nanoclusters was assessed for ammonia synthesis and compared with two catalysts produced by conventional incipient wetness impregnation. For the ALD-prepared Ru nanoclusters, a pre-reaction H2-reduction step induced partial encapsulation of suboxide species on Ru sites due to strong metal-support interactions, limiting Ru nanocluster sintering and …
A New Air-Assisted Flare Tip Design For Managing Gas Flare Emissions (Cfd Analysis), Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana
A New Air-Assisted Flare Tip Design For Managing Gas Flare Emissions (Cfd Analysis), Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana
Chemical and Biochemical Engineering Faculty Research & Creative Works
Recently, flares have been considered as a major source of air pollution from the petroleum refining industry. The United Nations has instigated an international effort related to the management of flare emissions to reduce the global warming impact related to flaring. Eliminating or removing the need for gas flares is difficult because these devices are generally used as safety devices to allow the combustion of flammable gases in a controlled fashion which supports safe operation. However, reducing flaring is generally possible using well-designed, efficiently operated flare equipment. In general, flare performance can be enhanced following the API-521 methodology and using …
Antibiotic-Loaded Dendrimer Hydrogels In Periodontal Bone Regeneration: An In Vitro Release Feasibility Study, Nicholas Yesbeck, Da Huang, Caroline Carrico, Parthasarathy Madurantakam, Hu Yang
Antibiotic-Loaded Dendrimer Hydrogels In Periodontal Bone Regeneration: An In Vitro Release Feasibility Study, Nicholas Yesbeck, Da Huang, Caroline Carrico, Parthasarathy Madurantakam, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
The prescription of a course of oral antibiotics following bone grafting procedures is a common practice in clinical periodontics to reduce surgical site infections. The goal of this study is to characterize the release profile of antibiotics via local delivery using dendrimer hydrogels (DH) and to analyze the effect of two different particulate bone allografts on the release of the antibiotics in vitro. DH were synthesized from Poly amidoamine (PAMAM) dendrimer G5 and polyethylene glycol diacrylate, and cefazolin was chosen as the antibiotic. The antibiotic-loaded samples were bathed in PBS and incubated at 37 °C; aliquots were taken (1 h, …
Consistent Intraocular Pressure Reduction By Solid Drug Nanoparticles In Fixed Combinations For Glaucoma Therapy, Da Huang, Pedro Norat, Lin Qi, Anna Chernatynskaya, James D. Cole, Vimalin Jeyalatha Mani, Lei Xu, Xiaorong Liu, Hu Yang
Consistent Intraocular Pressure Reduction By Solid Drug Nanoparticles In Fixed Combinations For Glaucoma Therapy, Da Huang, Pedro Norat, Lin Qi, Anna Chernatynskaya, James D. Cole, Vimalin Jeyalatha Mani, Lei Xu, Xiaorong Liu, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Efficient topical drug delivery remains a significant challenge in glaucoma management. Although nanoparticle formulations offer considerable promise, their complex preparation processes, co-delivery issues, and batch consistency have hindered their potential. A scalable fabrication strategy is developed here for preparing solid drug nanoparticles (SDNs) with enhanced drug delivery efficiency. Utilizing hydrophobic antiglaucoma drugs brimonidine (BM) and betaxolol (BX), uniform fixed combination BM/BX SDNs are fabricated through a continuous process, improving batch-to-batch consistency for combined glaucoma treatment. With trehalose being used as a lyoprotectant, BM/BX SDNs can be stored as dry powder and easily reconstituted in phosphate buffered saline. Importantly, reconstituted BM/BX …
Design And Development Of Uio-67-Coated Pim-1-Based Composites And Demonstration Of Their Detoxification Performance, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Design And Development Of Uio-67-Coated Pim-1-Based Composites And Demonstration Of Their Detoxification Performance, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Polymer-supported MOF composites have emerged as versatile candidates for various separation and catalytic applications. In this study, we demonstrate design and development of UiO-67-coated Ce(OH)4@PIM-1 composites via dip-coating, drop-casting, solid-phase coating, and supramolecular assembly, and assess their preparation-structure-performance relations. The catalytic performance of the composites was investigated through hydrolysis of dimethyl 4-nitrophenyl phosphate (DMNP), as a nerve agent simulant. The findings revealed that while dip-coating method was unable to achieve a thick and uniform coverage of the MOF layer on the Ce(OH)4@PIM-1, the supramolecular assembly gave rise to 16 wt.% MOF loading and the composite prepared …
Examination And Improvement Of The Taguchi-Based Nanofluids Impact On Co2 Absorption Using Al2o3 Nanoparticles, Safa Waleed Shakir, Saif Saleh Hussein, Shaymaa Hasan Khazaal, Hyder Akram Al-Naseri, Ahmed Mohammed Ahmed, Rana Najah Hachim, Muthanna Hikmat Al-Dahhan
Examination And Improvement Of The Taguchi-Based Nanofluids Impact On Co2 Absorption Using Al2o3 Nanoparticles, Safa Waleed Shakir, Saif Saleh Hussein, Shaymaa Hasan Khazaal, Hyder Akram Al-Naseri, Ahmed Mohammed Ahmed, Rana Najah Hachim, Muthanna Hikmat Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
In this study, a batch absorption reactor was used to evaluate the nanofluid of a binary aqueous solution of monoethanolamine and 2-amino-2-methyl-1-propanol (MEA/AMP) with nanoparticles of aluminium oxide (Al2O3) as a solvent used to remove carbon dioxide (CO2) from simulated flue gas. Furthermore, the application of the Taguchi experiment design method determined the optimal conditions for the absorption process. This research focuses on the CO2 absorption process and the optimal conditions related to nanoparticle addition. The main effects of using nanofluid were investigated. The concentration of nanoparticles, nanoparticle size, and stirrer speeds were …
Determination Of Binary Co2/H2 Adsorption Isotherms And Kinetics Over Porous Organic Cage Cc3 Via Zero-Length Column Technique, Jimmy D.L. Moreno, Kyle Newport, Ali A. Rownaghi, Fateme Rezaei
Determination Of Binary Co2/H2 Adsorption Isotherms And Kinetics Over Porous Organic Cage Cc3 Via Zero-Length Column Technique, Jimmy D.L. Moreno, Kyle Newport, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Understanding the dynamics of mixed-gas adsorption is essential for industrial-scale adsorptive separations. Also, obtaining binary adsorption isotherms is essential to gain a better understanding of adsorbate-adsorbent interactions in multicomponent gas mixtures. Porous organic cages (POCs) are highly porous, crystalline materials, with a small average pore window that make them promising candidates for separation applications. In this work, we utilized zero-length column (ZLC) technique to not only determine the kinetics of CO2/H2 separation over CC3 but also obtain the binary adsorption isotherms. The ultra crystalline diffusivities of 1.49 x 10–4 and 8.31 x 10–5 cm2 …
Emulsion Liquid Membrane (Elm) Enhanced By Nanoparticles And Ionic Liquid For Extracting Vanadium Ions From Wastewater, Qusay Al-Obaidi, Nora Yehia Selem, Muthanna H. Al-Dahhan
Emulsion Liquid Membrane (Elm) Enhanced By Nanoparticles And Ionic Liquid For Extracting Vanadium Ions From Wastewater, Qusay Al-Obaidi, Nora Yehia Selem, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Emulsion liquid membrane (ELM) stands out as an extraction process that has drawn much attention due to its promising prospects in industrial wastewater treatment technology. Nevertheless, the pivotal challenge is to reach high membrane stability to overcome the obstacle of applying ELM at the industrial scale. In this study, ELM was boosted by using nanoparticles (superparamagnetic iron oxide (Fe2O3)) in the stripping phase (W1) and ionic liquid (1-methyl-3-octyl-imidazolium-hexafluorophosphate [OMIM][PF6) in the oil phase (O) for recovering/extracting vanadium from synthetic wastewater to near completion and at the same time enhancing emulsion stability to be appropriate for industrial …
Induction Vacuum Swing Adsorption Over Magnetic Sorbent Monoliths And Extrudates For Ethylene/Ethane Separation, Khaled Baamran, Usman Shareef, Fateme Rezaei
Induction Vacuum Swing Adsorption Over Magnetic Sorbent Monoliths And Extrudates For Ethylene/Ethane Separation, Khaled Baamran, Usman Shareef, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Electrification of adsorption processes is emerging as an adaptable solution for future gas separations. This study develops magnetic sorbent structures for use in induction vacuum swing adsorption (IVSA) process specifically designed for olefin/paraffin separation. Two sorbents, namely Fe3O4/ZIF-7 (ethane-selective) and Fe3O4/13X (ethylene-selective) were developed and formulated into extrudates (Fe20/ZIF-7-P) and monoliths (Fe20/13X-M), and tested under different regeneration scenarios, including simultaneous and subsequent induction-evacuation, induction only, and evacuation only. The dynamic adsorption results demonstrated that regeneration under subsequent induction-evacuation improves desorption rate and capability. Under this regeneration scenario, Fe …
Experimental Investigation Of Liquid Holdup In A Co-Current Gas–Liquid Upflow Moving Packed Bed Reactor With Porous Catalyst Using Gamma-Ray Densitometry, Ali Toukan, Ahmed Jasim, Vineet Alexander, Hamza Albazzaz, Muthanna H. Al-Dahhan
Experimental Investigation Of Liquid Holdup In A Co-Current Gas–Liquid Upflow Moving Packed Bed Reactor With Porous Catalyst Using Gamma-Ray Densitometry, Ali Toukan, Ahmed Jasim, Vineet Alexander, Hamza Albazzaz, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
This study explores the dynamics of liquid holdup in a lab-scale co-current two-phase up flow moving packed bed reactor, specifically examining how superficial gas velocity influences the line average external liquid holdup at a fixed superficial liquid velocity. Utilizing gamma-ray densitometry (GRD) for precise measurements, this research extends to determining line average internal porosity within catalyst particles. Conducted with an air–water system within a bed packed with 3 mm porous particles, the study presents a novel methodology using Beer–Lambert's law to calculate liquid, gas, and solid holdups and catalyst porosity that is equivalent to the internal liquid holdup that fills …
Kinetic Studies Of Liquid Phase Hydrogenation Of Acetylene For Ethylene Production Using A Selective Solvent Over A Commercial Palladium/Alumina Catalyst, Humayun Shariff, Muthanna H. Al-Dahhan
Kinetic Studies Of Liquid Phase Hydrogenation Of Acetylene For Ethylene Production Using A Selective Solvent Over A Commercial Palladium/Alumina Catalyst, Humayun Shariff, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
The Kinetics of Selective Hydrogenation of Acetylene in the Liquid Phase over a Commercial 0.5 Wt % Pd/Al2O3 Spherical Catalyst Was Investigated in a Stirred-Tank Basket Reactor. the Liquid Phase Was Acetylene Gas Absorbed in a Selective Solvent, N-Methylpyrrolidone (NMP). the Reactor Was Operated at a Pressure Range of 15-250 Psig with Temperature Varying from 60 to 100 °C using Different Catalyst Loadings to Identify the Suitable Operating Conditions. the Kinetic Experiments Were Conducted in the Absence of External Mass Transfer Resistances with the Liquid Phase in Batch Mode and the Gas Phase Being Continuous. the Initial Rates Varied Linearly …
Localized Sustained Release Of Copper Enhances Antitumor Effects Of Disulfiram In Head And Neck Cancer, Juan Wang, Boxuan Li, Remy C. Cooper, Da Huang, Hu Yang
Localized Sustained Release Of Copper Enhances Antitumor Effects Of Disulfiram In Head And Neck Cancer, Juan Wang, Boxuan Li, Remy C. Cooper, Da Huang, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Drug Repurposing Uses Approved Drugs as Candidate Anticancer Therapeutics, Harnesses Previous Research and Development Efforts, and Benefits from Available Clinically Suitable Formulations and Evidence of Patient Tolerability. in This Work, the Drug Used Clinically to Treat Chronic Alcoholism, Disulfiram (DSF), Was Studied for its Antitumor Efficacy in a Copper-Dependent Manner. the Combination of DSF and Copper Could Achieve a Tumor Cell Growth Inhibition Effect Comparable to Those of 5-Fluorouracil and Taxol on Head and Neck Cancer Cells. Both Bulk Dendrimer Hydrogel and Microsized Dendrimer Hydrogel Particles Were Utilized for the Localized Sustained Release of Copper in the Tumor Site. the …
Liquid-Phase Adsorption Of Dimethyl Methylphosphonate On Poly(Ether Imide) And Its Metal Hydroxide-Integrated Composites, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Liquid-Phase Adsorption Of Dimethyl Methylphosphonate On Poly(Ether Imide) And Its Metal Hydroxide-Integrated Composites, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Understanding the Adsorption Behavior of Dimethyl Methylphosphonate (DMMP), a Key Simulant for Some Nerve Agents, is Crucial for Developing Effective Protective Measures and Ensuring Environmental Safety Against Harmful Chemical Warfare Agents. This Study Systematically Explores the Liquid-Phase Adsorption of DMMP over Branched Poly (Ether Imide) (Ultem) and its Ce (OH)4/Zr (OH)4 Metal Hydroxide Composites. Utilizing UV-Visible (UV-Vis) Spectroscopy, the Adsorption Process Was Monitored over Time to Analyze the Interplay between Various Ultem-Based Composites and DMMP Molecules. Nonreactive Ultem Materials Were Experimentally Identified as Suitable Adsorbents for Liquid-Phase DMMP Capture, Providing a Novel Avenue for Protective Filtration Technologies. It Was Found …
L-Ergothioneine Slows The Progression Of Age-Related Hearing Loss In Cba/Caj Mice, Mark A. Bauer, Parveen Bazard, Alejandro A. Acosta, Nidhi Bangalore, Lina Elessaway, Mark Thivierge, Moksheta Chellani, Xiaoxia Zhu, Bo Ding, Joseph P. Walton, Robert D. Frisina
L-Ergothioneine Slows The Progression Of Age-Related Hearing Loss In Cba/Caj Mice, Mark A. Bauer, Parveen Bazard, Alejandro A. Acosta, Nidhi Bangalore, Lina Elessaway, Mark Thivierge, Moksheta Chellani, Xiaoxia Zhu, Bo Ding, Joseph P. Walton, Robert D. Frisina
Chemical and Biochemical Engineering Faculty Research & Creative Works
The naturally occurring amino acid, l-ergothioneine (EGT), has immense potential as a therapeutic, having shown promise in the treatment of other disease models, including neurological disorders. EGT is naturally uptake into cells via its specific receptor, OCTN1, to be utilized by cells as an antioxidant and anti-inflammatory. In our current study, EGT was administered over a period of 6 months to 25–26-month-old CBA/CaJ mice as a possible treatment for age-related hearing loss (ARHL), since presbycusis has been linked to higher levels of cochlear oxidative stress, apoptosis, and chronic inflammation. Results from the current study indicate that EGT can prevent aging …
Cooperative And Bifunctional Adsorbent-Catalyst Materials For In-Situ Vocs Capture-Conversion, Sukanta K. Mondal, Peter Aina, Ali A. Rownaghi, Fateme Rezaei
Cooperative And Bifunctional Adsorbent-Catalyst Materials For In-Situ Vocs Capture-Conversion, Sukanta K. Mondal, Peter Aina, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Volatile Organic Compounds (VOCs) Are Gases that Are Emitted into the Air from Products or Processes and Are Major Components of Air Pollution that Significantly Deteriorate Air Quality and Seriously Affect Human Health. Different Types of Metals, Metal Oxides, Mixed-Metal Oxides, Polymers, Activated Carbons, Zeolites, Metal-Organic Frameworks (MOFs) and Mixed-Matrixed Materials Have Been Developed and Used as Adsorbent or Catalyst for Diversified VOCs Detection, Removal, and Destruction. in This Comprehensive Review, We First Discuss the General Classification of VOCs Removal Materials and Processes and Outline the Historical Development of Bifunctional and Cooperative Adsorbent-Catalyst Materials for the Removal of VOCs from …
Future Of Process Safety: Insights, Approaches, And Potential Developments, Hossein Abedsoltan, Amirhesam Abedsoltan, Zeinab Zoghi
Future Of Process Safety: Insights, Approaches, And Potential Developments, Hossein Abedsoltan, Amirhesam Abedsoltan, Zeinab Zoghi
Chemical and Biochemical Engineering Faculty Research & Creative Works
This review explores the evolving landscape of process safety, emphasizing the integration of digitalization and advanced technologies. It assesses the role of the industrial Internet of Things, artificial intelligence, and machine learning (ML) in enhancing safety protocols. The paper examines predictive analytics, sensor technology advancements, and digital twins' contributions to safety optimization. It also discusses the future perspectives of risk management approaches, including proactive safety management systems, quantitative risk assessment techniques, and human reliability analysis. This comprehensive analysis provides insights into future developments and challenges in process safety.
Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant, Peter O. Aina, Sukanta K. Mondal, Ali A. Rownaghi, Fateme Rezaei
Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant, Peter O. Aina, Sukanta K. Mondal, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
In recent years, significant attention has been directed toward evaluating the reactivity of diverse polymers to gauge their catalytic activity against hazardous chemicals. Among these polymers, pim-1 has emerged as an exceptional candidate due to its noteworthy attributes including high surface area, excellent solubility, and the capability to fine-tune the nitrile functional groups along its polymeric backbone. In this study, we explored the impact of different functional groups, such as amidoxime (ax), aldoxime (ox), and carboxylate (cooh), on the degradation of dimethyl 4-nitrophenylphosphonate (dmnp) in comparison to pure pim-1 and their respective ce(oh)4-loaded polymer composites. Remarkably, the pim-1-ax analog exhibited …
Mitigation Of Potential Risks In Chemical Laboratories: A Focused Review, Hossein Abedsoltan, Mark B. Shiflett
Mitigation Of Potential Risks In Chemical Laboratories: A Focused Review, Hossein Abedsoltan, Mark B. Shiflett
Chemical and Biochemical Engineering Faculty Research & Creative Works
This review paper presents an analysis of safety practices in chemical laboratories. It encompasses a systematic exploration of various facets including risk assessment, hazard mitigation, and the implementation of safety protocols. Emphasis is placed on the critical role of continuous education and training, advocating a proactive safety culture, and adapting to technological advancements. Additionally, the paper underscores the importance of adhering to regulatory standards, promoting exceeding baseline compliance toward establishing best practices in laboratory safety. This comprehensive approach highlights the dynamic, multifaceted nature of laboratory safety, positioning it as a fundamental aspect of scientific research.
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Chemical and Biochemical Engineering Faculty Research & Creative Works
Carbon nanotube-encapsulated nickel selenide composite nanostructures were used as nonenzymatic electrochemical sensors for dopamine detection. These composite nanostructures were synthesized through a simple, one-step, and environmentally friendly chemical vapor deposition method, wherein the CNTs were formed in situ from pyrolysis of a carbon-rich metallo-organic precursor. The composition and morphology of these hybrid NiSe2-filled carbon nanostructures were confirmed by powder X-ray diffraction, Raman, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy images. Electrochemical tests demonstrated that the as-synthesized hybrid nanostructures exhibited outstanding electrocatalytic performance toward dopamine oxidation, with a high sensitivity of 19.62 μA μM-1 cm-2, low detection limit, broad linear …
Challenges And Opportunities In Electrification Of Adsorptive Separation Processes, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Challenges And Opportunities In Electrification Of Adsorptive Separation Processes, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
A global energy transition from fossil-based to renewable-based systems requires advancements in various energy sectors. Current chemical separation processes are quite energy-intensive and require significant advancement to make this transition happen. In the energy transition era, reducing the dependency of separation processes on fossil-based thermal energy seems inevitable for transitioning smoothly and meeting the stringent timelines. In particular, adsorption-based separation processes have the potential to be fully electrified through innovative strategies in developing stimuli-responsive adsorbents and swing processes. In this review, we discuss the recent efforts in electrification of adsorption processes and provide an overview of emerging materials and processes. …
Advancement In Heavy Oil Upgrading And Sustainable Exploration Emerging Technologies, Youssef Yatimi, Jihane Mendil, Meena Marafi, Ahmed Alalou, Muthanna H. Al-Dahhan
Advancement In Heavy Oil Upgrading And Sustainable Exploration Emerging Technologies, Youssef Yatimi, Jihane Mendil, Meena Marafi, Ahmed Alalou, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Upgrading heavy oil is a subject of high importance for fossil fuel industry due to the rapid depletion of light oil reservoirs and the consequent increased demand for upgrading heavy oil. In this review, the advancement made in heavy oil upgrading and the proposed sustainable emerging technologies dedicated to heavy oil processing have been discussed in a comprehensive and informative manner with consideration to the encountered associated with properties of heavy oil including its significant content of undesirable large molecular weight hydrocarbons, its high viscosity, and its elevated impurity level. The shortcomings of conventional crude oil upgrading technologies are outlined, …
Applications Of Plastics In The Automotive Industry: Current Trends And Future Perspectives, Hossein Abedsoltan
Applications Of Plastics In The Automotive Industry: Current Trends And Future Perspectives, Hossein Abedsoltan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Plastics have transformed the automotive industry, contributing substantially to automobile design, weight reduction, fuel efficiency, safety, and sustainability. This review paper examines the applications of plastics in the automotive sector, evaluates the present trends, and describes the future plastic consumption possibilities, emphasizing emerging technology and sustainable practices. The paper delineates how plastics have become an essential component of automotive innovation and illustrates the possibilities for additional breakthroughs in this dynamic industry. Highlights: Advances in plastics, bioplastics, and smart materials in the auto industry. Plastic role in design, safety, and sustainability in the auto industry. Recycling and the circular economy of …
Pd-Modified Cuo-Zno-Al2o3 Catalysts Via Mixed-Phases-Containing Precursor For Methanol Synthesis From Co2 Hydrogenation Under Mild Conditions, Xiao Fan, Kaiying Wang, Xiaoqing He, Shiguang Li, Miao Yu, Xinhua Liang
Pd-Modified Cuo-Zno-Al2o3 Catalysts Via Mixed-Phases-Containing Precursor For Methanol Synthesis From Co2 Hydrogenation Under Mild Conditions, Xiao Fan, Kaiying Wang, Xiaoqing He, Shiguang Li, Miao Yu, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
A series of palladium-modified (Pd-modified) CuO-ZnO-Al2O3 (CZA) catalysts with various Pd loadings (0.3 wt% to 2.4 wt%) were prepared using the wetness impregnation method, on two CZA supports with different structures that are CZA-aged precursor composed of a mixture of zincian-malachite and hydrotalcite-like phases (CZA-zH), and CuO-ZnO-Al2O3 metal oxide nanoparticles (CZA-MO). Enhancement on catalytic activity can be observed on both Pd-modified CZA catalysts in a temperature range of 180–240 °C for methanol synthesis via CO2 hydrogenation. Pd/CZA-zH catalysts exhibited a more efficient and stable production of methanol at a relatively low reaction temperature of 180 °C for 100 hrs. of …