Chemical Engineering Commons^™

Removal Of Hexavalent Chromium From Water By Chitosan-Enhanced Ultrafiltration, Putu A. Y. Indiasih, Anindita D. Syaifudin, Nurul Faiqotul Himma, Bambang Ismuyanto

Makara Journal of Technology

Polymer-enhanced ultrafiltration has gained increasing attention as a selective separation process to remove small solutes, such as metal ions, from water or wastewater. Hexavalent chromium Cr(VI) is one of the metal ions in wastewater that has received considerable attention because of its toxicity. Chitosan was used in this study as the polymer to bind Cr(VI) to enhance its removal by ultrafiltration. The effects of chitosan-to-Cr(VI) ratio on Cr(VI) rejection and permeate flux were investigated. In addition, the fouling tendency was evaluated. Results showed that the addition of chitosan with a mass ratio of 12.5 increased the Cr (VI) rejection from …

Remote Alignment Fixing Device With Vizir Marks In Base Lcd Indicator, Nodirbek Rustambekovich Yusupbekov, Zahidov Muratovich Nematjon

Chemical Technology, Control and Management

The article substantiates the needs to increase the level of automation of methods and geodetic support of geometric parameters during the construction of buildings and structures. In particular, the method of alignment measurements is considered. This is widely used in determining deviations from the straightness and alignment of the installation of elements in engineering building structures, including hydraulic structures, as well as in the control of process equipment installations, rolling mills, conveyor lines, crane tracks, when monitoring precipitation. and deformations of techno objects. One of the methods of alignment measurements with the use of a visual-optical device – aliniometer and …

The Magnetic Chain Mathematical Models Of A New Angular Displacement Converter With A Variable Active Area Of A Movable Core, Sultan Faizullayevich Аmirov, Ulugbek Shukhratovich Mamadaliyev, Islom Azim Ugli Karimov

Chemical Technology, Control and Management

The article develops mathematical models of the magnetic chain of new differential type angular displacement transformer converter with a variable active area of the movable core, in which the width of the movable ferromagnetic core is a function of the angular displacement of the converter. In this case, the magnetic chain of the converter, divided into three characteristic (before the mobile ferromagnetic core, ferromagnetic core and after the ferromagnetic core) sections, is considered as a magnetic chain with distributed parameters. It is established that when the magnetic resistance of the magnetic chain steel part is not taken into account, the …

Choice Of Instruments For Verification And Calibration Of Gas Analyzers, Ortigali Khakimov, Paraxat Mayliyevna Matyakubova, Mirolim Muhammad O'G'Li Maxmudjonov

Chemical Technology, Control and Management

This article analyzes the process of metrological control of gas analyzers and metrological requirements for them. The current state of the standards used in the state metrological control of gas analyzers and the results of the analyzes were studied. The task of choosing the measuring instruments used in the verification process and optimizing the requirements for them is set. An experimental verification process was organized in three groups using several measuring devices, and the reliability of the verification results was assessed. With the use of modern measuring instruments, a graph of the output value was built during the experimental verification …

Mathematical Description Of A Bleach Impregnation Reservoir, Bekobod Ibragimov

Chemical Technology, Control and Management

This article discusses the issues of constructing a mathematical model of the technological process of bleaching textile materials in an impregnating reservoir using the heat balance equation, on the basis of which a qualitative analysis of the dynamic properties of an object has been carried out in order to create highly efficient control systems with the use of energy-saving technologies. While constructing a mathematical model characterizing the established and non-established modes of the control object (impregnating reservoir) used changes in heat flow and mass velocity of the incoming tissue. An algorithm for constructing a mathematical model of the process of …

Mathematical Description And Algorithm For Solving The Model Of The Ionite Regeneration Process In The Ion Exchange Method Of Water Softening, Djalolitdin Paxritdinovich Mukhitdinov, Nilufar Abdusami Qizi Yunusova

Chemical Technology, Control and Management

Based on the modern representation of the water softening process by the ion exchange method, modeling was carried out, an algorithm was developed and the ionite regeneration process was calculated in a water softening plant with a fixed ionite layer. To solve the system of equations of the model, special, but simple enough for use in engineering calculations, techniques and methods have been developed and applied. The constructed model and its solution algorithm can be used to predict the process of ionite regeneration in an ion exchange apparatus. It can also be used to calculate the time of the ionite …

Synthesis Methods And Algorithms For Expanding The Dynamic Range Of The Adc, Jumaev Odil Abdujalilovich, Rashidov G'Olibjon Xayriddinovich

Chemical Technology, Control and Management

The modern development of new technologies, in particular, the intensive use of programmable logic integrated circuits in digital information processing tasks, allows for algorithmically and programmatically solving problems, opens up real opportunities to increase accuracy and ensure the required signal conversion speed, and also, it will be possible to take into account the effects of noise and their elimination over the entire time interval band. The article discusses the main methods of digital information processing, analyzes the ways and possibilities of expanding the dynamic range of analog-to-digital converters, as well as the synthesis of appropriate conversion devices, primarily digital filters.

Methods And Algorithms For Monitoring And Prediction Of Various Fire Hazardous Situations, Mizaakbar Xakkulmirzayevich Hudayberdiyev, Oybek Zokirovich Koraboshev

Chemical Technology, Control and Management

This article analyzes emergency situations arising from natural disasters (fires, explosions, earthquakes, floods, landslides, etc.) and man-made accidents. The event in which the values of fire risks in the area decrease uniformly and at the same time the amount of fire risks is minimal is considered optimal. Models, methods, and logistic regression algorithm have been used to predict fire hazard situations and identify potential fire safety measures.

Modeling And Adjustment Of A Fuzzy Controller In A Bioreactor Control System, Mahmudov Giyosjon Baqoyevich

Chemical Technology, Control and Management

The article describes the modeling and configuration of a fuzzy controller for the control system of the bacterial oxidation of hard-to-enrich gold-bearing sulfide ores. The simulated logical fuzzy controller allows you to save the consumption of refrigerant water consumed in the process by 4,3%, using it to control the process of bacterial oxidation.

Synergetic Synthesis Of Multivariate Nonlinear Dynamic Objects, Isamiddin Siddikov, Komil Usmanov

Chemical Technology, Control and Management

Based on the synergetic approach, the article solves the problem of analyzing a chemical reactor as a control object and formulates recommendations on the structural and topological synthesis of various control system options. The main feature of technological control objects, in which, as a result of hydromechanical, physical, chemical influences on the flows of the starting substances, their physical properties, state of aggregation and composition change, is their multidimensionality, nonlinearity, multiconnectedness, as well as parametric uncertainty of the mathematical model at the design stage. This type of facility includes a chemical reactor, thermal management, which in most cases is carried …

Investigating Myosin Ensemble Force Generation Using Optical Tweezers, Janie Watts

Honors Theses

Myosin is a motor protein that facilitates muscle contraction and movement by stepping along actin filaments using energy from ATP hydrolysis. If myosin or other motors are disrupted throughout the body, it can have many harmful effects. Hypertrophic cardiomyopathy is a disease caused by gene mutations that affect myosin heavy chains in the heart. The tissue of the heart becomes abnormally thick, which can make it more difficult to pump blood or block blood flow out of the heart. Our goal is to discern the mechanistic difference function of a healthy and diseased heart. To accomplish this, we construct model …

Pole Placement Of Linear Multidimensional Systems Using Unlimited Rank Output Feedback, Jasur Usmonovich Sevinov, Okila Khusanovna Boeva

Chemical Technology, Control and Management

The problem of placing poles in linear multidimensional systems using a feedback matrix of unlimited rank is considered. The effect of output feedback of indefinite rank of the characteristic polynomial of a system with several variables is studied. The results are then used to obtain a recurrent pole placement algorithm without any restrictions on the rank of the output feedback matrix used. The algorithm is based on the pseudo-inverse concept of obtaining solutions to systems of linear equations using the least squares method and is computationally efficient.

Poly(Ether Imide)S: Synthesis And Properties, Rachel Price

Honors College Theses

The synthesis of strong polymers is crucial to the creation of heat-resistant, durable, and mechanically useful plastics that we use every day. Poly(ether imide)s are used in applications such as food service, aerospace, automotive, and many more. This thesis will discuss the synthesis and properties of these plastics to help express a larger understanding of these polymers.

Lunar In-Situ Aluminum Production Through Molten Salt Electrolysis (Lisap-Mse), Jacob Ortega, Jeffrey D. Smith, Fateme Rezaei, David Bayless, William P. Schonberg, Daniel S. Stutts, Daoru Frank Han

NASA-Missouri Space Grant Consortium

The goal of Artemis is to establish a sustained presence on the Moon. To achieve so, numerous resources are necessary. The Moon contains several essential elements needed to sustain human presence. Most of those elements are trapped in the form of minerals. To refine those minerals into useful materials, reduction methods are needed. Most reduction methods on Earth require large amounts of mass and power which is unrealistic for early stages of building a lunar base. To solve this problem, we are developing a concept of Lunar In-Situ Aluminum Production through Molten Salt Electrolysis (LISAP-MSE).

The LISAP-MSE project, if successful, …

Semi-Differentiation Of Reversible, Soluble-Insoluble Potential Sweep Voltammograms, Tyler Williams, Ranon Fuller, Cameron Vann, Devin Rappleye

Faculty Publications

Semi-differentiation, or convolution as it is sometimes known, is a mathematical technique commonly used to disentangle overlapping peaks in cyclic or linear sweep voltammograms. However, this technique is often misapplied due to misunderstandings of fractional calculus. Additionally, rigorous treatment and validation of the theory of semi-differential analysis of reversible, soluble-insoluble electrochemical reactions is lacking. Peculiarities of semi-differentiation are explored; theoretical relations for semi-differentiated voltammograms are given; the exponential nature of the theoretical curve is explored; theoretical relations are compared to experimental voltammograms for AgNO₃ in 1 M nitric acid at 298 K, NiCl₂ in LiCl at 974 K, …

The Impact Of Solution Ionic Strength, Hardness, And Ph On The Sorption Efficiency Of Polychlorinated Biphenyls In Magnetic Nanocomposite Microparticle (Mnm) Gels, Angela M. Gutierrez, Thomas D. Dziubla, J. Zach Hilt

Chemical and Materials Engineering Faculty Publications

Environmental conditions of groundwater and surface water greatly vary as a function of location. Factors such as ionic strength, water hardness, and solution pH can change the physical and chemical properties of the nanocomposites used in remediation and the pollutants of interest. In this work, magnetic nanocomposite microparticle (MNM) gels are used as sorbents for remediation of PCB 126 as model organic contaminant. Three MNM systems are used: curcumin multiacrylate MNMs (CMA MNMs), quercetin multiacrylate MNMs (QMA MNMs), and polyethylene glycol-400-dimethacrylate MNMs (PEG MNMs). The effect of ionic strength, water hardness, and pH were studied on the sorption efficiency of …

Api Drying And Packaging Technology Upgrades, Destiny Washington

Honors Theses

Certain classes of active pharmaceutical ingredients (APIs) require higher levels of containment during handling. This project explores upgrades and new technology to improve currently used systems. The upgrades will include containment during drying and packaging while maintaining required ergonomic, industrial health, and GMP requirements. Design of this system and a full economic analysis have been performed for these upgrades.

This project details the profits and costs that are associated with the conversion of the API drying process from a batch process to a semi continuous process using an agitated thin film evaporator. The implementation of the new equipment is expected …

Conversion Of Biomass To Bio-Fuel Using Fast Pyrolysis With Companion Coal Gasification, Nicholas Hayes

Honors Theses

The objective for this design is to determine the economic benefits of using soybeans to combine biomass pyrolysis with coal pyrolysis processes to reduce the complexity and cost of producing bio-oils. Biomass is produced in multiple industries and is converted to a usable fuel substitute for petroleum. There will be many methods to analyse the pros and cons which will be used for comparison of biomass to bio-oils reactors system which in this case would be soybeans vs coal gasification.

After thorough research, the team selected a fluidized bed reactor as the main equipment for the fast pyrolysis. The reactor …

Air Pre-Heat System Optimization For Flash Dryers, Sophia Louden

Honors Theses

Primient, a leading producer of food and industrial ingredients made from plant-based, renewable sources is the industrial sponsor for this project. The company is currently using Plate & Frame Heat exchangers to heat up a 40% by-weight glycol and water solution that is then used to preheat the incoming ambient air. Glycol is being added to reduce the risks of freezing in the system during the winter season. It is important to highlight that this fact affects the heat transfer properties of the liquid overall. Since air heating is a highly energy-demanding process, an outlet stream of hot water produced …

Cobalt Oxide Functionalized Ceramic Membrane For 4-Hydroxybenzoic Acid Degradation Via Peroxymonosulfate Activation, Rajan Arjan Kalyan Hirani, Hong Wu, Abdul Hannan Asif, Nasir Rafique, Lei Shi, Shu Zhang, Zhentao Wu, Lai-Chang Zhang, Shaobin Wang, Yu Yin, Martin Saunders, Hongqi Sun

Research outputs 2022 to 2026

Membrane separation and sulfate radicals-based advanced oxidation processes (SR-AOPs) can be combined as an efficient technique for the elimination of organic pollutants. The immobilization of metal oxide catalysts on ceramic membranes can enrich the membrane separation technology with catalytic oxidation avoiding recovering suspended catalysts. Herein, nanostructured Co₃O₄ ceramic catalytic membranes with different Co loadings were fabricated via a simple ball-milling and calcination process. Uniform distribution of Co₃O₄ nanoparticles in the membrane provided sufficient active sites for catalytic oxidation of 4-hydroxybenzoic acid (HBA). Mechanistic studies were conducted to determine the reactive radicals and showed that …

Influence Of Henna Extracts On Static And Dynamic Adsorption Of Sodium Dodecyl Sulfate And Residual Oil Recovery From Quartz Sand, Mohd Syazwan Mohd Musa, Priveqa Yaashini Gopalan, Nurudeen Yekeen, Ahmed Al-Yaseri

Research outputs 2022 to 2026

The application of surfactant flooding for enhanced oil recovery (EOR) promotes hydrocarbon recovery through reduction of oil-water interfacial tension and alteration of oil-wet rock wettability into the water-wet state. Unfortunately, surfactant depletion in porous media, due to surfactant molecule adsorption and retention, adversely affects oil recovery, thus increasing the cost of the surfactant flooding process. Chemical-based materials are normally used as inhibitors or sacrificial agents to minimize surfactant adsorption, but they are quite expensive and not environmentally friendly. Plant-based materials (henna extracts) are far more sustainable because they are obtained from natural sources. However, there is limited research on the …

Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang

Chemistry Publications

No abstract provided.

Mitochondrial Complex Iii Bypass Complex I To Induce Ros In Gpr17 Signaling Activation In Gbm, Sana Kari, Jeyalakshmi Kandhavelu, Akshaya Murugesan, Ramesh Thiyagarajan, Srivatsan Kidambi, Meenakshisundaram Kandhavelu

Department of Chemical and Biomolecular Engineering: Faculty Publications

Guanine nucleotide binding protein (G protein) coupled receptor 17 (GPR17) plays crucial role in Glioblastoma multiforme (GBM) cell signaling and is primarily associated with reactive oxidative species (ROS) production and cell death. However, the underlying mechanisms by which GPR17 regulates ROS level and mitochondrial electron transport chain (ETC) complexes are still unknown. Here, we investigate the novel link between the GPR17 receptor and ETC complex I and III in regulating level of intracellular ROS (ROSi) in GBM using pharmacological inhibitors and gene expression profiling. Incubation of 1321N1 GBM cells with ETC I inhibitor and GPR17 agonist decreased the ROS level, …

Dynamic And Equilibrium Contribution Of Nematic Order In Wetting And Contact Angles, Partho Neogi, Xianjie Qiu, Amer Al-Shareef

Chemical and Biochemical Engineering Faculty Research & Creative Works

A Model for the Dynamic Contact Angles and the Spreading Kinetics of Nematic Liquid Crystals on a Solid Surface is Presented for the First Time using the Continuum Theory of Liquid Crystals. the Equations of Motion for This System Are Integrated for a Wedge or a Drop that is Thin and Moves Slowly. the Dynamic Contact Angle is Found to Depend on the Capillary Number that Represents the Importance of Viscocapillarity and on the Elasticity Number that is the Ratio between the Elastic and Surface Forces. the Model Provides an Explanation for the Extra Volume Dependence that is Reported in …

Design And Synthesis Of Plasmonic Nanoparticles For Nir Bioimaging: Investigating The Role Of Absorption And Scattering, Luis Dias Bumba Manuel

LSU Doctoral Dissertations

Nanoparticles have made vast advances in the realm of nanomedicine and bioimaging, enabling technologies such as photothermal therapy of malignant tumors and noninvasive monitoring of living tissue. Many of these innovations have only arisen in the last few decades with potential for growth in many avenues. The research shown in this work addresses some of the existing literature's void. Particularly solving synthesis challenges that have existed for more than 20 years in synthesizing Au nanoshells and establishing the potential for molecular-level deep imaging of plants. A novel investigation of the role of light absorption and scattering in bioimaging led to …

Beirut Arab University - Faculty Of Engineering - Newsletter Issue 0, Faculty Of Engineering, Beirut Arab University

Engineering Newsletters

No abstract provided.

Improving Wastewater-Based Epidemiology Performance Through Streamlined Automation, Mohammad Dehghan Banadaki, Soroosh Torabi, William Strike, Ann Noble, James W. Keck, Scott M. Berry

UK CARES Faculty Publications

Wastewater-based epidemiology (WBE) has enabled us to describe Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2) infections in populations. However, implementation of wastewater monitoring of SARS- CoV-2 is limited due to the need for expert staff, expensive equipment, and prolonged processing times. As WBE increases in scope (beyond SARS-CoV-2) and scale (beyond developed regions), there is a need to make WBE processes simpler, cheaper, and faster. We developed an automated workflow based on a simplified method termed exclusion-based sample preparation (ESP). Our automated workflow takes 40 min from raw wastewater to purified RNA, which is several times faster than conventional WBE …

On Hydrophobic Deep Eutectic Solvents: Thermo-Physical Properties And Applications In Gas Solubility, Shan Khai Liew

Masters Theses

Carbon dioxide (CO2) has been widely recognized as one of the greenhouse gases (GHGs) in the atmosphere. GHGs cause global warming, which will bring a lot of problems and irreversible changes. To curb CO2 emissions, much effort has been done. There are many technologies available for CO2 capture, such as amine scrubbing, pressure or temperature swing adsorption, membrane separation, and many solvents and absorbents that have been proposed for CO2 capture (e.g., zeolite, silica materials, graphene, activated carbon, etc.) at every stage (pre-combustion, post-combustion, oxy-combustion). However, these materials have their own drawbacks. Hydrophobic deep eutectic solvents (HDES) is a green …

Hydrogen Storage In Depleted Gas Reservoirs: A Comprehensive Review, Nasiru S. Muhammed, Md Bashirul Haq, Dhafer A. Al Shehri, Amir Al-Ahmed, Mohammad M. Rahman, Ehsan Zaman, Stefan Iglauer

Research outputs 2022 to 2026

Hydrogen future depends on large-scale storage, which can be provided by geological formations (such as caverns, aquifers, and depleted oil and gas reservoirs) to handle demand and supply changes, a typical hysteresis of most renewable energy sources. Amongst them, depleted natural gas reservoirs are the most cost-effective and secure solutions due to their wide geographic distribution, proven surface facilities, and less ambiguous site evaluation. They also require less cushion gas as the native residual gases serve as a buffer for pressure maintenance during storage. However, there is a lack of thorough understanding of this technology. This work aims to provide …

Advanced Materials For High Performance Lithium-Sulfur Batteries, Jian Yang

Dissertations

With the advantages of high capacity and low cost, lithium-sulfur batteries (LSBs) have been considered as one of the most promising candidates for next-generation batteries. However, the wide adoption of LSBs to the commercial markets is limited due to the fast capacity decay and low utilization of sulfur. To address these issues, advanced cathodes with high electronic conductivity and strong affinity to elemental sulfur and lithium polysulfides, which are intermediate products during the charge/discharge process, have been developed in this program. Carbon aerogels (RFCs) with controllable porous architectures have been fabricated through adjusting the process parameters and used as the …