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2018

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Articles 121 - 150 of 703

Full-Text Articles in Chemical Engineering

Electrochemical Hydrogenation Of Acetone To Produce Isopropanol Using A Polymer Electrolyte Membrane Reactor, Chen Li, Ashanti M. Sallee, Xiaoyu Zhang, Sandeep Kumar Oct 2018

Electrochemical Hydrogenation Of Acetone To Produce Isopropanol Using A Polymer Electrolyte Membrane Reactor, Chen Li, Ashanti M. Sallee, Xiaoyu Zhang, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

Electrochemical hydrogenation (ECH) of acetone is a relatively new method to produce isopropanol. It provides an alternative way of upgrading bio-fuels with less energy consumption and chemical waste as compared to conventional methods. In this paper, Polymer Electrolyte Membrane Fuel Cell (PEMFC) hardware was used as an electrochemical reactor to hydrogenate acetone to produce isopropanol and diisopropyl ether as a byproduct. High current efficiency (59.7%) and selectivity (>90%) were achieved, while ECH was carried out in mild conditions (65 degrees C and atmospheric pressure). Various operating parameters were evaluated to determine their effects on the yield of acetone and …

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Development Of A Simple Lab-Scale Vacuum Assisted Resin Transfer Molding (Vartm) Process, Donald A. Klosterman Oct 2018

Development Of A Simple Lab-Scale Vacuum Assisted Resin Transfer Molding (Vartm) Process, Donald A. Klosterman

Chemical and Materials Engineering Faculty Publications

The goal of the current study was to develop and demonstrate a simple and quick lab-scale VARTM process for the purpose of making flat panels for subsequent characterization, for example in new materials development efforts. This process was not intended to be optimized for final production, rather it served as the quickest way to make lab-scale composite panels using VARTM while maintaining all the salient features of typical VARTM processes used in larger scale manufacturing. There is a wide variety of ways to implement VARTM, as well as a diverse list of potential materials and supplies from which to choose. …

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Nanoflower-Like Bi2moo6/Ag3po4 In Water Treatment, Xavier Morgan-Lange, Jaeyun Moon, Kaleab Ayalew Sep 2018

Nanoflower-Like Bi2moo6/Ag3po4 In Water Treatment, Xavier Morgan-Lange, Jaeyun Moon, Kaleab Ayalew

McNair Poster Presentations

• Environmental issues continue to intensify causing natural resources such as clean water to become increasingly scarce while demand only continues to grow. • Some of the most effective measures taken appear to be bioremediation tactics and their synthetic counterparts. • A critical area of interest are semi-conducting photocatalytic nanomaterials that take advantage of the photo-electric effect and use the introduction of ultra violet (UV) and visible light to induce oxidation and reduction reaction in p-type semiconductors. This results in the decomposition of certain pollutants and/or deactivates certain microbes in water. • These materials have the potential to operate using …

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The Flow Reactor Technology As A Modern Synthetic Tool For Preparation Of Pd/Fe3o4 Nanoparticles As A High Efficient Magnetic Catalyst For Co Oxidation, Hany A. Elazab Sep 2018

The Flow Reactor Technology As A Modern Synthetic Tool For Preparation Of Pd/Fe3o4 Nanoparticles As A High Efficient Magnetic Catalyst For Co Oxidation, Hany A. Elazab

Chemical Engineering

No abstract provided.

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Cysteine As An Eco-Friendly Corrosion Inhibitor, Hany A. Elazab Dr Sep 2018

Cysteine As An Eco-Friendly Corrosion Inhibitor, Hany A. Elazab Dr

Chemical Engineering

In this paper, the aim was finding the most efficient corrosion inhibitor for mild steel placed in a 0.5M Sulfuric acid. The comparison was implemented between Cysteine (an eco-friendly corrosion inhibitor) and 4 different Ions-Cysteine Inhibitors (Copper- Cysteine, Nickel-Cysteine, Iron-Cysteine, and Cobalt-Cysteine). The solutions were prepared and evaluated while placed with a working electrode of mild steel with a copper rod attached to its end. To determine the best eco-friendly corrosion inhibitors two experiments were implemented: Electrochemical Impedance Spectra, and Linear Polarization. By the end of the experiment it was found that Copper- Cysteine was the most efficient eco-friendly corrosion …

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A Nonlinear Systems Framework For Cyberattack Prevention For Chemical Process Control Systems, Helen Durand Sep 2018

A Nonlinear Systems Framework For Cyberattack Prevention For Chemical Process Control Systems, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Recent cyberattacks against industrial control systems highlight the criticality of preventing future attacks from disrupting plants economically or, more critically, from impacting plant safety. This work develops a nonlinear systems framework for understanding cyberattack-resilience of process and control designs and indicates through an analysis of three control designs how control laws can be inspected for this property. A chemical process example illustrates that control approaches intended for cyberattack prevention which seem intuitive are not cyberattack-resilient unless they meet the requirements of a nonlinear systems description of this property.

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Suitability Of Active And Intelligent Packaging For Local And Organic Food – A Case Study In Southern Finland, Sara Paunonen, Marja Pitkänen, Mika Vähä-Nissi, Ville Leminen, Mika Kainusalmi Sep 2018

Suitability Of Active And Intelligent Packaging For Local And Organic Food – A Case Study In Southern Finland, Sara Paunonen, Marja Pitkänen, Mika Vähä-Nissi, Ville Leminen, Mika Kainusalmi

Journal of Applied Packaging Research

This study explores the suitability of innovative packaging for local and organic food. Attitudes and opinions in local and organic food chains in Southern Finland were collected via eighteen semi-structural interviews. The respondents were small-scale producers and processors of fish, meat, berries, and mushrooms, wholesalers, retailers, and institutional kitchens. The aim of this study was to understand factors promoting and preventing the penetration of innovative packaging solutions into the organic and local food market. A clear majority (89%) of respondents considered active and intelligent solutions to be equally suitable for local and organic food as for conventional food. However, less …

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Measuring Up: Engineering Stronger And Faster Cardiomyocytes, Kaitlyn Mcentire, Dr. Alonzo Cook Sep 2018

Measuring Up: Engineering Stronger And Faster Cardiomyocytes, Kaitlyn Mcentire, Dr. Alonzo Cook

Journal of Undergraduate Research

If a heartbeat connotes life, then cardiomyocytes are the life givers. When heart disease results in cardiomyocyte death, however, these life-giving, beating cells are unable to reproduce, and portions of the heart irreversibly die. Despite modern technology and developments in heart disease treatment and prevention, heart disease remains the number one cause of death in America. With an inability to meet an ever-increasing demand for heart transplants, any potential alternative must be pursued.

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Differentiation Of Kidney Progenitors Using Induced Pluripotent Stem Cells And Conditioned Media Of Renal Cortical Tubular Epithelial Cells, Steven Passey, Dr. Alonzo Cook Sep 2018

Differentiation Of Kidney Progenitors Using Induced Pluripotent Stem Cells And Conditioned Media Of Renal Cortical Tubular Epithelial Cells, Steven Passey, Dr. Alonzo Cook

Journal of Undergraduate Research

According to the National Kidney Foundation, 26 million American adults have kidney disease, 47,000 Americans died from kidney disease in 2013, and over 100,000 people await kidney transplants. Current treatment of kidney failure includes dialysis and kidney transplant. Unfortunately, those undergoing dialysis may experience fatigue and other complications. In addition, there is a vast shortage of available kidneys for transplant.

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Equilibration Of Chloride Ions In Concrete Bridge Decks After Rehabilitation Using Hydro-Demolition And Concrete Overlay, Elizabeth Newbill, Dr. Spencer Guthrie Sep 2018

Equilibration Of Chloride Ions In Concrete Bridge Decks After Rehabilitation Using Hydro-Demolition And Concrete Overlay, Elizabeth Newbill, Dr. Spencer Guthrie

Journal of Undergraduate Research

In cold regions like northern Utah, harsh winters can lead to decreases in the service life of concrete bridge decks. Chloride-based deicing salts, which are commonly used to remove snow and ice from the surface of concrete bridge decks during winter months, are of particular concern. Even in uncracked concrete, chloride ions can diffuse into the bridge deck and eventually lead to corrosion of the embedded reinforcing steel. When chlorides corrode the steel, expansive rust forms, which causes cracks to form in the deck. These cracks allow for greater chloride ingress, accelerating the corrosion and deterioration processes within the bridge …

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Hips Turbulent Flow Modeling For High Schmidt Number Flow A Novel Approach To An Old Problem, Joshua Frei, Dr. David Lignell Sep 2018

Hips Turbulent Flow Modeling For High Schmidt Number Flow A Novel Approach To An Old Problem, Joshua Frei, Dr. David Lignell

Journal of Undergraduate Research

The whorls and vortices of smoke plumes, churning waterfalls, and crashing waves have a captivating sense of mystery about them. This chaotic, seemingly random fluid motion is known as turbulent flow, and it is ubiquitous both in day-to-day life and in engineering problems. Despite the many advances in technology, much of turbulence remains a mystery. It has been called the most important unsolved problem in physics [1].

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Hierarchal Parcel Swapping (Hips) A Comprehensive Multiscale Subgrid Model For Turbulent Reacting Flow, Justin Ward, Dr. David Lignell Sep 2018

Hierarchal Parcel Swapping (Hips) A Comprehensive Multiscale Subgrid Model For Turbulent Reacting Flow, Justin Ward, Dr. David Lignell

Journal of Undergraduate Research

The purpose of this project is to address the unmet need for a comprehensive, multiscale, regime- and fuel-independent turbulent reacting model by using a novel, physics-based strategy called Hierarchal Parcel Swapping (HiPS). Turbulent flow has been called the most important unsolved problem of classical physics. Modeling turbulent flow is extremely important due to the fact that nearly all flows in the real world are turbulent. Though the exact details of turbulent flow are not of great importance to an engineer, the effect turbulence has on chemical reactions and the overall chemical properties is vital. The solution to the turbulence problem …

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Hand-Powered Washing Machine For The Developing World, Chris Bailey, Sean Larson, Megan Peffer, Sarah Ann Skousen, Judith Westwood, Dr. Randy Lewis Sep 2018

Hand-Powered Washing Machine For The Developing World, Chris Bailey, Sean Larson, Megan Peffer, Sarah Ann Skousen, Judith Westwood, Dr. Randy Lewis

Journal of Undergraduate Research

Many countries still hand wash all their clothing. The community of the Uros Islands in Peru is no exception. Our goal was to develop a hand powered washing machine that will be useful to and improve the quality of life of the Uru people. The washing machine must be built out of materials that are inexpensive and readily available to the community. It must also be simple enough for the people to perform any necessary repairs. Furthermore, the final washing machine system could be implemented any developing area with similar needs.

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Engineering Metal-Ligand Interface For Selective Electrochemical Carbon Dioxide Reduction, Yuxin Fang Sep 2018

Engineering Metal-Ligand Interface For Selective Electrochemical Carbon Dioxide Reduction, Yuxin Fang

LSU Doctoral Dissertations

Unsustainable exploitation of fossil fuel and its massive greenhouse gas emission necessitates the development in alternative energy sources. Chemical fuels (CH3OH or C2H5OH) outperform other choices, such as batteries for their high energy densities, which is key to portability. Electrochemical reduction of CO2is capable of producing a wide range of valuable fuels (Syngas, formic acid, methane and methanol, etc.). Converting CO2into carbon-based fuels further closes the carbon neutral cycle, which contributes to the effort in reducing global CO2emission. Integration of organic ligands with transition metals shows great potential …

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Rapid Biosensor Screening Blood And Urine, Rebecca Whitney Bills, Dr. Bradley Bundy Sep 2018

Rapid Biosensor Screening Blood And Urine, Rebecca Whitney Bills, Dr. Bradley Bundy

Journal of Undergraduate Research

Endocrine Disrupting Chemicals (EDCs) have led to worldwide health problems, including cancers, developmental disorders, and reproductive disorders. A recent study estimates that annual health and economic costs caused by EDCs in the European Union is $200 Billion and that the costs are even greater in the US (1). This is largely due to the extensive number of undetected Endocrine Disrupting Chemicals (EDCs) that we come into contact with on a daily basis. EDCs have been found in dietary, environmental, and household chemicals. Despite this only a handful of EDCs have been characterized. The purpose of this project is to optimize …

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Investigating The Agricultural Applications Of Acryl Amide Based Hydrogel, Hany A. Elazab Dr Sep 2018

Investigating The Agricultural Applications Of Acryl Amide Based Hydrogel, Hany A. Elazab Dr

Chemical Engineering

Hydrogel is classified as one of the most effective materials due to its widely used applications either in tissue or agriculture engineering. This scientific research aims to investigate the potential applications of hydrogels in the field of desert agriculture in dry places. In this research hydrogel was prepared under several conditions in order to evaluate and optimize the conditions. The research included optimiz-ing several factors including cross-linking agent, water temperatures and pH. The potential agricultural applications of hydrogel were also investigated.

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Self-Cleaning Nanocomposite Membranes With Phosphorene-Based Pore Fillers For Water Treatment, Joyner Eke, Katherine Elder, Isabel Escobar Sep 2018

Self-Cleaning Nanocomposite Membranes With Phosphorene-Based Pore Fillers For Water Treatment, Joyner Eke, Katherine Elder, Isabel Escobar

Chemical and Materials Engineering Faculty Publications

Phosphorene is a two-dimensional material exfoliated from bulk phosphorus and it possesses a band gap. Specifically, relevant to the field of membrane science, the band gap of phosphorene provides it with potential photocatalytic properties, which could be explored in making reactive membranes that can self-clean. The goal of this study was to develop an innovative and robust membrane that is able to control and reverse fouling with minimal changes in membrane performance. To this end, for the first time, membranes have been embedded with phosphorene. Membrane modification was verified by the presence of phosphorus on membranes, along with changes in …

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Creation Of Non-Electric Cooling System For Food Preservation In Peru, Eleanor Ott, Dr. Randy Lewis Sep 2018

Creation Of Non-Electric Cooling System For Food Preservation In Peru, Eleanor Ott, Dr. Randy Lewis

Journal of Undergraduate Research

Food preservation is an issue in third-world countries around the world where electricity and monetary means are not present to maintain a modern refrigerator. The short shelf life of unrefrigerated food items creates waste, requires time and energy with frequent trips to buy food, and lowers quality of life. Multiple solutions for this problem have been devised which are principally applicable in Asia and Africa. Implementation of these solutions has increased shelf-life of perishable foods and eliminated the need for daily trips to the market for food. A natural consequence has been increased profits, more educational opportunities for women, and …

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Statistically Guided Synthesis Of Mov- Based Mixed Oxide Catalysts For Ethane Partial Oxidation, Juan D. Jimenez, Kathleen Mingle, Teeraya Bureerug, Cun Wen, Jochen Lauterbach Sep 2018

Statistically Guided Synthesis Of Mov- Based Mixed Oxide Catalysts For Ethane Partial Oxidation, Juan D. Jimenez, Kathleen Mingle, Teeraya Bureerug, Cun Wen, Jochen Lauterbach

Faculty Publications

The catalytic performance of Mo8V2Nb1-based mixed-oxide catalysts for ethane partial oxidation is highly sensitive to the doping of elements with redox and acid functionality. Specifically, control over product distributions to ethylene and acetic acid can be afforded via the specific pairing of redox elements (Pd, Ni, Ti) and acid elements (K, Cs, Te) and the levels at which these elements are doped. The redox element, acid element, redox/acid ratio, and dopant/host ratio were investigated using a three-level, four-factor factorial screening design to establish relationships between catalyst composition, structure, and product distribution for ethane partial oxidation. Results show that the balance …

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Statistically Guided Synthesis Of Mov-Based Mixed-Oxide Catalysts For Ethane Partial Oxidation, Juan D. Jimenez, Kathleen Mingle, Teeraya Bureerug, Cun Wen, Jochen A. Lauterbach Sep 2018

Statistically Guided Synthesis Of Mov-Based Mixed-Oxide Catalysts For Ethane Partial Oxidation, Juan D. Jimenez, Kathleen Mingle, Teeraya Bureerug, Cun Wen, Jochen A. Lauterbach

Faculty Publications

The catalytic performance of Mo8V2Nb1-based mixed-oxide catalysts for ethane partial oxidation is highly sensitive to the doping of elements with redox and acid functionality. Specifically, control over product distributions to ethylene and acetic acid can be afforded via the specific pairing of redox elements (Pd, Ni, Ti) and acid elements (K, Cs, Te) and the levels at which these elements are doped. The redox element, acid element, redox/acid ratio, and dopant/host ratio were investigated using a three-level, four-factor factorial screening design to establish relationships between catalyst composition, structure, and product distribution for ethane partial oxidation. Results show that the balance …

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Atomically Dispersed Pd On Nanodiamond/Graphene Hybrid For Selective Hydrogenation Of Acetylene, Fei Huang, Yuchen Deng, Yunlei Chen, Xiangbin Cai, Mia Peng, Zhimin Jia, Pengju Ren, Dequan Xiao, Xiaodong Wen, Ning Wang, Hongyang Liu, Ding Ma Sep 2018

Atomically Dispersed Pd On Nanodiamond/Graphene Hybrid For Selective Hydrogenation Of Acetylene, Fei Huang, Yuchen Deng, Yunlei Chen, Xiangbin Cai, Mia Peng, Zhimin Jia, Pengju Ren, Dequan Xiao, Xiaodong Wen, Ning Wang, Hongyang Liu, Ding Ma

Chemistry and Chemical Engineering Faculty Publications

An atomically dispersed palladium (Pd) catalyst supported onto a defective nanodiamond-graphene (ND@G) is reported here for selective hydrogenation of acetylene in the presence of abundant ethylene. The catalyst exhibits remarkable performance for the selective conversion of acetylene to ethylene: high conversion (100%), ethylene selectivity (90%), and good stability (i.e., steady for at least 30 hours). The unique struc-ture of the catalyst (i.e., atomically dispersion of Pd atoms on graphene through Pd-C bond anchoring) ensure the facile desorption of ethylene against the over-hydrogenation of ethylene to undesired ethane, which is the key for the outstanding selectivity of the catalyst.

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Assembling Of Niox/Mwcnts-Gc Anodic Nanocatalyst For Water Electrolysis Applications, Yaser M. Asal Mr., Islam M. Al-Akraa Dr, Saher D. Khamis Eng Sep 2018

Assembling Of Niox/Mwcnts-Gc Anodic Nanocatalyst For Water Electrolysis Applications, Yaser M. Asal Mr., Islam M. Al-Akraa Dr, Saher D. Khamis Eng

Chemical Engineering

Glassy carbon (GC) electrode is intended to be modified with nickel oxide (NiOx) and multiwalled carbon nanotubes (MWCNTs) in the anodic reaction of water electrolysis. NiOx deposition time is optimized and a 5 min was enough to attain the maximum activity. A further modification of the catalyst with MWCNTs could greatly enhance its stability during continuous electrolysis. As an outcome, an energy amount of 21.7 kWh/KgO2 is minimized. Several electrochemical and materials characterization setups will be utilized to test the catalyst activity and to know its geometry and structure.

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Shape-Based Separation Of Micro-/Nanoparticles In Liquid Phases, Behrouz Behdani, Saman Monjezi, Mason J. Carey, Curtis G. Weldon, Jie Zhang, Cheng Wang, Joontaek Park Sep 2018

Shape-Based Separation Of Micro-/Nanoparticles In Liquid Phases, Behrouz Behdani, Saman Monjezi, Mason J. Carey, Curtis G. Weldon, Jie Zhang, Cheng Wang, Joontaek Park

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The production of particles with shape-specific properties is reliant upon the separation of micro-/nanoparticles of particular shapes from particle mixtures of similar volumes. However, compared to a large number of size-based particle separation methods, shape-based separation methods have not been adequately explored. We review various up-to-date approaches to shape-based separation of rigid micro-/nanoparticles in liquid phases including size exclusion chromatography, field flow fractionation, deterministic lateral displacement, inertial focusing, electrophoresis, magnetophoresis, self-assembly precipitation, and centrifugation. We discuss separation mechanisms by classifying them as either changes in surface interactions or extensions of size-based separation. The latter includes geometric restrictions and shape-dependent transport …

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A Spatio-Temporal Model Reveals Self-Limiting Fcɛri Cross-Linking By Multivalent Antigens, Md Shahinuzzaman, Jawahar Khetan, Dipak Barua Sep 2018

A Spatio-Temporal Model Reveals Self-Limiting Fcɛri Cross-Linking By Multivalent Antigens, Md Shahinuzzaman, Jawahar Khetan, Dipak Barua

Chemical and Biochemical Engineering Faculty Research & Creative Works

Aggregation of cell surface receptor proteins by multivalent antigens is an essential early step for immune cell signalling. A number of experimental and modelling studies in the past have investigated multivalent ligand-mediated aggregation of IgE receptors (FcɛRI) in the plasma membrane of mast cells. However, understanding of the mechanisms of FcɛRI aggregation remains incomplete. Experimental reports indicate that FcɛRI forms relatively small and finite-sized clusters when stimulated by a multivalent ligand. By contrast, modelling studies have shown that receptor cross-linking by a trivalent ligand may lead to the formation of large receptor superaggregates that …

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Numerical Simulation Study On Miscible Eor Techniques For Improving Oil Recovery In Shale Oil Reservoirs, Dheiaa Alfarge, Mingzhen Wei, Baojun Bai Sep 2018

Numerical Simulation Study On Miscible Eor Techniques For Improving Oil Recovery In Shale Oil Reservoirs, Dheiaa Alfarge, Mingzhen Wei, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Shale formations in North America such as Bakken, Niobrara, and Eagle Ford have huge oil in place, 100—900 billion barrels of oil in Bakken only. However, the predicted primary recovery is still below 10%. Therefore, seeking for techniques to enhance oil recovery in these complex plays is inevitable. Although most of the previous studies in this area recommended that CO2 would be the best EOR technique to improve oil recovery in these formations, pilot tests showed that natural gases performance clearly exceeds CO2 performance in the field scale. In this paper, two different approaches have been integrated to …

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Arrhenius Rate Chemistry Informed Inter-Phase Source Terms (Arciist) For Macro-Scale Explosive Hydrocodes, Matthew J. Schwaab Sep 2018

Arrhenius Rate Chemistry Informed Inter-Phase Source Terms (Arciist) For Macro-Scale Explosive Hydrocodes, Matthew J. Schwaab

Theses and Dissertations

A critical factor in hydrocodes designed to simulate explosive material is defining the chemical reaction rate under various conditions. This rate determines how quickly the granular solid explosive is converted to its gaseous products. Currently, the state of the art for macro-scale hydrocodes is to use one of numerous burn models. These burn models are designed to estimate the bulk chemical reaction rate. Unfortunately, these burn rate models are largely based on empirical data and must be recalibrated for every new material being simulated. This research proposes that the use of Arrhenius Rate Chemistry Informed Interphase Source Terms (ARCIIST) in …

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An Initial Study Of The Catalytic Reforming Of Crop Oil‐Derived 1‐Alkenes With Hzsm‐5 To Aromatic Hydrocarbons, Shelby Amsley‐Benzie, Swapnil Fegade, Brian Tande, Alena Kubatova, Evguenii Kozliak, Wayne Seames Aug 2018

An Initial Study Of The Catalytic Reforming Of Crop Oil‐Derived 1‐Alkenes With Hzsm‐5 To Aromatic Hydrocarbons, Shelby Amsley‐Benzie, Swapnil Fegade, Brian Tande, Alena Kubatova, Evguenii Kozliak, Wayne Seames

Chemical Engineering Faculty Publications

This study explored the production of aromatic hydrocarbons from the longer‐chain alkenes produced by the pyrolysis/cracking of crop oils. 1‐Tetradecene, serving as a model compound for these alkenes, was reformed in a batch reactor with a HZSM‐5 catalyst to produce a liquid hydrocarbon mixture with a high‐aromatic content. These reactions resulted in a >99% conversion of the 1‐tetradecene feedstock with a yield of up to 22 wt% of aromatic hydrocarbons. Surprisingly, isomers of C3‐substituted benzenes along with xylenes and diaromatics (lower homologs of alkyl‐substituted indanes and naphthalenes) were the main aromatic products rather than their lower‐molecular‐weight (MW) homologs, benzene, toluene, …

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Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain Aug 2018

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …

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An Aqueous All-Metal Oxide Asymmetric Supercapacitor With High Gravimetric And Volumetric Energy Densities, Xin Jing, Xu Zhang, Wei Wang, Jun-Wei Lang Aug 2018

An Aqueous All-Metal Oxide Asymmetric Supercapacitor With High Gravimetric And Volumetric Energy Densities, Xin Jing, Xu Zhang, Wei Wang, Jun-Wei Lang

Journal of Electrochemistry

Only with both high gravimetric and high volumetric energy densities, can supercapacitors find more extensive applications.In this paper, by making good use of the interesting nanostructures and the high packing densities of RuO2 (nanoshpheres,1.69 g·cm-3) and Co-Ni oxide (nanoflakes, 2.14 g·cm-3), the RuO2//KOH//Co-Ni oxide all-metal oxide asymmetric supercapacitors with high performance were successfully fabricated, which led to the maximum specific capacitance of 217.5 F·g-1 (412.3 F·cm-3) and specific energy density of 61.8 Wh·kg-1 (121 Wh·L-1) in a cell voltage between 0 and 1.5 V in KOH electrolyte. …

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Electrochemical Performances Of Neodymium Doped Lead Dioxide Composite Anode, Hong-Hui Wang, Ming-Jie Ma, Jie Feng, Huang-Ya Kang, Wen-Jie Huang Aug 2018

Electrochemical Performances Of Neodymium Doped Lead Dioxide Composite Anode, Hong-Hui Wang, Ming-Jie Ma, Jie Feng, Huang-Ya Kang, Wen-Jie Huang

Journal of Electrochemistry

Neodymium (Nd) doped titanium (Ti)-based lead dioxide (PbO2) composite anode was prepared by electrodeposition. The surface morphologies and crystal structures of the as-prepared anodes were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) technique, respectively. The electrochemical performances of PbO2-Nd anode were studied by electrochemical impedance spectroscopy, linear sweep voltammetry and cyclic voltammetry. Additionally, the electrocatalytic activity and durability of PbO2-Nd anode were investigated through the degradation of simulative refractory organic wastewater of phenol. The results showed that Nd doping made the PbO2 anode surface structure dense and uniform with smaller …

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