Chemical Engineering Commons^™

Supported Metal Bifunctional And Bimetallic Catalysts With Precisely Controlled Structures And Properties, Anhua Dong

Theses and Dissertations

In heterogenous catalysis, metallic nanomaterials play vital roles in numerous chemical processes. However, monofunctional catalysts are greatly impeded in their applications especially in the systems including tandem and/or sequential reaction steps. Besides, the catalytic performance can also be greatly influenced by the particle size, morphology, and geometry of the surface metal atoms.

The goal of this work is to synthesize bifunctional or bimetallic nanoparticles with high metal dispersion and homogenous alloys by rational synthetic strategies to facilitate the catalyst function. Strong electrostatic adsorption (SEA) is an effective and facile methodology to produce well dispersed and uniform nanoparticles. Metal-acid bifunctional catalysts …

Development Of An Integrated Salt Cartridge-Reverse Electrodialysis (Red) Device To Increase Electrolyte Concentrations To Biomedical Devices, Efecan Pakkaner, Jessica L. Orton, Caroline G. Campbell, Jamie A. Hestekin, Christa N. Hestekin

Chemical Engineering Faculty Publications and Presentations

Emerging technologies in nanotechnology and biomedical engineering have led to an increase in the use of implantable biomedical devices. These devices are currently battery powered which often means they must be surgically replaced during a patient’s lifetime. Therefore, there is an important need for a power source that could provide continuous, stable power over a prolonged time. Reverse electrodialysis (RED) based biopower cells have been previously used to generate continuous power from physiologically relevant fluids; however, the low salinity gradient that exists within the body limited the performance of the biopower cell. In this study, a miniaturized RED biopower cell …

Prospective Life Cycle Assessment And Cost Analysis Of Novel Electrochemical Struvite Recovery In A U.S. Wastewater Treatment Plant, Karla G. Morrissey, Leah English, Greg Thoma, Jennie S. Popp Ph.D.

Chemical Engineering Faculty Publications and Presentations

Nutrient recovery in domestic wastewater treatment has increasingly become an important area of study as the supply of non-renewable phosphorus decreases. Recent bench-scale trials indicate that co-generation of struvite and hydrogen using electrochemical methods may offer an alternative to existing recovery options utilized by municipal wastewater treatment facilities. However, implementation has yet to be explored at plant-scale. In the development of novel nutrient recovery processes, both economic and environmental assessments are necessary to guide research and their design. The aim of this study was to conduct a prospective life cycle assessment and cost analysis of a new electrochemical struvite recovery …

Estimation Of The Bubble Point Pressure Of Multicomponent Reservoir Hydrocarbon Fluids, Benjamin Sunday Usen, Chidi Obi

Makara Journal of Science

This study developed a novel C-sharp (C#) programming language for the estimation of bubble point pressure (BPP) of various hydrocarbon mixtures at equilibrium state. The methodology was based on vapor–liquid equilibrium calculation using Peng Robinson equation of state implementation, thermodynamic equilibrium calculation and Newton-Raphson’s method for the successive substitution of the unknown variables. The equal fugacity constraint can be satisfied by obtaining the equilibrium which serves as a criterion for two or more phases to exist at equilibrium. The problem was resolved by searching for a pressure that will satisfy the two constraints. Complex calculation was performed by successively substituting …

Towards Environmentally Sustainable, High-Performance, Lightweight Composites For Automotive Applications, Jasmin Zamudio Vasquez

Theses and Dissertations

The increasing public demand in the world automotive industry to improve the environmental sustainability of their manufactured vehicles without sacrificing drivers' comfort and safety and the high cost of lightweight materials have driven researchers to reconsider materials used in the automotive application. Thus, this work aims toward the production of environmentally sustainable, high-performance, lightweight composites, utilizing recycled carbon fibers (RCFs) and pyrolyzed tire particles (PTPs) reclaimed from pyro-gasification of CFRP wastes and end-of-life tires (ELTs), respectively, as reinforcements for cardanol-based epoxy resins. The fabricated composites exhibited rubbery-like behavior at 25 °C. Spectroscopic, rheological, physical, thermal, thermomechanical, and mechanical characterizations were …

Preface To Special Issue On Water Electrolysis For Hydrogen Production, Li Li, Jin-Song Hu, Zi-Dong Wei

Journal of Electrochemistry

No abstract provided.

Perovskite-Type Water Oxidation Electrocatalysts, Xiao Liang, Ke-Xin Zhang, Yu-Cheng Shen, Ke Sun, Lei Shi, Hui Chen, Ke-Yan Zheng, Xiao-Xin Zou

Journal of Electrochemistry

The development of energy conversion/storage technologies can achieve the reliable and stable renewable energy supply, and bring us a sustainable future. As the core half-reaction of many energy-related systems, water oxidation is the bottleneck due to its sluggish kinetics of the four-concerted proton-electron transfer (CPET) process. This necessitates the exploitation of low cost, highly active and stable water oxidation electrocatalysts. Perovskite-type oxides possess diverse crystal structures, flexible compositions and unique electronic properties, enabling them ideal material platform for the optimization of catalytic performance. In this review, we provide a comprehensive summary for the crystal structures, electronic structures and synthetic methods …

Recent Development Of Low Iridium Electrocatalysts Toward Efficient Water Oxidation, Jing Ni, Zhao-Ping Shi, Xian Wang, Yi-Bo Wang, Hong-Xiang Wu, Chang-Peng Liu, Jun-Jie Ge, Wei Xing

Journal of Electrochemistry

Developing high-performance and low-cost electrocatalysts for oxygen evolution reaction (OER) is the key to implementing polymer electrolyte membrane water electrolyzer (PEMWE) for hydrogen production. To date, iridium (Ir) is the state-of-the-art OER catalyst, but still suffers from the insufficient activity and scarce earth abundance, which results in high cost both in stack and electricity. Design low-Ir catalysts with enhanced activity and stability that can match the requirements of high current and long-term operation in PEMWE is thus highly desired, which necessitate a deep understanding of acidic OER mechanisms, unique insights of material design strategies, and reliable performance evaluation norm, especially …

The Rapid Preparation Of Efficient Mofeco-Based Bifunctional Electrocatalysts Via Joule Heating For Overall Water Splitting, Ao Zhou, Wei-Jian Guo, Yue-Qing Wang, Jin-Tao Zhang

Journal of Electrochemistry

Water electrolysis is an available way to obtain green hydrogen. The development of highly efficient electrocatalysts is a current research hotspot for water splitting, but it remains challenging. Herein, we demonstrate the synthesis of a robust bifunctional multi-metal electrocatalysts toward water splitting via the rapid Joule-heating conversion of metal precursors. The composition and morphology were well regulated via altering the ratio of metal precursors. In particular, the trimetal MoC/FeO/CoO/carbon cloth (CC) electrode revealed the outstanding bifunctional electrocatalytic performance due to the unique composition and large electrochemical active surface area. Typically, the MoC/FeO/CoO/CC catalyst needed low overpotentials of 121 and 268 …

A Co Porphyrin With Electron-Withdrawing And Hydrophilic Substituents For Improved Electrocatalytic Oxygen Reduction, Hong-Bo Guo, Ya-Ni Wang, Kai Guo, Hai-Tao Lei, Zuo-Zhong Liang, Xue-Peng Zhang, Rui Cao

Journal of Electrochemistry

Understanding factors that influence the catalyst activity for oxygen reduction reaction (ORR) is essential for the rational design of efficient ORR catalysts. Regulating catalyst electronic structure is commonly used to fine-tune electrocatalytic ORR activity. However, modifying the hydrophilicity of catalysts has been rarely reported to improve ORR, which happens at the liquid/gas/solid interface. Herein, we report on two Co porphyrins, namely, NO₂-CoP (Co complex of 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin) and 5F-CoP (Co complex of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin), and their electrocatalytic ORR features. By simultaneously controlling the electronic structure and hydrophilic property of the meso-substituents, the NO₂-CoP showed higher electrocatalytic activity than …

Surface Structure Engineering Of Feni-Based Pre-Catalyst For Oxygen Evolution Reaction: A Mini Review, Jia-Xin Li, Li-Gang Feng

Journal of Electrochemistry

Nitrite, a widespread raw material, is harmful to human health for long-term consumption. At present, the detection methods of nitrite mainly include chemical analysis, fluorescence, ultraviolet spectrophotometry and chromatography. These methods have ideal sensitivity and selectivity, but also have some characteristics: cumbersome operation, expensive equipment and professional personnel. Therefore, the development of a simple and sensitive nitrite assay is of great significance. In this paper, the Au/rGO/FeOOH composite materials, which revealed good synergistic catalytic performance among the three elements in the composite, were prepared by simple hydrothermal method and reduction method for the first time with large specific surface area …

Accurate Predictions Of Thermoset Resin Glass Transition Temperatures From All-Atom Molecular Dynamics Simulation, Gregory Odegard, Sagar Patil, Prashik Gaikwad, Prathamesh Deshpande, Aaron Krieg, Sagar P. Shah, Aspen Reyes, Tarik Dickens, Julia A. King, Marianna Maiaru

Michigan Tech Publications, Part 1

To enable the design and development of the next generation of high-performance composite materials, there is a need to establish improved computational simulation protocols for accurate and efficient prediction of physical, mechanical, and thermal properties of thermoset resins. This is especially true for the prediction of glass transition temperature (Tg), as there are many discrepancies in the literature regarding simulation protocols and the use of cooling rate correction factors for predicting values using molecular dynamics (MD) simulation. The objectives of this study are to demonstrate accurate prediction the Tg with MD without the use of cooling rate correction factors and …

A Control Barrier Function Perspective On Lyapunov-Based Economic Model Predictive Control, Helen Durand, Aaron D. Ames

Chemical Engineering and Materials Science Faculty Research Publications

No abstract provided.

Design Of Solvent-Assisted Plastics Recycling: Integrated Economics And Environmental Impacts Analysis, Austin L. Lehr, Kayla L. Heider, Emmanuel A. Aboagye, John D. Chea, Jake P. Stengel, Pahola T. Benavides, Kirti Maheshkumar Yenkie

Henry M. Rowan College of Engineering Departmental Research

In 2018, the United States generated over 35. 7 million tons of plastic waste, with only 8.4% being recycled and the other 91.6% incinerated or disposed of in a landfill. The continued growth of the polymer market has raised concerns over the end of life of plastics. Currently, the waste management system is faced with issues of inefficient sorting methods and low-efficiency recycling methods when it comes to plastics recycling. Mechanical recycling is the commonest recycling method but presents a lower-valued recycled material due to the material incompatibilities introduced via the inefficient sorting methods. Chemical recycling offers a promising alternative …

Design Of Solvent-Assisted Plastics Recycling: Integrated Economics And Environmental Impacts Analysis, Austin L. Lehr, Kayla L. Heider, Emmanuel A. Aboagye, John D. Chea, Jake P. Stengel, Pahola Thathiana Benavides, Kirti M. Yenkie

Henry M. Rowan College of Engineering Departmental Research

In 2018, the United States generated over 35. 7 million tons of plastic waste, with only 8.4% being recycled and the other 91.6% incinerated or disposed of in a landfill. The continued growth of the polymer market has raised concerns over the end of life of plastics. Currently, the waste management system is faced with issues of inefficient sorting methods and low-efficiency recycling methods when it comes to plastics recycling. Mechanical recycling is the commonest recycling method but presents a lower-valued recycled material due to the material incompatibilities introduced via the inefficient sorting methods. Chemical recycling offers a promising alternative …

A Cfd-Based Scaling Analysis On Liquid And Paint Droplets Moving Through A Weak Concurrent Airflow Stream, Masoud Arabghahestani, Nelson Akafuah, Tianxiang Li, Kozo Saito

Progress in Scale Modeling, an International Journal

We conducted volume of fluids (VOF) multiphase model numerical simulations to obtain the interaction among all the major governing forces identified in our previous paper. Our numerical experiments are intended to assess the droplet generation process and the jetting behavior by providing specific input conditions, offering CFD as a tool to study scaling correlations instead of physical experiments. Water droplets that can represent waterborne paints were generated by piezo-generated sinusoidal waveforms at the inlet of the nozzle. The governing forces included the external piezo-based wave-generation force, the inertial force of droplets, the inertial force of air, the viscose force of …

Effect Of Degradation Of Methylene Blue Dye (Mb) By Using Erbium Oxide (Er2o3) Nps, Hind Ahmed Jasim, Farah Farman Abbass, Sarah A. Hamood, Hind Mohammed Hassan, Mohammed Sellab Hamza

Al-Esraa University College Journal for Engineering Sciences

In an experiment investigating the photo catalytic degradation of methylene blue using varied concentrations of Er2O3 nanoparticles, different conditions were tested including with and without sunshine, as well as in the absence of a UV source. The presence of a UV source was also considered in the research. UV-Visible spectroscopy was utilized to characterize the catalysts. The degradation of methylene blue dye was monitored by spectrophotometry by tracking dye absorbance at regular time intervals and adjusting the dye concentration. The results indicated that the most effective degradation of methylene blue dye occurred during a 5-hour irradiation time and in the …

Architecture Between Development And Ability Programs, Allaa Ahmed Rasheed, Ibrahim Jawad Kadhim

Al-Esraa University College Journal for Engineering Sciences

The development of architecture and its pursuit of perfection can only be achieved through society to reach a specific result when meeting new desires that arise as a result of human development, expanding individual and societal needs, and deepening their relationships in multifaceted ways. The research focuses on development as it requires a clear cumulative vision of the integrative relationship between practice and participation in interpreting the act (effect) from the force (influence). It emphasizes that the power of capabilities is understood through learning and education in describing the capabilities of architecture. This involves adopting new ideas and intellectual premises …

The Designing Of Contemporary Teaching- Learning Spaces According To Interactive Flow Action Local School Spaces-A Case Study, Aseel Jasem Al-Ataby, Anwar Subhi Ramadan Al-Qaraghuli

Al-Esraa University College Journal for Engineering Sciences

The world today faces many challenges related to environmental issues, as well as other social and economic challenges, and in light of intellectual, cognitive, and technical transformations, which led to the emergence of many new phenomena and concepts that correspond to them, including the concept of flow. This concept has been associated with many aspects of life, including architecture, whose importance has emerged recently in light of the challenge of the spread of the Corona virus and its effects on architecture with its residential, educational, and other spaces. This research focuses on the flow in the architectural space in general, …

A New Compact Triple-Band Micro-Strip Monopole Antenna Based On Minkowski Fractal Geometry, Hayder S. Ahmed, Zahra' Salah Ahmed, Sarah A. Hamood, Mohammed Sellab Hamza, Taha A. Elwi

Al-Esraa University College Journal for Engineering Sciences

Wireless communication systems have made significant advancements in size reduction, with antenna terminals remaining a primary challenge for system compatibility. As a result, much of industrial research is focused on antenna miniaturization in wireless systems. In this work, a novel compact Triple-Band Fractal (TBF) antenna is proposed, utilizing three coupling fractal patches with varying iteration levels of Minkowski geometry to provide three resonant bands. The antenna design is implemented using an antenna substrate with a dielectric constant of 10.8 and a thickness of 1.27 mm within the CST Microwave Studio environment. The zero iteration patch resonator is responsible for the …

The Role Of Community Participation In The Architectural Production, Allaa Ahmed Rasheed, Ibrahim Jawad Kadhim

Al-Esraa University College Journal for Engineering Sciences

The role of community participation as a power in building architectural output at the level of the act of thinking in architecture and the design process in non-existence is related to power and presence with act. The research is concerned with expanding knowledge in the direction of the holistic language and searching for the role that builds the privacy of the architectural product versus the community's societal identity. It studies the concept of act within the limits of existence at the level of community participation since the act of architecture is the act of man to meet certain needs and …

The Communicative Deviation In Contemporary Architectural Production, Haneen Hosham Abd-Alrahman, Panrizat Q. Hussein Fehmi

Al-Esraa University College Journal for Engineering Sciences

Deviation is one of the most important concepts discussed in various architectural and non-architectural theses when addressing the topic of creative production. It involves breaking away from the familiar and surpassing established architectural rules to create unique and excellent products that are characterized by their creativity and aesthetic appeal. Recognizing the significance of this concept in shaping contemporary architectural production, the research endeavors to explore the concept of connective displacement in architecture and delve into its essential aspects. The research identifies the research problem as the "cognitive deficiency surrounding connective displacement in the semantic structures embedded in architecture." The objective …

Developed Rc4 Algorithm With Double Reverse For Better Data Protect, Fouad Sahib Muhamed Alkhazraji

Al-Esraa University College Journal for Engineering Sciences

Computer security plays a crucial role in protecting users' data, and cryptographic techniques are commonly used for this purpose. Encryption is a method employed to ensure data confidentiality, whether it is stored on hard drives or transferred through various media. RC4 (Rivest Cipher 4) is a cryptographic algorithm that utilizes the same key for both encryption and decryption processes. It falls under the category of stream ciphers, which are widely utilized in numerous protocols due to their flexibility and speed. RC4 employs XOR (exclusive OR) function to implement its encryption and decryption steps. In this paper, a technique known as …

Laboratory Evaluation Of A Novel Self-Healable Polymer Gel For Co2 Leakage Remediation During Co2 Storage And Co2 Flooding, Tao Song, Zhanmiao Zhai, Junchen Liu, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Ze Wang, Thomas P. Schuman, Baojun Bai

Chemistry Faculty Research & Creative Works

For CO₂ storage in subsurface reservoirs, one of the most crucial requirements is the ability to remediate the leakage caused by the natural fractures or newly generated fractures due to the increasing pore pressure associated with CO₂ injection. For CO₂ Enhanced Oil Recovery (EOR), high conductivity features such as fractures and void space conduits can severely restrict the CO₂ sweep efficiency. Polymer gels have been developed to plug the leakage and improve the sweep efficiency. This work evaluated a CO₂ resistant branched self-healable preformed particle gel (CO₂-BRPPG) for CO₂ plugging purpose. This …

Long-Time Kinetic Impact On Key Factors Affecting Asphaltene Precipitation, Ato Kwamena Quainoo, Abdulmohsin Imqam

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The employment of predictive techniques combining kinetic and thermodynamic analyses is the succinct solution to effectively control asphaltene precipitation during crude oil production. Although thermodynamic processes and conditions have been well studied in the literature, the effect of long-time kinetics on the key factors affecting the precipitation of asphaltenes was not critically studied. This work employed a model oil for asphaltene precipitation long-time kinetic observations. Filtration and confocal microscopy experimentations for time periods of 0-7200 min were utilized to study asphaltene yields and sizes at room and high temperatures (25, 50, and 70 °C), rotation speeds (60 and 150 rpm), …

A Comprehensive Review Of Experimental Evaluation Methods And Results Of Polymer Micro/Nanogels For Enhanced Oil Recovery And Reduced Water Production, Junchen Liu, Abdulaziz Almakimi, Mingzhen Wei, Baojun Bai, Ibnelwaleed Ali Hussein

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In recent years, polymer micro/nanogels which are re-crosslinked polymers with 3D networks, have attracted a lot of interest in Enhanced Oil Recovery (EOR) field. In size of micro/nanometers, these gel particles are designed to be conformance control agents for in-depth fluid diversion, and various experimental research have been undertaken to investigate the possibilities of applying micro/nanogels in oilfield. However, it is still unclear that how to utilize micro/nanogels to their full potential in oilfield because the transport mechanisms and EOR mechanisms of micro/nanogels are not well studied currently. By reviewing experimental evaluations and corresponding results of micro/nanogels, including evaluation of …

Reduced Building Energy Consumption By Combined Indoor Co2 And H2o Composition Control, Anshuman Sinha, Harshul Thakkar, Fateme Rezaei, Yoshiaki Kawajiri, Matthew J. Realff

Chemical and Biochemical Engineering Faculty Research & Creative Works

Rapid growth in global energy consumption has raised concern on the environmental impacts such as ozone layer depletion and climate change. Enclosed space, such as commercial buildings, accounts for about 40% of global energy consumption and the demand is constantly increasing due to increasing population, urbanization, and economic development. The energy demands in the building sector calls for strategic measures to develop energy efficient technologies. This paper presents a strategy to decrease energy demands inside buildings by proposing a ventilation system which regulates the enclosed air quality resulting in reduced air conditioning. The system consists of multiple adsorption beds with …

Atomic Layer Deposited Pt/Tio2-Sio2 And Pt/Zro2-Sio2 For Sequential Adsorption And Oxidation Of Vocs, Busuyi O. Adebayo, Han Yu, Ali A. Rownaghi, Xinhua Liang, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this work, Pt nanoparticles were loaded on SiO₂, TiO₂-thin-film-modified SiO₂ (TiO₂-SiO₂), or ZrO₂-thin-film-modified SiO₂ (ZrO₂-SiO₂) particles and the composites were investigated for sequential adsorption and desorption/catalytic oxidation of benzene. The SiO₂ was prepared via sol–gel method, while TiO₂-SiO₂ and ZrO₂-SiO₂ were synthesized via atomic layer deposition (ALD) thin film coating of TiO₂ or ZrO₂ on SiO₂ particles substrate. In the sequential capture-reaction tests, the materials were first exposed to ca. 500 ppmv benzene …

Mesures À Haute Sensibilité Du Passage De Contaminants Nanométriques À Travers Les Gants De Protection Par Imagerie Médicale, Mahmoud Mohamed Omar, Amélie Augé, Myriam Laprise-Pelletier, Ludovic Tuduri, Marc-André Fortin

Rapports de recherche scientifique

Les gants de polymère sont utilisés comme équipements de protection individuels dans de nombreux secteurs d’activité professionnelle où les risques chimiques sont présents. Leur efficacité à bloquer le passage de certains contaminants doit être mesurée par des méthodes d’essais précises et standardisées. Les mesures de résistance chimique sont généralement effectuées en utilisant une cellule de perméation, un petit appareil contenant deux réservoirs séparés par la membrane dont on veut mesurer le potentiel-barrière : l’un contient le contaminant, l’autre contient un milieu collectant le contaminant après que celui-ci ait passé à travers la membrane. Au fur et à mesure de l’expérience, …

Mathematical Model For Sei Growth Under Open-Circuit Conditions, Shiv Krishna Madi Reddy, Wei Shang, Ralph E. White

Faculty Publications

A solid electrolyte interphase (SEI) growth model is developed in a mixed mode that contains solvent diffusion through the SEI layer and corresponding solvent reduction kinetics at the SEI/electrode interface. The governing equations are solved by the Landau transformation, which makes the moving layer fixed to predict the open circuit potential, SEI layer thickness, and capacity loss. The estimated parameters fitted with experimental data from the literature are computed using COMSOL and MATLAB. Results show that the mixed mode model predicts lower capacity loss and thinner SEI layer due to its growth under open circuit conditions than previously reported by …